Feasibility of Mussel Shells in Making Hollow Blocks
Feasibility of Mussel Shells in Making Hollow Blocks
Feasibility of Mussel Shells in Making Hollow Blocks
Arceo, Chester Lim, Kyle Mabasa, Jojo Marquez, Avery Sonza, Ethan
Lourdes School of Mandaluyong St. Ignatius of Laconi
Armand John Yangat February 22, 2013
DEDICATION
This study is dedicated to people who have curious minds that could devote their
time, body, mind, money, and heart for the sake of Science and for the sake of
the improvement of civilization. This study is also aimed for the sake of the pr
ominent minds and bright futures of the future students of Lourdes School of Man
daluyong.
This study is also dedicated to the researchers prominent, outstanding, inspirati
onal Physics teacher, Sir Armand John Yangat for being their light and guide in
conducting the research.
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ACKNOWLEDGEMENT
The researchers express their utmost gratitude to their Physics teacher, Sir Arm
and John Yangat, for giving them the opportunity to conduct this experiment and
for the support, encouragement, patience and perseverance he portrayed. Sir Yang
at is, indeed, a true inspiration and role model to society. The researchers wou
ld also like to thank the people who have had helped them in conducting, researc
hing and printing the experiment and research such as the parents of the researc
hers for providing the materials, mainly the mussel shells, the High School Libr
ary of Lourdes School of Mandaluyong for providing useful and detailed informati
on related to the research, the University of the Philippines Institute of Civi
l Engineering for providing past, similar, researches and for testing the compon
ents of the hollow blocks. Lastly but certainly not the least, the researchers w
ould like to thank the people who have whole-heartedly read, studied and used th
is research for the greater good of the world.
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ABSTRACT
This study aims to develop with stronger and tougher hollow blocks by the means
of adding mussel shells to the base composition of the hollow block so that it c
ould withstand greater compressive strength. This will also serve as a substitut
e for the regular, commercial hollow blocks that are deemed quite expensive in t
he current market. Based on initial research, the researchers believe that musse
l shells, or rather a crustacean shell, can offer extra strength and durability
when used properly hence, leading to mussel shells used as an additive in hollow
block making. The study is mainly for the betterment and improvement of civiliz
ation by killing two birds with one stone: addressing the pollution and solid wa
ste problem by recycling mussel shells and by improving infrastructures by stren
gthening the foundations of it through improving the base which, in the Philippi
nes, is usually hollow blocks integrated with the famous cooking thought: Better
ingredients, better food.
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TABLE OF CONTENTS
Dedication - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - i Acknowledgement - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - ii Abstract - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - iii Table of Contents - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - iv Chapter I: Introduction - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - 1-4
Background of the Study - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - 1 Statement of the Problem - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - 2 Hypothesis of the Study - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - 3 Significance of the Study - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - 3 Scope and Limitatio
ns of the Study - - - - - - - - - - - - - - - - - - - - - - - - - - - 3 - 4 Defi
nition of Terms - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - 4
Chapter II: Review of Related Studies and Literature - - - - - - - - - - - - - - - - 5 - 9 Chapter III: Methodology - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - Research Design - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - Sampling Procedure - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - 10 11 11
Instrumentation - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - 11 Research Procedure - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - 11 - 12 Research Diagram - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - 12 Chapter IV: Presenta
tion, Analysis and Interpretation of Data - - - - - - - - - 13 - 14
Chapter V: Summary, Conclusion and Recommendation - - - - - - - - - - - - - - 15
- 16 Summary - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - 15 Conclusion - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - 15 - 16 Recommendation - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - Bibliography - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - 16 v
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CHAPTER I INTRODUCTION
Background of the Study
The world progresses alongside civilization, culture and technology; innovation
is a must. As part of human nature, man continues to make life easier through
inventions, discoveries and innovations hence, the assurance of the best possibl
e service and materials available for the daily lives of man. As an attempt to
innovate , the researchers have decided to commit ourselves to a research that w
ill do just that. An experiment revolving around a common building tool used in
almost every infrastructure around the world: hollow blocks.
Hollow blocks are large rectangular bricks used in construction. It is a basic b
uilding tool. It is also known as concrete blocks, cement blocks and as foundati
on blocks. These are made in several different ways such as, in Portland, cement
and either sand and fine gravel aggregates for high density-blocks or industria
l wastes for low density-blocks. Those that use cinders -fly ash or bottom ashare called cinder blocks in Canada, the US and New Zealand, breeze blocks -breez
e is a synonym of ash- in the UK. Hollow blocks in the Philippines and are also
known as besser blocks or bricks in Australia. Clinker blocks use clinker as agg
regate. In non-technical usage, the terms cinder block and breeze block are ofte
n generalized to cover all of these varieties. Lightweight blocks can also be pr
oduced using aerated concrete.
Several environmentalist groups, researchers and students has had experimented o
ver the matter of what additive is suitable to increase the effectiveness of hol
low blocks wherein lime soil, coconut coir, rice hull, plastic and a few others
were used as an additive. This,
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however, did the opposite wherein the hollow block became less solid , making i
ts building options lesser for instance, walls and fences were the only stable p
roducts.
After initial research, the researchers stumbled upon a common product that coul
d strengthen materials with its high calcium carbonate that will supposedly stre
ngthen cement. Mussel shells, the common product, are considered waste for it is
usually thrown out immediately after consumed. Mussel shells contain 95-99% cal
cium carbonate by weight, while an organic component makes up the remaining 1-5%
. The resulting composite has fracture toughness ~3000 times greater than that o
f the crystals themselves. In the biomineralization of the mollusk shell, specia
lized proteins are responsible for directing crystal nucleation, phase, morpholo
gy, and growths dynamics and ultimately give the shell its remarkable mechanical
strength. The application of biomimetic principles elucidated from mollusk shel
l assembly and structure may help in fabricating new composite materials with en
hanced optical, electronic, or structural properties.
Statement of the Problem
How will mussel shells used as an additive affect the h
ollow block s compressive strength? Would the ratio of sand to mussel shells aff
ect it? o o o 40% Mussel Shells while 60% Sand 50% Mussel Shells while 50% Sand
60% Mussel Shells while 40% Sand
Will a commercial hollow block be better than the home-made hollow block with mu
ssel shells as an additive in terms of compressive strength?
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The limitation of the study is that the researchers will not conduct the experim
ent inside the school, but rather outside of its premises hence, the hollow bloc
k would be homemade. The study cannot be successful without seeking professional
help due to the fact that compressive strength needs to be determined through t
horough laboratory analysis. The study will be tested at the University of the P
hilippines Institute of Civil Engineering. Additionally, the research is only l
imited in determining the compressive strength of the hollow blocks, making the
conclusions and interpretations of this experiment solely based on the PSI. Any
form of building shall not be used either.
Definition of Terms
cement. a building material made by grinding calcined limestone and clay to fine
powder, which can be mixed with water and poured to form a solid mass; used as
an ingredient in making mortar or concrete compressive strength. maximum stress
a material can sustain under crush loading hollow block. concrete or burnt clay
hollow blocks used for construction of hollow-tile floors mussel. any of various
marine bivalves of the genus Mytilus and related genera especially medulis. edi
ble mussel; having a dark, slightly elongated shell and, usually, attached to ro
cks psi. a unit of pressure or of stress based on avoirdupois units. It is the p
ressure resulting from a force of one pound-force applied to an area of one squa
re inch ultimate load. a statistical figure of the maximum weight a substance ca
n withstand
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soft chalky deposits which consist of amorphous material. This layer makes up th
e major part of the shell, hypostracum layer is made or shell material under the
abductor muscle. In the crassostrea virginica the layer is pigmented and consis
ts of aragonite. As the oyster grows the adductor muscle increases in size and t
he new areas or attachment become covered with aragonite.
Shells grow by the accretion of material secreted at their edges. The rings on t
he outer surfaces or a bivalve shell represent the contours of the shell at diff
erent ages. Rings are common to all bivalves shells. Depending on the shape of th
e shell, the rings are either circular or oval with a common point or origin at
the extreme dorsal side near the umbo. The rate of growth along the edge of the
shell is not uniform and may actually change direction in response to environmen
tal factors
The mantle of the mussel; the animal inside the shell is covered by a mantle. Th
e principal function of the mantle is the formation or the shell and its calcifi
cation. It is made up of soft and freshly tissue. The structure of the mantle co
nsists of a sheet of connective tissue containing muscles, blood vessels, nerves
and it is covered on both sides by epithelium. The mantle receives sensory stim
uli, and conveys them to the nervous system and aid in the shedding and dispersa
l of eggs. It also participates in respiration, stores reserve materials, secret
es large quantities of mucous and aids in excretion. The most obvious components
of the mantle are the radial muscles, blood vessels and nerves. The radial musc
les are large bands of fibers which extend almost the entire width of the mantle
. The radial muscle contracts and pulls the entire mantle inside and throws its
surface into ridges. The mantles blood vessel are the circumpallial artery which
sends out many branches; the common pallial artery, and a large pulsating vessel
in the anteriorventral part of
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the mantle called the accessory heart. The nerve provides communication. Close n
erve contact is maintained between the muscles and the organs of the mantle thro
ugh a fine nerve network.
An important use of calcium carbonate is in the building industry. Due to its wi
de abundance and properties, it has been used as a building substance since anci
ent times. For example, the Egyptians used limestone for building their pyramids
. Another notable monument made up of white marble is the Taj Mahal in India. To
day, calcium carbonate is used in construction of buildings, roads and other eng
ineering works.
Besides construction, calcium carbonate is also used in other industries like pa
int, plastic, rubber, ceramic, cement, glass, steel, oil refining, iron ore puri
fication and biorock creation for mariculture of sea organisms. It is used as a
blackboard chalk and as pH correcting compound in swimming pools. As per statist
ics, about 200 tons of chalk is used every year. Calcium carbonate is the most p
referred mineral in the paper industry, used for filling and coating paper. It h
elps in production of the best quality printing papers.
Since calcium is essential for healthy bones and teeth, calcium carbonate is use
d as dietary calcium supplement. Calcium carbonate supplement is effective to tr
eat certain ailments related to calcium deficiency, for example, osteoporosis an
d acidity problems. Calcium supplements, made from calcium carbonate, are prescr
ibed in various doses as per the requirement of the patients. Calcium carbonate
is used in homeopathy, production of toothpaste and as an inert substance in tab
lets.
Calcium carbonate is a primary component of garden lime, also known as agricultu
ral lime, which is used for neutralizing soil. Acidic soils can be treated with
garden lime to enhance
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the soil quality. Garden lime when added in soil acts as a calcium source for pl
ants as well as increases the pH and water retaining capacity of acidic soils. C
alcium carbonate sources such as limestone and chalk, along with other chemical
compounds are used in preparation of garden lime.
Calcium carbonate has various environmental applications. It is used in the trea
tment of drinking water, desulphurisation of flue gas and waste water treatments
. Water bodies affected by acid rain can be neutralized by using calcium carbona
te. However, care has to be taken as it can increase the concentration of alumin
um ions.
Compressive strength is the capacity of a material or structure to withstand axi
ally directed pushing forces. It provides data (or a plot) of force vs deformati
on for the conditions of the test method. When the limit of compressive strength
is reached, brittle materials are crushed. Concrete can be made to have high co
mpressive strength, e.g. many concrete structures have compressive strengths in
excess of 50 MPa, whereas a material such as soft sandstone may have a compressi
ve strength as low as 5 or 10 MPa. By contrast, a small plastic container might
have a compressive strength of less than 250 N.
Calcium carbonate is a chemical compound with the formula CaCO3. It is a common
substance found in rocks in all parts of the world, and is the main component of
shells of marine organisms, snails, coal balls, pearls, and eggshells. Calcium
carbonate is the active ingredient in agricultural lime, and is usually the prin
cipal cause of hard water. It is commonly used medicinally as a calcium suppleme
nt or as an antacid, but excessive consumption can be hazardous.
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Amount of Cement Amount of Water Dried Mussel Shells Size of the Hollow Block (M
old)
Sampling Procedure
This part of the study briefly discusses the procedures in conducting the study.
The follow steps were taken by the researchers to complete their study; first,
they gathered all the required materials: a hammer, spatula, Tupper wear, mussel
shells, sand and water, second; they sun-dried the shells then crushed them tho
roughly, third; prepare the four set-ups. Testing would be done by people from t
he University of the Philippines due to the researcher s lack of equipment. Thei
r laboratory is a necessity and a must in this experiment.
Instrumentation
The researchers aim to make hollow blocks with mussel shells as an additive. To
do so, several tools and materials are required such as: a hammer to crush the s
hells; a weighing scale to measure the materials like sand, cement, mussel shell
s; shovel, a spatula or a wooden rod for mixing substances and mixtures and; a T
upper wear or any molding material to mold the hollow block. The study will be g
oing to the University of the Philippines Institute of Civil Engineering for th
e testing of compressive strength.
Research Procedure
This part of the study is a detailed procedure of the whole experiment. The gath
ered mussel shells were sun dried for half a day on a sheet of foil. These were
then crushed with the hammer. The set-ups were made by the people from the Unive
rsity of the Philippines wherein the researchers only provided the materials. As
recorded by UP, there were 4 set-ups: A, B, C and D. Set-up A was a commercial
block; set-up B s additive composition had 60% mussel shells and 40% sand while;
set-up C had 50% mussel shells and 50% sand and; set-up D with
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40% mussel shells and 60% sand. They also claim that similar students has had do
ne this exact request before, making it easier for them. The blocks were left to
harden up and will be tested at their laboratories immediately after the comple
ted hollow block making process. The laboratory tests would test the four blocks
compressive through pound force per square inch or PSI. The results would be sen
t to the researchers for further analysis and interpretations that would lead to
this experiment s conclusion.
Research Diagram
Gather the materials.
Let the professionals do their thing.
Conduct the experiment by... Testing its compressive strength.
Clean the mussel shells.
Bring them to the laboratory.
Sun dry them for half a day.
Flowchart 1.1. Procedure
Crush them.
Observe and record.
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appear superior. Same goes to set-up C: 50% mussel shell additive and set-up D:
40% mussel shell additive in contrast with set-up A. These set-ups support the s
tatement that the more mussel shell additive added to the hollow block would mak
e the hollow blocks compressive strength greater wherein these set-ups determined
that the less mussel shell additives made the hollow blocks compressive strength
lower. Therefore, the conclusion: mussel shells used as an additive in hollow b
lock making would make the hollow block stronger in terms of compressive strengt
h and, additionally, ultimate load.
Recommendation
The researchers would like to recommend: planning ahead of time is highly recomm
ended for the next batch of researchers for collecting a sizable amount of musse
l shells poses to be an easy task but in reality, it is rather a tedious act. Ad
ditionally, the testing laboratory at the University of the Philippines is highl
y recommended for testing various quantities, qualities and compositions such as
, in this experiments case, ultimate load and compressive strength. However, plan
ning the tests ahead of schedule would be, also, highly recommended due to the f
act that the people at the University of the Philippines are quite busy; a sched
uled appointment is a must. It is also recommended that instead of using mussel
shells, several other additives may be used such as, as mentioned in the introdu
ction, lime soil, coconut coir, rice hull, plastic or other Mollusks such clams,
oysters, crabs, lobsters and the like. It is also recommended to, as the origin
al plan of this experiment, try pure additives without the mix of others such as
, in this case, sand; making the experiment only 100% mussel shells or 100% chos
en additive which, by theory, should make the hollow block even stronger. Anothe
r recommendation would be seeking professional help in making the hollow block t
o secure the best and most accurate results, as did in this experiment. Proper t
esting, however, would cost at least 2, 500 Pesos.
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