Exercise For Iit

ATOMIC STRUCTURE Page # 39
Class Room Problems

3. A particle of mass m moves along a circular
Class room problems orbit in a centra symmetrical potential field U(r)
=kr2/2. Using the Bohr quantization condition.
1. To what minimum distance will an alpha particle Find the permissible orbital radii and energy
with kinetic energy T=0.40 MeV approach in levels moving along it:
the case of a head-on collision to Sol.
(a) a stationary Pb nucleus:
(B) a stationary free Li7 nucleus?
Sol.
4. Calculate for a hydrogen atom and a He+ ion:

(a) the radius of the first Bohr orbit and the
velocity of an electron moving along it:
2. A H-like neutral species is in some excited state (b) the kinetic energy and the binding energy
(A) and on absorbing a photon of energy 3.066 of an electron in the ground state :
eV gets promoted to a new state B. When the (c) the ionization potential, the first excitation
electron from state B return back, photons of potential and the wavelength of the resonance
a maximum ten different wavelengths can be line (n' = 2 → n =1).
observed in which some photons have energy Sol.
smaller than 3.066 eV. Some of the equal energy
and only four photon having energy greater
than 3.066 eV. Determine the orbit number of
states A and B and ionization energy.
Sol.
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Page # 40 ATOMIC STRUCTURE
5. Calculate the angular frequency of an electron 7. To what series does the spectral line of atomic
occupying the second Bohr orbit of He+ ion. hydrogen belong if its wave number is equal
Sol. to the difference between the wave numbers
of the following two lines of the balmer series:
486.1 and 410.2 nm? What is the wavelength
of that line?
Sol.
6. Calculate the magnetic field induction at the

8. The threshold wavelength for photoelectric
centre of a hydrogen atom caused by an
emi ss i on i n tungsten i s 2300 Å. What
electron moving along the first Bohr orbit.
wavelength of light must be used to eject
Sol. electrons with a maximum energy of 1.5 eV?
Sol.
9. De te rm i ne the de -Brogl i e w av el engt h 11. At what minimum kinetic energy must a

associated with an electron in the 3rd Bohr's hydrogen atom move for its inelastic head-on
orbit of He+ ion. collision with another, stationary, hydrogen
Sol. atom to make one of them capable of emitting
a photon? Both atoms are supposed to be in
the ground state prior to the collision.
Sol.
10. Find the velocity of photoelectrons liberated

by electromagnetic radiation of wavelength λ
= 18.0 nm from stationary He+ ions in the
12. Calculate the de Broglie wavelengths of an
ground state.
electron, proton, and uranium atom, all having
Sol.
the same kinetic energy 100 eV.
Sol.
13. What amount of energy should be added to an 15. Calcul ate the most probabl e de Brogl ie
electron to reduce its de Brogie wavelengths wavelength of hydrogen molecules being in
from 100 to 50 pm? thermody nami c eq ui l i bri um at room
Sol. temperature.
Sol.
16. An automobile of mass 500 kg is moving with

speed of 50±0.001 km hr –1 . Determine
14. Find the de Broglie wavelength of hydrogen uncertainty in position of moving automobile
molecules, which corresponds to their most and interpret the result.
probable velocity at room temperature. Sol.
Sol.
17. Find the quantum number n corresponding to 19. Show that for the particle whose coordinate
the excited state of He+ ion if on transition to uncertainty is ∆x = λ/2π, where λ is its de
the ground state that ion emits two photons Broglie wavelength, the velocity uncertainty is
in succession with wavelengths 108.5 and 30.4 of the same order of magnitude as the particle's
nm. velocity itself.
Sol. Sol.
18. Estimate the minimum errors in determining the

velocity of an electron, a proton, and a ball of
mass of 1 mg if the coordinates of the particles
and of the centre of the ball are known with
uncertainly 1 µm. 20. If a photon of wavelength 200 pm strikes an
Sol. atom and one of the inner bound electrons is
injected out with a velocity of 2×107 ms–1 .
Calculate the energy with which it is bound to
nucleus?
Sol.
21. When radiation of wavelength 253.7nm falls 23. Calculate de-Brogie wavelength of a hydrogen
on a copper surface, electrons are ejected. atom with translational energy corresponding
Calculate work function if the stopping potential to a temperature of 27ºC.
is 0.5 V. Sol.
Sol.
22. The size of an atomic nucleus is 10–14 m.

Calculate uncertainty in momentum of an 24. Calculate the electrostatic potential energy of
electron if it were to exist inside the nucleus. two electrons separated by 3 Å in vacuum?
Sol. Sol.
Sol.
25. The wave function for electron in ground state

1 r
−
of hydrogen atom is ψ = (πa3 )− 2 e a0 , where
1s 0
"a0" is radius of Bohr's orbit. Calculate the

probability of finding the electrons somewhere
between 0 and 2a0.
Sol.
30. Locate the nodal surfaces in

1/2 3/2
1 2   1   r
6 r 2  − r / 3a0 cos θ
ψ 310 (r, θ, φ) =    
a  − 2 e
81  π   a0 a 
 0  0 
Sol.
26. The normalized wave function of the hydrogen

1 r
−
atom for the 1s orbital is ψ = (πa3 )− 2 e a0 .
1s 0
Show that in such a state the most probable

distance from nucleus to electron is a0.
31. Determine de-Broglie wavelength associated

with He atom at room temperature 25ºC.
Sol.
33. A hypothetical element "positronium" consists

of an electron moving in space around a nucleus
consisting a positron. Using the Bohr's atomic
model, determine the first Bohr radius, Positron
is a subatomic particle similar to electron in all
respect except possessing a positive charge.
Sol.
32. At what temperature the transitional kinetic

energy of atomic hydrogen equal that for n2
=1 to n2 =2 transition.
Sol.
Exercise - I
Bohr’s Model
1. Calculate the wavelength of radiation emitted,
producing a line in Lyman series, when an electron
falls from fourth stationary state in hydrogen atom.
Sol.
5. Calculate the Rydberg constant R if He+ ions are

known to have the wavelength difference between
the first (of the longest wavelength) lines of Balmer
and Lyman series equal to 133.7 nm.
Sol.
2. Calculate energy of electron which is moving in

the orbit that has its radius. Sixteen times the
radius of first Bohr orbit for H–atom.
Sol.
6. What transition in the hydrogen spectrum would

have same wavelength as the Balmer transition,
n = 4 to n = 2 of He+ spectrum.
Sol.
3. The wavelength of a certain line in the Paschen

series in 1093.6 nm. What is the value of nhigh for
this line. [RH = 1.0973 × 10+7 m–1]
Sol.
7. Calculate the total energy emitted when electrons

of 1.0g atom of hydrogen undergo transition giving
the spectral line of lowest energy in the visible
region of its atomic spectrum.
Sol.
4. Wavelength of the Balmer Hα line is 6565 Å.
Calculate the wavelength of Hβ , line of same
hydrogen like atom.
Sol.
8. A photon having λ = 854 Å causes the ionization Sol.

of a nitrogen atom. Give the I.E. per mole of nitrogen
in kJ.
Sol.
12. The radius of the an orbit of hydrogen atom

is 0.85 nm. Calculate the velocity of electron in this
orbit.
Sol.
9. H–atom is exposed to electromagnetic radiation of
1028 Å and gives out induced radiations (radiations
emitted when e– returns to ground state). Calculate
λ of induced radiations.
Sol.
13. The velocity or e– in a certain Bohr orbit of the

hydrogen atom bears the ratio 1 : 275 to the
velocity of light. What is the quantum no. “n” of the
orbit and the wave no. of the radiation emitted for
the transition from the quantum state (n + 1) to the
10. The electron energy in hydrogen atom is given ground state.
Sol.
− 21.7 × 10 −12
by En = ergs. Calculate the energy
n2
required to remove an e– completely from n = 2
orbit. What is the largest wavelength in cm of light
that can be used to cause this transition.
Sol.
14. A doubly ionised lithium atom is hydrogen like

with atomic number z = 3. Find the wavelength of
the radiation required to excite the electron in Li2+
from the first to the third Bohr orbit.
Sol.
11. Calculate the wavelength in angstrom of

photon that is emitted when an e – in Bohr orbit
n = 2 returns to the orbit n = 1. The ionization
potential of the ground state of hydrogen atom
is 2.17 × 10 –11 erg/atom.
18. The energy of an excited H–atom is –3.4 eV.

Calculate angular momentum of e– in the given
orbit.
Sol.
15. Estimate the difference in energy between I

and II Bohr orbit for a hydrogen atom. At what
minimum atomic number a transition from n = 2 to
n = 1 energy level would result in the emission of
X–rays with λ = 3.0 × 10–8m? Which hydrogen like
species does this atomic number correspond to.
Sol.
19. The vapours of Hg absorb some electrons

accelerated by a potential difference of 4.5 volt as
a result of which light is emitted. If the full energy
of single incident e– is supposed to be converted
into light emitted by single Hg atom, find the wave
number of the light.
Sol.
16. Calculate the wave no. for the shortest

wavelength transition in the Balmer series of atomic
hydrogen.
Sol.
20. If the average life time of an excited state of

H atom is of order 10–8 sec, estimate how many
orbits an e– makes when it is in the state n = 2
and before it suffers a transition to n = 1 state.
17. 1.8g hydrogen atoms are excited to radiations. Sol.
The study of spectra indicates that 27% of the
atoms are in 3rd energy level and 15% of atoms in
2nd energy level and the rest in ground state. If I.P.
of H is 21.7 × 10–12 erg. Calculate :
(i) No. of atoms present in III & II energy level.
(ii) Total energy evolved when all the atoms return
to ground state.
Sol.
21. Calculate the frequency of e– in the first Bohr

orbit in a H–atom.
Sol. Sol.
22. A single electron orbits around a stationary

nucleus of charge +Ze where Z is atomic number
and ‘e’ is the magnitude of the electric charge. The
hydrogen like species required 47.2 eV to excite the
electron from the second Bohr orbit to the third
PHOTOELECTRIC EFFECT
Bohr orbit. Find :
25. Calculate the threshold frequency of metal if
(i) the value of Z and give the hydrogen like species
the binding energy is 180.69 kJ mol–1 of electron.
formed.
Sol.
(ii) the kineitc energy and potential energy of the
electron in the first Bohr orbit.
Sol.
26. Calculate the binding energy per mole when

threshold wavelength of photon is 240 nm.
Sol.
23. A stationary He + ion emitted a photon
corresponding to a first line of the Lyman series.
The photon liberated a photoelectron from a
stationary H atom in ground state. What is the
velocity of photoelectron.
Sol.
27. A metal was irriadated by light of frequency

3.2 × 1015 S–1. The photoelectron produced had its
K.E., 2 times the KE of the photoelectron which was
produced when the same metal was irriadated with
a light of frequency 2.0 × 1015 S–1. What is work
function.
24. To what series does the spectral lines of atomic Sol.
hydrogen belong if its wave number is equal to the
difference between the wave numbers of the following
two lines of the Balmer series 486.1 and 410.2 nm.
What is the wavelength of this.
31. The eyes of certain member of the reptile

family pass a single visual signal to the brain when
the visual receptors are struck by photon of
wavelength 850 nm. If a total energy of 3.15 × 10–14
J is required to trip the signal, what is the minimum
number of photons that must strike the receptor.
Sol.
28. U.V. light of wavelength 800 Å & 700 Å falls

on hydrogen atoms in their ground state & liberates
electrons with kinetic energy 1.8 eV and 4eV
respectively. Calculate planck’s constant.
Sol.
32. Find the number of photons of radiation of

frequency 5 × 1013 s–1 that must be absorbed in
order to melt one gm ice when the latent heat of
fusion of ice is 330 J/g.
Sol.
29. A potential difference of 20 kV is applied across

an X–ray tube. Find the minimum wavelength of X-
ray generated.
Sol.
33. Suppose 10–17J of light energy is needed by
the interior of the human eye to see an object. How
many photons of green light (λ = 550 nm) are
needed to generate this minimum amount of energy.
Sol.
30. The KE of an electron emitted from tungstan

surface is 3.06 eV. What voltage would be required
to bring the electron to rest.
Sol.
GENERAL
34. What is de–Broglie wavelength of a He–atom in
a container at 300 K. (Use Uavg)
Sol.
35. Through what potential difference must an Sol.

electron pass to have a wavelength of 500 Å.
Sol.
36. A proton is accelerated to one–tenth of the

velocity of light. If its velocity can be measured
with a precision ±1%. What must be its uncertainty 39. He atom can be excited to 1s1 2p1 by λ = 58.44nm.
in position. If lowest excited state for He lies 4857 cm–1 below the
Sol. above. Calculate the energy of the lower excitation
state.
Sol.
37. To what effective potential a proton beam be

sub jected to give its protons a wavelength of
1×10–10 m.
Sol.
40. A certain dye absorbs 4530 Å and fluoresces

at 5080 Å these being wavelengths of maximum
absorption that under given conditions 47% of the
absorbed energy is emitted. Calculate the ratio of
the number of quanta emitted to the number
absorbed.
Sol.
38. Calculate magnitude of orbital angular momentum

of an e– that occupies 1s, 2s, 2p, 3d, 3p.
41. The reaction between H2 and Br2 to form HBr

in presence of light is initiated by the photo
decomposition of Br2 into free Br atoms (free radicals)
by absorption of light. The bond dissociation energy
of Br2 is 192 kJ/mole. What is the longest wavelength 44. The dissociation energy of H2 is 430.53 KJ/
of the photon that would initiate the reaction. mole. If H2 is exposed to radiant energy of wavelength
Sol. 253.7 nm, what % of radiant energy will be converted
into K.E..
Sol.
42. The quantum yield for decomposition of HI is

0.2. In an experiment 0.01 moles of HI are
decomposed. Find the number of photons absorbed.
Sol.
45. X–ray emitted from a copper target and a
molybdenum target are found to contain a line of
wavelength 22.85 nm attributed to the Kα line of an
impurity element. The Kα lines of copper (Z = 29)
and molybdenum (Z = 42) have wavelength 15.42
nm and 7.12 nm respectively. Using Moseley’s
law, γ1/2 = a(Z – b), calculate the atomic number
of the impurity element.
Sol.
43. Calculate the wavelength of the radiation that

would cause photo dissociation of chlorine molecule
if the Cl–Cl bond energy is 243 kJ/mole.
Sol.
46. What is de–Broglie wavelength associated with an

e– accelerated through potential difference = 100 KV.
Sol.
49. An electron has a speed of 40 m/s, accurate

up to 99.99%. What is the uncertainity in locating
its position.
Sol.
47. Calculate the de–Broglie wavelength associated

with motion of earth (mass 6 × 1024 kg) orbiting
around the sun at a speed of 3 × 106 m/s.
Sol.
50. The electrons identified by quantum numbers 'n'

and :
(a) n = 4, = 1
(b) n = 4, = 0
(c) n = 3, = 2
(d) n = 3, = 1
can be placed in order of increasing energy as :
(A) (b) < (d) < (a) < (c)
(B) (a) < (c) < (b) < (d)
(C) (c) < (d) < (b) < (a)
(D) (d) < (b) < (c) < (a)
Sol.
48. A base ball of mass 200 g is moving with

velocity 30 × 102 cm/s. If we can locate the base
ball with an error equal in magnitude to the λ of the
light used (5000 Å), how will the uncertainty in
momentum be compared with the total momentum
of base ball.
Sol.
Integer Type
51. If electron shows transition from n2 = 4 to n1 = 2
Then, number of fine lines in the spectral line
according to Sommerfeld model is ?
Sol. Sol.
54. Find the maximum nuber of electrons in ground

state configuration of Zn which have l = any
positive integral value and m = any non zero value.
Sol.
52. If the spin quantum number can have the following

 3 1 1 3
val ues  − ,− ,0,+ ,+  then, number of
 2 2 2 2
elements in 10th period of periodic table.
Sol.
55. Find the difference in the value of (n + ) for 19th

electron of Cr and 21st electron Sc.
Sol.
53. What is the atomic number of first atom in which

l ast e l e ct ron has ente re d 5g 1 e l e ct roni c
configuration according to n + rule
56. Fe+x ion have spin magnetic moment m = 35 58. Calculate Zeff(effective nuclear charge) using
B.M. slater rules on last electron of V+4.
Find the maximum multiplicity of the electrons in Sol.
d-subshell in Fe+x.
Sol.
59. A proton is fired from very far away towards a

nucleus with charge Q = 120 e, where e is the
electronic charge. It makes a closest approach
of 10 fm to the nucleus. The de Broglie
wavelength (in units of fm) of the proton at its
start is: (take the proton mass, mp = (5/3) x
-27 -15 1
10 kg; h/e = 4.2 x 10 J.s/C; =9X
4πε o
9 -15
57. Total number of subshell vacant upto outer most 10 m/F; 1 fm = 10 m)
of Ca. Sol.
Sol.
Exercise - II
1. An energy of 68eV is required to excite a Sol.
hydrogen like atom from its second Bohr orbit to
the third. The nuclear charge is Ze. Find the
value of Z, the kinetic energy of the electron in
the first Bohr orbit and the wavelength of the
radiation required to eject the electrons from the
first Bohr orbit to infinity.
Sol.
3. An alpha particl e after passing through a

potential difference of 2 × 106 volts falls on a
silver foil. The atomic number of silver is 47.
Calculate (i) the K.E. of the alpha–particle at the
time of falling on the foil. (ii) K.E. of the α–
particle at a distance of 5 × 10–14m from the
nucleus, (iii) the shortest distance from the nucleus
of silver to which the α–particle reaches.
2. A particle of charge equal to that an electron
Sol.
and mass 208 times the mass of the electron
moves in a circular orbit around a nucleus of
charge +3e. Assuming that the Bohr model of the
atom is applicable to this system, (a) derive an
expression for the radius of the nth bohr orbit,
(b) find the value of n for which the radius of the
orbit is approximately the same as that of the
first Bohr orbit for the hydrogen atom, and (c)
find the wavelength of the radiation emitted when
the revolving particle jumps from the third orbit
to the first.
5. A proton captures a free electron whose KE is

zero & forms a hydrogen atom of lowest energy-
level (n = 1). If a photon is emitted in this
process, what will be the wavelength of radiation?
In which region of electromagnetic spectrum, will
this radiation fall? (Ionisation potential of hydrogen
= 13.6 volt, h = 6.6 × 10–34 K/s, C = 3.0 × 108
m/s)
Sol.
4. Suppose the potential energy between electron

ke 2
and proton at a distance r is given by – . Use
3r 3
Bo hr’ s the ory to ob ta i n ene rgy of s uch a
hypothetical atom.
Sol.
6. The ionisation energy of the hydrogen atom is

given to be 13.6 eV. A photon falls on a hydrogen
atom which is initially in the ground state and
excites it to the (n = 4) state.
(a) show this transition in the energy–level diagram
&
(b) calculate the wavelength of the photon.
Sol.
8. The ionisation energy of a H–like Bohr atom is

4 Rydbergs.
(i) What is the wavelength of radiation emitted
when the e – jumps from the first excited state to
the ground state.
(ii) What is the radius of first Bohr orbit for this
atom. [1 Rydberg = 2.18 × 10–18 J]
Sol.
7. Find the wavelength of the first line of He+ ion

spectral series whose interval between extreme
1 1 
line is  − = 2.7451× 10 4 cm −1  .
λ
 1 λ 2 
Sol.
9. Photon having wavelength 12.4 nm was allowed

to strike a metal plate having work function 25
eV. Calculate the
(a) Maximum kinetic energy of photoelectrons
emitted in eV.
(b) Wavelength of electron with maximum kinetic
energy in Å.
(c) Calculate the uncertainity in wavelength of
emitted el ectron if the uncertaini ty i n the
momentum is 6.62 × 10–28 Kg m/sec.
Sol.
11. The angular momentum of an electron in a

Bohr’s orbit of H–atom is 3.1652 × 10–34 kg-m 2/
sec. Calculate the wavenumber in terms of Rydberg
constant (R) of the spectral line emitted when an
electron falls from this level to the ground state.
[Use h = 6.626 × 10–34 Js]
Sol.
10. Electron present in single electron specie

jumps from energy level 3 to 1. Emitted photons
when passed through a sample containing excited
He + ion causes further excitation to some higher
Z2
energy level (Given En = − 13.6 ). Determine
n2
(i) Atomic number of single electron specie.
(ii) principal quantum number of initial excited
level and higher energy level of He +.
Sol.
12. A cylindrical source of light which emits 13. Mr. Santa has to decode a number “ABCDEF”
radiation radially (from curved surface) only, placed where each alphabet is represented by a single
at the centre of a hollow, metallic cylindrical digit. Suppose an orbital whose radial wave
surface, as shown in diagram. functional is represented as :
The power of source is 90 watt and it emits light

Ψ(r ) = k1·e −r / k 2 (r2 – 5k 3r + 6k 32)
of wavelength 4000 Å only. The emitted photons
strike the metallic cylindrical surface which results
i n e j e ct i o n o f p ho to e l ec t r ons . Al l e j e ct e d From the following information given about each
photoelectrons reaches to anode (light source). alphabet then write down the answers in the form
The magnitude of photocurrent is [Given : h = 6.4 of “ABCDEF”, for above orbital.
× 10–34 J/sec]
Info A = Value of n where “n” is principal quantum
number.
Cathode 120º
Info B = No. of angular nodes
Info C = Azimuthal quantum number of subshell to

orbital belongs
Inf o D = N o. o f subs hel l s hav i ng e ne rg y

between (n + 5)s to (n + 5)p where n is principal
quantum number.
Anode (light source)
Sol. Info E = Orbital angular momentum of given orbital.
Info F = Radial distance of the spherical node

which is farthest from the nucleus.
(Assuming k 3 = 1)
Sol.
14. In the Bohr’s model, for unielectronic species

following symbols are used,
rn,z → Radius of nth orbit with atomic number

“z”. 15. Calculate the distance of spherical nodes for
‘3s’ orbital from nucleus ?
Un,z → Potential energy of electron in nth orbit
with atomic number “z”.
σ
1 −
K n,z → Kinetic energy of electron in nth orbit R3s = (6 − 6σ + σ2 )e 2
9 3a30 / 2
with atomic number “z”.
v n,z → Velocity of electron in nth orbit with

2r
atomic number “z”. where σ =
na0
T n,z → Time period of revolution of electron in
Sol.
nth orbit with atomic number “z”.
Calculate z in all in cases.
(i) U1,2 : K 1,z = –8 : 1 (ii) r1,z : r2,1 = 1 : 8

(iii) v 1,z : v 3,1 = 9 : 1 (iv) T 1,2 : T 2,z = 9 : 32
Represent your answer as abcd, where a,b,c and

d represent number from 0 to 9. a,b,c and d
represents the value of "z" in parts (i), (ii), (iii)
& (iv). Suppose your answer is 1,2,3 & 4 then the
same must be filled in OMR sheet as 1234.00.
Sol.
Exercise - III
Fill in the blanks : 7. Which electronic level would allow the hydrogen
1. Radiation of λ = 155 nm was irradiated on Li (work atom to absorb a photon but not to emit a photon:
function = 5eV) plate. The stopping potential (in (A) 3s (B) 2p (C) 2s (D) 1s
eV) is ______________. Sol.
2. Increasing order of magnetic moment among the

following species is __________ .
Na+, Fe+3, Co2+, Cr+2
3. If in the hydrogen atom P.E. at ∞ is choosen to
be 13.6 eV then the ratio of T.E. to K.E. for 1st orbit
of H-atom is __________ .
4. The light radiations with discrete quantities of

energy are called ___________ .
Single Correct :
5. The ratio of the energy of a photon of 2000 Å
wavelength radiation to that of 4000 Å radiation is
(A) 1/4 (B) 4 (C) 1/2 (D) 2
8. The third line in Balmer series corresponds to an
Sol.
electronic transition between which Bohr’s orbits in
hydrogen :
(A) 5 → 3 (B) 5 → 2
(C) 4 → 3 (D) 4 → 2
Sol.
6. The energy of electron is maximum at :

(A) Nucleus (B) Ground state
(C) First excited state
(D) Infinite distance from the nucleus 9. The orbital angular momentum of an electron in
Sol. 2s orbital is :
1
(A) + . (B) Zero (C) (D) 2.
2 2π 2π 2π
Sol.
10. Which quantum number is not related with 13. An electron, a proton and an alpha particle
Schrodinger equation : have kinetic energies of 16E, 4E and E respectively.
(A) Principal (B) Azimuthal What is the qualitative order of their de-Broglie
(C) Magnetic (D) Spin wavelengths?
Sol. (A) λe > λp = λα (B) λp = λα > λe
(C) λp > λe > λα (D) λα < λe >> λp
Sol.
11. The shortest wavelength of He atom in Balmer

series is x, then longest wavelength in the Paschene
14. Given ∆H for the process Li(g) → Li+3(g) + 3e–
series of Li+2 is :
is 19800 kJ/mole & ΙE1 for Li is 520 then ΙE2 & ΙE3 of
36 x 16 x 9x 5x Li+ are respectively (approx, value) :
(A) (B) (C) (D)
5 7 5 9 (A) 11775, 7505 (B) 19280, 520
Sol. (C) 11775, 19280 (D) Data insufficient
Sol.
12. An electron in a hydrogen atom in its ground

state absrobs energy equal to the ionisation energy 15. The ratio of difference in wavelengths of 1st
of Li+2. The wavelength of the emitted electron is and 2nd lines of Lyman series in H–like atom to
(A) 3.32 × 10–10 m (B) 1.17 Å difference in wavelength for 2nd and 3rd lines of
(C) 2.32 × 10–9 nm (D) 3.33 pm same series is :
Sol. (A) 2.5 : 1 (B) 3.5 : 1
(C) 4.5 : 1 (D) 5.5 : 1
Sol.
16. If radius of second stationary orbit (in Bohr’s

atom) is R. Then radius of third orbit will be :
(A) R/3 (B) 9R (C) R/9 (D) 2.25R
Sol.
19. ( )
The Value of (n2 + n1) and n22 − n12 for He+ ion
in atomic spectrum are 4 and 8 respectively. The
wavelength of emitted photon when electron jump
from n2 to n1 is
32 9 9 32
(A) R (B) RH (C) 32 R (D) 9 R
9 H 32 H H
Sol.
17. T he r at i o o f wa ve l engt h of p ho to n
corresponding to the α-line of lyman series in H-
atom and β -line of Baimer series in He+ is ;
(A) 1 : 1 (B) 1 : 2
(C) 1 : 4 (D) 3 : 16
Sol.
20. Number of possible spectral lines which may be

emitted in bracket series in H atom if electrons
present 9th excited level returns to ground level, are
(A) 21 (B) 6 (C) 45 (D) 5
Sol.
18. Three energy levels P, Q, R of a certain atom

are such that EP < EQ < ER. If λ1, λ2, and λ3, are
the wave length of radiation corresponding to
transition R → Q : Q → P and R → P respectively.
The correct relationship between λ1, λ2 and λ3 is
1 1 1
(A) λ1 + λ2 = λ3 (B) λ = λ + λ
3 1 2
2 1 1
(C) λ 3 = λ1λ 2 (D) λ = λ + λ
3 1 2
Sol.
21. The first use of quantum theory to explain the

structure of atom was made by :
(A) Heisenberg (B) Bohr (C) Planck (D) Einstein
Sol. Sol.
22. The wavelength associated with a golf weighing

200g and moving at a speed of 5m/h is of the order: 25.Consider the following nuclear reactions involving X & Y.
(A) 10–10 m (B) 10–20 m X → Y + 2He4 Y → 8O18 + 1H1
(C) 10–30 m (D) 10–40 m If both neutrons as well as protons in both the sides
Sol. are conserved in nuclear reaction then moles of
neutrons in 4.6 gm of X :
(A) 2.4 NA (B) 2.4 (C) 4.6 (D) 0.2 NA
Sol.
23. The longest wavelength of He+ in Paschen

series is “m”, then shortest wavelength of Be3+ in
Paschen series is (in terms of m) :
5 64 53 7
(A) m (B) m (C) m (D) m 26. Electromagnetic radiations having λ = 310 Å are
36 7 8 64 subjected to a metal sheet having work function =
Sol. 12.8 eV. What will be the velocity of photoelectrons
with maximum Kinetic energy.
(A) 0, no emission will occur
(B) 2.18 × 106 m/s
(C) 2.18 2 × 106 m/s (D) 8.72 × 106 m/s
Sol.
24. What is uncertainity in location of a photon of

wavelength 5000 Å if wavelength is known to an
accuracy of 1 pm?
(A) 7.96 × 10–14 m (B) 0.02 m
(C) 3.9 × 10–8 m (D) none
27. Assuming Heisenberg Uncertainity Principle to independent of θ and φ.

be true what could be the miniumum uncertainity in (IV) ‘2p’ orbital with quantum numbers. n = 2, l = 1,
de–Broglie wavelength of a moving electron m = 0, also shows angular dependence
accelerated by Potential Difference of 6V whose Sol.
uncertainity in position is 7/22 n.m.
(A) 6.25 Å (B) 6 Å
(C) 0.625 Å (D) 0.3125 Å
Sol.
29. Correct statement(s) regarding 3py orbital is/are :

(A) Angular part of wave function is independent of
angles (θ and φ).
(B) No. of maxima when a curve is plotted between
4πr2R2(r) vs r are ‘2’.
(C) ‘xz’ plane acts as nodal plane.
(D) Magnetic quantum number must be ‘–1’.
More than one may be correct : Sol.
1. When photons of energy 4.25 eV strike the surface
of a metal A, the ejected photoelectrons have
maximum kinetic energy T A eV and de Broglie
wavelength λ A . The maximum kinetic energy of
photoelectrons liberated from another metal B by
photons of energy 4.70 eV is TB = (TA – 1.50) eV. If
the de Broglie wavelength of these photoelectrons is
λB = 2λA, then select the correct statement (s)
(A*) the work function of A is 2.25 eV.
(B*) the work function of B is 4.20 eV.
(C*) TA = 2.00 eV.
(D) TB = 2.75 eV.
Sol.
30. Select the correct statement(s) :
(A) All electromagnetic radiation travel with speed of
light in vaccum.
(B) Energy of photon of UV light is lower than that
of yellow light.
(C) He+ and H have similar spectrum.
(D) The total energy of an electron in unielectronic
specie is greater than zero.
Sol.
28. Choose the correct statement among the

following :
(I) Radial distribution function (ψ 2.4πr2dr) give
probability at a particular distance along one chosen
direction.
(II) ψ 2(r) give probability density at a particular
distance over a spherical surface.
(III) For ‘s’ orbitals ψ (r)ψ (θ)ψ (φ) = ψ (x, y, z) is
31. Choose the incorrect statement(s) :

(A) Increasing order of wavelength is
Micro waves > Radio waves > IR waves > visible
waves > UV waves
(B) The order of Bohr radius is (rn : where n is orbit
number for a given atom) r1 < r2 < r3 < r4
(C) The order of total energy is (En : where n is
orbit number for a given atom) E1 > E2 > E3 > E4
(D) The order of velocity of electron in H, He+, Li+, 33. Which is/are correct statement.
Be3+ species in second Bohr orbit is
(A) The difference in angular momentum associated
Be3+ > Li+2 > He+ > H with the electron present in consecutive orbits of H-
Sol. h
atom is (n–1)
2π
(B) Energy difference between energy levels will be
charged if, P. E. at infinity assigned value other than
zero.
(C) Frequency of spectral line in a H-atom is in the
order of (2 →1) < (3 → 1) < (4 →1)
(D) On moving away from the nucleus, kinetic energy
of electron decreases.
Sol.
32. Select the correct curve(s) :

If v = velocity of electron in Bohr’s orbit.
r = Radius of electron in Bohr’s orbit.
P.E. = Potential energy of electron in Bohr’s orbit.
K.E. = Kinetic energy of electron in Bohr’s orbit.
v r
Assertion and Reason :
(A) (B)
34. It is a data sufficiency problem in which it is
n n to be decided on the basis of given statements
whether the given question can be answered or
P.E. K.E. not. No matter whether the answer is yes or no.
Question : Is the orbital of hydrogen atom 3px?
(C) 1/n (D) Statement–1 : The radial function of the orbital is
n 1 r
R(r) = (4 – σ)σe–σ/2, σ =
9 6a 30 / 2 2
Sol.
Statement–2 : The orbital has 1 radial node & 0
angular node.
(A) Statement (1) alone is sufficient.
(B) Statement (2) alone is sufficient.
(C) Both together is sufficient.
(D) Neither is sufficient.
Sol. Match the column :

37. Match the column
Column–I and Column–II contain data on Schrondinger
Wave–Mechanical model, where symbols have their
usual meanings. Match the columns.
Column–I
ψr
35. Statement–1 : Energy emitted when an (A) (B) ψr2 4π r2

electron jump from 5 → 2 (energy level) is less than
when an electron jump from 2 → 1 in all ‘H’ like r
atom. (C) ψ (θ, φ) = K (independent of θ & φ)
Statement–2 : The |total energy difference| (D) atleast one angular node is present
between 1st & 2nd energy level is greater than that Column–II
of any two energy level provided level ‘1’ is not part
(P) 4s (Q) 5px (R) 3s (S) 6dxy
of those two energy levels.
(A) Statement–1 is true, statement–2 is true and Sol.
statement–2 is correct explanation for statement–1.
(B) Statement–1 is true, statement–2 is true and statement–
2 is not the correct explanation for statement–1.
(C) Statement–1 is true, statement–2 is false.
(D) Statement–1 is false, statement–2 is true.
Sol.
36. Statement–1 : Emitted radiations will fall in

visible range when an electron jump from higher
level to n = 2 in Li+2 ion.
Statement–2 : Balmer series radiations belong to
visible range in all H–like atoms.
(A) Statement–1 is true, statement–2 is true and
statement–2 is correct explanation for statement–1.
(B) Statement–1 is true, statement–2 is true and statement–
38. Match the column
2 is not the correct explanation for statement–1.
Column–I
(C) Statement–1 is true, statement–2 is false.
(A) Electron moving in 2nd orbit in He+ electron is
(D) Statement–1 is false, statement–2 is true.
(B) Electron moving in 3rd orbit in H–atom
Sol.
(C) Electron moving in 1st orbit in Li+2 ion
(D) Electron moving in 2nd orbit in Be+3 ion
Column–II
(P) Radius of orbit in which moving is 0.529 Å
(Q) Total energy of electron is (–)13.6 × 9 eV
2.188 × 10 6
(R) Velocity of electron is m/s
3
150
(S) De–broglie wavelength of electron is Å
13.6
Sol. ∆x and the uncertainity in the momentum ∆(mv)

must be greater than or equal to h/4π. i.e.
h
∆x ∆(mv) ≥
4π
39. The correct order of wavelength of Hydrogen

(1H1), Deuterium (1H2) and Tritium (1H3) moving
with same kinetic energy is :
(A) λH > λD > λT (B) λH = λD = λT
(C) λH < λD < λT (D) λH < λD > λT
Sol.
Comprehension–1 (Q.39 to Q.41) (3 questions)

The French physicist Louis de-Broglie in 1924
postulated that matter, like radiation, should exhibit
a dual behaviour. He proposed the following
relationship between the wavelength λ of a material
particle, its linear momentum p and planck constant
h.
h h
λ = =
p mv
The de Broglie relation implies that the wavelength
of a particle should decreases as its velocity 40. The transi ti on, so that the de–Brogl i e
increases. It also implies that for a given velocity wavelength of electron becomes 3 times of its initial
heavier particles should have shorter wavelength value in He+ ion will be :
than lighter particles. The waves associated with (A) 2 → 5 (B) 3 → 2
particles in motion are called matter waves or de
(C) 2 → 6 (D) 1 → 2
Broglie waves. These waves differ from the
electromagnetic waves as they, Sol.
(i) have lower velocities
(ii) have no electrical and magnetic fields and
(ii i) are not emi tted by the parti cl e under
consideration.
The experimental confirmation of the de–Broglie
relation was obtained when Davisson and Germer, in
1927, observed that a beam of electrons is diffracted
by a nickel crystal. As diffraction is a characteristic
property of waves, hence the beam of electron
behaves as a wave, as proposed by de–Broglie.
Werner Heisenberg considered the limits of how
precisely we can measure properties of an electron
or other microscopic particle like electron. He
determined that there is a fundamental limit of how
closely we can measure both position and momentum.
The more accurately we measure the momentum of
a particle, the less accurately we can determine its 41. If the uncertainty in velocity & position is
position. The converse is also ture. This is summed same, then the uncertainty in momentum will be :
up in what we now call the “Heisenberg uncertainty
principle : It is impossible to determine simultaneously hm h h 1 h
(A) (B) m (C) (D)
and precisely both the momentum and position of a 4π 4π 4πm m 4π
particle. The product of undertainty in the position,
Sol. (A) 1.76 × 10–18 J (B) 1.98 × 10–18 J

(C) 1.76 × 10–17 J (D) None of these
Sol.
Comprehension–2 (Q.42 to Q.45) (4 questions)

The only electron in the hydrogen atom resides 43. In a collection of H–atom, electrons make
under ordinary conditions on the first orbit. When transition from 5th excited state to 2nd excited
energy is supplied, the electron moves to higher state then maximum number of different types of
energy orbit depending on the amount of energy photons observed are :
absorbed. When this electron returns to any of the (A) 3 (B) 4 (C) 6 (D) 15
lower orbits, it emits energy. Lyman series is formed Sol.
when the electron returns to the lowest orbit while
Balmer series is formed when the electron returns to
second orbit. Similarly, Paschen, Brackett and Pfund
series are formed when electron returns to the
third, fourth and fifth orbits from higher energy
orbits respectively.
Maximum number of lines produced when an electron
jumps from nth level to ground level is equal to
n(n − 1)
. For examle, in the case of n = 4, number 44. The difference in the wavelength of the 1st line
2 of Lyman series and 2nd line of Balmer series in a
o f l i ne s pr od uc ed i s 6. ( 4 → 3, 4 → 2, hydrogen atom is :
4 → 1, 3 → 2, 3 → 1, 2 → 1). When an electron
returns from n2 to n1 state, the number of lines in 9 4 88
(A) (B) (C) (D) None
the spectrum will be equal to 2R R 15R
(n2 − n1 )(n2 − n1 + 1) Sol.
2
If the electron comes back from energy level having
energy E2 to energy level having energy E1, then
the difference may be expressed in terms of energy
of photon as :
hc
E2 – E1 = ∆E, λ =
∆E
Since h and c are constants, ∆E corresponds to
definite energy; thus each transition from one energy
level to another will produce a light of definite 45. The wave number of electromagnetic radiation
wavelength. This is actually observed as a line in emitted during the transition of electron in between
the spectrum of hydrogen atom. two levels of Li2+ ion whose principal quantum
Wave number of line is given by the formula numbers sum is 4 and difference is 2 is :
(A) 3.5 R (B) 4 R (C) 8 R (D) 8/9 R
 1 1 
ν = R − . Sol.
 n2 n2 
 1 2
where R is a Rydberg’s constant (R = 1.1 × 107 m–1)

42. The energy photon emitted corresponding to
transition n = 3 to n = 1 is [h = 6 × 10–34 J-sec]
Exercise - IV JEE-Problems
1. With what velocity should an α–particle travel
towards the nucleus of a Cu atom so as to arrive
at a distance 10–13 m. [JEE 1997]
Sol.
4. Which of the following statement(s) is (are) correct

2. A compound of Vanadium has magnetic moment of
? [JEE 1998]
1.73 BM work out electronic configuration of Vanadium
(A) The electronic configuration of Cr is [Ar] 3d54s1
Ion in the compound. [JEE 1997]
(Atomic Number of Cr = 24)
Sol.
(B) The magnetic quantum number may have a
negative value
(C) In silver atom, 23 electron have a spin of one
type and 24 of the opposite type. (Atomic Number
of Ag = 47)
(D) The oxidation state of nitrogen in HN3 is -3.
Sol.
3. The energy of an electron in the first Bohr orbit

of H atom is –13.6 eV. The possible energy value(s)
of the excited state(s) for electrons in Bohr orbits
of hydrogen is/are : [JEE 1998]
(A) –3.4 eV (B) –4.2 eV
(C) –6.8 eV (D) +6.8 eV
Sol.
5. Assertion: Zn2+ is diamagnetic. [JEE 1998] 7. Ground state electronic configuration of nitrogen
Reason: The electrons are lost from 4s orbital to atom can be represented by [JEE 1999]
form Zn2+.
(A) Both assertion and reason are correct and reason (A)
is the correct explanation of the assertion.
(B) Both assertion and reason are correct but the (B)
reason is not the correct explanation of the assertion.
(C) Assertion is correct but reason is incorrect. (C)
(D) Assertion is incorrect but reason is correct.
Sol. (D)
Sol.
6. The electrons, identified by quantum numbers n

and l (i) n = 4, l = 1, (ii) n = 4, l = 0 (iii) n = 3,
l = 2 and (iv) n = 3, l = 1 can be placed in order
of increasing energy, from the lowest to highest, as
[JEE 1999]
(A) (iv) < (ii) < (iii) < (i) (B) (ii) < (iv) < (i) < (iii)
(C) (i) < (iii) < (ii) < (iv) (D) (iii) < (i) < (iv) < (ii)
Sol. 8. Electronic confi guration of an element is
1s22s22p63s23p63d54s1. This represents its
[JEE 2000]
(A) excited state (B) ground state
(C) cationic form (D) anionic form
Sol.
9. The wavelength associated with a golf ball weighing 11. Calculate the energy required to excite one
200 g and moving at a speed of 5 m/h is of the litre of hydrogen gas at 1 atm and 298 K to the first
order [JEE 2001] excited state of atomic hydrogen. The energy for
(A) 10-10 m (B) 10-20m the dissociation of H–H is 436 kJ mol–1.
(C) 10-30 m (D) 10-40 m Sol.
Sol.
12. The quantum numbers +1/2 and –1/2 for the

electron spin represent :
(A) rotation of the electron in clockwise and
10. The number of nodal planes in a px orbital is anticlockwise direction respectively.
: [ J E E (B) rotation of the electron in anticlockwise and
2000] clockwise direction respectively.
(A) one (B) two (C) three (D) zero (C) magnetic moment of the electron pointing up
Sol. and down respectively.
(D) two quantum mechanical spin states which have
no classical analogue. [JEE 2001]
Sol.
13. Rutherfords experiment, which established the 15. The radius of which of the following orbit is
nuclear model of atom, used a beam of : same as that of the first Bohr’s orbit of hydrogen
(A) β –particles, which impinged on a metal foil and atom?
get absorbed. (A) He+ (n = 2) (B) Li2+ (n = 2)
(B) γ–rays, which impinged on a metal foil and (C) Li2+ (n = 3) (D) Be3+ (n = 2)
ejected electron. [JEE 2004]
(C) Helium atoms, which impinged on a metal foil Sol.
and got scattered.
(D) Helium nuclie, which impinged on a metal foil and
got scattered. [JEE 2002]
Sol.
16. The Schrodinger wave equation for hydrogen

atom is
14. The magnetic moment of cobalt of the 3/2 r0
compound Hg[Co(SCN)4] is [Given : Co+2] 1  1   r  −
Ψ2s =    2 − 0 e a0
   a0 
(A) 3 (B) 8 (C) 15 (D) 24 4 2π  a0  
[JEE 2004] Where a0 is Bohr's radius. If the radial node is 2s
Sol. be at r0, then find r0 in term of a0.
[JEE 2004]
Sol.
17. A ball of mass 100 g is moving with 100 m/s.

Find its wavelength [JEE 2004]
Sol.
20. Given in hydrogenic atom rn, Vn, E, Kn stand

for radius, potential energy, total energy and kinetic
energy in nth orbit. Find the value of U, v, x, y.
[JEE 2006]
Column-I
(A) U = Vn / Kn
18. The number of radial nodes of 3s and 2p 1
(B) ∝ Ex
orbitals are respectively. [JEE 2004] rn
(A) 2,0 (B) 0,2 (C) 1,2 (D) 2,1 (C) rn ∝ Zy (Z = atomic number)
Sol. (D) v = (Orbital angular momentum of electron in
its lowest energy.)
Column-II
(P) 1
(Q) –2
(R) –1
(S) 0
Sol.
19. Find the velocity(m/s) of electron in first Bohr's

orbit of radius a0. Also find the de Broglie's
wavelength (in m). Find the orbital angular momentum
h
of 2p orbital of hydrogen atom in units of .
2π
[JEE 2004]
Sol.
21. Match the entries is Column–I with the correctly
related quantum number(s) in Column–II. Indicate
your answer by darkening the appropriate bubbles of
the 4 × 4 matrix given in the ORS. [JEE 2008]
Column–I
(A) Orbital angular momentum of the electron in a
hydrogen-like atomic orbital
(B) A hydrogen-like one-electron wave function
function obeying Pauli principle
(C) Shape, size and orientation of hydrogen like
atomic orbitals
(D) Probability density of electron at the nucleus
in hydrogen-like atom
Column–II
(P) Principal quantum number
(Q) Azimuthal quantum number
(R) Magnetic quantum number
(S) Electron spin quantum number Paragraph for questions 23 to 25
Sol. The hydrogen-like species Li2+ is in a spherically
symmetric state S1 with one radial node. Upon
absorbing light the ion undergoes transition to a state
S2. The state S2 has one radial node and its energy is
equal to the ground state energy of the hydrogen
atom.
[JEE 2010]
23. The state S1 is
(A) 1 s (B) 2s (C) 2p (D) 3s
Sol.
22. Assuming that Hund's rule is violated, the bond

order and magnetic nature of the diatomic molecular
B2 is [JEE 2010]
(A) 1 and diamagnetic (B) 0 and diamagnetic
(C) 1 and paramagnetic (D) 0 and paramagnetic
Sol. 24. Energy of the state S1 in units of the hydrogen
atom ground state energy is
(A) 0.75 (B) 1.50 (C) 2.25 (D) 4.50
Sol.
25. The orbital angular momentum quantum number

of the state S2 is
(A) 0 (B) 1 (C) 2 (D) 3
Sol. Sol.
28. The kinetic energy of an electron in the second

Bohr orbit of a hydrogen atom is [a0 is Bohr radius]
[JEE 2012]
26. The maximum number of electrons that can have 2 2
principal quantum number, n = 3, and spin quantum h h
(A) 4π2ma2 (B) 16π2ma2
number, ms = – 1/2, is: [JEE 2011] 0 0
Sol.
2 2
h h
(C) 32π2ma2 (D) 64π2ma2
0 0
Sol.
27. The work function (φ) of some metals is listed

below. The number of metals which will show
photoelectric effect when light of 300 nm wavelength
falls on the metal is [JEE 2011]
Metal Li Na K Mg Cu Ag Fe Pt W
(eV) 2.4 2.3 2.2 3.7 4.8 4.3 4.7 6.3 4.75
ANSWER-KEY
Exercise-I
1. 9.7 × 10–8 m 2. –1.36 × 10–19 J 3. 6
4. 4863 Å 5. 1.096 × 107 m–1 6. n1 = 1, n2 = 2
7. 1.827 × 105 J/mol 8. 1403 KJ/mol 9. 6563 Å; 1216 Å; 1026 Å
10. 5.425 × 10–12 ergs, 3.7 × 10–5 cm 11. 1220 Å
12. 5.44 × 105 m/s 13. 2; 9.75 × 104 cm–1 14. 113.74 Å
15. 10.2 eV, z = 2 16. 27419.25 cm–1
17. 292.68 × 1021 atoms, 162.60 × 1021 atoms, 832.50 KJ 18. h/ π
19. 3.63 × 106 m–1 20. 8 × 106 21. 6530 × 1012 Hz
22. 340 ev, –680 eV 23. 3.09 × 108 cm/sec 24. Brackett; 2.63 × 10–4 cm
25. 4.5 × 1014 s–1 26. 497 KJ/mol 27. 319.2 KJ/mol
28. 6.57 × 10–34 Js 29. 0.62 Å 30. 3.06 Å
31. 1.35 × 105 32. 1022 33. 28 photons
34. 0.79 Å 35. 6.03 × 10–4 volt 36. 1.05 × 10–13 m
h h ; h
37. 0.0826 volts 38. 0 ; 0 ; 2 ; 6 2
2π 2π 2π
39. 3.3 × 10–18 J 40. 0.527
41. 6235 Å 42. 3 × 1022 43. 4.9 × 10–7 m
44. 8.68% 45. 24 46. 3.88 pm
47. 3.68 × 10–65 m 48. 1.75 × 10–29 49. 0.0144 m
50. D
Integer Type
51. 8 52. 180 53. 121 54. 16
55. 1 56. 6 57. 4 58. 5
59. 7
Exercise-II
n 2h 2
1. 6 ; 489.6 eV, 25.28 Å 2. rn = n = 25 ; 55.2 pm
4Kπ 2 × 3e 2 × 208m e
n6h6
3. 6.4 × 10–13 J, 2.1 × 10–13 J, 3.4 × 10–14 m 4. E =
384 m3K 2 e 4 π 6
5. 910 Å; U.V. 6. 973.5 Å 7. 4689 Å
8. 303.89 Å, 2.645 × 10–9 cm 9. (a) 75 eV; (b) 1.414 Å; (c) 2 × 10–14 m
10. Energy of emitted photons can not be greater than 13.6 eV (otherwise He+ will ionise) therefore single electron specie
must be hydrogen energy emitted = E3 – E1 = –1.51 + 13.6 = 12.09
For He+ ion this energy corresponds to excitation from 2 to 6. 11. R(8 / 9) 12. 10 amp
9+3 3 9−3 3
13. 300303 14. 1233.00 15. a0 , a0
2 2
Exercise-III
1. 3 eV 2. Na+, Co2+, Cr2+, Fe3+ 3. zero 4. Photons 5 D
6 D 7 D 8 B 9 B 10 D 11 B
12 B 13 A 14 A 15 B 16 D 17 A
18 B 19 C 20 B 21 B 22 C 23 D
24 B 25 B 26 C 27 C 28 AD 29 BC
30 AC 31 AC 32 BCD 33 CD 34 B 35 A
36 D 37 A-P, B-P,Q,S, C-P,R, D-Q,S 38 A-S, B-R, C-Q,D-P 39 A
40 C 41 A 42 A 43 C 44 B 45 C
Exercise-IV
1. 6.3 × 106 m/s 2. 23V
+2 : [Ar] 3d1 3. A 4. ABC 5. B
6. A 7. AD 8. B 9. A 10. A 11. 98.2 kJ
12. D 13. D 14. C 15. D 16. 2a0 17. 6.6 × 10–35 s–1
18. A 19. 3.34 × 10–10 m/sec 20. A-Q, B-P, C-R, D-S
21. A–QR; B–P,Q,RS ; C–P,Q,R; D–P,Q 22. A 23. B 24. C
25. B 26. 0009 27. 0004 28. C

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ATOMIC STRUCTURE Page # 39

Class Room Problems

4. Calculate for a hydrogen atom and a He+ ion:

6. Calculate the magnetic field induction at the

9. De te rm i ne the de -Brogl i e w av el engt h 11. At what minimum kinetic energy must a

10. Find the velocity of photoelectrons liberated

16. An automobile of mass 500 kg is moving with

18. Estimate the minimum errors in determining the

22. The size of an atomic nucleus is 10–14 m.

25. The wave function for electron in ground state

"a0" is radius of Bohr's orbit. Calculate the

30. Locate the nodal surfaces in

26. The normalized wave function of the hydrogen

Show that in such a state the most probable

31. Determine de-Broglie wavelength associated

33. A hypothetical element "positronium" consists

respect except possessing a positive charge.

32. At what temperature the transitional kinetic

5. Calculate the Rydberg constant R if He+ ions are

2. Calculate energy of electron which is moving in

6. What transition in the hydrogen spectrum would

3. The wavelength of a certain line in the Paschen

7. Calculate the total energy emitted when electrons

8. A photon having λ = 854 Å causes the ionization Sol.

12. The radius of the an orbit of hydrogen atom

13. The velocity or e– in a certain Bohr orbit of the

14. A doubly ionised lithium atom is hydrogen like

11. Calculate the wavelength in angstrom of

18. The energy of an excited H–atom is –3.4 eV.

15. Estimate the difference in energy between I

19. The vapours of Hg absorb some electrons

16. Calculate the wave no. for the shortest

20. If the average life time of an excited state of

21. Calculate the frequency of e– in the first Bohr

22. A single electron orbits around a stationary

26. Calculate the binding energy per mole when

27. A metal was irriadated by light of frequency

31. The eyes of certain member of the reptile

28. U.V. light of wavelength 800 Å & 700 Å falls

32. Find the number of photons of radiation of

29. A potential difference of 20 kV is applied across

30. The KE of an electron emitted from tungstan

35. Through what potential difference must an Sol.

36. A proton is accelerated to one–tenth of the

37. To what effective potential a proton beam be

40. A certain dye absorbs 4530 Å and fluoresces

38. Calculate magnitude of orbital angular momentum

41. The reaction between H2 and Br2 to form HBr

42. The quantum yield for decomposition of HI is

43. Calculate the wavelength of the radiation that

46. What is de–Broglie wavelength associated with an

49. An electron has a speed of 40 m/s, accurate

47. Calculate the de–Broglie wavelength associated

50. The electrons identified by quantum numbers 'n'

48. A base ball of mass 200 g is moving with

54. Find the maximum nuber of electrons in ground

52. If the spin quantum number can have the following

55. Find the difference in the value of (n + ) for 19th