The document is a practice exam for a final exam containing 20 multiple choice questions related to chemistry topics such as thermodynamics, kinetics, spectroscopy, and molecular orbital theory. The questions cover concepts like entropy change calculations, Langmuir adsorption isotherms, wavefunctions, molecular symmetry, and half-cell reactions.
The document is a practice exam for a final exam containing 20 multiple choice questions related to chemistry topics such as thermodynamics, kinetics, spectroscopy, and molecular orbital theory. The questions cover concepts like entropy change calculations, Langmuir adsorption isotherms, wavefunctions, molecular symmetry, and half-cell reactions.
Original Description:
This documents contain the MCQ of Quantum mechanics
The document is a practice exam for a final exam containing 20 multiple choice questions related to chemistry topics such as thermodynamics, kinetics, spectroscopy, and molecular orbital theory. The questions cover concepts like entropy change calculations, Langmuir adsorption isotherms, wavefunctions, molecular symmetry, and half-cell reactions.
The document is a practice exam for a final exam containing 20 multiple choice questions related to chemistry topics such as thermodynamics, kinetics, spectroscopy, and molecular orbital theory. The questions cover concepts like entropy change calculations, Langmuir adsorption isotherms, wavefunctions, molecular symmetry, and half-cell reactions.
(a) a- 1,b-2 ,c-3, d-4 b) a-2,b-1, c-4,d- 3 c ) a-2,b-1,c-3,d-4 d) a-3,b-1,c-4,d-2
2. The change in entropy when one mole of an ideal gas compressed to one fourth of its initial volume and simultaneously heated to twice its initial temperature is
(a) CV - R ln4 b) 2(CV - R ln2) c) (CV - 2R ) ln4 d) (CV + 2R ) ln2
3. In Langmuir adsorption isotherm the plot between P / V vs P gives slope =.012 cm-3 and Intercept = .048 cm -3 the value of adsorption constant is
(a) 0.5 (b) 0.05 (c) 0.25 (d) 4
4. The dissociation of H2 leads to the adsorption on a solid surface the extent of
adsorption depends on rate constant as
(a) ⍺√ (b) K ⍺
(c) K 1/ √p (d) K ⍺ p-1
5. The wave function of a diatomic molecule has the form ψ = 0.89 + 0.45 .The chance of both the electron of the bond will be found on the same atom in 100 inspection of the molecule approximately is :
(a) 79 (b) 20 (c) 60 (d) 45
6. The allowed transition among the following is:
(a) 2∑ → 3∑ (b) 2∏ → 2∑ (c) 3∆ →3∏ (d) 1∑ →) 2∑
7. . Character table for trans N2 F2 ( C2h point group ) is given below
The corresponding Reducible representation and Irreducible representation corresponding to that
reducible representation is
(a) 16 0 0 4 and 4 Ag + 2 Bg +2 Au + 4 Bu (b) 12 0 0 4 and 4 Ag + 2 Bg +2 Au + 4 Bu (c) 12 4 0 0 and 2 Ag + 2 Bg +4 Au + 4 Bu (d) 12 0 4 0 and 2 Ag + 4 Bg +4 Au + 2 Bu
8. For H2 molecule having electronic configuration 1 the corresponding slater determinant
for the ionic part of this molecule is :
1 (1) 1 (2) 1 (1) 1 (1)
(a) √ (b) 1 (1) 1 (2) √ 1 (1) 1 (2)
1 (1) 1 (1) 1 (1) 1 (1)
(c) (d) √ 1 (1) 1 (2) √ 1 (2) 1 (2)
9. A particle is described by a wave function ψ(x) = in one dimension.what is the
| |
probability that it will be found in the region | |≤ a, a > 0 ?
(a) (b) (c) 1 − (d) 1 −
10. The following mechanism has been proposed for the reaction of NO and Br2 to form NOBr
If the second step is rate determining step, at low pressure of NO the order of the reaction
with respect to NO(g) is
(A) 0 (B) 3 (C) 2 (D) 1
11. The J=0 to J=1 rotational transition for 1 79 occurs at 500.72 GHz. Assuming the molecule to be rigid rotor ,the J=3 to J=4 transition occurs at
(a) 50.1 (b) 66.8 (c) 16.7 (d) 83.5
12. The rotational Raman spectra of 19 shows a series of stock’s lines at 19230.769 19227.238 and 19223.707 .The rotational constant for 19 in GHz is ?
(a) 26.484 (b) 52.968 (c) 105.936 (d) 3.531
13. The symmetry element ( )for SO3 molecule is
(a) 6 (b) 2 (c) 4 (d) 1
14. The possible number of way of distribution of two particles among four energy state when the particles are indistinguishable and distinguishable are :
(a) 4 and 16 (b) 8 and 16 (c) 16 and 16 (d) 8 and 4
15. The probability of forming k-mers for a polymer chain is given by :
(a) (1 + ) (b) (1 + ) (c) (1 − ) (d)
( )
16. Consider the following statement about IR spectroscopy :
1. Vibrational modes are IR active only if a change in dipole moment occurs during the vibration .
2. Bending vibration of a bond occurs at higher frequency compare to stretching vibrations at the same bond.
3. As the bond strength increases , the vivrational frequency increases.
4. As the reduced mass of the atoms on a vibrating system decreases ,the frequency of vibration decreases.
Which of the above statements are correct ?
(a) 1 ,2 and 4 (b) 1 and 3 (c) 2 and 4 (d) 1 ,2 ,3 and 4
17. In the Michaelis-Menten mechanism for enzyme catalysed reaction the michaelis constant is ?
(a) (b) (c) (d)
18.Consider the given data
Half-cell reaction standard reduction potential ( )(Volts)
(I) + 14 +6 ⇌2 +7 1.33
(II) +3 ⇌ Cr(s) 0.74
(III) + ⇌ Cu 0.52
(IV) +2 ⇌ Cu 0.34
The numerical value of standard cell potential for the reaction
