CHEMISTRY SOLUTIONS

1-YEAR
FINAL TEST
PAPER-2

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XII CHEMISTRY FINAL TEST PAPER-2
Q.31 Select the correct statement
(A*) [Fe(NO)(H2O)5]SO4 is coloured because of d–d transition
(B) [Fe(NO)(H2O)5]SO4 is coloured because of charge transfer
(C*) [Fe(NO)(H2O)5]SO4 is brown ring
(D*) [Fe(NO)(H2O)5]SO4 is high spin complex

Q.32 Select the correct statement(s):

(A*) ∆G > 0 for oxidation-reduction reaction (Redox) performed in electrolytic cell
(B*) The rate constants of the forward & reverse reactions are equal at chemical equilibrium.
(C) Molar conductivity for a strong electrolyte increases as the electrolyte concentration increases.
228
(D) 89 Ac is a member of 4n + 3 series.

NaOH
Q.33 (A) →
∆

Reactant (A) is
O O O O
|| || || ||
(A) CH 3 − C − (CH 2 )5 − C − CH 3 (B*) CH 3 − C − (CH 2 ) 4 − C − H

O O O
|| || ||
(C) H − C − (CH 2 )5 − C − H (D) CH 3 − C − (CH 2 ) 4 − CH 2 − OH
[Sol: e.g. of intramolecular aldol condensation

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Q.34 Saturated solution of SO2 is heated at 150°C in a closed container. The product obtained is treated
with BaCl2 solution. What is/are the most suitable observation(s)
(A) No ppt. (B) white turbidity
(C) evolution of SO2 (D*) The turbidity becomes white ppt

O
|| CH N 2 CH CO 3H
Q.35 CH 3 − C − CH 2 − CH 3 2→ A (Major) 3  → B (Major)
Product B is:
O O
|| ||
(A) CH 3 − O − C − CH 2 − CH 2 − CH 3 (B*) CH 3 − C − O − CH 2 − CH 2 − CH 3

O O
|| ||
(C) CH 3 − CH 2 − C − O − CH 2 − CH 3 (D) CH 3 − C − O − CH 2 − CH 3
[Sol:

Q.36 Which reaction is(are) possible

(A) MgCl2 + NaNO3 → (B) BaSO4 + HCl →
(C*) ZnSO4 + BaS → (D*) BaCO3 + CH3COOH →

PCl
Q.37 5 → (A)
∆

Identify product (A). Name of the reaction.

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 O
||
(A) NH − C Cl, Beckmann rearrangement

O
||
(B) C − NH Cl, Hoffmann bromamide reaction

O
||
(C) NH − C Cl, Hoffmann bromamide reaction

O
||
(D*) C − NH Cl, Beckmann rearrangement

[Sol: e.g. of Beckmann rearrangement

That group migrate which is anti to –OH group
Ans: (D) ]

Q.38 Which of the following complex are coloured

(A*) MnO4– (B*) CrO42– (C*) Cr2O72– (D*) MnO42–

Q.39 Compound (X) C4H8O, which gives 2,4-Dinitrophenyl hydrazine derivative and negative haloform
test.
O
||
(A) CH 3 − C − CH 2 − CH 3 (B*) CH 3 − CH − CHO
|
CH 3
(C) (D*) CH3 – CH2 – CH2 – CHO

[Sol. (B) & (D) due to absence of Keto methyl group]

Q.40 Which of the following statements is/are true

(A*) In Ferrocyanide ion, the effective atomic number is 36
(B*) Chelating ligands are atleast bidentate ligands
(C*) [CrCl 2 (CN) 2 ( NH 3 ) 2 ]– and [CrCl3(NH3)3] both have d2sp3 hybridisation
(D*) As the number of rings in complex increases, stability of complex (chelate) also increases

Q.41 Which of following reaction product is Diastereomer.

Br
(A*) 2 → (B*) (
i ) NaCN
→
CCl4 (ii ) H +

(C) HBr
→ (D*) CH 3 − CH − CH = CH − Ph HCl →
CCl4 peroxide
|
Et
[Sol: A, B, D form threo and erythro diastereomers. In ‘C’ we get racemic mixture.]

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Q.42 Select the correct statement
(A*) Resonance energy is temperature dependent
(B*) 4d & 5d series metals forms low spin complex
(C*) Cisplatin express geometrical isomerism
(D*) Benzene reacts with CrCl3 and forms organometallic compound

Q.43 Which among the following are correctly matched

(A) (B*) 2 C = O + HCl+ ZnCl2

NaNH
2 / NH3
→ H   →

HNO
 +  →  O →
(C*) Ac O
3 2
(D*)
||
CH 3 − C − NO 3
[Sol: (A) Aryne mechanism


→
– →
NaNH
 H
N 3 due to –I effect of OMe
2
– NH 3
– NaCl
(B) e.g. of chloromethylation
2HCl + 2ZnCl2 → ZnCl42– + 2H+
.. +
H2C = O
. . + H → H2C = O H
+

HCl

→
− H 2O

(C) HNO3 + Ac2O → O–Pdt + (major) six membered ring formation and high polarisability of
− NH − C − O
||
O
(D) Acetyl nitrate O–Product is major
Ans: B, C, D ]

Q.44 The correct order of energies of d-orbitals of metal ion in a square planar complex is
(A) dxy = dyz = dzx > d =d (B) d = d 2 > dxy = dyz = dzx
x 2 − y2 z2 x 2 − y2 z

(C) d >d > dxy > dyz = dzx (D*) d > dxy > d > dzx = dyz
x 2 − y2 z2 x 2 − y2 z2

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Q.45 In the given reaction:

[X]

[X] is:

(A) 2 moles (B*)

(C) one mole (D) All of these

[Sol: e.g. of wittig reaction

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