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    Safety Data Sheet in Accordance With Regulation (EC) No 1907/2006

    Uploaded by

    Fiaz jutt
    This document provides safety information for Arkofix ELF liq c. It identifies the product and company details, lists methanol and diethylene glycol as hazardous ingredients, and outlines first aid measures, firefighting methods, accidental release measures, handling and storage guidelines, exposure controls, and physical/chemical properties. Toxicity testing on similar formulations found the product to have an oral LD50 over 2000 mg/kg, be non-irritating to skin and eyes, and non-sensitizing.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd

    Safety Data Sheet in Accordance With Regulation (EC) No 1907/2006

    Uploaded by

    Fiaz jutt
    141 views7 pages
    This document provides safety information for Arkofix ELF liq c. It identifies the product and company details, lists methanol and diethylene glycol as hazardous ingredients, and outlines first aid measures, firefighting methods, accidental release measures, handling and storage guidelines, exposure controls, and physical/chemical properties. Toxicity testing on similar formulations found the product to have an oral LD50 over 2000 mg/kg, be non-irritating to skin and eyes, and non-sensitizing.

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    This document provides safety information for Arkofix ELF liq c. It identifies the product and company details, lists methanol and diethylene glycol as hazardous ingredients, and outlines first aid measures, firefighting methods, accidental release measures, handling and storage guidelines, exposure controls, and physical/chemical properties. Toxicity testing on similar formulations found the product to have an oral LD50 over 2000 mg/kg, be non-irritating to skin and eyes, and non-sensitizing.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    141 views7 pages

    Safety Data Sheet in Accordance With Regulation (EC) No 1907/2006

    Uploaded by

    Fiaz jutt
    This document provides safety information for Arkofix ELF liq c. It identifies the product and company details, lists methanol and diethylene glycol as hazardous ingredients, and outlines first aid measures, firefighting methods, accidental release measures, handling and storage guidelines, exposure controls, and physical/chemical properties. Toxicity testing on similar formulations found the product to have an oral LD50 over 2000 mg/kg, be non-irritating to skin and eyes, and non-sensitizing.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 7

    Safety Data Sheet in accordance with Regulation (EC) No

    1907/2006
    Arkofix ELF liq c Page 1

    Substance key: 000000312612 Revision Date: 04.06.2009


    Version : 3 - / EU Date of printing : 14.09.2009

    1. Identification of the substance/preparation and of the company/undertaking

    Trade name
    Arkofix ELF liq c
    Material number: 230161
    Use of the substance/preparation.
    Industry sector : Textile processing industry
    Type of use : Textile finishing
    Identification of the company
    Clariant Production (France)

    Usine de Lamotte
    60350 Trosly Breuil
    Telephone no. : +33 3 44 85 40 00
    Information about the substance/preparation
    Product Safety Dpt.
    tel.: +33 1 46 96 97 82
    e-mail: France.ProductSafety@clariant.com
    Emergency telephone number : +33 1 45 42 59 59 (24 h)

    2. Hazards identification
    Does not require a hazard warning label, but the normal safety precautions for handling
    chemicals must be observed.

    3. Composition/information on ingredients
    Chemical characterization
    N-Methyloldihydroxyethylenurea modified aqueous medium

    Hazardous ingredients
    Methanol
    Concentration : <= 3 %
    CAS number : 67-56-1
    EINECS number : 200-659-6
    Hazard symbols F T
    R phrases 11 23/24/25 39/23/24/25
    Diethylene glycol
    Concentration : <= 25 %
    CAS number : 111-46-6
    EINECS number : 203-872-2
    Hazard symbols Xn
    R phrases 22
    The text of the R-phrases is shown in section 16.

    4. First aid measures


    Safety Data Sheet in accordance with Regulation (EC) No
    1907/2006
    Arkofix ELF liq c Page 2

    Substance key: 000000312612 Revision Date: 04.06.2009


    Version : 3 - / EU Date of printing : 14.09.2009

    General information
    Remove soiled or soaked clothing immediately
    After inhalation
    When inhaled remove to fresh air and seek medical aid.
    After contact with skin
    In case of contact with skin wash off immediately with plenty of water
    After contact with eyes
    In case of contact with eyes rinse thoroughly with plenty of water and seek medical advice
    After ingestion
    Call in a physician immediately and show him the Safety Data Sheet.

    5. Fire-fighting measures
    Suitable extinguishing media
    Product itself is non-combustible; Fire extinguishing method of surrounding areas must be
    discussed.
    Special hazards from the substance itself, its combustion products or from its vapours
    In the event of fire the following can be released:
    Carbon dioxide (CO2)
    Carbon monoxide (CO)
    Special protective equipment for firefighting
    Use self-contained breathing apparatus
    Wear full protective suit.
    Further information
    Fire residues must be disposed of in a proper manner

    6. Accidental release measures


    Personal precautions
    Ensure adequate ventilation.
    Environmental precautions
    Do not allow to enter drains or waterways
    Methods for cleaning up/taking up
    Cover with absorbent material (eg sand, peat, earth) and then pick it up.
    Dispose of contaminated material as prescribed

    7. Handling and storage


    Safety Data Sheet in accordance with Regulation (EC) No
    1907/2006
    Arkofix ELF liq c Page 3

    Substance key: 000000312612 Revision Date: 04.06.2009


    Version : 3 - / EU Date of printing : 14.09.2009

    Advice on safe handling


    It cannot be ruled out, that traces of following substances are present.
    Formaldehyde
    Ensure adequate ventilation.
    Local exhaust ventilation.
    It cannot be ruled out, that traces of following substances are present.
    Methanol
    Formaldehyde
    Ensure adequate ventilation.
    Local exhaust ventilation.
    Advice on protection against fire and explosion
    Observe the general rules of industrial fire protection
    Requirements for storage rooms and vessels
    Keep only in the original container
    Further information on storage conditions
    Keep container tightly closed in a cool, well-ventilated place
    Storage temperature should not exceed 40 C
    - sensitive to frost - In case of the product becoming opaque, thickening or being frozen due
    to the effects of cold, allow to thaw slowly at room temperature. Stir briefly before use.
    Storage stability
    Storage period up to 12 months

    8. Exposure controls / personal protection


    Occupational exposure controls
    Exposure limit values
    Methanol
    CAS number : 67-56-1
    Directive on indicative exposure limits (amended)
    EU OEL - Directive on indicative exposure limits
    Revision : 07/02/2006
    Time-weighted average (8 hrs)
    Values: 260 mg/m3 200 ppm
    Methanol
    CAS number : 67-56-1
    Directive on indicative exposure limits (amended)
    EU OEL - Directive on indicative exposure limits
    Revision : 07/02/2006
    Notations
    Skin
    Methanol
    CAS number : 67-56-1
    Directive on indicative exposure limits (amended)
    EU OEL - Directive on indicative exposure limits
    Revision : 29/05/1991
    Threshold Limit Values
    Values: 260 mg/m3 200 ppm
    Safety Data Sheet in accordance with Regulation (EC) No
    1907/2006
    Arkofix ELF liq c Page 4

    Substance key: 000000312612 Revision Date: 04.06.2009


    Version : 3 - / EU Date of printing : 14.09.2009

    Hygiene measures
    Wash hands before breaks and after work.
    Respiratory protection : Use respiratory protection in case of insufficient exhaust
    ventilation or prolonged exposure
    Filter A (organic gases and vapours) to standard DIN EN 141
    Hand protection : Nitrile rubber gloves.
    These types of protective gloves are offered by various
    manufacturers. Please note the manufacturers detailed
    statements, especially about the minimum thickness and the
    minimum breakthrough time. Consider also the particular
    working conditions under which the gloves are being used.
    Eye protection : safety glasses
    see respiratory protection
    Body protection : protective clothing

    9. Physical and chemical properties


    Form : Liquid
    Colour : colourless to slightly yellow
    Odour : slightly perceptible
    Solidifying temperature : < -40 C
    Boiling point : approx. 104 C
    Flash point : Method : NFT 60103 (closed cup)
    No flash point - Measure made up to the boiling point.
    Ignition temperature : not tested.
    Self-ignition temperature : Not applicable
    Flammability
    Lower explosion limit : not tested.
    Upper explosion limit : not tested.
    Vapour pressure : not tested.

    Density : approx. 1,22 g/cm3 (20 C)

    Bulk density : Not applicable


    Solubility in water : miscible in all proportions
    pH value : 4-5
    Determined in the undiluted form
    Octanol/water partition Not determined
    coefficient (log Pow) :
    Viscosity (dynamic) : < 200 mPa.s (23 C)
    Safety Data Sheet in accordance with Regulation (EC) No
    1907/2006
    Arkofix ELF liq c Page 5

    Substance key: 000000312612 Revision Date: 04.06.2009


    Version : 3 - / EU Date of printing : 14.09.2009

    10. Stability and reactivity


    Thermal decomposition : not tested.
    Hazardous decomposition products
    Carbon monoxide and carbon dioxide

    11. Toxicological information


    Acute oral toxicity : LD50 > 2.000 mg/kg (rat)
    Source : Analogy
    Test conducted with a similar formulation.

    Irritant effect on skin : non-irritant (rabbit)


    Source : Analogy
    Test conducted with a similar formulation.
    Irritant effect on eyes : non-irritant (rabbit eye)
    Source : Analogy
    Test conducted with a similar formulation.
    Sensitization : non-sensitizing (Guinea pig)
    Method : OECD 406 - EEC 92/69, B.6
    Source : Analogy
    Test was carried out with a comparable product

    12. Ecological information


    Biodegradability : not tested.

    Fish toxicity : LC50 > 500 mg/l (Brachydanio rerio)


    Source : Analogy
    Test conducted with a similar formulation.

    Daphnia toxicity : not tested.

    Algae toxicity : not tested.

    Bacteria toxicity : EC50 > 1.000 mg/l (activated sludge)


    Source : Analogy
    Test conducted with a similar formulation.

    Chemical oxygen demand 752.000 mg/g


    (COD) :

    Biochemical oxygen demand 81.800 mg/l


    (BOD5) : 5d
    Safety Data Sheet in accordance with Regulation (EC) No
    1907/2006
    Arkofix ELF liq c Page 6

    Substance key: 000000312612 Revision Date: 04.06.2009


    Version : 3 - / EU Date of printing : 14.09.2009

    Remarks
    The ecotoxicity of the product has not been tested. The information given is based on
    products of similar structure or composition.
    Product does not contain any organic bound Halogens which could lead to AOX-values.

    13. Disposal considerations


    Product
    Disposal in an incineration plant in accordance with the regulations of the local
    authorities.
    Uncleaned packaging
    Packaging that cannot be cleaned should be disposed of as product waste

    14. Transport information

    ADR not restricted


    ADNR not restricted
    RID not restricted
    IATA not restricted
    IMDG not restricted

    15. Regulatory information


    Labelling in accordance with EC-Directives
    hazard warning labelling not compulsory
    The product does not require a hazard warning label in accordance with EC directives/the
    relevant national laws.
    Chemical Safety Assessment
    No Chemical Safety Assessment (CSA) is yet available for the substance, or for the
    component substances, contained in this product.
    Special labelling for certain preparations
    Safety Data Sheet available for professional user on request.
    Safety Data Sheet in accordance with Regulation (EC) No
    1907/2006
    Arkofix ELF liq c Page 7

    Substance key: 000000312612 Revision Date: 04.06.2009


    Version : 3 - / EU Date of printing : 14.09.2009

    16. Other information


    See product leaflet
    Text of the R-phrases assigned to the ingredients/components mentioned in
    section 3 :
    11 Highly flammable.
    22 Harmful if swallowed.
    23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
    39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in
    contact with skin and if swallowed.

    Decimal notation: "Thousands" places are identified with a dot (example: 2.000 mg/kg
    means "two thousand mg/kg"). Decimal places are identified with a comma (example: 1,35
    g/cm3).

    The data are based on the current state of our knowledge, and are intended to describe the
    product with regard to the requirements of safety. The data should not be taken to imply
    any guarantee of a particular or general specification. It is the responsibility of the user of
    the product to ensure to his satisfaction that the product is suitable for the intended purpose
    and method of use. We do not accept responsibility for any harm caused by the use of this
    information. In all cases, our general conditions of sale apply.

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