4 Diesel Combustion and Emission
4 Diesel Combustion and Emission
4 Diesel Combustion and Emission
Domain Training on
Aftertreatment Strategies
Catalyzed Diesel Particulate Filter (DPF) Diesel Oxidation Catalyst (DOC) Selective Catalytic Reduction (SCR) NOx adsorbers
One scenario is the use of SCR aftertreatment for NOx reduction and in-cylinder combustion for PM control together with some particulate aftertreatment.
The other scenario is to use combustion optimization and cooled EGR for NOx reduction along with a catalyzed Diesel Particulate Filter (DPF) for PM control. Key engine systems such as VGT, HPCR and electronics are critical components.
50%
25% 10% 0%
WF
0.10
0.15
Steady-state test characterizes emissions at eight (8) isolated points typical of engine operation. Emissions are measured under a hot-stabilized engine condition
SPEED
Transient test operation (NRTC cycle) captures emissions across a broad range of engine speed and load combinations attained during actual-use conditions. The procedure requires measurement of both cold-start and hot-start emissions over the transient duty cycle.
NRTC cycle
Deterioration Factor !!
The term deterioration refers to the degradation of an engines exhaust emissions performance over its lifetime due to normal use or misuse (i.e., tampering or neglect). Engine deterioration increases exhaust emissions, usually leads to a loss of combustion efficiency, and can in some cases increase non-exhaust emissions. The amount of emissions increase depends on an engines design, production quality, and technology type. Other factors, such as the various equipment applications in which an engine is used, usage patterns, and how it is stored and maintained, may also affect deterioration.
The term deterioration rate refers to the degree to which an engines emissions increase per unit of activity.
Nonroad engine activity is expressed in terms of hours of use or fraction of median life. The term deterioration factor refers to the ratio of an engines emissions at its median life divided by its emissions when new. Useful life is a regulatory term used to indicate the amount of time during the life of a nonroad engine that a manufacturer must certify to the statutory authority that the engine meets a required emission standard as defined by a regulation. Median life refers to the age at which 50 percent of the engines sold in a given year have ceased to function and have been scrapped.
Other factors emission & FE Factors, other than engine technology, influencing emission & fuel economy
Periodic phasing out of older vehicles Infrastructure development Improved roads / express highways / ring roads etc Removal / reduction of traffic congestions inside city Synchronization of traffic signals to have least stoppages at signals Fuel quality improvement
16,000,000
All engines
14,000,000 12,000,000 10,000,000 8,000,000 6,000,000 4,000,000 2,000,000 0
1980 1982 1984 1986 1988 1990 1992 1994 1996 1998 2000 2002
Turbocharged
Naturally Aspirated
Year
Governing Factors
Economy improvements:
reduced fuel consumption reduced oil consumption increased filter change period increased oil drain interval increased life, wear & durability
Emission regulation :
continuously getting more stringent controlled fuel quality reduced oil consumption engine design technology development
Legislation
mixture preparation
(physical properties of fuel)
Ignition
combustion
(Chemical properties of fuel) (chemical properties of fuel)
Conflicting Demands
Combustion trend
MAIN CHAMBER
Glow plug
Glow plugs is essentially used in diesel engines equipped with a pre-combustion chamber ( IDI diesel engines ) and may be used in direct injection ( DI ) diesel engines to aid starting. A glow plug is a heating element that uses 12 volts from the battery and aids in the starting of a cold engine. As the temperature of the glow plug increases, the resistance of the heating element inside increases, thereby reducing the current in amperes needed by the glow plugs. Glow plugs are used to help start a cold diesel engine and help prevent excessive white smoke during warm-up.
DI
(1) (2) (3) NOx CO HC
IDI
(4)
(5)
PM
Smoke : Full load Part load
(6)
Fuel Consumption
Direct injection (DI) diesel engine Direct injection ( DI ) engines have two design philosophies: High-swirl design
which have a deep bowl in the piston, a low number of holes in the injector and moderate injection pressures.
Phases of DI combustion
Ignition occurs in a diesel engine by injecting fuel into the air charge, which has been heated by compression to a temperature greater than the ignition point of the fuel or about 1,000F (538C). There are three distinct phases or parts to the combustion in a diesel engine : Ignition delay Rapid combustion Controlled combustion
Delay period
Atomisation of fuel into small droplets Evaporation Mixing with air Reaching auto-ignition temperature
Pre-mixed combustion
Fuel injected in delay period burns abruptly raising temperature and pressure at a high rate. Combustion depends upon rate of injection i.e. quantity of fuel injected.
Diffusion combustion
In this phase fuel burns, as it is injected, in the presence of mixture of unused air and products of combustion of previous cycles. Combustion depends upon quality of airfuel mixing.
Tail burning
1
3
RoHR
Deg CA
Swirl vs emissions
NOx
HC
BSFC
smoke X
Swirl
2X
Engine
Visible emission
Smoke
Invisible emission
NOx ( NO, NO2, N2O, etc ) CO HC Particulates (PM )
Liquid fuel
Close to the nozzle tip
Vapour
Surrounding the liquid core
SWIRL
Start of ignition HIGH PRESSURE INJECTION + LOW AIR SWIRL HIGH AIR SWIRL + LOW PRESSURE INJECTION
SWIRL
Start of combustion
Smaller nozzle hole sizes with larger number of holes More centrally positioned injector Larger bowl dia More intense swirl Higher mean injection pressures
Open Bowl
BOWL SWIRL
Compressi on stroke
Expansio n stroke
TD C
deg CA
swirl
Smoke
The general condition of diesel engine can be determined by type of smoke it emits.
Smoke is generally considered as The
pulse of the
Smoke formation depends on the density in the centre of fuel spray and entrainment of air into it. If adequet oxygen is made available at the centre of fuel spray, smoke formation reduces.
Smoke
During later part of combustion (diffusion combustion), if air swirl assists to swipe products of combustion around the injected fuel spray by fresh air, smoke formation reduces.
Black Smoke Black smoke is formed due to insufficient oxygen availability, poor air fuel mixing and over fuelling.
Black smoke denotes improper combustion due to : Less Air : Chocked / wrong air cleaner More Fuel : Defective fuel injection equipment
Excess Back pressure : Chocked exhaust system or wrong size exhaust pipe
Overloading: Wrong loading / incorrect application.
Blue Smoke
Blue smoke denotes burning of oil in the combustion chamber due to : 1. 2. 3. 4. 5. Excess oil in oil bath type air cleaner Excess oil in the sump Excess lub. oil pressure Worn piston rings or liners. Worn valve stem or valve guides.
white Smoke
This is caused by presence of water in the combustion chamber due to : Cracked cylinder head Cracked or damaged liner Water in diesel Burnt / Damaged cylinder head gasket Cold start
Soot formation R a t e
Soot in exhaust
20
TDC
Maximum useful number of spray holes for best distribution of fuel in combustion chamber
Intake swirl level optimisation. Swirl variability.
HC Control measures
Optimised combustion chamber shape & volume Increased compression ratio Reduced quench area Reduced dead volumes Optimum spray hitting plane Low sac / zero sac nozzles VCO nozzles Optimum injection timing Rapid needle closing no dribble No secondary or after injection High injection pressure atomisation Ring pack optimisation Oil consumption control
Formation of Carbon Monoxide (CO) Carbon monoxide is formed due to in-homogenity of fuel distribution with fuel-rich mixture. This is an intermediate product in the combustion of hydro-carbon fuels.
CO is formed when Oxygen is not available in adequate quantity Cycle temperatures are low CO will be oxidised into CO2 at higher cycle temperatures when oxygen is available adequately.
Generally, CO emission is significant at full loads, close to smoke limits, as the air availability reduces.
As the diesel engine operates with excess air, CO emissions are comparatively lower.
CO control measures
Combustion chamber optimisation
High air-fuel ratio high excess air Turbocharging Multi-valve configuration Swirl optimisation
Controlled wall wetting Optimum injection duration reduce late burning Higher compression ratio
Formation of NOx Emission Diesel engine works with excess air Diesel engine works with higher compression ratio. Thus higher combustion pressures and temperatures are characteristic of diesel engine combustion.
According to EPA definition, all components excluding water collected on a prescribed filter after dilution with air at a temperature below 51.7 deg C are called Particulate Matter.
incomplete combustion of lubricating oil past through piston and piston ring passages and valve guide clearance owing to inadequate air and temperatures cause SOF fraction of particulates originating from lub. oil. c) Sulfates due to sulphur content in diesel
Particulates
Carbon Fuel
sulfates
Lub oil
Fuel composition
Mixture formation Injection pressure Bowl shape Intake swirl Nozzle design
Oil consumption O/C control design Oil leaks Lub oil formulation
Sulphur content
Sources of PM Emissions
Excessive black smoke Inadequate a/f ratio Poor combustion Acceleration / turbolag Partial fuel evaporation during cold Partial combustion of fuel due to misfire
White smoke
HC emission sources
Fuel quality
Sources of PM Emissions
SOURCE Carbon Fuel Mixture Formation
Injection pressure Bowl shape Intake swirl Nozzle design
Lub oil
Oil consumption
Oil consumption design parameters Oil leaks into combustion chamber Lub oil formulation
Sulphates
Fuel composition
Constituent of PM (typical)
OriginFUEL
66%
Insoluble
5%
SOF lub
Origin LUBRICANT
10 %
29%
34%
NOx / PM Trade-off
NOx / PM Trade-off
critical diesel tuning
PM NOx
lean
Fuel/air ratio
Low NOx/PM combustion region Low
Flame temp
high
HG nozzle
25% HG nozzle
NOx
Cold EGR
SOOT
SOOT
NOx
NOx
Pumping rate
Pumping rate NOx
Injection parameters
noise
Needle lift
NOx PM
Time or deg CA
Injection pressure Injection rate shaping Orifice size Orifice shape Multiple injections
NOx
SoI
DoI(a)
DoI(b)
EoI(a)
EoI(b)
SOOT
Start of injection CONSTANT
dP/d
EGR
Smoother burning
Effect of EGR
Replacement of air by inert combustion products Exhaust gas has higher specific heat than air Reduce in-cylinder oxygen content Reduced temperature in the combustion chamber
NOx reduces, PM increases
EGR
Types of EGR
Internal EGR External EGR Hot EGR Cooled EGR Partially cooled EGR Choice for EGR systems High pressure EGR Internal or External EGR Low pressure EGR Cooled or un-cooled EGR High pressure or low pressure EGR
Internal EGR
Using a cooled EGR system raises the density of the intake air so the amount of air entering the combustion chamber increases. This helps to make combustion more complete, thereby reducing the generation of PM.
In the EGR system equipped with the check valve, it prevents new air from entering the EGR gas pipe as well as a back-flow of gas. Also, the check valve increases the EGR recirculation amount by ensuring the gas flows in one direction.
Cooled EGR
Cooled Exhaust Gas Recirculation (EGR) technology is very effective at controlling NOx.
The EGR system takes a measured quantity of exhaust gas and passes it through a cooler before mixing it with the incoming air charge to the cylinder.
The EGR adds heat capacity and reduces oxygen concentration in the combustion chamber by diluting the incoming ambient air with cool exhaust gas. During combustion, the lower oxygen content has the effect of reducing flame temperatures, which in turn reduces NOx, since NOx production is exponentially proportional to flame temperature. This allows the engine to be tuned for the best fuel economy and performance at low NOx levels. In EGR engines, exhaust gasses are cooled by engine coolant which raises the cooling system requirement.
Intercooler
PM Trap
50
Intercooler
Air Filter
49
SMOKE
NOx
HC
EGR (%)
50
PM Control Strategy
Reduction of insolubles
Reduction of SOF
Soot Air swirl Combustion chamber shape Injection Timing & rate
low toxicity
volatility
viscosity density
flash point fire point
Cetane number
aromatic content sulfur content
Parameter Change
Influence
Cetane no Density
Viscosity
Aromatic content Sulfur content
CO, HC, NOx BSFC Smoke, power HC,CO,PM Smoke Cetane no PM , SO2
injection
evaporation
Precombustion
Start of combustion
End of combustion
density
cetane no volatility
viscosity
Lack of Oxygen
NOx Formation:
Excess Air
HC Formation: