ATOMIC STRUCTURE

SOLVED EXAMPLE
Ex.1 The mass charge ratio for A+ ion is 1.97 × 10–7 kg C–1. Calculate the mass of A atom.

m
Sol. Given = 1.97 × 10–7
e

(since e = 1.602 × 10–19 C)  m = 1.97 × 10–7 × 1.602 × 10–19 kg

m = 3.16 × 10–26 kg
Ex.2 Write down the numerical value of h and its unit
Sol. h = 6.625 × 10–27 erg sec = 6.625 × 10–34 joule sec

 h  E 
 
The unit of h = joule sec. or erg sec. E
h   erg 
  sec 1 

Ex.3 AIR service on Vividh Bharati is transmitted on 219 m band. What is its transmission frequency in Hertz ?

c
Sol. Given  = 219 m Thus,  =


3.0  108
or = = 1.37 × 106 Hz
219

Ex.4 The ionization energy of He+ is 19.6 × 10–18 J atom –1. The energy of the first stationary state of Li+2 will be :
[1] 84.2 × 10–18 J/atom [2] 44.10 × 10–18 J/atom [3] 63.2 × 10–18 J/atom [4] 21.2 × 10–18 J/atom
Ans. [2]
+2 2
Sol. E1 for Li = E1 for H × Z = E1 for H × 9
E1 for He+ = E1 for H × Z2He = E1 for H × 4

9 9
or E1 for Li+2 = E1 for He+ = 19.6 × 10–18 × = 44.10 × 10–18 J/atom
4 4

Ex.5 Atomic radius is of the order of 10–8 cm and nuclear radius is of the order of 10–13 cm. Calculate what fraction of
atom is occupied by nucleus ?

4 3 4
Sol. Volume of nucleus = r =  (10–13)3 cm 3
3 3

4
Volume of atom =  (10–8)3 cm 3
3

VN 10 –39
VAtom = = 10–15
10 –24

VNucleus = 10–15 × VAtom

Ex.6 Which of the following set of quantum numbers are not permitted
(a) n = 3, l = 2, m = – 2, s = +1/2 (b) n = 3, l = 2, m = – 1, s = 0
(c) n = 2, l = 2, m = +1, s = – 1/2 (d) n = 2, l = 2, m = +1, s = – 1/2
ATOMIC STRUCTURE

Sol. (a) This set of quantum number is permitted.

(b) This set of quantum number is not permitted as value of ‘s’ cannot be zero.
(c) This set of quantum number is not permitted as the value of ‘l’ cannot be equal to ‘n’.

(d) This set of quantum number is not permitted as the value of ‘m’ cannot be greater than ‘l’.

 Ze2 
Ex.7 Prove that un =   where u is velocity of electron in a one electron atom of at. no. Z at a distance rn from
 mrn 

the nucleus, m and e are mass and charge of electron.

1
Sol. Kinetic energy of electron = mu2
2

2 2
1 Ze 1 1 Ze
Also from Bohr’s concept K.E. =  mu2 =
2 rn 2 2 rn

 Ze2 
  
 mrn 

Ex.8 Calculate the number of proton emitted in 10 hours by a 60 W sodium lamp ( or photon = 5893 Å)
Sol. Energy emitted by sodium lamp in one sec.
= Watt × sec = 60 × 1 J

hc
Energy of photon emitted =


6.626  10 –34  3  108

= = 3.37 × 10–19 J
5893  10 –10

60
 No of photons emitted per sec. =
3.37  10 –19

 No. of photons emitted in 10 hours = 17.8 × 1019 × 10 × 60 × 60 = 6.41 × 1024

Ex.9 Find out the energy of H atom in first excitation state.The value of perm ittivity factor
40 = 1.11264 × 10–10 C2 N–1 m –2.
Sol. In M.K.S. system

22 Z 2me2 2  (3.14)2  (1)2  9.108  10 –31  (1.602  10 –19 )4

En = – = = 5.443 × 10–19 joule
(4 0 )2 n2 h2 (1.11264  10 –10 )2  (2)2  (6.625  10–34 )2

Ex.10 The shortest wave length in H spectrum of Lymen series when RH = 109678 cm –1 is
[1] 1002.7 Å [2] 1215.67 Å [3] 1127.30 Å [4] 911.7 Å
Ans. [4]
 ATOMIC STRUCTURE

Sol. For Lymen series n1 = 1

For shortest ‘l’ or Lymen series the energy difference in two levels showing transition should be maximum

1 1 1
(i.e. n2 = ) = RH  2 – 2 
 1  

= 109678 = 911.7 × 10–8 = 911.7 Å

Ex.11 Electromagnetic radiations of wavelength 242 nm is just sufficient to ionise sodium atom. Calculate the ionisation
energy of sodium in kJ mol–1.

6.625  10 34  3.0  108

Sol. Energy associated with a photon of 242 nm = = 8.21 × 10–19 joule
242  10 9

 1 atom of Na for ionisation requires = 8.21 × 10–19 J

 6.023 × 1023 atoms of Na for ionisation requires
= 8.21 × 10–19 × 6.023 × 1023
= 49.45 × 104 J = 494.5 kJ mol–1
Ex.12 How many electrons in a given atom can have the following quantum numbers
(a) n = 4, l = 2, m = 0 (b) n = 3
(c) n = 2, l = 1, m = – 1, s = + 1/2 (d) n = 4, l = 1
2
Sol. (a) l = 2 means d-subshell and m = 0 refer to dz orbital
 Number of electrons are 2.
(b) For n = 3, l = 0, 1, 2
l=0 m=0 2 electrons
l= 1 m = –1 6 electrons
l=2 m = –2, –1, 0, +1, +2 10 electrons
Total electrons 18 electrons
Alternatively, number of electrons for any energy level is given by
2n2 i.e. 2 × 32 = 18 electrons
(c) l = 1 refers to p-subshell, m = – 1 refers to px or py orbital whereas, s = + 1/2 indicate for only 1 electron.
(d) l = 1 refers to p-subshell which has three orbitals (px, py and pz) each having two electrons. Therefore , total
number of electrons are 6.
Ex.13 Calculate the longest wavelength which can remove the electron from I Bohr’s orbit. Given E1 = 13.6 eV.
Sol. The photon capable of removing electron from I Bohr’s orbit must possess energy
= 13.6 eV
= 13.6 × 1.602 × 10–19 J = 21.787 × 10–19 J

hc 6.625  10 34  3.0  108

 E= ; 21.787 × 10–19 =
 

  = 912.24 × 10–10 m = 912.24 Å

Ex.14 Naturally occurring boron consists of two isotopes whose atomic weights are 10.01 and 11.01. The atomic
weight of natural boron is 10.81. Calculate the percentage of each isotope in natural boron
ATOMIC STRUCTURE

Sol. Let the percentage of isotope with atomic wt. 10.01 = x

 Percentage of isotope with atomic wt. 11.01 = 100 – x

m1x1  m2 X2
Average atomic wt. = x1  x2

x  10.01  (100 – x)  11.01

or Average atomic wt. =
100

x  10.01  (100 – x)  11.01

10.81 = = 20
100

 % of isotope with atomic wt. 10.01 = 20

% of isotope with atomic wt. 11.01 = 100 – x = 80
Ex.15 What transition in the hydrogen spectrum would have the same wavelength as the Balmer transition n = 4 to
n = 2 of He+ spectrum ?

1 1 1
Sol. For He+, = RHZ2  2 – 2 
 2 4 

1 1 1
For H, = RH  2 – 2 
 n
 1 n2

Since  is same

1 1 1 1
 Z2  2 – 2  =  2 – 2 
2 4  n
 1 n 2

 Z=2

1 1 1 1
  12 – 22  =  n2 – n2 
   1 2

 n1 = 1 and n2 = 2

Ex.16 The ionization energy of H-atom is 13.6 eV. The ionization energy of Li+2 ion will be
[1] 54.4 eV [2] 122.4 eV [3] 13.6 eV [4] 27.2 eV Ans. [2]
Sol. E1 for Li+2 = E1 for H × Z2 [for Li, Z = 3]
= 13.6 × 9
= 122.4 eV
Ex.17 Calculate momentum of radiations of wavelength 0.33 nm.

h h
Sol. We have =  mu =
mu 

6.625  10 –34
= = 2.01 × 10–24 kgmsec–1
0.33  10 9
 ATOMIC STRUCTURE

Ex.18 On the basis of Heisenberg’s uncertainty principle, show that the electron cannot exist within the nucleus.

Sol. Radius of the nucleus is of the order of 10–13 cm and thus uncertainty in position of electron, i.e., (x), if it is
within the nucleus will be 10–13 cm.

h
Now x.u  4  m

6.626  10 –27
 u =
4  3.14  9.108  10 –28  10 –13

= 5.79 × 1012 cm/sec

i.e., order of velocity of electron will be 100 times greater than the velocity of light which is impossible. Thus,
possibility of electron to exist is nucleus is zero.

Ex.19 Oxygen consists of isotopes of O16, O17 and O18 and carbon consists of isotopes of C12 and C13. How many types
of CO2 molecule can be formed ? Also report their mol, wt.

Sol. Total no. of molecules of CO2 = 12

[1] C12O16O16 Mol. wt. = 44

[2] C12O17O17 = 46

[3] C12O18O18 = 48

[4] C12O16O17 = 45

[5] C12O16O18 = 46

[6] C12O17O18 = 47

Similarly six molecules with C13 isotopes.

Ex.20 The atomic masses of two isotopes of O are 15.9936 and 17.0036. Calculate in each atom

[1] No. of neutrons [2] No. of protons [3] No. of electrons [4] Mass no.

Ans. [1]

Sol. I isotope of O II isotope of O

Atomic masses are 15.9936 17.0036

 Mass no. are 16 17 (Integer values)

 No of neutrons = 16 – 8 = 8 17 – 8 = 9

and no. of electrons =8 =8

Mass no. – At no. = No. of neutrons

ATOMIC STRUCTURE

EXERCISE-1
Q.1 An atom of an element contains the number of electrons equal to :
[1] Atomic mass [2] Atomic number [3] Equivalent weight [4] Electron affinity
Q.2 If a neutral atom changes to cation its :
[1] atomic size decreases [2] atomic number decreases
[3] atomic size increase [4] atomic number increases
Q.3 The K.E. of an electron in first Bohr’s orbit of H-atom is 13.6 eV. Total energy of first orbit is :

1 1
[1] – × 13.6 eV [2] – 13.6 eV [3] 2 × 13.6 eV [4] × 13.6 eV
2 2

Q.4 Which of the following radioactive isotope of carbon is used for the calculate of life period of a planet ?

12 13 14 16
[1] 6 C [2] 6 C [3] 6 C [4] 6 C

Q.5 The shape of p-orbital is :

[1] Elliptical [2] spherical [3] dumb-bell [4] None of these
Q.6 C11 and 5B11 are called :
6

[1] Nuclear isomers [2] Isobars [3] Isotopes [4] Fission products
Q.7 No two electrons of an atom can have same :
[1] principle quantum number [2] azimuthal quantum number
[3] set of four quantum numbers [4] magnetic quantum number
Q.8 Correct set of four quantum numbers for the valence (outermost) electron of rubidium (Z = 37) is :
[1] 5, 0, 0 + 1/2 [2] 5, 1, 0, + 1/2 [3] 5, 1, 1, + 1/2 [4] 6, 0, 0, + 1/2
th
Q.9 Which of the following formula represents the K.E. of an electron in n Bohr’s orbit of H-atom ?

Rhc Rhc 2Rhc 2Rhc

[1] 2 [2] – 2 [3] – 2 [4]
n n n n2

Q.10 The number of electrons arranged in an orbital is :

[1] One [2] Two [3] Three [4] Four
Q.11 The frequency of a radiobulletin is 600 kilocycles. What is the wavelength of the signal ?
[1] 100 m [2] 250 m [3] 500 m [4] 600 m
Q.12 The energy of electron in excited H-atom is – 3.4 eV. What is the angular momentum of electron ?

h h 2h 3h
[1] [2] [3] [4]
 2  
Q.13 What is the frequency of the electron in an orbit of radius r, if its velocity is v ?

2r vr v
[1] [2] 2rv [3] [4]
v 2 2 r

Q.14 How many spectral lines will be obtained by the various transitions when an electron comes from excited state
n = 5 to its original state ?
[1] 20 [2] 5 [3] 4 [4] 10
 ATOMIC STRUCTURE

Q.15 Principal, azimuthal and magnetic quantum numbers are respectively related to :
[1] size, shape and orientation [2] shape, size and orientation
[3] size, orientation and shape [4] None of these
Q.16 Bohr’s model of the atom can explain :
[1] The spectrum of H-atom only
[2] The spectrum of hydrogen molecule
[3] The spectrum of atom or ion containing one electron only
[4] The solar spectrum
Q.17 The electromagnetic radiation with highest wavelength is :
[1] Ultraviolet [2] Radio waves [3] X-rays [4] Infra red
Q.18 The angular momentum of electron in Bohr’s orbit is J. What will be the K.E. of that Bohr’s orbit ?

1 Jv Jv J2 J2
[1] [2] [3] [4]
2 r r 2m 2

Q.19 The electronic configuration of H– is :

[1] 1s0 [2] 1s1 [3] 1s2 [4] 1s1 2s1
Q.20 The wavelength of first line of Balmer series of H-atom is – (R = Rydberg’s constant)

36 36R 5R 5
[1] [2] [3] [4]
5R 5 36 36R

Q.21 The excitation energy of an electron from second orbit to third orbit of an atom with + Ze nuclear charge is 47.2
eV. If the energy of H-atom in lowest energy state is – 13.6 eV. What will be the value of Z ?
[1] 4 [2] 5 [3] 6 [4] 7
Q.22 The statement ‘It is not possible to estimate accurately the position and momentum of an electron simulta-
neously is associated with :
[1] Heisenberg’s uncertainty principle [2] De-Broglie’s principle
[3] Pauli’s uncertainty principle [4] Aufbau principle
Q.23 K, L and M shells of an atom contain 2, 8 and 6 electrons respectively. Total number of s-electrons in this
element are :
[1] 6 [2] 5 [3] 7 [4] 10
Q.24 W hen -particle are passed through thin metal foil, most of the particles pass-through straight
because :
[1] -particles are lighter than electrons [2] -particles are positively charged
[3] Most of the part of atom is empty [4] -particles move with high speed
Q.25 The increasing order (lowest first) for the value of e/m (charge/mass) for :
[1] e, p, n,  [2] n, p, e,  [3] n, p, , e [4] n, , p, e
Q.26 The electron of H-atom transits from n = 1 to n = 4 by absorbing energy. If the energy of n = 1 state
is – 21.8 × 10–19 Joule then its energy in n = 4 state will be :
[1] – 21.8 × 10–19 Joule [2] – 5.45 × 10–19 Joule
[3] – 2.725 × 10–19 Joule [4] – 1.362 × 10–19 Joule
ATOMIC STRUCTURE

Q.27 The wavelength of first line of Lymen series is 1216 Å. What is the wave length of last line ?
[1] 3648 Å [2] 608 Å [3] 912 Å [4] 2432 Å
Q.28 Energy of orbit :
[1] Increases as we move away from nucleus
[2] Decreases as we move away from nucleus
[3] Remains same as we move away from nucleus
[4] None of these
Q.29 Which electronic level would allow the hydrogen atom to absorb a photon but not to emit a photon ?
[1] 3s [2] 2p [3] 2s [4] 1s
Q.30 The electronic configuration of a diapositive metal M2+ is, 2, 8, 14 and its atomic weight is 56 amu. The number
of neutrons in its nuclei would be :
[1] 30 [2] 32 [3] 34 [4] 42
Q.31 The electrostatic force of attraction between the electron of first Bohr’s orbit of H-atom and it nucleus is :
[1] 10 × 10–3 dyne [2] 8 × 10–3 dyne [3] 8 × 10–4 dyne [4] 10 × 10–4 dyne
Q.32 de’ Broglie equation tells about :
[1] the relation between electron and nucleus [2] the relation between electron and proton
[3] the relation between electron and neutron [4] electrons’ dual nature of wave and particle
Q.33 When an electron jumps from L to K shell :
[1] energy is absorbed
[2] energy is released
[3] energy is sometimes released and sometimes absorbed
[4] energy is neither absorbed nor released
Q.34 Helium atom is two times heavier than a hydrogen molecule. At 298 K, the average kinetic energy of helium
atom is :
[1] two times that of hydrogen molecule [2] same as that of hydrogen molecule
[3] four times that of hydrogen molecule [4] half that of hydrogen molecule
Q.35 Positronium is the name given to an atom like combination formed between :
[1] A positron and a proton [2] A positron and a neutron
[3] A positron and -particle [4] A positron and an electron
Q.36 The potential energies of first, second and third Bohr’s orbits of He+ cation are E1, E2 and E3. The correct
sequence of these energies is :
[1] E1 > E2 > E3 [2] E1 = E2 > E3 [3] E1 = E2 = E3 [4] E3 > E2 > E1
Q.37 The circumference of first Bohr’s orbit of hydrogen atom is how many times the circumference of second Bohr’s
orbit of He+ ?
[1] two times [2] half [3] equal [4] none of these
Q.38 The sum of the number of neutrons and protons in the isotopes of hydrogen is :
[1] 6 [2] 5 [3] 4 [4] 3
Q.39 According to Sommerfeld, the numbers of circular and elliptical suborbits in n th Bohr’s orbit are
respectively :
[1] 1 and (n – 1) [2] (n – 1) and 1 [3] 2 and (n – 1) [4] (n – 2) and 1
 ATOMIC STRUCTURE

Q.40 According to Pauli’s exclusion principle :

[1] No two electrons can have the same energy in an orbital
[2] No two electrons can have the parallel spin in an orbital
[3] As far as possible the electrons fill in different orbitals
[4] Electron try to occupy the orbital of lower energy
Q.41 The mass of a cricket ball is 0.21 kg. If the order of uncertainty in position is 100 pm then uncertainty in its
velocity will be :
[1] 3.5 × 10–24 m/sec [2] 6.02 × 1023 m/sec [3] 6.602 × 10–27 m/sec [4] 2.5 × 10–24 m/sec
Q.42 The molecular weight of an oxide of nitrogen is 30. The number of electrons present in one molecule of this
compound is :
[1] 15 [2] 30 [3] 6.02 × 1023 × 15 [4] 6.02 × 1023 × 30
Q.43 Which of the following are isoelectronic with one another :
[1] Na+ and Ne [2] K+ and O [3] Ne and O [4] Na+ and K+
Q.44 Which of the following statements is false ?
[1] (n + ) rule arranges the orbitals in increasing order of energy
[2] Wavelength of a particle is inversely proportional to its momentum
[3] Aufbau’s principle was given a scientist named Aufbau
[4] Velocity of all types of electromagnetic radiation is same
Q.45 The electron with highest energy is :
[1] in nucleus [2] in ground state
[3] in first excited state [4] At infinite distance from the nucleus
Q.46 Electron density in the region between 1s and 2s- orbital is :
[1] high [2] low [3] zero [4] None of these
Q.47 If the radius of first orbit of H-atom is 5 pm, the radius of third orbit Li2+ will be :
[1] 106 pm [2] 23 pm [3] 32 pm [4] 15 pm
Q.48 If the Rydberg constant is R then the energy of electron in ground state of H-atom will be :

ch Rc
[1] – [2] – Rch [3] – [4] – R/ch
R h

Q.49 In which of the following planes of s-orbitals, the probability of finding the electrons is not zero ?
(a) xy plane (b) yz plane (c) along the x axis (d) xyz plane
Correct answer is :
[1] (a) and (d) only [2] (b) and (c) only [3] (d) only [4] (a) and (c) only
Q.50 The number of neutrons in the tritium nucleus is :
[1] 1 [2] 2 [3] 3 [4] 4
Q.51 An atom has an atomic weight of W and atomic number N then :
[1] Number of electrons = W – N [2] Number of protons = W – N
[3] Number of neutrons = W – N [4] Number of neutrons = N
Q.52 When an electron of charge e and mass m moves with velocity v about the nuclear charge Ze in the circular orbit
of radius r, then the potential energy of the electron in given by :
[1] Ze2/r [2] –Ze2/r [3] Ze2/r2 [4] mv2/r
ATOMIC STRUCTURE

Q.53 The number of electrons shared by each atom of nitrogen in nitrogen molecule is :
[1] 2 [2] 6 [3] 3 [4] 4
Q.54 If uncertainty in position of electron is zero, then the uncertainty in its momentum would be :
[1] Zero [2] h/2 [3] 3h/2 [4] Infinity
Q.55 It is known that atoms contain protons, neutrons and electrons. If the mass of neutron is assumed to be half of
its original value whereas that of electron is assumed to be twice to this original value. The atomic mass of 6C12
will be :
[1] Twice [2] 75% less [3] 25% less [4] One half of its original value
Q.56 If the energy of an electron in hydrogen atom is given by expression, –1312/n2 kJ mol–1, then the energy required
to excite the electron from ground state to second orbit is :

[1] 328 kJ/mol [2] 656 kJ/mol [3] 984 kJ/mol [4] 1312 kJ/mol
Q.57 Krypton (36Kr) has the electronic configuration (18Ar) 4s2 3d10 4p6. The 37th electron will go into which of the
following sub levels :
[1] 4f [2] 4d [3] 3p [4] 5s

Q.58 Which of the following statements is false :

[1] The energy of red photon is more than the energy of violet photon
[2] The momentum of photon is inversely proportional to its wave length
[3] The energy of a photon is inversely proportional to its wave length
[4] The particle nature of electromagnetic radiations is able to explain the photoelectric effect

Q.59 Calculate the de-Broglie wave length of the electron in the ground state of hydrogen atom, given that its kinetic
energy is 13.6 eV : (1eV = 1.602 × 10–19 J)
[1] 3.328 × 10–10 m [2] 2.338 × 10–10 m [3] 3.328 × 1010 m [4] 2.338 × 10 m
Q.60 Which of the following pair having same number of orbitals :

(a) N, O (b) O, F (c) Na, K (d) S, Cl

The correct answer is :
[1] a, b, c [2] b, c, d [3] c, d, a [4] a, b, d
Q.61 The speed of a proton is one hundredth of the speed of light in vacuum. What is its de-Broglie wavelength ?
Assume that one mole of protons has a mass equal to one gram [h = 6.626 × 10–27 erg sec] :
[1] 13.31 × 10–3 Å [2] 1.33 × 10–3 Å [3] 13.13 × 10–2 Å [4] 1.31 × 10–2 Å
Q.62 The value of charge on the oil droplets experimentally observed were – 1.6 × 10–19 and –4 × 10–19 coulomb. The
value of the electronic charge, indicated by these results is :
[1] 1.6 × 10–19 [2] –2.4 × 10–19 [3] –4 × 10–19 [4] –0.8 × 10–19
Q.63 The ratio of ionization energy of H and Be+3 is :
[1] 1 : 1 [2] 1 : 3 [3] 1 : 9 [4] 1 : 16
Q.64 Hydrogen spectrum consists of :

[1] An intense line [2] Six series of lines [3] Three series of lines [4] Four series of lines
Q.65 Which of the following salt has isoelectronic cation and anion :
[1] KF [2] NaCl [3] SrCl2 [4] MgF2
 ATOMIC STRUCTURE

Q.66 Which set of quantum numbers is possible for the last electron of Mg+ ion :

1 1
[1] n = 3, l = 2, m = 0, s = + [2] n = 2, l = 3, m = 0, s = +
2 2

1 1
[3] n = 1, l = 0, m = 0, s = + [4] n = 3, l = 0, m = 0, s = +
2 2

Q.67 The discovery of neutron became very late because :

[1] Neutrons are present in nucleus [2] Neutrons are fundamental particles

[3] Neutrons are charge less [4] All

Q.68 If E1, E2 and E3 represent respectively the kinetic energies of an electron, an alpha particle and a proton each
having same de Broglie wavelength then :

[1] E1 > E3 > E2 [2] E2 > E3 > E1 [3] E1 > E2 > E3 [4] E1 = E2 = E3

Q.69 The value of : [2p(energy) – 1s(energy)] for H-atom would be :

[1] 10.2 eV [2] 13.6 eV [3] 3.4 eV [4] None of these

Q.70 In hydrogen atom, If an electron jumps from n = 6 to n = 2, how many possible spectral lines are obtained :

[1] 15 [2] 10 [3] 6 [4] 12

Q.71 If Hund’s rule is followed, magnetic moment of Fe2+, Mn+ and Cr all having 24 electrons will be in order :

[1] Fe2+ < Mn+ < Cr [2] Fe2+ < Cr = Mn+ [3] Fe2+ = Mn+ < Cr [4] Mn2+ = Cr < Fe2+

Q.72 The speed of the electron in the 1st orbit of the hydrogen atom in the ground state is–

[1] c/1.37 [2] c/1370 [3] c/13.7 [4] c/137

Q.73 Five ionization energy values in kJ mol–1 are 834, 869, 1008, 1170, 376 shows :

[1] Successive ionization energies for the element of atomic number 5

[2] The first ionization energies for successive elements in Groups 5, 6, 7, 0 and 1

[3] The first ionization energies for elements with atomic number 1–5

[4] Successive ionization energies for transition element with 4 electron in the d-subshell

Q.74 If n and l are respectively the principal and azimuthal quantum numbers, then the expression for calculating the
total number of electrons in any energy level is :

l n l  n–1 l  n 1 l  n–1

[1]  2(2l  1)
l 0
[2] 
l 1
2(2l  1) [3] 
l 0
2(2l  1) [4] 
l 0
2(2l  1)

Q.75 If 10–17J of light energy is needed by the interior of human eye to see an object. The photons of green light
( = 550 nm) needed to see the object are :

[1] 27 [2] 28 [3] 29 [4] 30

Q.76 The potential energy of the electron present in the ground state of Li2+ ion is represent by :

3e2 3e 3e2
[1] + [2] – 4 r [3] – [4] None of these
40r 0 4 0r
ATOMIC STRUCTURE

Q.77 For the energy levels in an atom which one of the following statements is correct :

[1] The 4s sub-energy level is at a higher energy than the 3d sub-energy level

[2] The second principal energy level can have four orbitals and contain a maximum of 8 electrons

[3] The M-energy level can have maximum of 32 electrons

[4] None of these

Q.78 13.5 g of Aluminium when changes to Al+3 ion in solution, will lose :

[1] 18.0 × 1023 electrons [2] 6.022 × 1023 electrons

[3] 3.01 × 1023 electrons [4] 9.1 × 1023 electrons

Q.79 Assume that the nucleus of the F-atom is a sphere of radius 5 × 10–13 cm. What is the density of matter in
F–nucleus :

[1] 6.02 × 1011 g/ml [2] 6.02 × 1013 g/ml [3] 6.02 × 1018 g/ml [4] None

Q.80 The ionization energy of a hydrogen atom is 13.6eV. The energy of the third-lowest electronic level in doubly
ionized lithium (Z = 3) is :

[1] –28.7 eV [2] –54.4 eV [3] –122.4 eV [4] –13.6 eV

Q.81 Assuming the nucleus and an atom to be spherical, the radius of the nucleus of mass number a is given by
1.25 × 10–13 × A1/3 cm. The atomic radius of atom is 1Å. If the mass number is 64, the fraction of the atomic
volume that is occupied by the nucleus is :

[1] 1.25 × 10–13 [2] 2.50 × 10–13 [3] 5 × 10–5 [4] None

Q.82 An electron in a hydrogen atom in its ground state absorbs 1.50 times as much energy as the minimum required
for it to escape from the atom. What is the wavelength of the emitted electron :

[1] 4.70 Å [2] 4.70 nm [3] 9.4 Å [4] 9.40 nm

Q.83 For an electron in a hydrogen atom, the wave function,  is proportional to exp–(r/a0), where a0 is the Bohr’s radius.
What is the ratio of the probability of finding the electron at the nucleus to the probability of finding it at a0.

[1] e [2] e2 [3] 1/e2 [4] Zero

Q.84 Energy levels A, B, C of a certain atom corresponds to increasing values of energy, i.e., EA < EB < EC. If 1, 2 and
3 are the wavelengths of radiations corresponding to the transitions C to B, B to A and C to A respectively,
which of the following statement is correct :
C
1
B
2 3
A
1 2
[1] 3 = 1 + 2 [2] 3 =    [3] 1 + 2 + 3 = 0 [4]  23 =  12 +  22
1 2

Q.85 The energy difference between two electronic states is 46.12 kcal/mole. What will be the frequency of the light
emitted when an electron drops from the higher to the lower energy state (Planck constant = 9.52 × 10–14 kcal
sec mole–1)
[1] 4.84 × 1015 cycles sec–1 [2] 4.84 × 10–5 cycles sec–1
[3] 4.84 × 10–12 cycles sec–1 [4] 4.84 × 1014 cycles sec–1
 ATOMIC STRUCTURE

Q.86 Which of the following curves may represent the speed of the electron in a hydrogen atom as a function of the
principal quantum number n :

a
d
b
v c

[1] a [2] b [3] c [4] d

Q.87 The uncertainty in the position of an electron (mass 9.1 × 10–28 gm) moving with a velocity of 3 × 104 cm sec–1,
Accurate upto 0.011% will be :

[1] 1.92 cm [2] 7.68 cm [3] 0.175 cm [4] 3.84 cm

Q.88 A–1 kW radio transmitter operates at a frequency of 880 Hz. How many photons per second does it emit :

[1] 1.71 × 1021 [2] 1.71 × 1033 [3] 6.02 × 1023 [4] 2.85 × 1026

Q.89 Two particles A and B are in motion. It the wavelength associated with the particle A is 5.0 × 10–8 m, the
wavelength of particle B having momentum half of A is :

[1] 2.5 × 10–8 m [2] 1.25 × 10–8 m [3] 1.0 × 10–7 m [4] 1.0 × 10–8 m

Q.90 A particle A moving with a certain velocity has de Broglie wavelength of 1 Å. If particle B has mass 25% of that
A and velocity 75% of that of A, the de Broglie wavelength of B will be approximately :

[1] 1 Å [2] 5.3 Å [3] 3 Å [4] 0.2 Å

Q.91 Energy required to pull out an electron from 1st orbit of hydrogen atom to infinity is 100 units. The amount of
energy needed to pull out the electron from 2nd orbit to infinity is :

[1] 50 units [2] 100 units [3] 25 units [4] Zero

Q.92 The graphical representation of energy of e– and atomic number is :

2
E Z
E E E
[1] [2] [3] [4]
2 2 2
Z Z Z

Q.93 At atom has x energy level then total number of lines in its spectrum are :
[1] 1 + 2 + 3 ................ (x + 1) [2] 1 + 2 + 3 ................. (x)2
[3] 1 + 2 + 3 ................. (x – 1) [4] (x + 1) (x + 2) (x + 4)

Q.94 Which of the following statementsis wrong :

[1] Kinetic energy of an electron is halfof the magnitude of its potential energy
[2] Kietic energy of an electron is negative of total energy of electron
[3] Energy of an electron decreases with increases in the value of principal quantum number
[4] All of these
Q.95 If each hydrogen atom is excited by giving 8.4eV energy, then the number of spectral lines emitted is equal to:

[1] none [2] 2 [3] 3 [4] 4

ATOMIC STRUCTURE

Q.96 The orbital cylindrically symmetrical about x-axis is :

[1] pz [2] py [3] px [4] dxz

Q.97 Which of the d-orbital lies in the xy-plane :

[1] dxz only [2] dxy only [3] dx2  y2 only [4] dxy & dx2  y2 only

Q.98 The probability of finding an electron residing in a px orbital is zero in the :

[1] xy plane [2] yz plane [3] y direction [4] z direction

Q.99 If the series limit of wavelength of the Lyman series for the hydrogen atoms is 912Å, then the series limit of
wavelength for the Balmer series of the hydrogen atom is :

[1] 912 Å [2] 912 × 2 Å [3] 912 × 4 Å [4] 912/2 Å

Q.100 An element of atomic weight Z consist of two isotopes of mass number Z – 1 and Z + 2. Percentage of abundanc
of the heavier isotope is :

1 2
[1] 25 [2] 33 [3] 66 [4] 75
3 3

ANSWER KEY
Qus. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
Ans. 2 1 2 3 3 2 3 1 1 2 3 1 4 4 1 3 2 1 3 1
Qus. 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40
Ans. 2 1 1 3 4 4 3 1 4 1 2 4 2 2 4 4 2 1 1 2
Qus. 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
Ans. 4 1 1 3 4 3 4 2 3 2 3 2 2 4 3 3 4 1 1 4
Qus. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80
Ans. 2 1 4 2 4 4 3 4 1 2 2 4 2 4 2 3 3 4 2 4
Qus. 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100
Ans. 1 1 4 2 4 3 3 2 3 2 3 4 3 3 1 3 3 2 3 2
 ATOMIC STRUCTURE

EXERCISE-2
Q.1 From the given sets of quantum numbers the one that is inconsistent with the theory is :

[1] n = 3, l = 2, m = – 3, s = + 1/2 [2] n = 4, l = 3, n = 3, s = + 1/2

[3] n = 2, l = 1, m = 0, s = – 1/2 [4] n = 4, l = 3, m = 2, s = + 1/2

Q.2 The size of nucleus is measured in :

[1] amu [2] Angstrom [3] Fermi [4] cm

Q.3 The total number of electrons present in all the p-orbitals of bromine are :

[1] Five [2] Eighteen [3] Seventeen [4] Thirty five

Q.4 When an electron revolves in a stationary orbit then :

[1] It absorbs energy [2] It gains kinetic energy

[3] It emits radiation [4] Its energy remains constant

Q.5 The total number of valence electrons in 4.2 gm of N3– ion is (NA is the Avogadro’s number) :

[1] 1.6 NA [2] 3.2 NA [3] 2.1 NA [4] 4.2 NA

Q.6 If n = 3, then the value of ‘’ which is incorrect :

[1] 0 [2] 1 [3] 2 [4] 3

Q.7 Chlorine atom differs from chloride ion in the number of :

[1] Proton [2] Neutron [3] Electrons [4] Protons and electrons

Q.8 The uncertainty in the position of an electron (mass = 9.1 × 10–28 g) moving with a velocity of 3.0 × 104 cm s–1

h
accurate upto 0.001% will be (use in the uncertainty expression, where h = 6.62 × 10–27 erg-s)
4

[1] 1.92 cm [2] 7.68 cm [3] 5.76 cm [4] 3.84 cm

Q.9 A 3p orbital has :

[1] Two spherical nodes [2] Two non-spherical nodes

[3] One spherical and one non-spherical nodes [4] One spherical and two non-spherical nodes

Q.10 Zeeman effect refers to the :

[1] Splitting up of the lines in an emission spectrum in a magnetic field

[2] Splitting up to the lines in an emission spectrum in the presence of an external electrostatic field

[3] Emission of electrons from metals when light falls upon them

[4] Random scattering of light by colloidal particles

Q.11 For n = 3 energy level, the number of possible orbitals are :

[1] 1 [2] 3 [3] 4 [4] 9

Q.12 The orbital angular momentum of an electron in 2s orbital is :

1 h h h
[1] + . [2] Zero [3] [4] 2 . 2
2 2 2
ATOMIC STRUCTURE

Q.13 Which statement is not correct for n = 5, m = 3 :

[1] l = 4 [2] l = 0, 1, 2, 3 ; s = + 1/2

[3] l = 3 [4] All are correct

2 2 5 2
Q.14 1s , 2s 2p 3s shows configuration of :

[1] Al+3 in ground state [2] Ne in excited state

[3] Mg+1 in excited stated [4] All are correct

Q.15 In a Bohr’s model of atom when an electron jumps from n = 1 to n = 3, how much energy will be emitted or
absorbed :

[1] 2.15 × 10–11 ergs [2] 0.1911 × 10–10 ergs [3] 2.389 × 10–12 ergs [4] 0.239 × 10–10 ergs

Q.16 The shape of an orbital is given by the quantum number :

[1] n [2] l [3] m [4] s

Q.17 Which of the following metal ions will have maximum number of unpaired electrons :

[1] Fe+2 [2] Co+2 [3] Ni+2 [4] Mn+2

Q.18 The maximum probability of finding an electron in the dxy orbital is :

[1] Along the x-axis [2] Along the y-axis

[3] At an angle of 45º from the x and y-axes [4] At an angle of 90º from the x and y-axes

Q.19 CO has same electrons as or the ion that is isoelectronic with CO is :

[1] N2+ [2] CN– [3] O2+ [4] O–2

Q.20 The total number of orbital in an energy level designated by principal quantum number n, is equal to :

[1] 2n [2] 2n2 [3] n [4] n2

Q.21 Which electronic level would allow the hydrogen atom to absorb a photon but not to emit a photon :

[1] 3s [2] 2p [3] 2s [4] 1s

Q.22 An electron has principal quantum number 3. The number of its :

(i) subshells and (ii) orbitals would be respectively

[1] 3 and 5 [2] 3 and 7 [3] 3 and 9 [4] 2 and 5

Q.23 Aufbau principle is not satisfied by :

[1] Cr and Cl [2] Cu and Ag [3] Cr and Mg [4] Cu and Na

Q.24 The first use of quantum theory to explain the structure of atom was made by :

[1] Heisenberg [2] Bohr [3] Planck [4] Einstein

Q.25 Five valence electrons of 15P are labelled as . If the spin quantum number of B and Z is + 1/2, the

group of electrons with three of the quantum number same are :

[1] Ab, XYZ, BY [2] AB [3] XYZ, AZ [4] AB, XYZ

Q.26 In an element going away from nucleus, the energy of particle :

[1] Decreases [2] Unchanged [3] Increases [4] None of these

 ATOMIC STRUCTURE

Q.27 In neutral atom, which particles are equivalent :

[1] p+, e+ [2] e–, e+ [3] e–, p+ [4] p+, n0

Q.28 If n + l = 6, then total possible number of subshells would be :

[1] 3 [2] 4 [3] 2 [4] 5

Q.29 The configuration 1s2 2s2 2p5 3s1 shows :

[1] Ground state of fluorine atom [2] Excited state of fluorine atom

[3] Excited state of neon atom [4] Excited state of ion O2– ion

Q.30 The electron configuration of gadolinium (atomic no. 64) is :

[1] [Xe] 4f8 5d9 6s2 [2] [Xe] 4f7 5d1 6s2 [3] [Xe] 4f3 5d5 6s2 [4] [Xe] 4f6 5d2 6s2

Q.31 If electron falls from n = 3 to n = 2, then emitted energy is :

[1] 10.2 eV [2] 12.09 eV [3] 1.9 eV [4] 0.65 eV

Q.32 Number of protons, neutrons and electrons in the element 89X231 is :

[1] 89, 231, 89 [2] 89, 89, 242 [3] 89, 142, 89 [4] 89, 71, 89

Q.33 In the ground state configuration of Cr24 how many orbitals are present having paired and unpaired electrons :

[1] 10 [2] 12 [3] 15 [4] 16

Q.34 Discoverer of positron :

[1] Paulling [2] Anderson [3] Yukawa [4] Segre

Q.35 Which of the following species not contains neurtrons :

[1] H [2] Li+2 [3] C [4] O

Q.36 The energy of an electron in the first Bohr orbit of H atom is – 13.6 eV. The possible energy value of the first
excited state for electrons in Bohr orbits to hydrogen is (are) :

[1] – 3.4 eV [2] – 4.2 eV [3] – 6.8 eV [4] + 6.8 eV

Q.37 The energy of an electron in the first orbit of He+ is – 871.6 × 10–20 J. The energy of the electron in the first orbit
of hydrogen would be :

[1] – 871.6 × 10–20 J [2] – 435.8 × 10–20 J [3] – 217.9 × 10–20 J [4] – 108.9 × 10–20 J

Q.38 The position of both an electron and a helium atom is known within 1.0 nm and the momentum of the electron is
known within 50 × 10–26 kg ms–1. The minimum uncertainty in the measurement of the momentum of the helium
atom is :

[1] 50 kg ms–1 [2] 60 kg ms–1 [3] 80 × 10–26 kg ms–1 [4] 50 × 10–26 kg ms–1

Q.39 The Bohr orbit radius for the hydrogen atom (n = 1) is approximately 0.530 A. The radius for the first excited state
(n = 2) orbit is :

[1] 0.13 Å [2] 1.06 Å [3] 4.77 Å [4] 2.12 Å

Q.40 Which of the following explain the sequence of filling the electrons in different orbitals :

[1] Hund’s rule [2] Octet rule [3] Aufbau principle [4] All of these

Q.41 Number of orbitals having paired electrons for gaseous Fe are :

[1] 4 [2] 11 [3] 15 [4] 19

ATOMIC STRUCTURE

Q.42 [Ar] 3d6 is the configuration of the following ion :

[1] Fe+2 [2] Ti+3 [3] Co+2 [4] Cr+3

Q.43 Which triad of quantum number [n, l, m] is not applicable for 3d-electron :

[1] 3, 2, 0 [2] 3, 1 –1 [3] 3, 2, – 2 [4] 3, 2, +1

Q.44 Which of the following configuration follows the Hund’s rule :

2s 2p 2s 2p
[1] [He]    [2] [He]   

2s 2p 2s 2p
[3] [He]    [4] [He]   

Q.45 The ratio of radii of 3rd and 2nd Bohr’s orbit of hydrogen atom is :

[1] 3 : 2 [2] 4 : 9 [3] 9 : 4 [4] 9 : 1

Q.46 The four quantum number for the valence shell electron or last electron of sodium is :

[1] n = 2,  = 1, m = – 1, s = – 1/2 [2] n = 3,  = 0, m = 0, s = + 1/2

[3] n = 3,  = 2, m = – 2, s = – 1/2 [4] n = 3,  = 2, m = 2, s = + 1/2

Q.47 Heaviest particle is :

[1] Meson [2] Neutron [3] Proton [4] Electron

Q.48 Which is correct statement about proton :

[1] Proton is nucleus of deuterium [2] Proton is ionized hydrogen molecule

[3] Proton is ionized hydrogen atom [4] Proton is -particle

th
Q.49 The energy of an electron in n orbit of hydrogen atom is :

13.6 13.6 13.6 13.6

[1] – eV [2] – eV [3] – eV [4] – eV
n4 n3 n2 n

Q.50 If wavelength of photon is 2.2 × 10–11 m, h = 6.8 × 10–34 Js, then momentum of photon is :

[1] 3 × 10–23 Kg ms–1 [2] 3.33 × 1022 Kg ms–1

[3] 1.452 × 10–44 kg ms–1 [4] 6.89 × 1043 kg ms–1

Q.51 The electrons identified by quantum number n and l

(i) n = 4, l = 1 (ii) n = 4, l = 0 (iii) n = 3, l = 2 (iv) n = 3, l = 1

can be placed in order of increasing energy from the lowest to highest, as :

[1] (iv) < (ii) < (iii) < (i) [2] (ii) < (iv) < (i) < (iii)

[3] (i) < (iii) < (ii) < (iv) [4] (iii) < (i) < (iv) < (ii)

Q.52 Ground state electron configuration of nitrogen atom can be represent by :

[1]      [2]      [3]      [4] None of these

Q.53 Which of the following has more unpaired d-electron :

[1] Zn+ [2] Fe2+ [3] Ni3+ [4] Cu+

 ATOMIC STRUCTURE

Q.54 The uncertainty in momentum of an electron is 1 × 10–5 kg-m/s. The uncertainty in its position will be :

[1] 1.05 × 10–28 m [2] 1.05 × 10–26 m [3] 5.27 × 10–30 m [4] 5.25 × 10–28 m

Q.55 The de-Broglie wavelength of a particle with mass 1g and velocity 100 m/s is :

[1] 6.63 × 10–33 m [2] 6.63 × 10–34 m [3] 6.63 × 10–35 m [4] 6.65 × 10–35 m

Q.56 Which of the following set of quantum numbers belong to highest energy :

1 1
[1] n = 4, l = 0, m = 0, s = + [2] n = 3, l = 0, m = 0, s = +
2 2

1 1
[3] n = 3, l = 1, m = 1, s = + [4] n = 3, l = 2, m = 1, s = +
2 2

Q.57 Which of the following are isoelectronic species :

I – CH+3, II – NH2–, III – NH+4, IV – NH3

[1] I, II, III [2] II, III, IV [3] I, II, IV [4] I and II

Q.58 Which quantum number will determine the shape of the subshell :

[1] Principal quantum number [2] Azimuthal quantum number

[3] Magnetic quantum number [4] Spin quantum number

Q.59 A metal in its di positive state has the electronic configuration 2, 8, 14 and has the atomic weight equal to 56.
Number of neutrons in its nucleus would be :

[1] 30 [2] 32 [3] 34 [4] 28

Q.60 Which set of quantum number for an electron of an atom is not possible :

1 1
[1] n = 1, l = 0, m = 0, s = + [2] n = 1, l = 1, m = 1, s = +
2 2

1 1
[3] n = 1, l = 0, m = 0, s = – [4] n = 2, l = 1, m = – 1, s = +
2 2

Q.61 Outer electronic configuration of the element of atomic number 24 is :

[1] 3s2 3p6 3d5 4s1 [2] 3s2 3p6 3d4 4s2 [3] 3s2 3p6 3d6 [4] None

Q.62 The basis of three unpaired electrons in the configuration of nitrogen is :

[1] Aufbau principle [2] Pauli’s principle [3] Hund’s principle [4] Uncertainty principle

Q.63 Correct order of size is :

[1] I > I+ > I– [2] I > I– > I+ [3] I– > I > I+ [4] I+ > I > I–

Q.64 Which is not electromagnetic radiation :

[1] Infrared rays [2] X–ray [3] Cathode rays [4] Gamma rays

Q.65 Which of the following pair of orbitals posses two nodal planes :

[1] pxy, dx2 – y2 [2] dxy, dzx [3] pyz, dzx [4] dz2 , dx2 – y2
ATOMIC STRUCTURE

Q.66 The mass of a neutron is of the order of :

[1] 10–23 kg [2] 10–24 kg [3] 10–26 kg [4] 10–27 kg

Q.67 Smallest cation is :

[1] Na+ [2] Mg2+ [3] Ca2+ [4] Al3+

Q.68 Electron enters the sub-shell for which (n + l) value is minium. This is enunciated as :

[1] Hund’s rule [2] Aufbau principle

[3] Heisenberg uncertainty principle [4] Pauli’s exclusion principle

Q.69 The minium real charge on any particle which can exist is :

[1] 1.6 × 10–19 coulomb [2] 1.6 × 10–10 coulomb

[3] 4.8 × 10–10 coulomb [4] Zero

Q.70 Which sub-shell is not permissible :

[1] 2d [2] 4f [3] 6p [4] 3s

Q.71 Sub-shell designated by azimuthal quantum number l = 3 can have maximum number of electrons :

[1] 14 [2] 6 [3] 10 [4] 0

Q.72 Quantum number n = 3, l = 2, m = + 2 shows how many orbitals :

[1] 1 [2] 2 [3] 3 [4] 4

Q.73 Which is isoelectronic with sulphide ion :

[1] Cl [2] Ne [3] Ar [4] Kr

Q.74 Ground state electronic configuration of nitrogen is :

1 1
[1] 1s2, 2s2, 2p 1x , 2p y , 2p 1z [2] 1s2, 2s2, 2px2, 2p y

[3] 1s2, 2s2, 2px2, 2pz1 [4] 1s2, 2s2, 2px3

Q.75 In the Bohr’s orbit, what is the ratio of total kinetic energy and total energy of electron :

[1] – 1 [2] – 2 [3] 1 [4] + 2

Q.76 Rutherford -particle dispersion experiment concludes :

[1] All positive ions are deposited at small part [2] All negative ions are deposited at small part

[3] Protons moves around the electrons [4] Neutrons are charged particles

Q.77 Which of the following element outermost orbit’s last electron has magnetic quantum number m = 0 ?

[1] Na [2] O [3] Cl [4] N

Q.78 The value of Planck’s constant is 6.63 × 10–34 Js. The velocity of light is 3.0 × 108 m s–1. Which value is closest
to the wavelength in nanometers of a quantum of light with frequency of 8 × 1015 s–1 ?

[1] 5 × 10–18 [2] 4 × 101 [3] 3 × 107 [4] 2 × 10–25

h
Q.79 The orbital angular momentum for an electron revolving in an orbit is given by l (l  1) . . This momentum for
2
an s-electron will be given by :

h 1 h h
[1] 2. [2] + . [3] zero [4]
2 2 2 2
 ATOMIC STRUCTURE

Q.80 The number of d-electrons retained in Fe2+ (At. no. of Fe = 26) ion is :

[1] 6 [2] 3 [3] 4 [4] 5

Q.81 The de Broglie wavelength of a tennis ball of mass 60 g moving with a velocity of 10 metres per second is
approximately :

[1] 10–25 metres [2] 10–33 metres [3] 10–31 metres [4] 10–16 metres

Q.82 In Bohr series of lines of hydrogen spectrum, the third line from the red end corresponds to which one of the
following inter-orbit jumps of the electron for Bohr orbits in an atom of hydrogen ?

[1] 2  5 [2] 3  2 [3] 5  2 [4] 4  1

Q.83 Which of the following sets of quantum number is correct for an electron in 4f orbital ?

1 1
[1] n = 3, l = 2, m = – 2, s = + [2] n = 4, l = 4, m = – 4, s = –
2 2

1 1
[3] n = 4, l = 3, m = + 1, s = + [4] n = 4, l = 3, m = + 4, s = +
2 2

Q.84 consider the ground state of Cr atom (Z = 24). The numbers of electrons with the azimuthal quantum numbers,
l = 1 and 2 are, respectively :

[1] 16 and 5 [2] 12 and 5 [3] 16 and 4 [4] 12 and 4

Q.85 The wavelength of the radiation emitted, when in a hydrogen atom electron falls from infinity to stationary state
1, would be (Rydberg constant = 1.097 × 107 m –1) :

[1] 9.1 × 10–8 nm [2] 192 nm [3] 406 nm [4] 91 nm

Q.86 Which one of the following sets of ions represents the collection of isoelectronic species ?

[1] Na+, Mg2+, Al3+, Cl– [2] Na+, Ca2+, Sc3+, F– [3] K+, Cl–, Mg2+, Sc3+ [4] K+, Ca2+, Sc3+, Cl–

Q.87 Consider the following nuclear relations :

238
92 M xy N  2 24He x
y N BA L  2

The number of neutrons in the element L is :

[1] 146 [2] 144 [3] 140 [4] 142

Q.88 Which of the following have same radius as hydrogen n = 1 :

[1] He+, n = 2 [2] Be+3, n = 2 [3] Li+2, n =2 [4] Li+2, n = 3

ANSWER KEY
Qus. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
Ans. 1 3 3 4 1 4 3 1 3 1 4 2 2 3 2 2 4 3 2 4
Qus. 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40
Ans. 4 3 2 2 4 3 3 1 3 2 3 3 3 2 1 1 3 4 4 3
Qus. 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
Ans. 2 1 2 1 3 2 2 3 3 1 1 1 2 3 1 4 2 2 1 2
Qus. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80
Ans. 1 3 3 3 2 4 4 2 1 1 1 1 3 1 1 1 1 2 3 1
Qus. 81 82 83 84 85 86 87 88
Ans. 2 3 3 2 4 4 2 2
ATOMIC STRUCTURE

N OT E S
 ATOMIC STRUCTURE
CO NT EN TS
1. ATOM & MOLECULE
2. DALTON’S ATOMIC THEORY
2.1 Modern Concept
3. CATHODE RAYS
3.1 Nature of Cathode rays
4. POSITIVE RAYS
4.1 Properties of Positive rays
4.2 Nature of Positive rays
5. PROTON
6. ELECTRON
7. DISCOVERY OF NEUTRON
7.1 Neutron
8. OTHER PARTICLE OF ATOM
9. CLASSIFICATION OF ATOMIC PARTICLES
9.1 Stable Particle 9.2 Unstable Particle
9.3 Distinction of a, b and g rays
10. NUCLEUS
10.1 Nuclear Forces 10.2 Nuclear Stability
11. NUCLEAR CHARGE AND ATOMIC NUMBER
12. ATOMIC WEIGHT OR MASS NUMBER
13. IONS
14. ISOTOPES
15. ISOBARS
16. ISOTONES
17. ISOELECTRONIC
18. ATOMIC MODEL
18.1 Thomson’s Atomic model
18.2 Ruther ford’s Atomic model
18.2.1 Weight – weight percent
18.3 Bohr’s Atomic model
19. CALCULATION OF VELOCITY OF ELECTRON OF BOHR’S ORBIT
20. RADIUS OF BOHR’S ORBIT
21. ENERGY OF BOHR’S ORBIT
21.1 Kinetic Energy 21.2 Potential Energy
21.3 Total Energy 21.4 Calculation of Energy
21.5 Quantization of Electronic Energy levels
21.6 Ground State 21.7 Excited State
21.8 Excitation Potential 21.9 Ionisation Energy
21.10 Separation Energy
22 SPECTRAL EVIDENCE FOR QUANTIZATION
23. EMISSION SPECTRUM AND ABSORPTION SPECTRUM
23.1 Emission Spectrum
23.1.1 Continuous Spectrum
24.1.2 Line Spectrum
23.2 Absorption Spectrum
23.3 Molecular Spectrum
24. HYDROGEN SPECTRUM
24.1 Series of Lines in Hydrogen Spectrum
24.1.1 Lymen Series 24.1.2 Balmer Series
24.1.3 Paschen Series 24.1.4 Brackett Series
25.1.5 Pfund Series
25.1.6 Humphry
25. FAILURES OF BOHR’S ATOMIC MODEL
26. SO MME RFE LD MOD EL
27. WAVE THEORY OF LIGHT
27.1 Wavelength 27.2 Frequency
27.3 Velocity of light 27.4 Amplitude
27.5 Wave number
28. PLANCK’S QUANTUM THEORY
29. DUEL NATURE OF MATTER
30. BOHR’S THEORY & de-BROGLIE CONCEPT
31. QUANTUM MECHANICAL THEORY OF ATOM
31.1 Heisenberg Uncertainty Principle
31.2 Schrodinger’s Wave Equation
32. QU ANT UM N UMB ER
32.1 Principal Quantum Number
32.2 Azimuthal Quantum Number
32.3 Magnetic Quantum Number
32.4 Spin Quantum Number
33. AUFBAU PRINCIPLE
33.1 Pauli’s Exclusion Principle
33.2 Hund’s Rule
33.3 n + l Rule
34.4 Stabilityoffillingorfullfilled
34. MODE OF FILLING ORBITAL
35. DIFFERENCE BETWEEN ORBIT & ORBITAL
36. ORBITAL
36.1 s-Orbital 36.2 p-Orbital
36.3 d-Orbital 36.4 f-Orbital
37. CONTRIBUTION OF SOME SCIENTIST
38. IMPORTANT POINTS
39. SOLVED EXAMPLE
40. EXERCISE # 1
41. EXERCISE # 2 (Previous Competitive exam. Question)