Process Safety Notes 1
Process Safety Notes 1
Process Hazards: A conditions that has the potential to result in a release of, or exposure to a
hazardous substances, which in turn can cause serious injury to personnel, significant propriety
damage, or significant environmental harm.
Hazards can usually be classified as one of the following generic potential events:
o Explosion Effects
o Thermal Exposure
o Acute Toxic Exposure
o Serious Injury from Special Mechanical Hazard
o Serious Injury form Special Electrical Hazard
Block Diagrams (BDs): It represents the simplest form of flow sheet which sets the basic concept of
the process. They show only what each step has to achieve but not how it is done.
Process Flow Diagrams (PFDs): PFD show all major equipment items with descriptions and
interconnecting flow lines for process materials. Design flow rates, temperatures, pressures and
stream compositions are also shown.
Piping &Instrument Diagram: P&IDs show all process pipes and valves (including drains and vents)
with numbers and sizes which refer to pipe and valve lists, all pressure relief valves and bursting
discs.
The objective of a P&ID is to indicate all service lines, instruments, controls and data necessary for
the design groups.
The PFD is the principal source of information for developing the P&ID.
Process Design Basis: It is the Description of the process including process chemistry, material and
energy balances, process steps , process parameters for each steps, limits for each parameters
(maximum, minimum, normal) and the consequences of deviations ( i.e., above maximum conditions
and below minimum conditions).
Equipment Design Basis: The assumption and logic upon which the design of the equipment is
based includes engineering data, engineering drawings, process and equipment sizing calculations,
equipment specifications, vendors blue prints etc.
High Hazard Processes (HHP): An HHP is any activity manufacturing, handling, storing or using
hazardous substances that, when released or ignited can result in deaths or irreversible human
health effects, significant property or environment damage or off-site impacts due to acute toxicity,
flammability, exclusivity, corrosivity, thermal instability, latent heat or compression. Local regulations
like Control of Major Accidental Haz. Rule 1990, MSIHC Rule 1989.
Process: Any activity conducted by an employer as part of manufacturing / processing steps that
involves hazardous material, including any use, storage , manufacturing or handling of these
materials.
Equipment critical to Process safety: These are those equipments whose failure could result in
exposure to hazardous substances, which in turn could result in death or serious injury ( P) or which
could result in significant property/asset damage (A) or significant environment harm(E) or company
reputation (R).
These are those equipments for which there is a system of safeguard as indicated in the column of
what if check list. Every process taken for PSM should have a list of all PSM critical equipments.
Interlocks: A safety device normally automatically activated by a sensor to prevent hazardous
conditions in a process from occurring. Also called a trip or automatic shutdown in some situations.
Severity of Consequences: For a particular hazard scenario, the degree to which personnel,
property, or the environment may be adversely affected. There are usually two severity columns in a
worksheet: one that refers to the expected severity of an items (such as a consequences) and usually
represents the worst case scenario, and one that refers to the expected severity of an item after the
recommendations have been implemented
Likelihood (L): The probability or frequency of occurrences of a hazard scenario, based on the
agreed upon definitions for the study. There are usually two L columns in a worksheet: one that
refers to the expected likelihood of an items and one for the likelihood of the item after the
recommendations have been implemented.
Process Hazards Analysis: An organized program to identify, evaluate and control hazards
associated with manufacturing, storage and transportation activities. It is a systematic and
comprehensive study of a process using recognized methods of hazards identification. It is comprised
of a consequences analysis and a process hazards review.
Process Hazard Review: `A searching and organized examination of specific parts of a processes or
systems. Demonstrated methodologies are used to identify hazards, conclusions and
recommendations are the developed.
Reliability Engineering: Process of evaluating how long a system and its individual components
can be operated safely before they must be taken out of service for maintenance or replacement.
Safeguards: Protective features or measures to guard against or prevent hazardous conditions from
arising or to mitigate their consequences. For example, pressure relief, process safety interlocks,
preventive maintenance and emergency response plans are safe guards.
Personnel safety incidents (e.g., slips; trips; falls; being hit, struck, or crushed by non-process
equipment; and hand lacerations involving any employees associated with either non process
equipment or process equipment that is not operating/in use) are not considered process incidents.
B) Hazards of Materials
Hazards of Materials documentation includes the physical and chemical properties of process substances
pertaining to their toxicity, flammability, explosiveness, corrosiveness, reactivity, permissible exposure
limits, thermal/chemical stability and other characteristics that, when released, create hazards to people,
facilities and the environment.
Plan for collecting PSI for implementation of Baseline PSRM Form No.: PSRM/PSI_PLAN/0.1 Rev. No.:00 Eff.dt.:01.01.09
Department : Process :
Month1 Month2 Month3 Month4
Activity
Wk 1 Wk 2 Wk 3 Wk 4 Wk 1 Wk 2 Wk 3 Wk 4 Wk 1 Wk 2 Wk 3 Wk 4 Wk 1 Wk 2 Wk 3 Wk 4
a) Thermal Instability means under certain temperature & condition material changes own
chemical & physical properties i.e. unstable with increase/decrease in temperature
Example
LPG gas stored in Cylinder- it may explode due to exceeding the design limit with rise in temp.
Steam pipe line explosion due to water condensation (If Temp. decreases steam will convert in
to water)
d) Corrosive: A corrosive substance is one that will destroy or irreversibly damage another surface
or substance with which it comes into contact.
Example:
Alkali (NaOH) / Acid (H2SO4, HNO3 and HCl) passing through metal pipeline, will corrode the pipe
line after some time & pipe, valves, Pump may fail
e) Explosion: An explosion creates a shock wave & is a rapid increase in volume and release of
energy in an extreme manner, usually with the generation of high temperatures.
Example:
Mechanical Explosion / BLEVE - bursting of a sealed or partially-sealed container under internal
pressure- Propane Tank, Water & Hot metal etc.
Chemical explosives Explosives, Oxidation reaction i.e. explosion in furnaces (H2 & O2 mixing)
etc.
Dept: Doc.No.:
Hazards of Materials documentation includes the physical and chemical properties of process
substances pertaining to their toxicity, flammability, explosiveness, corrosiveness, reactivity, permissible
exposure limits, thermal/chemical stability (collected from msds supplied by supplier) and other
characteristics that, when released, can be hazardous to people, facilities and the environment.
Maximum intended inventories of hazardous substances are documented so that hazardous situations
are not inadvertently created; for example:
The deluge system may be designed based on an upper limit in storage quantity, or
An upper inventory limit in a vessel / tank/ gas holder is necessary to ensure room is available for
adding gases/liquids. Also this information serves as a back-up document for PHA.
Details of Equipment design Basis Data Sheet F o rm N o : P SR M / P SI/ ED B / 004 R ev.:00 Eff.D t.: 01.01.'09
9. Develop the PSI library along with document control system at Centralized location
For PSRM team members to discuss their process related study \
To keep their P&ID, Mech. Drawings, Electrical line diagrams, etc.
The PHA team must have an up-to-date Process Information Package before the PHA has begun. The
package includes:
The following sources, means, and methods shall be used to assist in identifying the above three
categories of the hazards:
Process safety information (PSI)
Serious process incident reports
Previous PHAs
Management of Change documents
Material Safety Data Sheet (MSDS)
Chemical Interaction Matrix
Process experts
Field tour
A chemical and material incompatibility matrix or equivalent, typically referred to as a chemical interaction
matrix, shall be developed to identify hazardous effects that could foresee ably occur from the inadvertent
mixing of different materials. The matrix should consist of qualitative to semi quantitative information
about the chemical reactivity hazards from intentional and unintentional chemical reactions.
Consequence analysis is an essential element in all process hazards analyses. It is the estimation of
potential harmful effects resulting from episodic process accidents that usually involve a fire, explosion, or
release of toxic material. It should
List types of process events possible such as fire, explosion, or toxic release (both worst case and
most probable case)
Estimate potential release quantities
Estimate distance to different levels of concern, such as toxic concentrations, thermal effects,
overpressure, or significant environmental effects
Estimate safety and health effects on the site and community for potential effects.
The above can be analyzed by using the following set of questionnaire as listed
Worst case scenario and the assumptions if most probable scenario is used.
Fire, explosion, and toxicity implications of the hazard being realized.
Facilities within the affected zone of the realized hazards .
Existence of the emergency response systems and facilities to handle the realized hazards.
Impact of the realized on the facilities identified above.
Occupancy of the facilities generally every manned area will have at least 2 persons per shift hence
Avg. Occupancy Rate shall be taken as 24*2*168= 336 per week.
No. of occupants and the impact on the occupants if the hazard is realized.
If the impact is fatality and/or significant environment damage, and/or huge financial loss, develop
recommendations
The purpose of Management Review is to recognize the work done by PHA team, understand reason for
recommendations, and ensure that all recommendations are adequately addressed with detail plan with
name-wise responsibility and that basic purpose of PSRM implementation is met.
It also communicates ownership of implementation lies with Management of the department and not on
the team conducting PHAs.
The team headed by Chief of department with all Heads of different section shall review
recommendations and will have authority to accept, or modify or reject the recommendation based on the
logic and reasons explained by PHA team. The PHA team will present the recommendations in the
following formats,
The management must assign follow up responsibility and dates for completion of each recommendation.
If the recommendation is rejected, the reasons must be documented and appended to the PHA report.
During the PHA, unsafe conditions or practices may be discovered, which could have potential for injury,
but not for causing a major hazardous event. These improvement opportunities should not be ignored,
and they should be reported to the designated manager in a separate letter. However, this information on
improvement opportunities should not appear in the PHA report.