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2012 Che211 hw11

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CHE 211 SPRING 2012 HW #11 (100 Points) Due: April 6, 2012

1. (30 Points).

At 25C, the Henrys Law constant for CO 2 in water is 1670 bar. What is the solubility of CO 2 in water at p = 3 bar? For solubility units, use g of CO 2 per kg of water. A solute S partitions between a water and an oil phase immiscible with water. The Nernst partition coefficient is
k C of S in oil 10. C of S in water

2. (20 Points).

The units of C are in mol/. If you initially have 1 liter of water at a concentration C0 5mM , and you use 2 liters of oil, what is the concentration of S in oil at equilibrium? 3. (50 Points). For the gas-phase reaction
CH 4 H 2 O CO 3H 2

the equilibrium constant at T is k(T) = 6 The pressure is 1 atm.

(a) (20 Points).

If initially you have 1 mol of CH 4 and 1 mol of H 2O , calculate the yield in H 2 , i.e. how many moles of H 2 will be produced at equilibrium? If initially you have 1 mol of CH 4 , 1 mol of H 2O , and 1 mol of N 2 (an inert gas), calculate the yield in H 2 .

(b) (30 Points).

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