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Chemistry Mock Test 2019: Exclusively On Expert Mdcat

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CHEMISTRY MOCK TEST 2019

EXCLUSIVELY ON EXPERT MDCAT


1. What volume in liters of oxygen required at STP to completely convert
1.5 moles of sulphur to sulphur dioxide?
a. 33.6
b. 67.2
c. 48.6
d. 11.2

2. Mass of one gram atom of hydrogen is :


a. 1.008 amu
b. 2.016 g
c. 1.008 g
d. 1/NA g

3. A compound with emperical formula CH2O has vapour density 30. Its
molecular formula
a. C3H6O3
b. C2H4O2
c. C2H2O2
d. C6H12O6

4. Vapour pressure is not affected by which of the following


factor/factors?

a. Surface area
b. Temperature
c. Nature of liqued
d. Surface area and amount of liqued

5. Ideal gas equation for 8g of oxygen :


a. PV=2RT
b. PV=RT
c. PV=RT/4
d. PV=8RT

6. In structure of NaCl, the distance between two sodium ions is :


a. 5.63 A°
b. 2.815 A°
c. 1.54 A°
d. 1.39 A°

7. An ion M+² has electronic configuration 2,8,14 and mass number 56.
The number of neutrons present in it?
a. 30
b. 32
c. 34
d. 28
8. First ionization energies of Na, Mg, Al and Si are in order of
a. Na > Mg > Al > Si
b. Na > Mg > Al < Si
c. Na < Mg < Al < Si
d. Na < Mg > Al < Si

9. A subshell lying in M shell has l = 1 and m = - 1, 0, +1. The subshell is


a. 4s
b. 4p
c. 2p
d. 3p

10. MgO is used to line industrial furnaces because it has very high
melting point. Which type of bond needs to be broken?
a. Ionic
b. Covalent
c. Coordinate
d. Metallic

11. Which of the following is correct set with respect to a molecule,


orbital overlaping and shape?
a. BeCl2, sp-p overlaping, linear
b. BCl3, sp2-p overlaping, trigonal pyramidal
c. BCl3, sp2-s overlaping, trigonal planar
d. BCl3, sp2-p overlaping, trigonal planar

12. Nitrogen is relatively inactive because


a. Dissociation energy of its molecule is high
b. It has low atomic radius
c. its E.N is fairly high
d. It has stable electronic configuration

13. Which of them has high bond energy?


a. C=C
b. C=N
c. C=O
d. C=S

14. H2 + Cl2 ..... > 2HCl H = - 194 Kj.


In this reaction, heat of formation of HCl is
a. +194 Kj
b. - 194 Kj
c. - 97 Kj
d. +97 Kj
15. The conditions for standard enthalpy change are :
a. 1atm and 298K
b. 1atm and 0°C
c. 1atm and Ok
d. 1atm and 25K

16. Standard hydrogen electrode potential of Cu is :


a. -0.34 V
b. +0.34 V
c. -0.76 V
d. +0.76 V

17. Which metal can react with steam strongly?


a. Mn
b. Ni
c. Pb
d. Sn

18. Which element is acting as reducing agent in the reaction, Zn +


H2SO4 ..... > ZnSO4 + H2?
a. Zn
b. S
c. O
d. H

19. For reaction H2 and I2 <....... > 2HI, (reversible reaction) the value
of Kp changes with
a. Pressure
b. Catalyst
c. Adding I2
d. Temperature

20. The addition of a catalyst to a reaction change the :


a. Enthalpy
b. Entropy
c. Nature of reactants
d. Energy of activation

21. Amongst the following hydroxide, the one which has lowest value of
ksp?
a. Mg(OH)2
b. Ca(OH)2
c. Ba(OH)2
d. Be(OH)2
22. Following mechanism is proposed for a reaction 2A + B ...... > D + E
(i) A + B ...... > C + D (slow)
(ii) A + C ...... > E (fast)
The rate law expression for the reaction is
a. R = k[A]²[B]
b. R = k[A][B]
c. R = k[A]²
d. R = k[A][C]

23. Consider an endothermic reaction, X....... >Y with the activation


energies Eb and Ef for backward and forward reaction respectively. In
general :
a. Eb > Ef
b. Eb < Ef
c. Eb = Ef
d. No relation between Eb and Ef

24. What is the effect of poisoning of catalyst ?


a. It reduces rate of reaction
b. It reduces activity of enzyme
c. It raises activation energy
d. It raises temperature of reaction

25. All of the following are condensation polymers except :


a. Teflon
b. Terylene
c. Ureaformaldehyde
d. Nylon-6,6

26. Which of the following is a primary pollutant?


a. CO
b. Aldehyde
c. PAN
d. H2SO4

27. Freon-12 is widely used in refrigerators. Its formula is :


a. CCl2F2
b. CClF3
c. C2F3Cl3
d. CCl2F

28. Which of the following is the major source of acid deposition in


atmosphere?
a. CO2
b. NO
c. SO2
d. CO
29. A nucleoside involves combination of:
a. Sugar + Base
b. Sugar + Acid
c. Sugar + Base + H3PO4
d. H3PO4 + Nucleotide

30. An element 'X' does not boil because it sublimates. This element 'X' is
a. Be
b. C
c. N
d. O

31. Which of the following is the correct order of electrical conductance


for coinage metals?
a. Ag<Cu>Au
b. Ag >Cu>Au
c. Au>Ag>Cu
d. Ag<Cu<Au

32. Which of the following bond has least Bond dissociation energy?
a. Cl-Cl
b. Br-Br
c. F-F
d. I-I

33. All of the following statements about CO2 are correct except:
a. Dipole moment is zerow
b. Carbon has partial - ve charge
c. Hybradization of C is sp
d. it is non-metal oxide

34. 5. Which oxidation state is shown by Halogen after decomposing


sodium hypochlorite at 70°C?
a. +1
b. +3
c. +5
d +7

35. Which of the following is called oil of vitrol?


a. H2SO4
b. SO3
c. H2S2O7
d. HSO4
36. All of the following hetrocylic compounds contain Nitrogen as a hetro
atom except?
a. Pyridine
b. Quinoline
c. Pyrole
d. Furan

37. Which of the does not show tautomerism?


a. C6H5-CO-CH3
b. CH3-CHO
c. CH3-CO-CH3
d. C6H5-CO-C(CH3) 3

38. Which alcohol is stable towards dehydration?


a. Ethylalcohol
b. Butanol
c. Sec. Alcohol
d. Ter. Alcohol

39. Antifreezing agent is formed by treating ethene with :


a. Hypohalous acid
b. Baeyer's reagent
c. Ozone/Zn
d. cold conc. Sulphuric acid

40. Reaction of alcohol with PBr3 is an example of which type of reaction?


a. Nucleophilic substitution
b. Electrophilic substitution
c. Nucleophilic addition
d. Electrophilic addition

41. Which of the following is more reactive towards nucleophilic


substitution bimolecular reactions?
a. CH3-CH2-Br
b. CH3-CH2-CH2-Br
c. (CH3) 3-C-Cl
d. CH3-CH(Br) - CH3

42. Which of the following is the strongest nucleophile?


a. HSO4¯
b. OH¯
c. NH2¯
d. OR¯
43. When alcohol undergoes dehydration at 140°C with conc. H2SO4,
which bonds are broken?
a. C-O and O-H
b. C-O and C-H
c. C-C and C-O
d. C-C and C-H

44. Reactions of aldehydes and ketones with ammonia derivatives are :


a. Oxidation
b. Phenylation
c. Acid catalyzed reaction
d. Addition Elimination

45. A carboxylic acid contains :


a. hydroxyl group
b. carboxyl group
c. hydroxyl and carboxyl group
d. carboxyl and aldehyde group

46. Compound X reacts witj halogen in presence of NaOH and form


compound Y which on hydrolysis gives formic acid. In this reaction
compound X indicates?
a. Ethanol
b. Formaldehyde
c. Propanol
d. Acetone

47. Reduction of CH2=CH-CO-CH3 with sodium borohydride gives


which of the following product?
a. CH2=CH-CHOH-CH3
b. CH3-CH2-CHOH-CH3
c. CH3-CH2-CO-CH3
d. CH2=CH-CO-CH3

48. Which of the following test is given by only aromatic aldehydes?


a. Fehling solution test
b. Sodium nitroprusside test
c. Sodium bisulphite test
d. Tollen's test

49. CH3CN + HCl...... > A + B. Here A and B indicates if this reaction


takes place in presence of water?
a. Acetic acid + ammonium chloride
b. Acetic acid + ammonia
c. Formic acid + ammonia
d. Acetic acid + ammonium
50. When ethanol is treated with formic acid then which ester is formed?
a. Ethyl propionate
b. Ethyl formate
c. Ethyl ethonate
d. Methyl ethonate

51. Which of the following amino acid is hetrocyclic?


a. Proline
b. Histidine
c. Lysine
d. Valine

52. In structure of Cyclohexene, there are how many pi bonds?


a. 3
b. 5
c. 6
d. 1

53. In which complex does the metal exhibit zero oxidation state?
a. [Ni(CO)4]
b. [Fe(H2O)6]X3
c. [Co(NH3)6]X3
d. [Fe(H2O)6]SO4

54. Which of the following acid is strongest?


a. F-CH2-CH2-CH2-COOH
b. CH3-CH(F)-CH2-COOH
c. CH3-CH2-CH(F)-COOH
d. Cl-CH2-CH2-CH2-COOH

55. (CH3) 3-C-CH2-Cl + Alcoholic KOH..... >?


a. E1
b. E2
c. it may be E1 or E2
d. This reaction is not possible

56. On oxidation, secondary alcohol gives :


Aldehyde
Alkane
Ketone
Carboxylic acid

57. Which nobel gas is used as cooling medium for nuclear reactors?
a. Neon
b. Xenon
c. Argon
d. Helium
58. Most commonly used halogen as disinfectant is?
a. F
b. Cl
c. Br
d. I

59. Which of the following role is played by nitrogen in plant growth?


a. it enhances yield and quality of the plants
b. it accelrates seed and fruit formation
c. it helps in ripening of see
60. Addition of HCN to aldehydes and ketones to form cyanohydrins
takes place in which media?
a. Acidic
b. Basic
c. Alcoholic
d. Aqueous

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