Diesel Car Emissions
Diesel Car Emissions
Diesel Car Emissions
1. INTRODUCTION
Selection of on engine combustion technology & after treatment devices is an important
decision. It is not only important to meet the emission legislation requirements but it is also
important to consider the parameters like packaging within existing space of an automobile.
Effectiveness of emission reduction in terms of UBHC/CO/NO X/PM. Effect on back pressure
& fuel economy, size & cost of the after treatment device, maintenance & serviceability
aspect of the after treatment device.
To optimise the car in order to meet the Bharat Stage VI norms, vehicle has to be optimised
in areas such as Engine, transmission, fuel injection system, after treatment system, all types
of electronic controls, rolling resistance, gross vehicle weight. Car is made to run on the
rolling Chassis Dynamometer for 1220 seconds on Indian Driving Cycle & exhaust gas
sampling is done by the exhaust gas anlalyser which are highly accurate.
2.1 Emission measurement method & equipment
Car driver will follow the Indian driving cycle & vehicle will run into various speeds in
different gears as per the cycle. Gas analyser will collect the samples of the exhaust gas.
Rolling resistance will be applied to the vehicle with the help of the dyanamometer. Fan
speed gets changed as per the speed of the vehicle to simulate real life condition. Humidity &
temperature are maintained. Following instruments are used to major the pollutants.
Carbon Monoxide (CO) will be measured by Non Dispersive Infra Red analyser. Carbon
Dioxide (CO2) measurement is done by Non Dispersive Infra Red analyser.
Chemiluminiscent detector measures Nitrogen Oxides (Nox). Flame ionisation detector
measures Hydrocarbons (HC). Particulate Matter (PM) measurement is done by PTFE (Poly
tetra fluro Ethylene) filter paper method.
HC gets produced due to too rich Mixture, too lean Mixture operating temperatures below
Ignition, poor atomization- Large Fuel Droplet Size, higher Crevice volumes.
HC can be controlled by increasing compression ratio, reduced quench area, reduced dead
volumes, optimum injection timing, rapid needle closing – no dribble, no secondary or after
injection ,high injection pressure, ring pack optimisation & oil consumption control.
CO formation is mainly due to incomplete combustion of carbon containing fuels, inadequate
oxygen availability and low cycle temperature.
CO can be controlled by Combustion chamber optimisation, high air-fuel ratio – high excess
air, turbocharging, multi-valve configuration, swirl optimisation, controlled wall wetting ,
optimum injection duration, reduce late burning Higher compression ratio, higher cylinder
temperatures.
Nox formation is mainly due to high temperature in combustion chamber i.e more than 1300
° C, excess air. Nitrogen Oxides (NOx) is a representation of mono Nitrogen oxides &
resultants are different Nitrogen Oxides.
N2 + O → NO + N
N + O2 → NO + O
N + OH → NO + H
NOx control is done by retardation of injection start, low swirl, Catalytic reduction,
Water/Steam injection, Lowering excess air operation , Staged combustion, Lowering pre-
heat air temperature, Exhaust gas recirculation (EGR),Selective Catalytic Reduction
(SCR),Selective Non Catalytic Reduction (SNCR),Lean NOx trap(LNT).
All components, excluding water, collected on a prescribed filter after dilution with air at a
temperature below 51.7 deg C, are called Particulate Matter (PM). Most have a fine particle
size distribution (<2.5μm) however ultra-fine (<0.1 μm) particles are also present. Most
important constituents are larger molecular Polycyclic Aromatic Hydrocarbons (PAHs) and
nitro-PAH compounds. Inadequate air – high soot, poor combustion. Sulphur in fuel
Aromatics are causes of PM formation.
PM is controlled by soot control, high injection pressures, combustion improvement and swirl
optimization & Sulphur control in fuel.
Soot is a mass of impure carbon particles resulting from the incomplete combustion of
hydrocarbons i.e Carbon & Ash, Soot is formed due to high Temperature, inadequate air –
high soot, lack of Oxygen. Soot is controlled by reduced wall wetting, good atomization,
enhanced mixing by re-entrant bowl shape & distribution of fuel in combustion chamber,
Intake swirl optimization further brings down the soot percentage.
Trade-off between HC, NOx & PM is very important while meeting emission norms for any
car.
The amount of EGR mixing puts limits on engine power. More than 30% mixing of EGR is
not advisable as it brings down maximum engine power. Figure 2 shows that with increase in
percentage of EGR, HC emissions goes up & NOx levels comes down.
Figure 4 shows general trade-off between NOx & PM. PM trap is often used to bring down
the Particulate Matter values. Fuel injection timing needs to be retarded to bring down the
peak combustion temperatures. It adversely affects the maximum power & specific fuel
consumption (SFC). Higher swirl ratio is recommended for EGR engine for proper mixing of
air & exhaust gas. Piston bowl design can be modified for proper mixing & combustion.
Diesel Oxycat is required to bring down HC & CO values. Precious metals like
Platinum/Palladium/Rhodium works as catalyst in Oxycat & performs the oxidation. With
increase in % of EGR, PM emissions goes up. & hence trade-off is required.
In common rail fuel system, fuel is extracted from tank & after filtration, fuel is pressured to
very high pressures such as 1400-1800 bars & pressure is maintained with the help of
common rail. Fuel is injected into combustion chamber as per the command from electronic
control unit (ECU).
Use of crank speed sensor, rail pressure sensor, accelerator pedal sensor, coolant temperature
sensor, oil pressure sensor, delta pressure sensor ,temperature & manifold pressure sensor,
exhaust manifold pressure sensor, water in fuel sensor, metering valve are typical name of
electronic controls used to control the emissions.
High level accuracy in terms of fuel injection, data monitoring & control, quick close loop
feedback system is possible with the help of electronic controls. Transmission control unit is
also required for better synchronization between engine, transmission & vehicle.
5. EMISSION CONTROL BY EGR & AFTER TREATMENT
Some portion of exhaust gas is recirculated from exhaust manifold to EGR cooler. The
percentage of the EGR is being decided based on the calibration strategy (for part load & full
load operating conditions) to meet the required emission norms.
The EGR cooler brings down the temperature of exhaust gas by exchanging the heat with
engine coolant. The EGR control valve regulates the amount of exhaust gas going to engine
based on the calibration strategy. Exhaust gas is mixed with intake air before going to
combustion chamber. Mixing of exhaust gas limits the fresh oxygen in the charge & hence
reduces the combustion temperature. Reduced combustion chamber brings down NOx levels.
To accomodate EGR cooler & EGR valve, exhaust manifold requires modification. Addition
of air & intake mixing device, temparature & pressure sensor, EGR mass flow sensor ,coolant
in & out pipe lines for EGR cooler needs to be done. Engine cooling system needs to be
modified. Radiator on vehicle needs to be redesigned to serve more heat rejection as 20-30%
more coolant gets circulated through EGR cooler w.r.t non EGR engine. Cylinder head &
block requires modification to meet additional coolant flow requirements. Piston design
change, addition of Particulate Matter trap, Diesel Oxycat may require in addition to EGR
system to meet overall emission requirements of HC, NOx, CO & PM for BSVI norms.
Selective Catalytic Reduction (SCR) is one more popular technique to bring down the
emissions levels of NOx. SCR can be used in addition with EGR. NOx limits of BS VI
emission norms can be met if these two techniques used at a time on car.
Diesel Oxidation Catalyst, SCR catalyst, Urea injection system, Urea tank & Dosing unit
addition, plumbing for Urea injection, mixer arrangement, inlet & outlet NOx sensor gets
added in exhaust system if SCR path is followed.
Reaction shown helps for complete oxidation of the exhaust gases & creates C02, H20 & N2
which helps to meet Bharat Stage VI emission norms.
7. METHODOLOGY
Following is the generic method to meet BS VI emissions
8. CONCLUSIONS
Use & combination of on engine & after treatment emission control techniques decides the
‘Strategy’
Every vehicle manufacture (OEM) decides its own strategy depends up on many
parmameters such as cost, packaging space, other performance parameters like fuel economy,
transient performance, acceleration, gradeability
Reliability, consistency in meeting emission norms on mass production vehicles, time lines
makes the emission compliance more challenging
Most of the car manufactures are geared up & working on product modifications to meet for
BSVI norms compliance.