Cinética Questões
Cinética Questões
Cinética Questões
Departamento de Ciência
0.01 dm3/(mol·min).
(a) Calculate the time to reach 90% conversion if the reactor is a batch
reactor filled to the brim.
Assuming a stoichiometric feed (10mol A/min) to a continuous-flow
reactor, calculate the reactor volume and space-time to achieve
90% conversion if the reactor is
(b) a CSTR (Ans.: V = 22,500 dm3)
(c) a PFR (Ans.: V = 2,250 dm3)
(d) Redo (a) through (c) assuming the reaction is first-order in B and
zero-order in A with k = 0.01/min.
(e) Assume the reaction is reversible with Ke = 2dm3/mol. Calculate the
equilibrium conversion and the CSTR and PFR volumes necessary
2 to achieve 98% of the equilibrium conversion.
Quinta Lista
Exercício P4-6 de Exercí
Exercícios
the reactor at 10 atm and 127°C and a molar flow rate of 2.5
mol/min.
Calculate the reactor volume and space time to achieve 90%
conversion In
(a) a CSTR
(b) a PFR
(c) Calculate the time necessary to achieve 90% conversion in
a constant volume batch reactor.
(d) Assume the reaction is reversible with Ke = 0.04mol2/dm6
and calculate the equilibrium conversion and then redo
(a) through (c) to achieve a conversion that is 98% of the
equilibrium value.
3
Quinta Lista
Exercício P4-8 de Exercí
Exercícios
be ignored?
[Ans.: v = vo(1 - 0.2χ)]
(b) What are the expressions for the concentrations of A, B,
and D as a function of conversion at any point along the
reactor?
(c) What is the feed concentration (units: mol/dm3) of A if the
feed temperature is 55°C?
(d) How large must the plug-flow reactor be to achieve a
conversion (based on A) of 0.70 if the temperature in the
reactor is uniform (55°C), the volumetric feed rate is 50
dm3/min, and the rate law at 55°C is
1
− rA = 2.5 ⋅ C A ⋅ C B kmol / m 3 ⋅ min
2
6
Quinta Lista
Solução do exercício P4-12 de Exercí
Exercícios