Ferromagnetism arises due to quantum mechanical exchange forces between electron spins. The original mechanism of exchange interaction, proposed by Heisenberg in 1928, describes how electrostatic forces between electrons on the same atom couple their spin states. This coupling energy between electron spins is equivalent to an interaction that can give rise to ferromagnetism. The alignment of these tiny electron dipoles within atoms produces large internal magnetic fields characteristic of ferromagnetic materials.
Ferromagnetism arises due to quantum mechanical exchange forces between electron spins. The original mechanism of exchange interaction, proposed by Heisenberg in 1928, describes how electrostatic forces between electrons on the same atom couple their spin states. This coupling energy between electron spins is equivalent to an interaction that can give rise to ferromagnetism. The alignment of these tiny electron dipoles within atoms produces large internal magnetic fields characteristic of ferromagnetic materials.
Ferromagnetism arises due to quantum mechanical exchange forces between electron spins. The original mechanism of exchange interaction, proposed by Heisenberg in 1928, describes how electrostatic forces between electrons on the same atom couple their spin states. This coupling energy between electron spins is equivalent to an interaction that can give rise to ferromagnetism. The alignment of these tiny electron dipoles within atoms produces large internal magnetic fields characteristic of ferromagnetic materials.
Ferromagnetism arises due to quantum mechanical exchange forces between electron spins. The original mechanism of exchange interaction, proposed by Heisenberg in 1928, describes how electrostatic forces between electrons on the same atom couple their spin states. This coupling energy between electron spins is equivalent to an interaction that can give rise to ferromagnetism. The alignment of these tiny electron dipoles within atoms produces large internal magnetic fields characteristic of ferromagnetic materials.
responsible for the phenomenon of Ferromagnetism. Ferromagnetism arises due to quantum mechanical exchange forces. The mechanism of exchange interaction, as originally proposed by Heisenberg in 1928, is one in which the forces involved are electrostatic in origin, but which, because of the constraints imposed by Pauli Exclusion Principle, are formally equivalent to a very large coupling between the electron spins. Consider two electrons with two spin states (up and down) each on different orbitals on the same atom. Their spins can couple to form three triplet and one singlet state. The triplet states are symmetrical with respect to the interchange of the two electrons whereas the singlet state is anti-symmetrical. Since only states whose overall symmetry is anti-symmetrical are allowed in nature (due to the Pauli Exclusion Principle), the spin triplet states can only be combined with the orbital
symmetric state, and the singlet spin state with
the orbital symmetric state. Although simple product of two electron (orbital) states has the same energy if the electrons are interchanged (one electron being considered exactly the same as the other electron), the symmetric or anti symmetric combinations formed from these products no longer have the same energy, because the symmetrical solution allows the wave function to have a large amplitude if the two electrons are at the same point, while the anti-symmetrical wave function then vanishes. Thus electrostatic repulsive energy between the two electrons is larger in the first case than in the second. Because of the association of orbital and spin states mentioned above, the energy difference between orbital states of different symmetry gets associated with an energy difference between the spin-singlet and the spintriplet situations. This is tantamount to introduction of a coupling energy between the electron spins which is of the right form and magnitude to give rise to Ferromagnetism.
The electron itself being a spinning charged
body acts like a spinning dipole (magnet). These tiny internal spinning dipoles can interact and get aligned to produce very large internal magnetic fields which are usually found in Ferromagnets. The original Heisenberg model, with the spins localized on the same atom, is a good approximation in an ionic solid. For Ni, Co or Fe, which are metals, an improved model, in which the conduction electrons serve as a medium through which an interaction is transmitted between spins (which are localized), is used. (Ref: Electricity and Magnetism, Bleaney and Bleaney, Oxford,1966, pp 650-1)