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Urea Formaldehyde

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Approximately 1 million metric tons of urea-formaldehyde resin are produced annually.

More than 70% of this urea-formaldehyde resin is used by the forest products industry for a variety of purposes. Urea-formaldehyde resins are the most prominent examples of the class of thermosetting resins usually referred to as amino resins. Ureaformaldehyde resins comprise about 80% of the amino resins produced worldwide.
CHEMISTRY OF UREA-FORMALDEHYDE RESIN FORMATION

The synthesis of a urea-formaldehyde resin takes place in two stages. In the first stage, urea is hydroxymethylolated by the addition of formaldehyde to the amino groups . This reaction is in reality a series of reactions that lead to the formation of mono-, di-, and trimethylolureas. The addition of formaldehyde to urea takes place over the entire pH range . The reaction rate is dependent on the pH. The second stage of urea-formaldehyde resin synthesis consists of the condensation of the methylolureas to low molecular weight polymers. The rate at which these condensation reactions occur is very dependent on the pH and, for all practical purposes, occurs only at acidic pHs. Applications 1. Amino resins are often used to modify the properties of other materials. These resins are added during the processing of such products as (i) textile fabrics to impart permanent press characteristics; (ii) automobile tires to improve the bonding of rubber to tire cord; (iii) paper to improve the tear strength, especially of wet paper; (iv) and alkyds and acrylics to improve their cure. 2. Amino resins are also used for molding products, such as electrical devices, jar caps, buttons, and dinnerware, and in the production of countertops.

3. The resin is used in the production of an adhesive for bonding particleboard Advantages The use of urea-formaldehyde resins as a major adhesive by the forest products industry is due to a number of advantages, including low cost, ease of use under a wide variety of curing conditions, low cure temperatures, water solubility, resistance to microorganisms and to abrasion, hardness, excellent thermal properties, and lack of color, especially of the cured resin. Disadvantages The major disadvantage associated with ureaformaldehyde adhesives as compared with other thermosetting wood adhesives, such as phenolformaldehyde and polymeric diisocyanates, is the lack of resistance to moist conditions.

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