Acmosil 36-4142 E

Safety Data Sheet
ACMOS CHEMIE KG according to Regulation (EC) No 1907/2006
ACMOSIL 36-4142
Issue date : 15.02.2013 Page 1 of 14
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier

ACMOSIL 36-4142
1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses
Release agent for PUR
Uses advised against
The product is for industrial and professional use only - no consumer product.
1.3. Details of the supplier of the safety data sheet
Manufacturer
Company name: ACMOS CHEMIE KG
Street: Industriestrasse 49
Place: D-28199 Bremen
Post-office box: 10 10 69
D-28010 Bremen
Telephone: +49 (0)421-5189-0 Telefax: +49 (0)421-511415
e-mail: acmos@acmos.com
Contact person: Mr. Dryhaus
Internet: www.acmos.com
Responsible Department: Laboratory (Division : Occupational- / Product security) - See under section 16
Supplier
Company name: ACMOS CHEMIE KG
Street: Industriestrasse 49
Place: D-28199 Bremen
Post-office box: 10 10 69
D-28010 Bremen
Telephone: +49 (0)421-5189-0 Telefax: +49 (0)421-511415
e-mail: acmos@acmos.com
Contact person: Mr. Dryhaus
Internet: www.acmos.com
Responsible Department: Laboratory (Division : Occupational- / Product security) - See under section 16
1.4. Emergency telephone +49 (0)551-19240 (Emergency information service / official advisory body:
number: Giftinformationszentrum Nord, Universität Göttingen, 24 h service)
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture

Classification according to Directive 67/548/EEC or Directive 1999/45/EC
R phrases:
May cause long-term adverse effects in the aquatic environment.
Repeated exposure may cause skin dryness or cracking.
This mixture is classified as hazardous according to the new EC-preparation directive 1999/45/EC.
2.2. Label elements
R phrases
53 May cause long-term adverse effects in the aquatic environment.
Revision No: 1,14 GB - EN Revision date: 13.02.2012

Safety Data Sheet
ACMOSIL 36-4142
66 Repeated exposure may cause skin dryness or cracking.
S phrases
23 Do not breathe spray .
24 Avoid contact with skin.
61 Avoid release to the environment. Refer to special instructions / Safety data sheets.
Additional advice on labelling
The product is classified and labelled in accordance with the CHIPS Regulations 1994.
Preparation Directive 1999/45/EC.
2.3. Other hazards
Adverse physicochemical effect(s) :
See section 9 for physical and chemical properties.
Adverse human health effect(s) and symptom(s) :
See section 11 for toxicological information.
Adverse environmental effect(s) :
See section 12 for environmental information.
Other adverse Hazard(s) :
No special remarkable hazards.
Results of PBT-/vPvB-assesment : See under section 12.
SECTION 3: Composition/information on ingredients
3.2. Mixtures
Chemical characterization
Mixture of active ingredients
Hazardous components
EC No Chemical name Quantity
CAS No Classification
Index No GHS classification
REACH No
918-167-1 hydrocarbons, C11-C12, isoalkanes, <2% aromatics 75 - 80 %
90622-57-4 Xn - Harmful R53-65-66
Asp. Tox. 1, Aquatic Chronic 4; H304 H413
01-2119472146-39
Further Information
Subdivision of relevant R-, H-, EUH-Phrases in full text (number and wording) see under section 16.
The above mentioned EC-No. (Provisional List Number 9xx-xxx-x) is a specific subset of the specified CAS-No. and was
associated with the registration process automatically (without CAS-No. or numeric identifier). An official announcement
by the EC inventory will follow after evaluation of substance identity by the ECHA. The new nomenclature of hydrocarbon
solvents is only related with group names of the HSPA (Hydrocarbon Solvents Producers Association). The previously
used CAS-No. continues serving as a reference for different global inventories .
SECTION 4: First aid measures
4.1. Description of first aid measures

General information
Take off all contaminated clothing immediately. Wash contaminated clothing before re-use.
If victim has stopped breathing: Artificial respiration and/or oxygen may be necessary.
If victim is unconscious but breathing: Victim to lie down in the recovery position, cover and keep him warm.
If victim is conscious: Move out of dangerous area.
If a person vomits when lying on his back, place him in the recovery position.
Consult a physician if necessary Show this safety data sheet to the doctor in attendance.

Safety Data Sheet
ACMOSIL 36-4142
Protection of first-aiders :
wear personal protective equipment See under section 8.
Notes to physician :
Aspiration may cause pulmonary oedema and pneumonitis. Symptoms may be delayed.
After inhalation
Move to fresh air in case of accidental inhalation of vapours. In case of shortness of breath, give oxygen.
Symptoms of overexposure are dizziness, headache, tiredness, nausea, unconsciousness, cessation of breathing. If
symptoms persist, call a physician.
After contact with skin
Wash off with soap and water.
Preventive skin protection.
After contact with eyes
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If eye irritation persists, consult a specialist.
After ingestion
Do not induce vomiting. Consult a physician.
Risk of product entering the lungs on vomiting after ingestion.
Never give anything by mouth to an unconscious person.
4.2. Most important symptoms and effects, both acute and delayed
See under section 11.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
In case of ingestion, the stomach should be emptied by gastric lavage under qualified medical supervision.
Later control for pneumonia and lung oedema.
SECTION 5: Firefighting measures
5.1. Extinguishing media

Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
water spray, sand, foam, dry chemical, carbon dioxide (CO2)
Extinguishing media which must not be used for safety reasons
Do not use a solid water stream as it may scatter and spread fire.
5.2. Special hazards arising from the substance or mixture
Fire will produce dense black smoke containing hazardous combustion products.
Under conditions giving incomplete combustion, hazardous gases produced may consist of : Carbon monoxide, carbon
dioxide (CO2), hydrocarbons, smoke
In principle, fire gasses of organic materials have to be classified as toxic to the respiratory system.
5.3. Advice for firefighters
In the event of fire, wear self-contained breathing apparatus.
In the event of fire and/or explosion do not breathe fumes.
Move to fresh air in case of accidental inhalation of fumes from overheating or combustion.
Additional information
Usual measures of preventive and averting fire protection.
In the event of fire, cool tanks with water spray.
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
SECTION 6: Accidental release measures

Safety Data Sheet
ACMOSIL 36-4142
6.1. Personal precautions, protective equipment and emergency procedures
Avoid contact with skin and eyes. Try to avoid breathing vapours or spray mist.
If product is heated or sprayed : Remove all sources of ignition. Do not smoke.
Keep people away from and upwind of spill/leak.
Special danger of slipping by leaking/spilling product.
Prevent further leakage or spillage if safe to do so.
Ensure adequate ventilation.
For non-emergency personnel :

Walk out of the danger zone and notify trained personnel .
If necessary, wear personal protective equipment. Never enter into a personal risk. See under section 8.
Keep the factory emergency plan and the information chain.
For emergency responders :

The personal protective equipment must be adapted to the situation.
6.2. Environmental precautions
Do not flush into surface water or sanitary sewer system.
6.3. Methods and material for containment and cleaning up
Clean-up methods - large spillage : Dam up. Shovel into suitable container for disposal. Local authorities should be
advised if significant spillages cannot be contained.
Clean-up methods - small spillage : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal
binder, sawdust). Take up mechanically and collect in suitable container for disposal .
6.4. Reference to other sections
Further information see under section 8, 13.
SECTION 7: Handling and storage

7.1. Precautions for safe handling
Advice on safe handling
Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentration higher
than the occupational exposure limits. The product should only be used in areas from which all naked lights and other
sources of ignition have been excluded. Use only in well-ventilated areas. When using, do not eat, drink or smoke.
Advice on protection against fire and explosion
Measures according to German "Explosion rules" required :
Prevention measures regarding formation of explosible atmosphere (restriction and supervision of concentration,
inertisation, airtightness, ventilation, warning device, etc.).
Prevention measures regarding ignition of explosible atmosphere (zone graduation, removing of ignition sources,
explosion-proof electrical installation, earthing, etc.).
Constructive measures for restriction of effects regarding explosions (resistance to pressure of explosions, discharge of
pressure of explosions, suppression of explosions, etc.).
Take precautionary measures against static discharges . Preparation may charge electrostatically: always use earthing
leads when transferring from one container to another. To avoid ignition of vapours by static electricity discharge , all
metal parts of the equipment must be grounded. Do not use pressure to empty drums.
Keep product and empty container away from heat and sources of ignition. Do not smoke.
Vapours may form explosive mixture with air.
Spray mist may be flammable at temperatures below the flash point.
Vapours are heavier than air and may spread along floors .
Electrical equipment should be protected to the appropriate standard.
Fire-fighting equipment on the basis of class B.
Further information on handling
Reference on types of contact requiring special precautionary measures :
Particularly at work places with filling and transfer procedures into other containers, as well as with weightening and
mixture processes an effective exhaust ventilation has to be guaranteed .

Safety Data Sheet
ACMOSIL 36-4142
For restriction of emission on volatile organic compounds (VOC) the solvent vapours should be supplied to an exhaust
air purification facility (filter, gas washer, incineration).
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage rooms and vessels
Keep containers tightly closed in a cool, well-ventilated place.
The valid water and zoning ordinances must be observed.
Design solvent resistant and tight floor.
Advice on storage compatibility
Stable under recommended storage conditions.
Incompatible with oxidising agents.
Further information on storage conditions
Indoor stockability in closed unopened original containers : 6 months.
Store at room temperature in the original container.
Keep at temperatures between +10 and +30 °C.
Do not store outside. Avoid heating and direct sunlight.
See also instuctions on the label.
7.3. Specific end use(s)
Possibilities for substitution and references to less hazardous products :
This product was designed for a special application purpose and optimized appropriately.
In case of questions regarding product and application, please contact our field service in line with customer service or
our technical sales department.
Specific regulations of branch industries :

Hazardous substance information systems of professional associations.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters

Additional advice on limit values
Recommended monitoring and observation processes : None known.
Control banding for chemicals according to the ILO CHEMICAL CONTROL TOOLKIT (ICCT) :
ICCT-Guidelines and - Control Guidance Sheets :
http://www.ilo.org/legacy/english/protection/safework/ctrl_banding/toolkit/main_guide.pdf
Consider appropriate model solutions according to good engineering practices on designing the working process, if
available.
8.2. Exposure controls
Appropriate engineering controls

Design of appropriate work processes and engineering controls and the use of adequate materials (physical cut- off of
man and machine, model solutions as certified working methods, working appliance according to the state of the art,
optimization of process / spray robots, working appliance for prevention of skin contact, models of working times).
Preliminary concentration measurements :

Suitable detector tubes for measuring the current concentration in the air at the workplace : DRÄGER test tubes -
short-term tubes (Internet : http://www.gasmesstechnik.de)
References for design of technical equipment : See under section 7.

Safety Data Sheet
ACMOSIL 36-4142
Execution of collective protection measures at source and appropriate organisational measures (local exhaust
ventilation, ventilation by technical means, general ventilation, measures on averting a danger at breakdowns / at
emergencies / after accidents, first-aid-measures, manner related measures : operating instruction / instruction of
employees, occupational medicine health precaution).
Provide appropriate exhaust ventilation at machinery. Where reasonably practicable this should be achieved by the use
of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of
particulates and solvent vapour below the OEL, suitable respiratory protection must be worn.
Execution of individual and personnel protection measures (personal protective equipment - PPE).
Individual protection measures, such as personal protective equipment
When using, do not eat, drink or smoke. General industrial hygiene practice.
Handle in accordance with good industrial hygiene and safety practice.
Respiratory protection
Breath protection at insufficient ventilation or prolonged exposition .
Breathing apparatus needed only when aerosol or mist is formed.
Observe limited carrying time. The use of filter equipment requires a minimum oxygen content of 17 Vol-% in the
surrounding atmosphere and that the maximum permitted gas concentration - normally 0,5 Vol-% - is not exceeded.
Half mask or quarter mask with combination filter A1P1/A2P2 for gases, vapors and particles.
Filtering half mask or quarter mask with combination filter FFA 1 P1/FFA2P2 for gases, vapors and particles. (EN 405)
Gas filtrating Half-face mask FFA (EN 405)
Model 4251 (FFA1P1 - 1000 ml/m3) / 4255 (FFA2P2SL - 5000 ml/m3) - 3M, Internet : http://www.3m.com
Half-face mask or Quarter-face mask with gas filter (EN 140)
Filter type 6051 (A1 - 1000 ml/m3) / 6055 (A2 - 5000 ml/m3) - 3M, Internet : http://www.3m.com
Full-face mask with gas filter (EN 136)
Gas filter type : A, Indication colour : brown
Skin protection
Hand protection :
Use only chemical protective gloves with CE-status of category III in accordance to EN 374. Suitable materials at long
term, direct contact (Recommended : Preventive index 6, accordingly > 480 min. permeation time in accordance to EN
374) :
Fluorine rubber / FKM / Viton (VITOJECT® - Art. No. 890) - Layer thickness : 0,7 mm
Nitrile rubber / NBR (CAMATRIL VELOURS® - Art. No. 730) - Layer thickness : 0,4 mm
Suitable materials at short term contact or splash (Recommended : Preventive index 3, accordingly > 60 min. permeation
time in accordance to EN 374) :
Disposable gloves of special nitrile rubber / NBR (DERMATRIL® P - Art. No. 743) - Layer thickness : 0,2 mm
Manufacturer :
Kächele-Cama Latex GmbH, Industriepark Röhn, Am Kreuzacker 9, D-36124 Eichenzell, c/ o Tony O'Donovan, 2
Wyndham Road, New Waltham, Grimsby, N. E. Lincs, GB-DN36 4WA
Telephone : +44-(0)1472232883, Telefax : +44-(0)1472232883, Internet : http://www.kcl.de, E-Mail : kcl-uk@kcl.de
The statements are based on self-tests, literary reference and information of glove manufacturers or have been derived
from similar substances by analogy. Source : CHEMIKALIEN-MANAGER - KCL software for hand protection. It has to be
noticed, that daily time of use of chemical protective gloves may be quite shorter in practice because of many factors of
influence (e.g. thermal and mechanical stress as well as special conditions on the floor) than the permeation time
determined in accordance to EN 374. The respective permeation time doubles/halvens at about 1,5 times larger/lower
layer thickness. Declared permeation times according to EN 374 are not carried out under practical conditions. Therefore
a maximum wearing time up to 50 % of breakthrough time is recommended. They relate to the pure solvent as mean
component.
Decrease wearing protection gloves to an inevitable degree to avoid skin rash. Technical and organizational protective
actions have to be preferred. Wear under gloves made of cotton as possible. Change preventive gloves once by hour or
Safety Data Sheet
ACMOSIL 36-4142
use special skin-protective preparations for protective gloves carrier, e.g. physioderm® proGlove
Before removing gloves clean them with soap and water. Dispose preventive gloves after defect or expiry of wearing
time. Check protective gloves to proper condition before usage.
Preventive skin protection. : Draw up skin protection programme.

Before starting work, apply solvent-resistant skincare preparations,
e.g. sansibal® / sansibon®, dualin®
Wash hands before breaks and on finishing work,
e.g. ecosan®, topscrub® soft / topscrub® extra / topscrub® nature
After cleansing, apply greasy skincare products,
e.g. physioderm® creme, cura soft® / cUrea soft®
Manufacturer :
Peter Greven Physioderm GmbH, Procter-&-Gamble-Str. 26, D-53881 Euskirchen
Telephone : +49-(0)2251 77617-61, Telefax : +49-(0)2251 77617-44, Internet : http://www.physioderm.de, E-Mail :
info@physioderm.de
Other :
Skin protection :
Light protective clothing (EN 340) :
Protective clothing (Category III according to EN 374, Type 4) - Spray tight clothing with protection against liquid aerosols
(EN 14605, EN 468),
e.g. TYVEK Classic Plus - Type 4/5/6 (Internet : http://www.dpp-europe.com/?lang=en),
safety shoes, antistatic boots (EN 344)
Eye / face protection
safety glasses with side-shields (EN 166)
Thermal hazards
No thermal hazards during use of this product.
Environmental exposure controls
Should not be released into the environment. Discharge exhaust air only with suitable seperators to atmosphere.
Further information see under section 6.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties

Physical state: liquid
Colour: colourless
Odour: characteristic
Test method
pH-Value: Not applicable
Changes in the physical state
Melting point: < - 20 °C Literary reference
Boiling point: > 170 °C Literary reference
Sublimation point: Not applicable
Softening point: not determined
Flash point: > 60 °C EN ISO 2719
Explosive properties
Vapour/air-mixtures are explosive at intense warming. The statements for steam pressure, ignition point and explosion
levels apply to the solvent / solvent mixture.
Lower explosion limits: 0,6 vol. % Literary reference

Safety Data Sheet
ACMOSIL 36-4142
Upper explosion limits: 7,0 vol. % Literary reference
Ignition temperature: > 200 °C Literary reference
Oxidizing properties
Not applicable
Vapour pressure: < 1 hPa Literary reference
(at 20 °C)
Vapour pressure: < 6 hPa Literary reference
(at 50 °C)
Density (at 20 °C): 0,8 g/cm³ DIN 51757
Water solubility: < 0,1 g/L Literary reference
(at 20 °C)
Solubility in other solvents: miscible with most organic solvents
Partition coefficient: Not applicable (Preparation)
Viscosity / dynamic: not determined
Viscosity / kinematic: > 7 mm²/s 3 EN ISO 2431
(at 23 °C)
Flow time: 39 s 3 EN ISO 2431
(at 23 °C)
Vapour density: ~5.4 (Air=1), M~168 g/mol Literary reference
(at 25 °C)
Evaporation rate: < 0.1 (n-BuAc=1) Literary reference
(at 20 °C)
Solvent separation test: Not applicable
Solvent content: not determined
9.2. Other information
Solid content: not determined
Gas group (94/9/EC) : IIA (maximum experimental safe gap > 0,9 mm)
Temperature class (94/9/EC) : T3 (T > 200 °C ... <= 300 °C)
Conductivity : < 10E-08 S/m
Odor threshold : no data available
SECTION 10: Stability and reactivity
10.1. Reactivity
No decomposition if stored and applied as directed.
10.2. Chemical stability
Stable at normal conditions
10.3. Possibility of hazardous reactions
Exothermic reaction : See under section 10.5.
10.4. Conditions to avoid
Heat.
Further information see under section 7.
10.5. Incompatible materials
oxidising agents
10.6. Hazardous decomposition products
No decomposition if stored and applied as directed.
Under fire conditions: See under section 5.

Safety Data Sheet
ACMOSIL 36-4142
SECTION 11: Toxicological information
11.1. Information on toxicological effects

Toxicocinetics, metabolism and distribution
No toxical dates available. Not proofed mixture.
The product was classified according to the conventionally method (based on the calculation procedure of the new
EC-preparation directive 1999/45/EC).
Information on likely routes of exposure /

Symptoms related to the physical, chemical and toxicological characteristics :
After ingestion :
Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhoea.
Risk of product entering the lungs on vomiting after ingestion.
Aspiration may cause pulmonary oedema and pneumonitis.
Based on available data, the classification criteria are not met.
After inhalation :
Inhalation of aerosols may cause irritation to mucous membranes.
Inhalation of vapours in high concentration can cause narcotic effects and metabolic acidosis .
Symptoms of overexposure are dizziness, headache, tiredness, nausea, unconsciousness, cessation of breathing.
After skin contact :

May cause skin irritation in susceptible persons. Repeated or prolonged contact with the preparation may cause removal
of natural fat from the skin resulting in non-allergic contact dermatitis and absorption through the skin. Solvents may
degrease the skin.
After eye contact :

Contact with eyes may cause irritation.
High concentration of vapours may cause irritation to eyes and respiratory system and produce narcotic effects .
Delayed and immediate effects as well as chronic effects from short and long -term exposure :
Not relevant / no data available
Interactive effects :
Absence of specific data :

No data is available on the product itself. Description of possible hazardous to health effects is based on experience
and/or toxicological characteristics of several components.
Based on manufacturer datas of the main components the acute toxixity, the skin irritation, the mucous membrane
irritation and the mutagenic potential of the mixture were evaluated. However, some datas are not complete regarding
particular main components. Nevertheless according to the experience of the manufacturer there are no other hazards
expected then those which are already mentioned on the label.
Mixture versus substance information :

Acute toxicity
The following informations are derived from the properties of the individual components.
LD50/oral/rat = > 2000 mg/kg
LD50/dermal/rabbit = > 2000 mg/kg
LC50/inhalation/4h/rat = > 20 mg/l

Safety Data Sheet
ACMOSIL 36-4142
CAS No Chemical name

Exposure routes Method Dose Species h
90622-57-4 hydrocarbons, C11-C12, isoalkanes, <2% aromatics
Acute oral toxicity LD50 > 5000 mg/kg rat
Acute dermal toxicity LD50 > 3160 mg/kg rabbit
Acute inhalation toxicity LC50 > 5,6 mg/l rat 4
Irritation and corrosivity

Sensitising effects
After inhalation : Based on available data, the classification criteria are not met.
After skin contact : Based on available data, the classification criteria are not met.
Severe effects after repeated or prolonged exposure
Subacute to chronical toxicity :
Carcinogenic/mutagenic/toxic effects for reproduction
Other information
no data available
SECTION 12: Ecological information
12.1. Toxicity
No ecotoxical dates available. Not proofed mixture.
The product was classified according to the conventionally method (based on the calculation procedure of the new
EC-preparation directive 1999/45/EC).
Aquatic toxicity (Fish toxicity, Algae toxicity, Daphnia toxicity) :

The following informations are derived from the properties of the individual components.
LC50/96h/guppy = > 100 mg/l
EC50/72h/algae = > 100 mg/l
EC50/48h/daphnia = > 100 mg/l
Terrestric toxicity (Bird toxicity, Beneficial insect, Rainworm toxicity) : no data available
Plant toxicity : no data available
Behaviour in waste water treatment plants : no data available
CAS No Chemical name
Aquatic toxicity Method Dose Species h
90622-57-4 hydrocarbons, C11-C12, isoalkanes, <2% aromatics
Acute fish toxicity LC50 > 1000 mg/l Oncorhynchus mykiss 96
Acute algae toxicity ErC50 > 1000 mg/l Pseudokirchnerella 72
subcapitata
Acute crustacea toxicity EC50 > 1000 mg/l Daphnia magna 48
12.2. Persistence and degradability

Abbiotic degradation (Hydrolysis, Photolysis) : Not applicable
Physicochemical elimination (Oxidation, Hydrolysis) : Not applicable
Photochemical elimination (Photooxidation) : no data available
Biodegradation :
hydrocarbons, C11-C12, isoalkanes, <2% aromatics :
Not readily biodegradable ( 31,3 % after 28 days). - OECD 301E, C.4-B

Safety Data Sheet
ACMOSIL 36-4142
12.3. Bioaccumulative potential
Partition coefficient n-octanol /water (log Pow) : Not applicable (Preparation)
Bioconcentration factor (BCF) : Not applicable (Preparation)
12.4. Mobility in soil
Surface tension : no data available
Transport soil-water (Adsorption coefficient) : The product is insoluble and floats on water.
Transport water-air (volatility rate, Henry-constant) : The product evaporates slowly.
Transport soil-air (volatility rate) : The product evaporates slowly.
This product contains one or more hydrocarbon UVCB's. Standard tests for this endpoint are intended for single
substances and are not appropriate for this complex substance.
12.5. Results of PBT and vPvB assessment
The product is neither a PBT- or vPvB-substance nor it contains PBT or VPvB substances.
12.6. Other adverse effects
Ozone depletion potential (ODP) : no data available
Photochemical ozone building potential (OBP) : no data available
Global warming potential (GWP) : no data available
Product does not contain any organic halogens. (AOX)
SECTION 13: Disposal considerations
13.1. Waste treatment methods

Advice on disposal
Disposal according to offical regulations. Do not flush into surface water or sanitary sewer system. Do not dispose of
waste into sewer. May not be disposed or deposited together with domestic garbage. Pack product waste or close and
label uncleaned empty packages in respect to the local and official regulations and supply to an appropriate way of
disposal.
The relation of waste-codes according to EWC has to be realized by branch and process. The waste producer is
resposible for correct coding and designation of his wastes. For small amounts (< 20 kg/L) contact next special waste
counter or a mobile service for harmful substances. Before discharge in public drains (e.g. residues of washing- and
rinsing liquids) please observe the relevant regulations. In case of further questions please contact your waste- or
environmental representative or the responsible authority.
List of proposed waste codes / waste designations in accordance with EWC :
Waste disposal number of waste from residues/unused products
070204 WASTES FROM ORGANIC CHEMICAL PROCESSES; wastes from the MFSU of plastics, synthetic rubber
and man-made fibres; other organic solvents, washing liquids and mother liquors
Classified as hazardous waste.
Waste disposal number of used product
070204 WASTES FROM ORGANIC CHEMICAL PROCESSES; wastes from the MFSU of plastics, synthetic rubber
and man-made fibres; other organic solvents, washing liquids and mother liquors
Waste disposal number of contaminated packaging
150110 WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND PROTECTIVE
CLOTHING NOT OTHERWISE SPECIFIED; packaging (including separately collected municipal packaging
waste); packaging containing residues of or contaminated by dangerous substances
Contaminated packaging
Contaminated packages must be completely emptied and may be reused after proper cleaning. Dipose of packages that
cannot be cleaned like the product. Cleaning by recycling company.
As well uncleaned (empty) containers remain contaminated by product residues and may be hazardous by vapours. They
have to be disposed by specialists or have to be supplied to a licensed reconditioning. The conditions of the regional
reconditioning companies have to be observed.

Safety Data Sheet
ACMOSIL 36-4142
Offer rinsed packaging material to local recycling facilities .
Recommended cleansing agent : Clean with detergents. Avoid solvents. Dispose of rinse water as waste water. Do not
contaminate water.
SECTION 14: Transport information
Land transport (ADR/RID)

Other applicable information (land transport)
Not classified as dangerous in the meaning of transport regulations.
Inland waterways transport (ADN)
Other applicable information (inland waterways transport)
Not relevant
Marine transport (IMDG)
Other applicable information (marine transport)
Air transport (ICAO)
Other applicable information (air transport)
14.5. Environmental hazards
Dangerous for the environment: no
14.6. Special precautions for user
Not relevant
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not relevant
Other applicable information
Not relevant
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulatory information
1999/13/EC (VOC): Content of volatile organic compounds (VOC) = 78 % w/w.
VOC-value (25 °C) = 626 g/L.
Regulation (EC) No 2037/2000 - Substances that deplete the ozone layer : Not applicable
Regulation (EC) No 648/2004 and No 907/2006 - Detergents : Not applicable
Regulation (EC) No 850/2004 - Persistent organic pollutants : Not applicable
Regulation (EC) No 689/2008 - Export and import of dangerous chemicals : Not applicable
Regulation (EC) No 552/2009 - Restriction of chemicals (REACH) as regards annex XVII : Not applicable
Authorisation of Chemicals (REACH) as regards Annex XIV : Not applicable
Directive 2004/42/EC - Use of organic solvents in certain paints and lacquers : Not applicable
Directive 96/82/EC - Control of major accident hazards involving dangerous substances (Seveso II), as last amended by
Directive 2003/105/EC : Not applicable
EC-Chemical inventories : All ingredients are listed in EINECS / ELINCS or excepted from listing.
A chemical safety assessment (CSA) has been carried out on following substance(s) :
hydrocarbons, C11-C12, isoalkanes, <2% aromatics, EC-No. : 918-167-1

Safety Data Sheet
ACMOSIL 36-4142
National regulatory information

Employment restrictions: Observe employment restrictions for young people. Observe employment
restrictions for child bearing mothers and nursing.
Water contaminating class (D): 1 - slightly water contaminating
International chemical inventories (Registration status on substances) : no data available
European product inventories (Registration status on mixtures) :

Istituto Superiore di Sanità / Archivio Preparati Pericolosi - ISS (http://www.preparatipericolosi.iss.it/iss/index.phtml) :
This product was registered.
Kemikalieinspektionen / Produktregistret / Swedish Chemicals Inspectorate - KemI
(http://apps.kemi.se/nclass/default.asp) :
Schweizerische Eidgenossenschaft - Bundesamt für Gesundheit - BAG (http://www.bag.admin.ch) / Informationssystem
für gefährliche und umweltrelevante Stoffe - IGS (http://igs.naz.ch/index.html) :
SECTION 16: Other information
Changes
This version replaces all former issues.
Changes made in this revision see section : 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16.
Disclaimer :
The information is based on present level of our knowledge. It does not, however, give assurances of product properties
and establishes no contract legal rights. The information given is designed only as a guidance for safe handling, use,
processing, storage, transportation, disposal and release The receiver of our product is singulary responsible for
adhering to existing laws and regulations. All descriptions are approximate values, they are not specified for construction
of specifications. This safety data sheet does not represent any operating instruction according to national chemical
regulations. It may be used for creation, but must not replace it. The employer is not relieved from his duties. All technical
information to occupational protection are directed predominately to experts first (safety engineers, occupational
medicines).
Abbreviations and acronyms
CAS: Chemical Abstracts Service.
DNEL: Derived No-Effect Level.
EC50: Effective concentration, 50 percent.
EC: European community.
EINECS: European Inventory of Existing Commercial Chemical Substances.
ELINCS: European List of Notified Chemical Substances.
IC50 / ErC50: Inhibitory concentration, 50 percent.
EN: European standard.
FDA: US-Food and Drug Administration.
GHS: Globally Harmonized System of Classification and Labelling of Chemicals.
ISO: A standard of International Standards Organisation.
LC50: Lethal concentration, 50 percent.
LD50: Lethal Dose, 50 percent.
log Kow (Pow): octanol-water partition coefficient.
OECD: Organisation for Economic Co-operation and Development.
PBT: Persistent, bioaccumulabe and toxic.
PNEC: Predicted No-Effect Concentration.
UN: United Nations.
vPvB: Very persistent and very bioaccumulable.

Safety Data Sheet
ACMOSIL 36-4142
Full text of R phrases referred to under Sections 2 and 3

53 May cause long-term adverse effects in the aquatic environment.
65 Harmful: may cause lung damage if swallowed.
66 Repeated exposure may cause skin dryness or cracking.
Full text of H statements referred to under Sections 2 and 3
H304 May be fatal if swallowed and enters airways.
H413 May cause long lasting harmful effects to aquatic life .
Further Information
Full text of all R-phrases which are referred to in section 2 and 3 of this safety data sheet - see previous list. These (this)
R-phrases/R-phrases apply/applies to the substance(s) of content, however, it does not necessarily show the
classification of the product.
Training references :
Yearly briefing and instruction of employees by means of operating instructions according to article 8 of EC-directive
98/24/EC.
Recommended restriction of application :

For more reference to application see separate product information. Please refer to our internet website for more
information.
Sources of most important data used for creation of the data sheet :
The classification corresponds to current EC-lists, but is completed by statements of technical literature and company
data. Other public accessible sources :
Regulation (EC) No. 1907/2006 (REACH) in the valid version in each case
Regulation (EC) No. 1272/2008 (CLP) in the valid version in each case
Substance Directive 67/548/EEC in the valid version in each case
Preparation Directive 1999/45/EC in the valid version in each case
European Agency for Safety and Health at Work - national air treshold values from european member states - EH 40
(http://osha.europa.eu/good_practice/topics/dangerous_substances/oel/members.stm)
European Chemical Substances Information System - ESIS (http://ecb.jrc.ec.europa.eu/esis)
MERCK Chemical Databases - MERCK Chemicals (http://www.merck-chemicals.com)
Further information and practical guides on the internet :

European Chemicals Agency - ECHA (http://ec.europa.eu/echa)
The access to European Union law - EUR-Lex (http://eur-lex.europa.eu)
Control of Substances Hazardous to Health Regulations - COSHH (http://www.coshh-essentials.org.uk/Home.asp)
Pollution Prevention and Control Act and Pollution Prevention and Control Regulations
Health and Safety Executive - HSE - Leaflets for Chemicals (http://www.hse.gov.uk/pubns/chindex.htm)
Classification of mixtures and used evaluation methods in accordance with Regulation (EC) No 1272/2008 (CLP) :
The transition period according to CLP-Regulation (Article 61) has not been expired yet.
Inquiry office : Laboratory (Division : Occupational- /Product security)

Contact person : Mr. Dryhaus (Telephone : +49-421-5189-0, Telefax : +49-421-5189-871)
Office hours : Mo - Th from 7.30 - 16.15 h and Fr from 7.30 - 13.30 h. Out of office hours no call diversion.

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Safety Data Sheet

ACMOS CHEMIE KG according to Regulation (EC) No 1907/2006

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Revision No: 1,14 GB - EN Revision date: 13.02.2012

ACMOS CHEMIE KG according to Regulation (EC) No 1907/2006

SECTION 3: Composition/information on ingredients

SECTION 4: First aid measures

4.1. Description of first aid measures

Revision No: 1,14 GB - EN Revision date: 13.02.2012

ACMOS CHEMIE KG according to Regulation (EC) No 1907/2006

SECTION 5: Firefighting measures

5.1. Extinguishing media

SECTION 6: Accidental release measures

Revision No: 1,14 GB - EN Revision date: 13.02.2012

ACMOS CHEMIE KG according to Regulation (EC) No 1907/2006

For non-emergency personnel :

For emergency responders :

SECTION 7: Handling and storage

Revision No: 1,14 GB - EN Revision date: 13.02.2012

ACMOS CHEMIE KG according to Regulation (EC) No 1907/2006

Specific regulations of branch industries :

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Appropriate engineering controls

Preliminary concentration measurements :

References for design of technical equipment : See under section 7.

ACMOS CHEMIE KG according to Regulation (EC) No 1907/2006

ACMOS CHEMIE KG according to Regulation (EC) No 1907/2006

Preventive skin protection. : Draw up skin protection programme.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Revision No: 1,14 GB - EN Revision date: 13.02.2012

ACMOS CHEMIE KG according to Regulation (EC) No 1907/2006

Odor threshold : no data available

SECTION 10: Stability and reactivity

Revision No: 1,14 GB - EN Revision date: 13.02.2012

ACMOS CHEMIE KG according to Regulation (EC) No 1907/2006

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Information on likely routes of exposure /

After skin contact :

After eye contact :

Absence of specific data :

Mixture versus substance information :

Revision No: 1,14 GB - EN Revision date: 13.02.2012

ACMOS CHEMIE KG according to Regulation (EC) No 1907/2006

CAS No Chemical name

Irritation and corrosivity

SECTION 12: Ecological information

Aquatic toxicity (Fish toxicity, Algae toxicity, Daphnia toxicity) :

12.2. Persistence and degradability

Revision No: 1,14 GB - EN Revision date: 13.02.2012

ACMOS CHEMIE KG according to Regulation (EC) No 1907/2006

Product does not contain any organic halogens. (AOX)

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Revision No: 1,14 GB - EN Revision date: 13.02.2012