Calculate The Standard Free Energy For The Following Reaction by Using Given Data
Calculate The Standard Free Energy For The Following Reaction by Using Given Data
Calculate The Standard Free Energy For The Following Reaction by Using Given Data
Calculate the standard free energy for the following reaction by using given data.
Solution:
By applying Hess’s law, given data can be written as follow.
CCl4(l) C(s) + 2Cl2(g) ΔH1 = – (–135.44 kJmol-1)
H2O(l) H2(g)+ ½O2(g) ΔH2 = – (–285.83 kJmol-1)
Overall reaction:
CCl4 (l) + H2O (l) COCl2 (g) + 2HCl (g) ΔH = +17.856 kJmol-1
Test Power 39
Write all energy changes involve in Born-Haber cycle for the formation of calcium
oxide
Solution:
Ca+(g) + O(g)
Ca2+(g) + O–(g)
Ca (g) + O(g)
Ca2+(g) + O2–(g)
Ca(g) + ½O2(g)
Ca(s) + ½ O2(g)
CaO(s)
Test Power 40:
Calculate the lattice enthalpy of calcium oxide from the following data.
Solution:
Δ Hf = Δ Ha°(Ca) + ∑ Δ HIE° + ΔHa°(O) + ∑ Δ HEA° °+ ∆HLE°
By using Born Haber cycle for the formation of silver chloride, calculate the
lattice enthalpy of silver chloride from the following data.
Solution:
∆HLE° = ∆Ha°(Ag)+ ∑∆HIE°+ ∆Ha°(Cl2)+ ∆Hea° - ∆Hf°
= 284 + (731+ 122) + (–349) – (–127)
= 788 – (–127)
= +915KJmol-1