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    Uploaded by

    Thakur Aryan Singh
    The document provides examples of solved problems related to atomic structure. Example 1 calculates the mass of atom A given its mass to charge ratio. Example 2 gives the numerical value and unit of Planck's constant h. Example 3 calculates the transmission frequency in Hertz of a radio station given the wavelength of its transmission. Example 4 identifies the correct energy of the first stationary state of Li+2 ion based on information about the ionization energy of He+.

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    © All Rights Reserved
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    1

    Uploaded by

    Thakur Aryan Singh
    48 views1 page
    The document provides examples of solved problems related to atomic structure. Example 1 calculates the mass of atom A given its mass to charge ratio. Example 2 gives the numerical value and unit of Planck's constant h. Example 3 calculates the transmission frequency in Hertz of a radio station given the wavelength of its transmission. Example 4 identifies the correct energy of the first stationary state of Li+2 ion based on information about the ionization energy of He+.

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    The document provides examples of solved problems related to atomic structure. Example 1 calculates the mass of atom A given its mass to charge ratio. Example 2 gives the numerical value and unit of Planck's constant h. Example 3 calculates the transmission frequency in Hertz of a radio station given the wavelength of its transmission. Example 4 identifies the correct energy of the first stationary state of Li+2 ion based on information about the ionization energy of He+.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    48 views1 page

    1

    Uploaded by

    Thakur Aryan Singh
    The document provides examples of solved problems related to atomic structure. Example 1 calculates the mass of atom A given its mass to charge ratio. Example 2 gives the numerical value and unit of Planck's constant h. Example 3 calculates the transmission frequency in Hertz of a radio station given the wavelength of its transmission. Example 4 identifies the correct energy of the first stationary state of Li+2 ion based on information about the ionization energy of He+.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 1

    ATOMIC STRUCTURE

    Solved Example
    Ex.1

    The mass charge ratio for A+ ion is 1.97 107 kg C1. Calculate the mass of A atom.

    Sol.

    Given

    m
    = 1.97 107
    e

    m = 1.97 107 1.602 1019 kg

    (since e = 1.602 1019 C)

    m = 3.16 1026 kg
    Ex.2

    Write down the numerical value of h and its unit

    Sol.

    h = 6.625 1027 erg sec = 6.625 1034 joule sec


    Qh = E

    h = E = erg
    sec 1

    The unit of h = joule sec. or erg sec.

    Ex.3

    AIR service on Vividh Bharati is transmitted on 219 m band. What is its transmission frequency in Hertz ?

    Sol.

    Given

    = 219 m

    or

    Ex.4

    Thus, =

    3.0 108
    = 1.37 106 Hz
    219

    The ionization energy of He+ is 19.6 1018 J atom1. The energy of the first stationary state of Li+2 will be :
    [1] 84.2 1018 J/atom

    [2] 44.10 1018 J/atom [3] 63.2 1018 J/atom

    [4] 21.2 1018 J/atom


    Ans. [2]

    Sol.

    E1 for Li+2 = E1 for H Z2 = E1 for H 9


    E1 for He+ = E1 for H Z2He = E1 for H 4
    or E1 for Li+2 =

    9
    9
    E1 for He+ = 19.6 1018
    4
    4

    = 44.10 1018 J/atom

    Ex.5

    Atomic radius is of the order of 108 cm and nuclear radius is of the order of 1013 cm. Calculate what fraction of
    atom is occupied by nucleus ?

    Sol.

    Volume of nucleus

    4 3 4
    r = (1013)3 cm3
    3
    3

    Volume of atom

    4
    (108)3 cm3
    3

    VN
    1039
    =
    = 1015
    VAtom
    1024

    VNucleus = 1015 VAtom


    Ex.6

    Which of the following set of quantum numbers are not permitted


    (a) n = 3, l = 2, m = 2, s = +1/2

    (b) n = 3, l = 2, m = 1, s = 0

    (c) n = 2, l = 2, m = +1, s = 1/2

    (d) n = 2, l = 2, m = +1, s = 1/2

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