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    SR Polar

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    amritrath
    The SR-POLAR property method is an extension of the Redlich-Kwong-Soave equation of state that can be applied to both non-polar and highly polar components at high temperatures and pressures. It requires polar parameters for polar components and binary parameters for accurate phase equilibria modeling, though these can be estimated if not provided. SR-POLAR provides an alternative to activity coefficient methods like WILSON for modeling nonideal systems.

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    SR Polar

    Uploaded by

    amritrath
    1K views1 page
    The SR-POLAR property method is an extension of the Redlich-Kwong-Soave equation of state that can be applied to both non-polar and highly polar components at high temperatures and pressures. It requires polar parameters for polar components and binary parameters for accurate phase equilibria modeling, though these can be estimated if not provided. SR-POLAR provides an alternative to activity coefficient methods like WILSON for modeling nonideal systems.

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    SR Polar

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    SR POLAR

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    The SR-POLAR property method is an extension of the Redlich-Kwong-Soave equation of state that can be applied to both non-polar and highly polar components at high temperatures and pressures. It requires polar parameters for polar components and binary parameters for accurate phase equilibria modeling, though these can be estimated if not provided. SR-POLAR provides an alternative to activity coefficient methods like WILSON for modeling nonideal systems.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    1K views1 page

    SR Polar

    Uploaded by

    amritrath
    The SR-POLAR property method is an extension of the Redlich-Kwong-Soave equation of state that can be applied to both non-polar and highly polar components at high temperatures and pressures. It requires polar parameters for polar components and binary parameters for accurate phase equilibria modeling, though these can be estimated if not provided. SR-POLAR provides an alternative to activity coefficient methods like WILSON for modeling nonideal systems.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 1

    SR-POLAR

    The SR-POLAR property method is based on an equation-of-state model by Schwarzentruber and Renon,
    which is an extension of the Redlich-Kwong-Soave equation of state. You can apply the SR-POLARmethod
    to both non-polar and highly polar components, and to highly nonideal mixtures. This method is
    recommended for high temperature and pressure applications

    SR-POLAR requires:

    Polar parameters for polar components. These parameters are determined automatically using vapor
    pressure data generated from the General Pure Component Liquid Vapor Pressure model.
    Binary parameters to accurately represent phase equilibria. The binary parameters are temperature-
    dependent.

    If you do not enter binary parameters, the Aspen Physical Property System estimates them automatically
    using VLE data generated from the UNIFAC group contribution method. Therefore, the SR-POLAR
    property method is predictive for any interaction that UNIFAC can predict at low pressures. The accuracy of
    the prediction decreases with increasing pressure. You cannot use UNIFAC to predict interactions with light
    gases.

    SR-POLAR is an alternative property method that you can use for nonideal systems, instead of using an
    activity coefficient property method, such as WILSON.

    Parameter requirements for the SR-POLAR property method are in the tables labeled Parameters Required
    for the SR-POLAR Property Method (see below) and Parameters Required for Common Flexible and
    Predictive Models. For details about optional parameters, and calculation of pure component and mixture
    properties, see Physical Property Models.

    Mixture Types
    You can use the SR-POLAR property method for mixtures of non-polar and polar compounds, in
    combination with light gases.

    Range
    You can use the SR-POLAR property method up to high temperatures and pressures. You can expect fair
    predictions up to about 50 bar. You can expect reasonable results at any condition, provided UNIFAC
    interaction parameters are available. But results are least accurate close to the critical point.

    Parameters Required for the SR-POLAR Property Method


    Thermodynamic Properties Models Parameter Requirements
    Vapor and liquid mixture Schwartzentruber-Renon TC, PC, OMEGA, Optional:
    Fugacity coefficient, RKUPPn, RKUCn,
    Density RKUKAn, RKULAn, RKUKBn
    n = 0, 1, 2
    Enthalpy, General pure component ideal (CPIG or CPIGDP)
    Entropy, gas heat capacity
    Gibbs energy
    Schwartzentruber-Renon Optional:
    RKUPPn, RKUCn,
    RKUKAn, RKULAn, RKUKBn
    n = 0, 1, 2

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