Page 1/7

Safety Data Sheet

according to 1907/2006/EC, Article 31
Printing date 12.08.2010 Revision: 12.08.2010

* 1 Identification of the substance/preparation and of the company/undertaking

. Product details
. Trade name: Bison Kit All Purpose Contact Adhesive
. Application of the substance / the preparation Adhesive
. Manufacturer/Supplier:
Bison International
Dr.A.F.Philipsstraat 9
NL-4462 EW Goes
PO Box 160
NL-4460 AD Goes
tel. +31 113 235700
fax. +31 113 232077
e mail: msds@bison.boltongroup.nl
. Further information obtainable from: Bison R&D
. Information in case of emergency: +31 113 235700

* 2 Hazards identification
. Hazard description:

Xn Harmful
F Highly flammable
N Dangerous for the environment

. Information concerning to particular hazards to man and environment:

The product has to be labelled due to the calculation procedure of the "General
Classification guideline for preparations of the EU" in the latest valid version.
R 11 Highly flammable.
R 20 Harmful by inhalation.
R 38 Irritating to skin.
R 48/20 Harmful: danger of serious damage to health by prolonged exposure through
inhalation.
R 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R 63 Possible risk of harm to the unborn child.
. Classification system:
The classification is according to the latest editions of the EU-lists, and extended
by company and literature data.
. GHS label elements

Danger

2.6/2 - Highly flammable liquid and vapour.

Warning

3.7/2 - Suspected of damaging fertility or the unborn child.

3.9/2 - May cause damage to organs through prolonged or repeated exposure.
(Contd. on page 2)
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 12.08.2010 Revision: 12.08.2010

Trade name: Bison Kit All Purpose Contact Adhesive

(Contd. of page 1)

Warning

3.2/2 - Causes skin irritation.

3.8/3 - May cause drowsiness or dizziness.

4.1/2 - Toxic to aquatic life with long lasting effects.

. Prevention:
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Use explosion-proof electrical/ventilating/lighting/equipment.
Do not breathe dust/fume/gas/mist/vapours/spray.
. Response:
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse
skin with water/shower.
. Storage:
Store locked up.
. Disposal:
Dispose of contents/container in accordance with local/regional/national/
international regulations.

* 3 Composition/information on ingredients
. Chemical characterization
. Description: Adhesive
. Dangerous components:
CAS: 108-88-3 toluene 25-50%
EINECS: 203-625-9 Xn, Xi, F; R 11-38-48/20-63-65-67
Danger: flame 2.6/2; health hazard 3.10/1, 3.7/2, 3.9/2
Warning: exclamation mark 3.2/2, 3.8/3
CAS: 64742-49-0 Naphtha (petroleum), hydrotreated light 25-50%
EINECS: 265-151-9 Xn, Xi, F, N; R 11-38-51/53-65-67
Danger: flame 2.6/2; health hazard 3.10/1
Warning: exclamation mark 3.2/2, 3.8/3
environment 4.1.C/2; 4.1.A/2
CAS: 110-54-3 n-hexane ≤ 2.5%
EINECS: 203-777-6 Xn, Xi, F, N; R 11-38-48/20-62-51/53-65-67
Danger: flame 2.6/2; health hazard 3.10/1, 3.7/2, 3.9/2
Warning: exclamation mark 3.2/2, 3.8/3
environment 4.1.C/2
CAS: 8052-10-6 Colophony ≤ 2.5%
EINECS: 232-484-6 Xi; R 43
Warning: exclamation mark 3.4.S/1
CAS: 1314-13-2 zinc oxide ≤ 2.5%
EINECS: 215-222-5 N; R 50/53
Warning: environment 4.1.A/1, 4.1.C/1
. Additional information:
For the wording of the listed risk phrases refer to section 16.

* 4 First-aid measures
. After inhalation:
In case of unconsciousness place patient stable in side position for transportation.
. After skin contact: Immediately wash with water and soap and rinse thoroughly.
(Contd. on page 3)
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 12.08.2010 Revision: 12.08.2010

Trade name: Bison Kit All Purpose Contact Adhesive

(Contd. of page 2)
. After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist,
consult a doctor.
. After swallowing: Do not induce vomiting; call for medical help immediately.

5 Fire-fighting measures
. Suitable extinguishing agents:
Water haze
Alcohol resistant foam
Fire-extinguishing powder
Carbon dioxide
. For safety reasons unsuitable extinguishing agents: Water with full jet
. Protective equipment: Mount respiratory protective device.
. Additional information
Cool endangered receptacles with water spray.
Collect contaminated fire fighting water separately. It must not enter the sewage
system.

6 Accidental release measures

. Person-related safety precautions:
Wear protective equipment. Keep unprotected persons away.
. Measures for environmental protection:
Prevent seepage into sewage system, workpits and cellars.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
. Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal
binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.

7 Handling and storage

. Handling:
. Information for safe handling:
Ensure good ventilation/exhaustion at the workplace.
Ensure good interior ventilation, especially at floor level. (Fumes are heavier than
air).
. Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
. Storage:
. Requirements to be met by storerooms and receptacles: Store in a cool location.
. Information about storage in one common storage facility: Not required.
. Further information about storage conditions:
Keep receptacle tightly sealed.
Store in cool, dry conditions in well sealed receptacles.

* 8 Exposure controls/personal protection

. Additional information about design of technical facilities:
No further data; see item 7.
(Contd. on page 4)
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 12.08.2010 Revision: 12.08.2010

Trade name: Bison Kit All Purpose Contact Adhesive

(Contd. of page 3)
. Ingredients with limit values that require monitoring at the workplace:
108-88-3 toluene
WEL () Short-term value: 384 mg/m³, 100 ppm
Long-term value: 191 mg/m³, 50 ppm
Sk
110-54-3 n-hexane
WEL () Long-term value: 72 mg/m³, 20 ppm
. Additional information: The lists valid during the making were used as basis.
. Personal protective equipment:
. General protective and hygienic measures:
The usual precautionary measures are to be adhered to when handling chemicals.
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Do not inhale gases / fumes / aerosols.
Avoid contact with the skin.
Avoid contact with the eyes and skin.
. Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of
intensive or longer exposure use self-contained respiratory protective device.
. Protection of hands:
Protective gloves
Solvent resistant gloves
The glove material has to be impermeable and resistant to the product/ the
substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the
product/ the preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of
diffusion and the degradation
. Material of gloves
The selection of the suitable gloves does not only depend on the material, but also
on further marks of quality and varies from manufacturer to manufacturer. As the
product is a preparation of several substances, the resistance of the glove material
can not be calculated in advance and has therefore to be checked prior to the
application.
. Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the
protective gloves and has to be observed.
. For the permanent contact of a maximum of 15 minutes gloves made of the following
materials are suitable:
PVC or PE gloves
. Eye protection: Tightly sealed goggles
. Body protection:
Use protective suit.
Solvent resistant protective clothing

* 9 Physical and chemical properties

. General Information
Form: Fluid
Colour: According to product specification
Odour: Characteristic
. Change in condition
Melting point/Melting range: Undetermined.
(Contd. on page 5)
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 12.08.2010 Revision: 12.08.2010

Trade name: Bison Kit All Purpose Contact Adhesive

(Contd. of page 4)
Boiling point/Boiling range: 60°C
. Flash point: < 0°C
. Ignition temperature: 535.0°C
. Self-igniting: Product is not selfigniting.
. Danger of explosion: Product is not explosive. However, formation of
explosive air/vapour mixtures are possible.
. Explosion limits:
Lower: 1.2 Vol %
Upper: 7.0 Vol %
. Vapour pressure at 20°C: 29.0 hPa
. Density at 20°C: 0.89705 g/cm³
. Solubility in / Miscibility with
water: Not miscible or difficult to mix.
. Viscosity:
Dynamic at 20°C: 3000 mPas
Water: 0.2 %
Solids content: 19.7 %

10 Stability and reactivity

. Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
. Materials to be avoided:
. Dangerous reactions No dangerous reactions known.
. Dangerous decomposition products: Danger of forming toxic pyrolysis products.

* 11 Toxicological information
. Acute toxicity:
. LD/LC50 values relevant for classification:
108-88-3 toluene
Oral LD50 5000 mg/kg (rat)
Dermal LD50 12124 mg/kg (rab)
Inhalative LC50/4 h 5320 mg/l (mus)
. Primary irritant effect:
. on the skin: Irritant to skin and mucous membranes.
. on the eye: No irritating effect.
. Sensitization: No sensitizing effects known.
. Additional toxicological information:
The product shows the following dangers according to the calculation method of the
General EU Classification Guidelines for Preparations as issued in the latest
version:
Irritant

* 12 Ecological information
. Ecotoxical effects:
. Remark: Toxic for fish
. Additional ecological information:
. General notes:
Also poisonous for fish and plankton in water bodies.
Toxic for aquatic organisms
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water
(Contd. on page 6)
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 12.08.2010 Revision: 12.08.2010

Trade name: Bison Kit All Purpose Contact Adhesive

(Contd. of page 5)
Danger to drinking water if even small quantities leak into the ground.

13 Disposal considerations
. Product:
. Recommendation
Must not be disposed together with household garbage. Do not allow product to reach
sewage system.
. Uncleaned packaging:
. Recommendation:
Disposal must be made according to official regulations.
Packagings that may not be cleansed are to be disposed of in the same manner as the
product.

* 14 Transport information
. Land transport ADR/RID (cross-border)
. ADR/RID class: 3 (F1) Flammable liquids.
. Danger code (Kemler): 33
. UN-Number: 1133
. Packaging group: III
. Hazard label 3
. Special marking: Symbol (fish and tree)
. Description of goods: 1133 ADHESIVES, special provision 640H
. Limited quantities (LQ) LQ7
. Transport category 3
. Tunnel restriction code D/E
. Maritime transport IMDG:
. IMDG Class: 3
. UN Number: 1133
. Label 3
. Packaging group: III
. EMS Number: F-E,S-D
. Marine pollutant: Yes
Symbol (fish and tree)
. Proper shipping name: ADHESIVES
. Air transport ICAO-TI and IATA-DGR:
. ICAO/IATA Class: 3
. UN/ID Number: 1133
. Label 3
. Packaging group: III
. Proper shipping name: ADHESIVES
. UN "Model Regulation": UN1133, ADHESIVES, 3, III
. Environmental hazards:
Product contains environmentally hazardous substances: Naphtha (petroleum),
hydrotreated light

* 15 Regulatory information
. Labelling according to EU guidelines:
The product has been classified and marked in accordance with EU Directives /
Ordinance on Hazardous Materials.
(Contd. on page 7)
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 12.08.2010 Revision: 12.08.2010

Trade name: Bison Kit All Purpose Contact Adhesive

(Contd. of page 6)
. Code letter and hazard designation of product:

Xn Harmful
F Highly flammable
N Dangerous for the environment

. Hazard-determining components of labelling:

toluene
. Risk phrases:
11 Highly flammable.
20 Harmful by inhalation.
38 Irritating to skin.
48/20 Harmful: danger of serious damage to health by prolonged exposure through
inhalation.
51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
63 Possible risk of harm to the unborn child.
. Safety phrases:
16 Keep away from sources of ignition - No smoking.
23 Do not breathe fumes.
24 Avoid contact with skin.
46 If swallowed, seek medical advice immediately and show this container or label.
57 Use appropriate container to avoid environmental contamination.
61 Avoid release to the environment. Refer to special instructions/safety data
sheets.
. Special labelling of certain preparations:
Contains Colophony. May produce an allergic reaction.
. National regulations:
. Technical instructions (air):
. Class Share in %
. Water ≤ 2,5
I ≤ 2,5
NK 50-100
. Waterhazard class: Water hazard class 2 (Self-assessment): hazardous for water.

16 Other information
This information is based on our present knowledge. However, this shall not
constitute a guarantee for any specific product features and shall not establish a
legally valid contractual relationship.
. Department issuing MSDS: R & D laboratory
. Contact: M.L. de Jager
. * Data compared to the previous version altered.
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