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    2012 Che211 hw6

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    feliasfranses
    This document outlines homework problems for a chemistry class. 1. Determine the compressibility factor of water vapor at 250°C and 20 atm using correlations from the textbook. Show water's isotherm from low to high pressures at 250°C in a table and plot. 2. Calculate the enthalpy change of the chemical reaction CH4 + 2O2 → CO2 + 2H2O at 400K using two approximation methods. 3. Calculate the adiabatic reaction temperature of methane combustion using pure O2 and using air with 4 moles N2 per mole O2, using the same two approximation methods.

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    2012 Che211 hw6

    Uploaded by

    feliasfranses
    12 views1 page
    This document outlines homework problems for a chemistry class. 1. Determine the compressibility factor of water vapor at 250°C and 20 atm using correlations from the textbook. Show water's isotherm from low to high pressures at 250°C in a table and plot. 2. Calculate the enthalpy change of the chemical reaction CH4 + 2O2 → CO2 + 2H2O at 400K using two approximation methods. 3. Calculate the adiabatic reaction temperature of methane combustion using pure O2 and using air with 4 moles N2 per mole O2, using the same two approximation methods.

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    This document outlines homework problems for a chemistry class. 1. Determine the compressibility factor of water vapor at 250°C and 20 atm using correlations from the textbook. Show water's isotherm from low to high pressures at 250°C in a table and plot. 2. Calculate the enthalpy change of the chemical reaction CH4 + 2O2 → CO2 + 2H2O at 400K using two approximation methods. 3. Calculate the adiabatic reaction temperature of methane combustion using pure O2 and using air with 4 moles N2 per mole O2, using the same two approximation methods.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    12 views1 page

    2012 Che211 hw6

    Uploaded by

    feliasfranses
    This document outlines homework problems for a chemistry class. 1. Determine the compressibility factor of water vapor at 250°C and 20 atm using correlations from the textbook. Show water's isotherm from low to high pressures at 250°C in a table and plot. 2. Calculate the enthalpy change of the chemical reaction CH4 + 2O2 → CO2 + 2H2O at 400K using two approximation methods. 3. Calculate the adiabatic reaction temperature of methane combustion using pure O2 and using air with 4 moles N2 per mole O2, using the same two approximation methods.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    of 1

    CHE 211 SPRING 2012 HW #6 Due: February 24, 2012

    1. (30 Points). (a) (15 Points). Using a generalized correlation from the book SVA, determine the compressibility factor Z of water vapor at 250C and 20 atm. (b) (5 Points). How accurate is the value of part (a)?

    (c) (10 Points). Show the isotherm of water at 250C, from low pressures to very high pressures (beyond condensation if applicable), using data from tables in your book; report the data in table form, and in a plot. 2. (20 Points). Calculate the enthalpy change H(J/mol) of the following chemical gas-phase reaction at T = 400K.

    NOTE :

    CH 4 2O 2 CO 2 2H 2 O. (1) Use constant heat capacities first (the values at 298K), for a first approximation. For a second approximation, use only the terms with A and B in the heat capacities Cp(T).
    For the above reaction (1).

    3.

    (50 Points)

    (a) (25 Points). Calculate the adiabatic reaction temperature when pure O2 is used. (b) (25 Points). Calculate the adiabatic reaction temperature when air is used, with 4 moles of N2 per mole of O2. NOTE : In both cases assume complete combustion of CH4. In both cases, use constant heat capacities first (the values at 298K), for a first approximation. For a second approximation, use only the terms with A and B in the heat capacities Cp(T).

    2/2012 EIF

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