MT Test 1 QP
MT Test 1 QP
MT Test 1 QP
Name:
Reg.
No.
.
MONSOON SEMESTER 2015
Test I
Duration: 1 hour
[2]
dy
[3]
6. Oxygen (A) is diffusing through non diffusing gas which is a mixture of methane (B) and
hydrogen (C) in the volume ratio 2:1 under steady-state conditions. The total pressure is
1l05 N/m2, and the temperature is 0C. The partial pressure of oxygen at two planes 2.0 mm
apart is 13,000 and 6,500 N /m2 respectively. Calculate the rate of diffusion of oxygen in
5
2
5
2
kmol/m2s if the diffusivities are estimated to be D0 H 6.99 10 m / s , D0 CH 1.86 10 m / s .
[3]
2
2 NH 3 N 2 3H 2
At one place in the apparatus, where the pressure is 1 std atm abs and the temperature 200C,
the analysis of the bulk gas is 33.33% NH 3 (A), 16.67% N2 (B), and 50.00% H2 (C) by
volume. The circumstances are such that NH3 diffuses from the bulk-gas stream to the
catalyst surface, and the products of the reaction diffuse back, as if by molecular diffusion
through a gas film in laminar flow 1 mm thick. Estimate the local rate of cracking. kg NH)/
(m2 catalyst surface .s), which might be considered to occur if the reaction is diffusioncontrolled (chemical reaction rate very rapid) with the concentration of NH 3 at the catalyst
surface equal to zero.
[3]
8. In an attempt to measure the diffusivity of ammonia in nitrogen by the twin-bulb method, a
student filled the two bulbs (each of volume 5 litre and connected by a tube 8 cm long and 3
cm in diameter) with mixtures of the gases. The initial partial pressures of NH 3 in the bulb
Test I Examination
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were 0.725 and 0.275 atm. At the end of 5.7 hours, he took samples of the gases from the
bulbs. The analysis of the samples showed that the mole fractions of ammonia in the bulbs
were maintained at 1 atm and the temperature was30C. Calculate the diffusivity of NH3 in
the mixture from these data.
[3]
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Test I Examination
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