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    Assignment 6: Solutions

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    chandrakiran
    1) The residual enthalpy of the system is calculated using equations of state and thermodynamic properties at the given conditions of 25 bar and 300 K. The compressibility factor is found to be 0.7731 using the Peng-Robinson equation of state. 2) The residual entropy at conditions of 29.28 bar and 290.23 K is calculated to be -6.4 J/mol-K using values from Lee/Kesler tables. 3) The saturated molar volume at 293.15 K is calculated to be 27.1 cm3/mol using the Rackett equation and properties at the critical point.

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    Assignment 6: Solutions

    Uploaded by

    chandrakiran
    21 views4 pages
    1) The residual enthalpy of the system is calculated using equations of state and thermodynamic properties at the given conditions of 25 bar and 300 K. The compressibility factor is found to be 0.7731 using the Peng-Robinson equation of state. 2) The residual entropy at conditions of 29.28 bar and 290.23 K is calculated to be -6.4 J/mol-K using values from Lee/Kesler tables. 3) The saturated molar volume at 293.15 K is calculated to be 27.1 cm3/mol using the Rackett equation and properties at the critical point.

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    W06A06 Solutions

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    1) The residual enthalpy of the system is calculated using equations of state and thermodynamic properties at the given conditions of 25 bar and 300 K. The compressibility factor is found to be 0.7731 using the Peng-Robinson equation of state. 2) The residual entropy at conditions of 29.28 bar and 290.23 K is calculated to be -6.4 J/mol-K using values from Lee/Kesler tables. 3) The saturated molar volume at 293.15 K is calculated to be 27.1 cm3/mol using the Rackett equation and properties at the critical point.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    21 views4 pages

    Assignment 6: Solutions

    Uploaded by

    chandrakiran
    1) The residual enthalpy of the system is calculated using equations of state and thermodynamic properties at the given conditions of 25 bar and 300 K. The compressibility factor is found to be 0.7731 using the Peng-Robinson equation of state. 2) The residual entropy at conditions of 29.28 bar and 290.23 K is calculated to be -6.4 J/mol-K using values from Lee/Kesler tables. 3) The saturated molar volume at 293.15 K is calculated to be 27.1 cm3/mol using the Rackett equation and properties at the critical point.

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    Assignment 6: Solutions Page |1

    Q1
    From (60) of the summary for Week 6

    𝐻𝑅 𝑑 ln 𝛼(𝑇𝑟 ) (A)
    =𝑍−1+[ − 1] 𝑞𝐼
    𝑅𝑇 𝑑 ln 𝑇𝑟
    We need to find Z and other terms on the RHS of (A) to evaluate the residual enthalpy.

    The compressibility factor Z is calculated from the EoS (Peng-Robinson) in this case.

    From (58) of summary for Week 5, Z is a root of the following cubic equation.

    𝑍 3 + 𝑍 2 [(𝜖 + 𝜎)𝛽 − 1 − 𝛽] + 𝑍𝛽[(𝑞 − 𝜖 − 𝜎) − (𝜖 + 𝜎 − 𝜖𝜎)𝛽] − 𝛽 2 (𝑞 − 𝜖𝜎𝛽 − 𝜖𝜎) = 0 (B)

    For PR EoS, again from (58), the following equations hold.

    𝜶(𝑻𝒓 ) 𝝈 𝝐 𝛀 𝚿
    PR 𝛼𝑃𝑅 (𝑇𝑟 ; 𝜔) 1 + √2 1 − √2 0.0778 0.45724

    1/2 2 (C)
    𝛼𝑃𝑅 (𝑇𝑟 ; 𝜔) = [1 + (0.37464 + 1.54226𝜔 − 0.26992𝜔2 ) (1 − 𝑇𝑟 )]

    𝑃𝑟 Ψ𝛼(𝑇𝑟 ) (D)
    β=Ω 𝑞=
    𝑇𝑟 Ω𝑇𝑟

    From the above equations the following calculations follow. (E)

    𝑃 25
    𝑃𝑟 = = = 0.5123
    𝑃𝑐 48.8

    𝑇 300
    𝑇𝑟 = = = 0.982
    𝑇𝑐 305.5

    1/2 2
    𝛼𝑃𝑅 = [1 + (0.37464 + 1.54226𝜔 − 0.26992𝜔2 ) (1 − 𝑇𝑟 )]
    2
    =[1 + (0.37464 + 1.54226 × 0.099 − 0.26992 × 0.0992 )(1 − √0.982)]
    =1.0095
    Assignment 6: Solutions Page |2

    𝑃𝑟 0.5122
    β=Ω = 0.0778 × = 0.040587
    𝑇𝑟 0.982
    Ψ𝛼(𝑇𝑟 ) 0.45724 × 1.0095
    𝑞= = = 6.0417
    Ω𝑇𝑟 0.0778 × 0.982

    The cubic in Z, i.e. Eq. (B) reduces to


    𝑍 3 + 0.959413 𝑍 2 + 0.159103𝑍 − 0.01167 = 0

    The only real root for this equation is, Z = 0.7731

    The value of I, from (62) in summary for week 6 is given by

    1 𝑍 + 𝜎𝛽
    If 𝜖 ≠ 𝜎, 𝑡ℎ𝑒𝑛 𝐼 = 𝑙𝑛 ( )
    𝜎−𝜖 𝑍 + 𝜖𝛽
    1 0.7731 + 0.040587(1 + √2)
    = 𝑙𝑛 ( ) = 0.049964
    (1 + √2) − (1 − √2) 0.7731 + 0.040587(1 − √2)

    From (65) in summary for week 6,


    𝑑 ln 𝛼(𝑇𝑟 )
    = −𝜁√𝑇𝑟 ⁄𝛼 = (0.37464 + 1.54226𝜔 − 0.26992𝜔2 )√𝑇𝑟 ⁄𝛼
    𝑑 ln 𝑇𝑟
    = (0.37464 + 1.54226 × 0.099 − 0.26992 × 0.0992 )√0.982⁄1.0095
    = −0.5175

    𝐻𝑅 𝑑 ln 𝛼(𝑇𝑟 )
    =𝑍−1+[ − 1] 𝑞𝐼 = 0.7731 − 1 + [−0.5175 − 1] × 6.0417 × 0.049964
    𝑅𝑇 𝑑 ln 𝑇𝑟
    = −0.685
    𝐻 𝑅 = −0.685𝑅𝑇 = −0.685 × 8.314 × 300 = −1708.5 J mol−1
    Assignment 6: Solutions Page |3

    Q2
    At the given conditions

    𝑃 29.28
    𝑃𝑟 = = = 0.6
    𝑃𝑐 48.8

    𝑇 290.23
    𝑇𝑟 = = = 0.95
    𝑇𝑐 305.5

    0 1
    𝑆𝑅 𝑆𝑅
    From Lee/Kesler tables we obtain ( ) , ( ) at the desired reduced conditions.
    𝑅 𝑅

    0 1
    𝑆𝑅 𝑆𝑅 𝑆𝑅
    = ( ) + 𝜔 ( ) = −0.671 + 0.099(−0.961) = −0.766
    𝑅 𝑅 𝑅
    𝑆 𝑅 = −0.766 × 8.314 = −6.4 J mol−1 K −1
    Assignment 6: Solutions Page |4

    Q3
    From the Rackett equation

    (1−𝑇𝑟 )2/7
    𝑉 𝑠𝑎𝑡 = 𝑉𝑐 𝑍𝑐
    To find 𝑉𝑐 we will use conditions at the critical point

    𝑍𝑐 𝑅𝑇𝑐 0.242 × 83.14 bar cm3 mol−1 K −1 × 405.7 K


    𝑉𝑐 = = = 72.16 cm3 mol−1
    𝑃𝑐 112.8 bar

    𝑇 293.15
    The reduced temperature 𝑇𝑟 = = = 0.7226
    𝑇𝑐 405.7

    So,

    (1−𝑇𝑟 )2/7 2/7


    𝑉 𝑠𝑎𝑡 = 𝑉𝑐 𝑍𝑐 = 72.1 × 0.242(1−0.7226) = 27.1cm3 mol−1

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