Quantum Mechanics MCQ

CLEVER MIND
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Final exam question for CSIR/UGC NET (June -2017)
1. Match List – I and List – II

List – I List – II
(a) T 1. - S
(b) P 2. V
(c) T 3. V
(d) 4. -H/T2
( /
P
(a) a- 1,b-2 ,c-3, d-4 b) a-2,b-1, c-4,d- 3 c ) a-2,b-1,c-3,d-4 d) a-3,b-1,c-4,d-2
2. The change in entropy when one mole of an ideal gas compressed to one fourth of its initial volume
and simultaneously heated to twice its initial temperature is
(a) CV - R ln4 b) 2(CV - R ln2) c) (CV - 2R ) ln4 d) (CV + 2R ) ln2
3. In Langmuir adsorption isotherm the plot between P / V vs P gives slope =.012 cm-3 and
Intercept = .048 cm -3 the value of adsorption constant is
(a) 0.5 (b) 0.05 (c) 0.25 (d) 4
4. The dissociation of H2 leads to the adsorption on a solid surface the extent of

adsorption depends on rate constant as
(a) ⍺√ (b) K ⍺
(c) K 1/ √p (d) K ⍺ p-1
5. The wave function of a diatomic molecule has the form ψ = 0.89 + 0.45 .The chance
of both the electron of the bond will be found on the same atom in 100 inspection of the molecule
approximately is :
(a) 79 (b) 20 (c) 60 (d) 45

6. The allowed transition among the following is:
(a) 2∑ → 3∑ (b) 2∏ → 2∑ (c) 3∆ →3∏ (d) 1∑ →) 2∑
7. . Character table for trans N2 F2 ( C2h point group ) is given below
The corresponding Reducible representation and Irreducible representation corresponding to that

reducible representation is
(a) 16 0 0 4 and 4 Ag + 2 Bg +2 Au + 4 Bu
(b) 12 0 0 4 and 4 Ag + 2 Bg +2 Au + 4 Bu
(c) 12 4 0 0 and 2 Ag + 2 Bg +4 Au + 4 Bu
(d) 12 0 4 0 and 2 Ag + 4 Bg +4 Au + 2 Bu
8. For H2 molecule having electronic configuration 1 the corresponding slater determinant

for the ionic part of this molecule is :
1 (1) 1 (2) 1 (1) 1 (1)

(a) √ (b)
1 (1) 1 (2) √ 1 (1) 1 (2)
1 (1) 1 (1) 1 (1) 1 (1)

(c) (d)
√ 1 (1) 1 (2) √ 1 (2) 1 (2)
9. A particle is described by a wave function ψ(x) = in one dimension.what is the

| |
probability that it will be found in the region | |≤ a, a > 0 ?
(a) (b) (c) 1 − (d) 1 −
10. The following mechanism has been proposed for the reaction of NO and Br2 to form NOBr
NO(g) + Br2 (g) ⇋ NOBr2(g) NOBr2 (g) + NO(g) → 2NOBr(g)
If the second step is rate determining step, at low pressure of NO the order of the reaction
with respect to NO(g) is
(A) 0 (B) 3 (C) 2 (D) 1

11. The J=0 to J=1 rotational transition for 1 79 occurs at 500.72 GHz. Assuming the molecule to
be rigid rotor ,the J=3 to J=4 transition occurs at
(a) 50.1 (b) 66.8 (c) 16.7 (d) 83.5
12. The rotational Raman spectra of 19 shows a series of stock’s lines at 19230.769
19227.238 and 19223.707 .The rotational constant for 19 in GHz is ?
(a) 26.484 (b) 52.968 (c) 105.936 (d) 3.531
13. The symmetry element ( )for SO3 molecule is
(a) 6 (b) 2 (c) 4 (d) 1
14. The possible number of way of distribution of two particles among four energy state when the
particles are indistinguishable and distinguishable are :
(a) 4 and 16 (b) 8 and 16 (c) 16 and 16 (d) 8 and 4
15. The probability of forming k-mers for a polymer chain is given by :
(a) (1 + ) (b) (1 + ) (c) (1 − ) (d)

( )
16. Consider the following statement about IR spectroscopy :
1. Vibrational modes are IR active only if a change in dipole moment occurs during the vibration .
2. Bending vibration of a bond occurs at higher frequency compare to stretching vibrations at the
same bond.
3. As the bond strength increases , the vivrational frequency increases.
4. As the reduced mass of the atoms on a vibrating system decreases ,the frequency of vibration
decreases.
Which of the above statements are correct ?
(a) 1 ,2 and 4 (b) 1 and 3 (c) 2 and 4 (d) 1 ,2 ,3 and 4
17. In the Michaelis-Menten mechanism for enzyme catalysed reaction the michaelis constant
is ?
(a) (b) (c) (d)

18.Consider the given data
Half-cell reaction standard reduction potential ( )(Volts)
(I) + 14 +6 ⇌2 +7 1.33
(II) +3 ⇌ Cr(s) 0.74
(III) + ⇌ Cu 0.52
(IV) +2 ⇌ Cu 0.34
The numerical value of standard cell potential for the reaction
2Cr(s) + 3 ( ) ⇌ 2 (aq) +3Cu(s) is
(a) -1.08 volts (b) -0.40 volts (c) 1.08 volts (d) 2.50 volts
19. For which one of the following processes is inter system crossing (ISC) is essential ?
(a) Fluorescence (b) Phosphorescence
(c) Chemiluminescence (d) Radioactive decay
20. The number of nodal plane in px orbital is ?
(a) 1 (b) 2 (c) 3 (d) 4

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CLEVER MIND

Final exam question for CSIR/UGC NET (June -2017)

1. Match List – I and List – II

(a) a- 1,b-2 ,c-3, d-4 b) a-2,b-1, c-4,d- 3 c ) a-2,b-1,c-3,d-4 d) a-3,b-1,c-4,d-2

(a) CV - R ln4 b) 2(CV - R ln2) c) (CV - 2R ) ln4 d) (CV + 2R ) ln2

(a) 0.5 (b) 0.05 (c) 0.25 (d) 4

4. The dissociation of H2 leads to the adsorption on a solid surface the extent of

(c) K 1/ √p (d) K ⍺ p-1

(a) 79 (b) 20 (c) 60 (d) 45

(a) 2∑ → 3∑ (b) 2∏ → 2∑ (c) 3∆ →3∏ (d) 1∑ →) 2∑

7. . Character table for trans N2 F2 ( C2h point group ) is given below

The corresponding Reducible representation and Irreducible representation corresponding to that

8. For H2 molecule having electronic configuration 1 the corresponding slater determinant

1 (1) 1 (2) 1 (1) 1 (1)

1 (1) 1 (1) 1 (1) 1 (1)

9. A particle is described by a wave function ψ(x) = in one dimension.what is the

probability that it will be found in the region | |≤ a, a > 0 ?

(a) (b) (c) 1 − (d) 1 −

NO(g) + Br2 (g) ⇋ NOBr2(g) NOBr2 (g) + NO(g) → 2NOBr(g)

with respect to NO(g) is

(A) 0 (B) 3 (C) 2 (D) 1

(a) 50.1 (b) 66.8 (c) 16.7 (d) 83.5

(a) 26.484 (b) 52.968 (c) 105.936 (d) 3.531

13. The symmetry element ( )for SO3 molecule is

(a) 6 (b) 2 (c) 4 (d) 1

(a) 4 and 16 (b) 8 and 16 (c) 16 and 16 (d) 8 and 4

15. The probability of forming k-mers for a polymer chain is given by :

(a) (1 + ) (b) (1 + ) (c) (1 − ) (d)

16. Consider the following statement about IR spectroscopy :

3. As the bond strength increases , the vivrational frequency increases.

Which of the above statements are correct ?

(a) 1 ,2 and 4 (b) 1 and 3 (c) 2 and 4 (d) 1 ,2 ,3 and 4

(a) (b) (c) (d)

Half-cell reaction standard reduction potential ( )(Volts)

(II) +3 ⇌ Cr(s) 0.74

The numerical value of standard cell potential for the reaction

2Cr(s) + 3 ( ) ⇌ 2 (aq) +3Cu(s) is

(a) Fluorescence (b) Phosphorescence

(c) Chemiluminescence (d) Radioactive decay

20. The number of nodal plane in px orbital is ?

(a) 1 (b) 2 (c) 3 (d) 4

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