Silicone Fluids Stable Inert Media
Silicone Fluids Stable Inert Media
Silicone Fluids Stable Inert Media
Notes:
All data on this table are for comparative purposes.
The classes of fluids have a range of properties that
do not represent the performance of an actual fluid. "Silicone Fluids: Stable Inert Media" by Barry Arkles
Values reported for fluids including the paraffin Supplement to the Gelest Catalogs, “Silicon Compounds:
hydrocarbon oil are without additives such as EP Silanes and Silicones” edited by Barry Arkles
agents or stabilizers.
& Gerald L. Larson, which are available upon request.
© Copyright 2012 Gelest, Inc.
TABLE OF CONTENTS
Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
Definitions and Terms. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
Selection Guide. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
Fluid Properties . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
SiBrid® Fluids . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26
Thermoplastic & Preceramic Materials. . . . . . . . . . . . . . . . . . . . 28
Refractive Indices of Pure Fluids . . . . . . . . . . . . . . . . . . . . . . . . 29
Viscosity Conversion Chart . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 30
Blending Chart . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 30
(215) 547-1015 FAX: (215) 547-2484 www.gelest.com
3
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SILICONE FLUIDS
Stable Inert Media
An introduction to silicone fluids Silicone Fluids can be divided into six general classes:
and their uses
Silicone fluids have unique properties because they are not ■ Conventional Fluids..................................8
products of petroleum or organic chemistry. They were the ■ Thermal Fluids ........................................16
first, and are still the only, major class of polymers that are ■ Organic Compatible Fluids ......................18
products of inorganic chemistry. Silicone fluids consist of a ■ Fluorosilicone Fluids ..............................20
broad range of different materials with the following charac- ■ Hydrophilic Fluids....................................21
teristics: ■ Low Temperature Fluids ..........................23
■ Wide Service Temperature Range The conventional fluids, also referred to as polydimethylsilox-
■ Low Viscosity Changes vs. Temperature anes, exhibit all the properties of the silicone family. The
■ Thermal Stability other classes of fluids can be considered modifications of the
■ Low Flammability conventional fluids in which one set of properties has been
■ Shear Stability enhanced, but generally other properties are altered or
■ Dielectric Stability sacrificed.
■ High Compressibility
■ Chemical Inertness
■ Low Surface Tension
■ Low Toxicity
Viscosity-Temperature Coefficient A measure of the change of fluid viscosity over the temperature range 38°C to 99°C;
V.T.C. = 1-(viscosity @99°C/viscosity @ 38°C). Thus, the lower the V.T.C. the less the
change in viscosity over the temperature range.
Acoustical* Density
Fluid Viscosity (cSt.) Velocity of sound, m/s Density vs. Temperature
30°C 50.7°C of Dimethylsiloxane Fluids
0.65 873 795 1.02
1.00
2.0 931 863 98
100
20 975 918 96 0 cS
t
94 100
Density g/cc
100 985 930 92
cSt
TEMPERATURE, °C
Electrical Dimethylsiloxane
used in smart
Dielectric Strength 350-400V/mil magnetic &
Dielectric Constant 102-106Hz, 20°C 2.44-2-2.76 electrorheological
Dissipation Factor 0.0001 fluids.
Volume Resistivity 1x1015ohm-cm at 20°C
16
3 14
kV/mm
2.5 12
2 10
TEMPERATURE, °C TEMPERATURE, °C
0.01
1015
0.001
1014
0.0001
1013
0 100 200 0 50 100 150 200 250
Mechanical
Coefficient of adiabatic compressibility 1.10x10-10cm2/dyne
Volume reduction of 100 cSt. fluid
at 1,000 psi 0.70-0.75%
at 10,000 psi 5.50-5.90%
at 20,000 psi 9.00-9.20%
at 40,000 psi 13.30-13.80%
100,000
Viscosity, μ, of Polydimethylsiloxanes as a function of a degree
of polymerization “n”.
10,000
VISCOSITY at 25°C. cSt
1,000
n 1 5 10 20 30 40
DMS-T31 Polydimethylsiloxane
1,000
200°C 25°C
150°C
PMM-0025 Polymethylphenylsiloxane
200°C 25°C
150°C
100 PMM-5021 Dimethyl-Phenylmethylsiloxane copolymer
0 10 100
Radiation dose (megarads)
Thermal
Specific heat 0.35-0.37 cal/gm/°C
Heat of formation -2.41 kcal/gm
Heat of combustion (>50 cSt.) 6.13 kcal/gm
Glass transition temperature -128°C
Gel time, 150°C indefinite
Gel time for intermediate viscosity fluids, 200°C 200 hours
Gel time for high viscosity fluids, 200°C 100 hours
Autoignition temperature for fluids >10 cSt. greater than 460°C
2,000,000 2,000,000
1,500,000
500,000
500,000
200,000
200,000
100,000
100,000
60,000
Viscosity in cSt.
50,000
30,000
20,000
20,000
12,500
10,000
10,000
5,000
5,000
2,000
2,000
1,000
1,000
500
Temperature 25°C
0.1 0.2 0.3 1 2 5 10 20 50 100 200 500 1,000 2,000 5,000 20,000 100,000 500,000
10,000 50,000 200,000 1,000,000
VELOCITY GRADIENT (s-1)
Low Volatility
PolyDimethylsiloxanes
Volatile, low molecular weight components are present in Reduced Volatility PolyDimethylsiloxanes
polydimethylsiloxanes as a consequence of the equilibrium wt% volatiles measured after 4 hours at 150°C in air
polymerization utilized in their manufacture. Typically, sili- Product Code Viscosity wt % Volatiles Price/1kg
cones with viscosities below 50 cSt. have >10% volatiles,
while those with viscosities greater than 50 cSt. have 0.5-4.0% DMS-T07R 7 10 $150.00
volatiles. Low molecular weight components can impart unde- DMS-T12R 20 3.0 $200.00
sirable effects in certain critical applications. These can cause
outgassing, migration, bleed, plasticization, and stress-crack- DMS-T21R 100 0.5 $140.00
ing in contact with certain plastics and rubbers. Devolatilized DMS-T31R 1,000 0.1 $225.00
silicones are offered in two classes. Reduced Volatility
see also FMS-222R in Fluorosilicone section
Silicones have >90% low-molecular weight components
removed and are generally acceptable for polymer contacting
applications. Extreme Low Volatility Silicones have virtually
zero volatiles and are suitable for extreme vacuum applica-
tions including systems deployed in space exploration and Extreme Low Volatility PolyDimethylsiloxanes
communication. An example of a space application is as a <0.01wt% volatiles measured after 24 hours at 125°C 10-5 torr
damping fluid for solar panels. vacuum, according to ASTM-E595-85 and NASA SP-R0022A
Product Code Viscosity Price/100g
Silicone Emulsions
Silicone emulsions are easy-to-use, water-dilutable, fine parti- ducing shell molds and cores for metal casting, wire and
cle dispersions of conventional polydimethylsiloxane fluids. cable extrusion and conveyance devices in high-speed print-
They are employed as release agents and lubricants in a vari- ing. They are usually diluted with water to a final solids con-
ety of rubber and plastic applications including molding of centration of 0.1-3.5% at the point of application.
mechanical rubber parts such as O-rings and footwear, pro-
Specific Refractive Surface Dielectric Flashpoint Ignition Comonomer Molecular Price Price Price
Gravity Index Tension Constant °C Temp., °C mole % Weight 100g 1kg 10kg
0.98 1.422 22.6 2.75 280 484 4-6* 3,500-4,000 $15.00 $108.00 $755.00
0.99 1.436 22.8 2.78 280 484 7-10* 2,800-3,200 $13.00 $92.00 $647.00
1.05 1.490 24.5 2.83 285 488 18-22* 1,600-2,400 $24.00 $176.00 $1232.00
*Diphenylsiloxane
1.00 1.425 25.0 2.77 275 482 8-12** 1,500-1,600 $20.00 $139.00 $972.00
1.00 1.425 24.5 2.79 280 482 8-12** 3,000-4,000 $28.00 $193.00 $1183.00
1.00 1.425 24.4 2.80 285 482 8-12** 9,000-11,000 $23.00 $165.00 $1155.00
1.00 1.425 24.8 2.82 285 482 8-12** 40,000-50,000 $64.00 $451.00 -
1.07 1.500 24.5 2.87 296 482 45-50** 2,000-2,200 $23.00 $165.00 $1155.00
1.08 1.507 2.89 285 482 58-62** 3,500-4,000 $22.00 $139.00 $972.00
**Phenylmethylsiloxane
1.05 1.428 21.0 2.90 300 480 - 1,600-3,000 $35.00 $242.00 $1694.00
Aryl-Alkyl Silicones
Aryl-alkyl silicones exhibit an extended range of organic compatibility and lubricity
when compared to dimethyl silicones. They behave as broad spectrum compatibilizing
agents for silicone/hydrocarbon/fatty acid formulations in the lubricant and cosmetic
industries. Fluids with methyl and 2-phenylpropyl groups maintain excellent release
properties without interfering with paintability, making them preferred in mold release
agent formulations for rubber and plastics and die casting. Other uses for organic com-
patible silicone fluids include surfactants or de-airing molded urethane and epoxy parts
during fabrication and die-cast metal lubrication.
AlkylMethylsiloxane-ArylalkylMethylsiloxane Copolymers
Viscosity Pour- Specific Refractive Flashpoint Price Price Price
Product Code cSt. Point, °C Gravity Index °C 100g 1kg 10kg
Fluorosilicone Fluids
Many advantages of fluorocarbons and silicones are combined
in fluorosilicones. The materials are useful from -40° to
230°C in a wide range of aggressive service environments.
They have achieved a number of unique applications due to
their chemical and solvent resistance to lubricity.
Fluorosilicones are not miscible with fuels or oils. They have a
solubility parameter of 9.6. They have been employed in
mechanical vacuum pumps where exposure to high from fluorosilicones and solid fluoropolymer thickeners have
temperature moisture and oxygen is encountered. been used in sealed transmission and other extreme pressure
The fluids are excellent lubricants under extreme pressure applications.
applications. This characteristic, considered with resistance to The high density of these fluids has led to their use as a flota
fuels has led to many automotive and aerospace lubrication tion medium for inertial guidance systems. Acoustic velocities
applications, since they are not easily leached by fuels from in fluorosilicones are lower than conventional silicones,
mechanical joints. In addition, fluorosilicones, particularly the allowing sonar lens development. Trifluoropropylmethylsiloxane
copolymers, have been employed as lubricants for electrical homopolymers have a compressibility of 7.5% at 20,000 psi.
contacts and precision timing devices. Greases formulated Volume resistivity for fluids >500cSt: 1013 ohms-cm.
Fluorosilicones
Poly (3,3,3-Trifluoropropylmethylsiloxane) CAS: [63148-56-1]
Viscosity, Viscosity Pour- Transition Specific Refractive Surface Dielectric Dielectric Flashpoint Molecular Price Price Price
Product Code cSt. Temp. Coeff. Point,°C Temp., Tg°C Gravity Index Tension Constant Strength Temp.,°C Weight 25g 100g 1kg
Specialty Fluorosilicones
Viscosity, Viscosity Pour- Transition Specific Refractive Surface Dielectric Dielectric Flashpoint Molecular Price Price Price
Product Code cSt. Temp. Coeff. Point,°C Temp., Tg°C Gravity Index Tension Constant Strength Temp.,°C Weight 25g 100g 1kg
Hydrophilic Silicones
Polyalkylene Oxide Silicones
Hydrophilic silicones differ from conventional silicones by demon- used as an anti-fog treatment for glass and optical surfaces. It is
strating a much greater compatibility with aqueous systems. They also used to facilitate wetting and spread of developers on litho-
have slight to complete solubility in water. They are composed of graphic plates. At the other extreme, DBE-224 is a water-insoluble
dimethylsiloxane molecular backbones in which some of the copolymer used as a lubricant in plastic on metal wear applica-
methyl groups are replaced by polyalkylenoxy or pyrrolidone tions and as a lubricant for fibers. Anti-tack and mar resistance
groups linked through a propyl group to the silicone atom. are imparted to urethane coatings. High molecular weight copoly-
They are widely used as surfactants and emulsifiers. By altering mers, such as DBE-224, are excellent emulsifiers. DBE-821
the amounts of hydrophile and lipophile, the desired surfactant reduces static charge generation during fiber processing. It has
properties may be balanced. The higher the alkylene oxide con- also been incorporated into rolling oil formulations for metal
tent the higher the hydrophilicity. Materials with ethylene oxide drawing and stamping. DBE-712 and DBP-732 provide slip in
contents of 75% and higher are freely soluble in water. flexographic and gravure inks.
DBE-712 is the lowest molecular weight material containing 6-8 CMS-832 is a high refractive index fluid that provides gloss and
EO units and is miscible with water in all concentrations. It is smooth touch in polishes.
DBE-224* 25 EO OMe 400 10,000 1.02 1.414 -29 68938-54-5 $18.00 $106.00 $739.00
DBE-311*** 30-35 EO OMe 10 800-1,200 0.97 1.425 - 68938-54-5 $25.00 $165.00 -
DBE-411*** 45-50 EO OMe 5-10 400-500 0.94 1.425 - 68938-54-5 $25.00 $165.00 -
DBE-621** 50-55 EO OMe 100 2,500 1.03 1.434 -15 68938-54-5 $18.00 $106.00 $739.00
DBE-712 ‡ 60-70 EO OMe 20 600 1.01 1.442 0 27306-78-1 $12.00 $84.00 $546.00
DBP-732 65-70 EO/PO (40/60) OMe 1800 20,000 1.02 1.446 -50 67762-85-0 $12.00 $84.00 $546.00
DBE-713 75 EO OAc 30 600-750 1.03 1.446 - 125997-17-3 $72.00 - -
DBE-814 ‡ 80 EO OMe 40-50 1000 1.04 1.452 -14 117272-76-1 $25.00 $165.00 $1240.00
DBE-821 ‡ 80-85 EO OMe 100-120 4400 1.07 1.454 0 68938-54-5 $12.00 $84.00 $546.00
DBE-921 85-90 EO OMe 100-120 5000 1.08 1.451 0 68938-54-5 $48.00 $288.00 $1995.00
*~10 mole% EO Substituted; DP~100 **~25% EO Substituted; DP~15 ***R&D only ‡ reduced volatility grades available
Polar Silicones
Polar silicones are utilized in specialty applications where readily hydrophilic and have compatibility with most conventional
swellable materials such as soft rubber have poor dimensional sta- silicones. Cyanoalkylsilicones have even less tendency to swell
bility in contact with other lubricants. Pyrrolidone functional sili- substrates than fluorosilicones and, in thin films, facilitate ion
cones are the most hydrophilic silicones that are not derived from transport. Fluorosilicones are the most common polar silicones,
polyethylene glycols (PEGs). Furan functional silicones are but are usually considered as a class by themselves.
Polar Silicones
(N-Pyrrolidonepropyl)Methylsiloxane - Dimethylsiloxane Copolymers
Viscosity Specific Water Refractive Price Price
Product Code Pyrrolidone Substitution cSt. Gravity Solubility Index CAS# 100g 1kg
Tetrahydrofurfuryloxypropylmethylsiloxane
Mole % Tetrahydrofurfuryloxypropyl- Viscosity Specific Water Refractive Price Price
Product Code methylsiloxane cSt. Gravity Solubility Index CAS# 100g 1kg
CyanopropylMethylsiloxane
Viscosity Specific Water Refractive Price Price
Product Code Mole % Cyanopropylmethylsiloxane cSt. Gravity Solubility Index CAS# 10g 100g
Amphiphilic Silicones
Silicone fluids which are both hydrophilic and olephilic are have the ability to form stable water-in-oil emulsions allowing
said to be amphiphilic. This is in distinction to the more general formulation of a wide range of gels and creams. They are also
definition that considers an amphiphile to be a material which useful as surface treatments for dispersion of polar particles in
is both hydrophilic and hydrophobic. Amphiphilic silicones hydrocarbon media.
Amphiphilic Silicones
DodecylMethylsiloxane-HydroxypolyalkyleneoxypropylMethylsiloxane, Copolymer CAS: [145686-74-4]
Viscosity Molecular Mole % Hydroxypolyalkyleneoxy- Active Specific Price Price
Product Code cSt. Weight propylMethylsiloxane % Gravity 100g 1kg
PolyDiEthylsiloxanes
Polydiethylsiloxanes offer improved metal-metal lubrication thermally stable under inert atmospheres to 225°C. These
and low temperature properties when compared to polydi- fluids are often used in low temperature aerospace hydraulics
methylsiloxanes. They are oxidatively stable to 150°C and or as performance addine to synthetic hydrocarbons.
PolyDiethylsiloxanes, Triethylsiloxy terminated CAS:[63148-61-8]
Viscosity Pour Thermal Refractive Flashpoint Molecular Price Price
Product Code cSt. Point,°C Conductivity, W/m°C Density Index °C Weight 100g 1kg
DES-T02 2 -115 - 0.844 1.434 76 245 $46.00 $275.00
DES-T03 3-5 -115 - 0.844 1.436 80 275-325 $48.00 $288.00
DES-T11 7-12 -110 3.177 0.913 1.439 110 350-400 $48.00 $288.00
DES-T12 15-20 -110 3.296 0.93 1.439 125 400-500 $70.00 $420.00
DES-T15 40-50 -110 3.392 0.958 1.442 170 500-800 $30.00 $205.00
DES-T23 200-400 -96 3.750 0.991 1.447 256 1300-2000 $38.00 $225.00
Other Properties: Glass Transition Temperature: -139°C Specific Heat, 20-100°: 0.40-0.47 cal/mole°C
Surface Tension: 25-28 dynes/cm Viscosity Temperature Coefficient: 0.77 Volume Resistivity: 1013-1014 ohm-cm@20°C
Silahydrocarbons
Silahydrocarbons are low molecular weight fluids that have a
remarkable ability to provide excellent lubrication and liquid bon compatability allows use of these material as internal
behavior at low temperatures. Low viscosity and hydrocar- lubricants in ink-jet and microfluidic applications.
Silahydrocarbons
Product Code Name CAS Viscocity, cSt. Density m.p. b.p. Refractive Index flashpoint °C Price/100g
Branched Fluids
Branched and low viscosity silicone fluids offer properties that are significantly different than higher molecular weight versions
since chain entanglements are limited and end-groups have influence on properties. Apart from the obvious mechanical
advantage of the low viscosity in many applications, they offer higher purity levels, discrete vapor pressures and more linear
rheology as a function of pressure and temperature.
Branched Fluids T-structure Siloxanes Organosilsesquioxanes, Trimethylsilyl Terminated Tris(Trimethylsiloxy)Silanes
Viscosity Pour Viscosity Temp. Refractive Flashpoint Molecular Price Price Price
Product Code cSt. Point,°C Coefficient Density Index °C Weight 100g 1kg 10kg
Methyltris(trimethylsiloxy)silane CAS: [17928-28-8]
SIM6592.0 1.6 -74 - 0.85 1.388 64 311 $21.00 $148.00 $1036.00
Methyl-T-Branched PolyDimethylsiloxane CAS: [68037-74-1]
MTT-1015 50-80 -85 0.57 0.97 1.403 285 1650 $30.00 $204.00 $1425.00
Octyltris(trimethylsiloxy)silane [R&D only] CAS: [187592-85-4]
SIO6715.7 4-5 <-76 - 0.86 1.411 106 409 $29.00 $114.00 $1176.00
Octyl-T-Branched Polysilsesquioxane, Trimethylsilyl terminated [R&D only] CAS: [187593-69-7]
OTT-1012 15-30 <-76 - 0.91 1.428 >110 1080 $21.00 $125.00 $878.00
OTT-1023 200-400 <-40 - 0.95 1.444 >110 1000 $30.00 $204.00 -
Phenyltris(trimethylsiloxy)silane CAS: [2116-84-9]
SIP6827.0 4 <-60 0.55 0.92 1.437 127 373 $20.00 $124.00 $868.00
Phenyl-T-Branched Polysilsequioxane, Trimethylsilyl terminated CAS: [73559-47-4]
PTT-1012 15-25 <-60 - 0.98 1.460 - 500-700 $20.00 $119.00 $832.00
PTT-1022 150-300 - - 1.01 1.481 - 700-900 $21.00 $125.00 -
PTT-1025 400-600 - - 1.05 1.489 - 900-1200 $29.00 $172.00 -
Phenethyltris(trimethylsiloxy)silane [R&D only] CAS: [211935-21-6]
SIP6722.8 4 -55 0.68 0.93 1.440 135 401 $96.00 - -
Tetrachlorophenyl-T-Branched PolyDimethylsiloxane CAS: [68857-05-1]
PTT-1117 70-75 -73 0.68 1.05 1.428 300 1600-3000 $35.00 $242.00 $1694.00
Refractive
Product Code Name Viscosity, cSt. Density m.p. b.p. Index flashpoint °C CAS Price/100g
SIT7283.0 TETRAKIS(2-ETHYLHEXOXY)SILANE 10 0.88 <-78° 198°/1mm 1.4388 188° [115-82-2] $28.00
100
KINEMATIC VISCOSITY, CENTISTOKES
50
30
Other Properties:
20
10
viscosity, 38°: 6.89 cSt;
SIT7283.0 viscosity, -40°: 310 cSt;
5.0
vapor pressure, 25°: <0.1mm
3.0
Hvap: 169 kcal/mole
2.0 coefficient of thermal expansion: 0.8 x 10-3
1.50 volume resistivity: 1x10-11 ohm-cm
1.00
dielectric constant: 2.46
0.90
0.80
surface tension: 26.7 dynes/cm
0.70 specific heat: 0.48 cal/g/°
0.60 autoignition temp.: 304°
-100°F -65°F 0°F 100°F 200°F 300°F 400°F 500°F
TEMPERATURE
Volatile Low
Temperature Fluids
Disiloxanes
Disiloxane fluids are utilized as vehicles and solvents where factors. Since they are pure chemicals, rather than polymers,
purity, low temperature or dielectric properties are critical viscosities and other properties have virtually no variation.
Refractive
Product Code Name Viscosity, cSt. Density m.p. b.p. / mm Index flashpoint °C CAS Price/100g
SIH6115.0 HEXAMETHYLDISILOXANE 0.65 0.764 -67° 99-100° 1.377 -1° 107-46-0 $12.00
SID3418.0 1,3-DIETHYLTETRAMETHYLDISILOXANE 1 0.797 -120° 155-6° 1.401 30° [R&D only] $220.00
SIH6070.0 HEXAETHYLDISILOXANE 2.35 0.844 -115° 231° 1.434 76° 999-49-0 $75.00
SID4406.0 1,3-DIOCTYLTETRAMETHYLDISILOXANE 4.11 0.891 -36° 122-5°/0.2 1.474 >110° [R&D only] $104.00
SID4588.0 1,3-DIPHENYLTETRAMETHYLDISILOXANE 3.45 0.976 -89° 155-8°/13 1.518 156° 56-33-7 $136.00
SIB1828.5 1,3-BIS(TRIFLUOROPROPYL)TETRAMETHYLDISILOXANE 2 1.085 -88 to -90 75°/10 1.363 - [R&D only] $270.00
SIB1709.0 BIS(NONAFLUOROHEXYL)TETRAMETHYLDISILOXANE 3.6 1.331 -89° 150°/45 1.340 156° 122179-35 25g/$72.00
SIB1816.0 1,3-BIS(TRIDECAFLUOROOCTYL)TETRAMETHYLDISILOXANE 6-7 1.460 -40 to -45 81-2°/11 1.337 >150° [R&D only] $320.00
SIB1120.0 1,3-BIS(HEPTADECAFLUORO-1,1,2,2-
7-10 1.51 -5 to 0 >130°/5 1.335 >110° 129498-18-6 10g/$190.00
TETRAHYDRODECYL)TETRAMETHYLDISILOXANE
SIB1055.0 1,3-BIS(CHLOROMETHYL)TETRAMETHYLDISILOXANE 2 1.05 -90° 204-5° 1.440 73° 2362-10-9 $91.00
SIB1735.0 BIS(PENTAMETHYLDISILOXANYL)ETHANE 2.7 0.82 -52° 254-5° 1.410 - [R&D only] $140.00
Trisiloxane Fluids
Trisiloxane fluids are low viscosity materials that have unique fluids, their stuctures are extremely well-defined in chemical
wetting, surfactant and solubility characteristics. Their terms since they are low molecular weight species. This
unusual characteristics are derived from having a small table identifies the common trisiloxane fluids. Further details
“cloud” of silicone hydrophobic groups from which other are found in Gelest Silicon Compounds literature.
functionalities extend. While they are considered polymeric
Trisiloxanes
Refractive
Product Code Name Viscosity, cSt. Density m.p. b.p. / mm Index flashpoint °C CAS Price/100g
SIE4895.0 3-ETHYLHEPTAMETHYLTRISILOXANE 1 0.82 <-60° 172° 1.394 45° [17861-60-8] $29.00
SID4627.6 3-DODECYLHEPTAMETHYLTRISILOXANE 5 0.83 14° 180°/0.3 1.422 >120° [R&D only] $80.00
SIO6622.0 3-OCTADECYLHEPTAMETHYLTRISILOXANE 13 0.82 - - 1.433 >120° [R&D only] $86.00
SIO6711.5 3-OCTYLHEPTAMETHYLTRISILOXANE 3 0.82 -62° 84°/0.3 1.413 69° [17955-88-3] $68.00
SIP6736.2 3-PHENYLHEPTAMETHYLTRISILOXANE 2 0.91 -56° 78°/0.5 1.447 64° [R&D only] $150.00
Substituted Trisiloxanes
SIT8365.0 (TRIFLUOROPROPYL)HEPTAMETHYLTRISILOXANE 2 0.93 <-78° 66-8°/10 1.375 69° [R&D only]] $179.00
SIA0075.0 2-(ACETOXYPOLYETHYLENEOXYPROPYL)- 30 1.03 - - 1.446 79° [12597-17-3] $72.00
HEPTAMETHYLTRISILOXANE
SIC2289.5 (CHLOROMETHYL)HEPTAMETHYLTRISILOXANE 1 0.92 -85° 185-6° 1.406 >65° [R&D only] $159.00
Solubility Panel
Product DMA-131 DCE-7521 MCR-NA07 MCR-NL07 DMS-NL04 PDMS
D5 S (hot) S S S S S
PDMS, 10cSt S (hot) S S S S S
Stearyl Methicone S S S S S S
Hydrogenated Polydecene S S S S S S
10% Microcrystalline wax S I I I I I
Ceresin S I I I I I
Octyldodecyl Stearate S S (hot) S S S I
Triisostearyl Citrate S S S S S I
Ethylhexyl Palmitate S S S S S S
Octyldodecanol S I S S S I
Castor Oil I I I S I I
S = Soluble I = Insoluble
OCH 3
CH3 CH3 O CH3
Si O Si CH2CH2CH2 O C O C O
CH3 m CH3 CH3 n p
SSP-080
(DIMETHYLSILOXANE)(BISPHENOL -A CARBONATE) copolymer
(15 - 20% polydimethylsiloxane)
thermoplastic; tensile strength: 50MPa Vicat mp: 145° density: 1.19
[202483-49-6] TSCA HMIS: 1-1-0-X 100g/$120.00
O O
O O CH 3 CH 3 CH 3 O O
N N N
N CH 2CH 2CH 2 Si O Si O Si CH 2CH 2CH 2 N
CH 3 CH 3 n CH 3
O O O O O
O
SSP-085
(DIMETHYLSILOXANE)(ETHERIMIDE) copolymer
(35-40% polydimethylsiloxane)phenylenediaminepolyetherimide
thermoplastic; tensile strength: 2800psi Tg: 168°C density: 1.18
[99904-16-2] TSCA HMIS: 1-1-0-X 100g/$120.00
SSP-070 CH3
POLY(TRIMETHYLSILYL)PROPYNE C C
forms viscous 5% solutions in toluene/tetrahydrofuran
high oxygen permeability1; PO2/PN2 = 1.7 SiMe 3
1. Masuda, T.; et al, J. Am. Chem. Soc., 1983, 105, 7473.
[87842-32-8] HMIS: 1-1-0-X 10g/$190.00
Pre-Ceramic Polymers
PSS-1M01
Poly(DIMETHYLSILANE)
employed in CVD of SiC films.1
1. Scarlete, M., et al; US Patent 7,396,563; 2008 (Label Licensed Gelest Product)
[30107-46-8] TSCA HMIS: 1-1-0-X 100g/$115.00
O
SSP-040 O B O Si O
POLY(BORODIPHENYLSILOXANE) solid, Tg: 95-100°, Tm: 140-1°
employed in preparation of ceramic fibers.1
1. Yajima, S.; et al, Nature, 1977, 266, 521.
[70914-15-7] TSCA HMIS: 2-0-0-X 25g/$72.00 100g/$234.00
6
5000 5
Locate the higher viscosity on the right hand scale. 4.5
4
Connect these two points with a straight line. 3.5
3
Locate the point where the line indicating the desired 2.5
2
blend viscosity intersects the constructed line. From this 2000
1.5
The calculation basis for blending is:
100
A log1 + B log2 10 20 30 40 50 60 70 80 90
log = Percent of Higher Viscosity Fluid
30 A+B
Gelest, Inc.
Telephone: General 215-547-1015
Order Entry 888-734-8344
FAX: 215-547-2484
Internet: www.gelest.com
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For further information consult our web site at: www.gelest.com
In Europe: For research quantities in Europe:
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and Ireland:
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For commercial and Fluorochem Ltd.
research quantities contact: Unit 14 Graphite Way
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Gulf Chemical
For commercial and
39 Jalan Pemimpin
research quantities contact:
Tai Lee Industrial Building #04-03
AZmax Co. Ltd. Tokyo Office Singapore 577182
Matsuda Yaesudori, Bldg F8 Tel: 65-6358-3185
1-10-7 Hatchoubori, Chuo-Ku Fax: 65-6353-2542
Tokyo 104-0032 e-mail: support@gulfchem.com.sg
Tel: 81-3-5543-1630
Fax: 81-3-5543-0312
e-mail: sales@azmax.co.jp
on-line catalog: www.azmax.co.jp
Sales of all products listed are subject to the published terms and conditions of Gelest, Inc.
31
Gelest, Inc.
11 East Steel Rd.
Morrisville, PA 19067
Phone: (215) 547-1015
FAX: (215) 547-2484
www.gelest.com