Coordination
Coordination
Coordination Compounds
1.
2.
[Cr(H2O)6]Cl3 (atomic number of Cr = 24) has a magnetic moment of 3.83 B.M. The correct distribution of 3d
electrons in the chromium present in the complex is
1
(a) 3d xy , 3d yz , 3d zx
(b) 3d xy , 3d yz , 3d z 2
(c)
(d)
3.
How many EDTA molecules are required to make an octahedral complex with a Ca2+ ion?
(a) Six
(b) Three
(c) One
(d) Two
4.
5.
The complex ion which has no d electrons in the central metal atom is (At No. Cr = 24, Mn = 25, Fe = 26, Co =
27)
(a) [MnO4]
(b) [Co(NH3)6]3+
(c) [Fe(CN)6]3
(d) [Cr(H2O)6]3+
6.
Which of the following forms with an excess of CN , a complex having coordination number two?
(a) Cu2+
(b) Ag+
(c) Ni2+
(d) Fe2+
7.
8.
9.
(c) [Co(en)2Cl2]Cl
(d) [Co(en)(NH3)2Cl2]Cl
Cl
Cl
Pt
Cl
10.
CH2
Cl
Cl
Cl
(b)
2-
(c)
Pt
Cl
Cl
Cl
H 3N
H 3N
Pt
(d)
Pt
Cl
Cl
H3N
Cl
NH3
(d) [Ni(NH3)6]2+
11.
12.
In which of the following coordination entities, the magnitude of 0 [CFSE in octahedral field] will be maximum?
(a) [Co(CN)6]3
(b) [Co(C2O4)3]3
(c) [Co(H2O)6]3+
(d) [Co(NH3)6]3+
13.
(d) 0 and 4
(d) 2
14.
15.
(c) 5.92
Geometry, hybridization and magnetic moment of the ions [Ni(CN)4]2, [MnBr4]2 and [FeF6]2 respectively are
(a) tetrahedral, square planar, octahedral : sp3, dsp2, sp3d2 : 5.9, 0, 4.9
(b) tetrahedral, square planar, octahedral : dsp2, sp3, sp3d2 : 0, 5.9, 4.9
(c) square planar, tetrahedral, octahedral : dsp2, sp3, d2sp3 : 5.9, 4.9, 0
(d) square planar, tetrahedral, octahedral : dsp2, sp3, sp3d2 : 0, 5.9, 4.9
WORKSHEET
Coordination Compounds
16.
In the complex with formula MCl3.4H2O, the coordination number of the metal M is six and there is no molecule
of hydration in it. The volume of 0.1 M AgNO3 solution needed to precipitate the free chloride ions in 200 mL of
0.01 M solution of the complex is
(a) 40 mL
(b) 20 mL
(c) 60 mL
(d) 80 mL
17.
18.
19.
(b) [Ni(CN)4]2
(d) [Fe(CN)6]4
Para magnetic
Diamagnetic
20.
21.
22.
23.
Which of the following statements is not true about the complex ion [CrCl2(en)2]+
(a) It has two geometrical isomers cis and trans
(b) Both the cis and trans isomers display optical activity
(c) Only the cis isomer displays optical activity
(d) Only the cis isomer has non-superimpossible mirror image
24.
Which one of the following species does not represent cationic species of vanadium formed in aqueous solution
(a)
25.
26.
VO +2
(b) VO2+
(c) [V(H2O)6]3+
(d)
VO2+
2
(d) [CoBr(NH3)5]SO4
(d) [Ag(NH3)3]Br
27.
In the formula of brown ring complex [Fe(H2O)5(NO)]SO4, the magnetic moment is 3.87 B.M. The oxidation state
of Fe and number of unpaired electrons present respectively are
(a) 1+, 3
(b) 2+, 3
(c) 3+, 3
(d) 3+, 5
28.
Zn(II) ion first gives a white precipitate with NaOH which dissolves in excess of NaOH. This is due to the
formation of a complex. The oxidation sate of zinc in this complex will be
(a) Zero
(b) +II
(c) +IV
(d) +VI
29.
30.
(c) [Sc(H2O)6]3+
(d) Na2[NiCl4]
WORKSHEET
Coordination Compounds
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30