DR.

SCHNELL Chemie GmbH

Safety Data Sheet

according to Regulation (EC) No 1907/2006

GLASAN
Print date: 21.07.2015 Product code: 70030_CLP Page 1 of 10

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

GLASAN
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Cleaning agent, alkaline
Uses advised against
No information available.
1.3. Details of the supplier of the safety data sheet
Company name: DR.SCHNELL Chemie GmbH
Street: Taunusstraße 19
Place: D-80807 München
Telephone: +49/89/350608-0 Telefax: +49/89/350608-47
e-mail: info@dr-schnell.de
Contact person: Josef Feuerstein Telephone: +49/89/350608-46
e-mail: sdb@dr-schnell.de
Internet: www.dr-schnell.de
Responsible Department: Labor
1.4. Emergency telephone Emergency CONTACT (24-Hour-Number) international:
number: GBK GmbH +49 (0) 61 32 - 8 44 63

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Hazard categories:
Skin corrosion/irritation: Skin Corr. 1A
Serious eye damage/eye irritation: Eye Dam. 1
Hazard Statements:
Causes severe skin burns and eye damage.
2.2. Label elements
Hazardous components which must be listed on the label
Alkohole, C12-14, ethoxyliert, sulfatiert, Natriumsalze
sodium hydroxide
Signal word: Danger
Pictograms:

Hazard statements
H314 Causes severe skin burns and eye damage.
Precautionary statements
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.

Revision No: 5 GB - EN Revision date: 21.07.2015

 DR.SCHNELL Chemie GmbH
Safety Data Sheet

according to Regulation (EC) No 1907/2006

GLASAN
Print date: 21.07.2015 Product code: 70030_CLP Page 2 of 10

P310 Immediately call a POISON CENTER/doctor.

2.3. Other hazards
The components in this formulation do not meet the criteria for classification as PBT or vPvB . High pH
value can damage water.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

Hazardous components
CAS No Chemical name Quantity
EC No Index No REACH No
Classification according to Regulation (EC) No. 1272/2008 [CLP]
68891-38-3 Alkohole, C12-14, ethoxyliert, sulfatiert, Natriumsalze 5 - < 10 %
500-234-8 01-2119488639-16
Skin Irrit. 2, Eye Dam. 1, Aquatic Chronic 3; H315 H318 H412
67-63-0 propan-2-ol 1-<5%
200-661-7 603-117-00-0
Flam. Liq. 2, Eye Irrit. 2, STOT SE 3; H225 H319 H336
1310-73-2 sodium hydroxide 1-<5%
215-185-5 011-002-00-6 01-2119457892-27
Skin Corr. 1A; H314
Full text of H and EUH phrases: see section 16.
Further Information
Regulation (EC) No. 648/2004 (Detergents regulation)
5 % - <15 % anionic surfactants
<5% phosphonates
perfumes, limonene

SECTION 4: First aid measures

4.1. Description of first aid measures

After inhalation
Move victim out of danger zone. Provide fresh air.
In all cases of doubt, or when symptoms persist, seek medical advice.
After contact with skin
After contact with skin, take off immediately all contaminated clothing, and wash immediately with
plenty of water. In case of skin irritation, seek medical treatment.
After contact with eyes
Rinse immediately carefully and thoroughly with eye-bath or water.
Remove contact lenses, if present and easy to do. Continue rinsing.
Call a physician immediately. To be accompanied by MSDS.
Protect uninjured eye. Consult an ophthalmologist.
After ingestion
Rinse mouth immediately and drink plenty of water.
Call a physician immediately.
4.2. Most important symptoms and effects, both acute and delayed
If applicable, delayed symptoms and effects can be found in section 11 . , i.e. under section 4.1 for
absorption methods.
It can take hours before symptoms of poisoning show up following exposure.

Revision No: 5 GB - EN Revision date: 21.07.2015

 DR.SCHNELL Chemie GmbH
Safety Data Sheet

according to Regulation (EC) No 1907/2006

GLASAN
Print date: 21.07.2015 Product code: 70030_CLP Page 3 of 10

4.3. Indication of any immediate medical attention and special treatment needed
No special measures are necessary.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media
Water spray. / alcohol resistant foam.
Unsuitable extinguishing media
High power water jet.
5.2. Special hazards arising from the substance or mixture
Hazardous combustion products
Oxides of carbon
Sulfur oxides.
Nitrogen oxides (NOx).
Phosphorus oxides.
Gas/vapours, toxic.
5.3. Advice for firefighters
In case of fire and/or explosion do not breathe fumes.
In case of fire: Wear self-contained breathing apparatus.
Alkali-resistant protective clothing (EN 13034)
If necessary Full protective suit.
Additional information
Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water.
Dispose of waste according to applicable legislation.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Provide adequate ventilation.
Avoid contact with skin and eyes.
Avoid breathing dust/fume/gas/mist/vapours/spray.
If necessary Caution, slippery
6.2. Environmental precautions
Prevent spread over a wide area (e.g. by containment or oil barriers).
Stop leak if safe to do so.
Prevent surface and ground-water infiltration, as well as ground penetration.
6.3. Methods and material for containment and cleaning up
Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents).
Treat the recovered material as prescribed in the section on waste disposal .
Can be diluted with water
Flush residue with plenty of water.
6.4. Reference to other sections
For personal protective equipment see Section 8 and for disposal instructions see Section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Advice on safe handling
In addition to the information contained in this section, relevant information can also be found in
sections 8 and 6.1.
Further information on handling
Provide adequate ventilation.
Revision No: 5 GB - EN Revision date: 21.07.2015
 DR.SCHNELL Chemie GmbH
Safety Data Sheet

according to Regulation (EC) No 1907/2006

GLASAN
Print date: 21.07.2015 Product code: 70030_CLP Page 4 of 10

Avoid contact with skin and eyes.

When using do not eat, drink or smoke.
Observe instructions for use.
Notice the directions for use on the label.
Working methods should be applied according to operating instructions .
General hygiene measures for the handling of chemicals are applicable.
Wash hands before breaks and after work.
Keep away from food, drink and animal feeding stuffs.
Contaminated work clothing should not be allowed out of the workplace.
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage rooms and vessels
Store in a place accessible by authorized persons only.
Store product closed and only in original packing.
Do not use materials not resistant to alkali.
storage temperature: at room temperature
7.3. Specific end use(s)
No information available.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Exposure limits (EH40)

CAS No Substance ppm mg/m³ fibres/ml Category Origin

67-63-0 Propan-2-ol 400 999 TWA (8 h) WEL

500 1250 STEL (15 min) WEL
1310-73-2 Sodium hydroxide - - TWA (8 h) WEL
- 2 STEL (15 min) WEL

8.2. Exposure controls

Appropriate engineering controls
Provide adequate ventilation.
This can be achieved by local exhaust ventilation or general ventilation.
When exceeding the occupational exposure limit (OEL):
Use appropriate respiratory protection.
Applies only if maximum permissible exposure values are listed here.
Protective and hygiene measures
General hygiene measures for the handling of chemicals are applicable.
Wash hands before breaks and after work.
Keep away from food, drink and animal feeding stuffs.
Contaminated work clothing should not be allowed out of the workplace.
Eye/face protection
Tightly sealed safety glasses. (EN 166)
If necessary Wear face protection. (EN 166)
Hand protection
Protective gloves made of natural latex (EN 374), Permeation time (penetration time) in minutes: 480
Protective gloves of nitrile (EN 374), Permeation time (penetration time) in minutes: 480
Recommendation: Manufacturer: KCL GmbH, D-36124 Eichenzell, E-mail: vertrieb@kcl.de
Specification No.: 706 Lapren, 730 Camatril Velours
Hand lotion are recommended.

Revision No: 5 GB - EN Revision date: 21.07.2015

 DR.SCHNELL Chemie GmbH
Safety Data Sheet

according to Regulation (EC) No 1907/2006

GLASAN
Print date: 21.07.2015 Product code: 70030_CLP Page 5 of 10

No tests have been carried out.

For special purposes, it is recommended to check the resistance to chemicals of the protective gloves
mentioned above together with the supplier of these gloves.
Skin protection
Alkali-resistant protective clothing (EN 13034)
Respiratory protection
When exceeding the occupational exposure limit (OEL): Filter A (EN 14387), brown
Observe the wear time limits according GefStoffV in combination with the rules for using respiratory
protection apparatus (BGR 190).
Environmental exposure controls
No information available.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state: liquid
Colour: yellow
Odour: characteristic
Test method
pH-Value: 13,6
Changes in the physical state
Melting point: not determined
Initial boiling point and boiling range: 95 °C
Flash point: 42 °C
Sustaining combustion: Not sustaining combustion
Flammability
Solid: not determined
Gas: not determined
Explosive properties
The product is not: Explosive.
Lower explosion limits: not determined
Upper explosion limits: not determined
Ignition temperature: not determined
Auto-ignition temperature
Solid: not determined
Gas: not determined
Oxidizing properties
not determined
Vapour pressure: not determined
Vapour pressure: not determined
Density: 1,028 g/cm³
Bulk density: not applicable
Water solubility: miscible.
Solubility in other solvents
not determined
Partition coefficient: not determined
Viscosity / dynamic: not determined

Revision No: 5 GB - EN Revision date: 21.07.2015

 DR.SCHNELL Chemie GmbH
Safety Data Sheet

according to Regulation (EC) No 1907/2006

GLASAN
Print date: 21.07.2015 Product code: 70030_CLP Page 6 of 10

Viscosity / kinematic: not determined

Vapour density: not determined
Solvent content: not determined
9.2. Other information
Mixability: not determined
Fat solubility (g/l): not determined
Conductivity: not determined
Surface tension: not determined

SECTION 10: Stability and reactivity

10.1. Reactivity
The product has not been tested.
10.2. Chemical stability
Stable with proper storage and handling.
10.3. Possibility of hazardous reactions
Contact with strong acids leads to strong reaction and heat production
10.4. Conditions to avoid
See also section 7.
No information available.
10.5. Incompatible materials
Avoid contact with strong acids.
Possibly extensive generation of hydrogen on contact with amphoteric metals (e.g. aluminium, lead,
zinc) (explosive hazard!).
Avoid contact with materials that are not alkali resistant .
10.6. Hazardous decomposition products
See also section 5.2.
No decomposition when used as directed.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Toxicocinetics, metabolism and distribution
Possibly more information on health effects, see Section 2.1 (classification).
Die Einstufung wurde nach dem Berechnungsverfahren der Zubereitungsrichtlinie (1999/45/EG)
vorgenommen.
Acute toxicity
Based on available data, the classification criteria are not met.

Revision No: 5 GB - EN Revision date: 21.07.2015

 DR.SCHNELL Chemie GmbH
Safety Data Sheet

according to Regulation (EC) No 1907/2006

GLASAN
Print date: 21.07.2015 Product code: 70030_CLP Page 7 of 10

CAS No Chemical name

Exposure routes Method Dose Species Source
68891-38-3 Alkohole, C12-14, ethoxyliert, sulfatiert, Natriumsalze
oral LD50 >2000 mg/kg Rat
dermal LD50 >2000 mg/kg Rat
67-63-0 propan-2-ol
oral LD50 5280 mg/kg Rat
dermal LD50 12800 mg/kg Rabbit
inhalative (4 h) vapour LC50 30 mg/l Rat
1310-73-2 sodium hydroxide
oral LD50 2000 mg/kg Rat

Irritation and corrosivity

Causes severe skin burns and eye damage.
Sensitising effects
Based on available data, the classification criteria are not met.
STOT-single exposure
Based on available data, the classification criteria are not met.
Severe effects after repeated or prolonged exposure
Based on available data, the classification criteria are not met.
Carcinogenic/mutagenic/toxic effects for reproduction
Based on available data, the classification criteria are not met.
Aspiration hazard
Based on available data, the classification criteria are not met.

SECTION 12: Ecological information

12.1. Toxicity
See section 2.1 (rating) for potentially additional information concerning environmental effects.
CAS No Chemical name
Aquatic toxicity Method Dose [h] | [d] Species Source
68891-38-3 Alkohole, C12-14, ethoxyliert, sulfatiert, Natriumsalze
Acute fish toxicity LC50 > 1-10 mg/l 96 h Brachydanio rerio
(zebra-fish)
Acute algae toxicity ErC50 >10 - 100 72 h Scenedesmus subspicatus
mg/l
Acute crustacea toxicity EC50 > 1-10 mg/l 48 h Daphnia magna
67-63-0 propan-2-ol
Acute fish toxicity LC50 9640 mg/l 96 h Pimephales promelas
Acute algae toxicity ErC50 >1000 mg/l 72 h Scenedesmus subspicatus
Acute crustacea toxicity EC50 13299 mg/l 48 h Daphnia magna
1310-73-2 sodium hydroxide
Acute fish toxicity LC50 45,4 mg/l 96 h Onchorhynchus mykiss
Acute crustacea toxicity EC50 >100 mg/l 48 h Daphnia magna

12.2. Persistence and degradability

The surfactants contained in this preparation comply with the biodegradability criteria as laid down in
Regulation (EC) No.648/2004 on detergents. Data to support this assertion are held at the disposal of

Revision No: 5 GB - EN Revision date: 21.07.2015

 DR.SCHNELL Chemie GmbH
Safety Data Sheet

according to Regulation (EC) No 1907/2006

GLASAN
Print date: 21.07.2015 Product code: 70030_CLP Page 8 of 10

the competent authorities of the Member States and will be made available to them, at their direct
request or at the request of a detergent manufacturer.
CAS No Chemical name
Method Value d Source
Evaluation
68891-38-3 Alkohole, C12-14, ethoxyliert, sulfatiert, Natriumsalze
OECD TG 301 A > 70 28
Easily biodegradable (concerning to the criteria of the OECD)

12.3. Bioaccumulative potential

No data available
12.4. Mobility in soil
No data available
12.5. Results of PBT and vPvB assessment
No data available
12.6. Other adverse effects
No data available

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Advice on disposal
Dispose of waste according to applicable legislation.
For example: designated incinerator
E.g. dispose at suitable refuse site.
Neutralisation possible by an expert.
Waste disposal number of waste from residues/unused products
200129 MUNICIPAL WASTES (HOUSEHOLD WASTE AND SIMILAR COMMERCIAL, INDUSTRIAL AND
INSTITUTIONAL WASTES) INCLUDING SEPARATELY COLLECTED FRACTIONS; separately
collected fractions (except 15 01); detergents containing dangerous substances
Classified as hazardous waste.
Waste disposal number of contaminated packaging
150102 WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND PROTECTIVE
CLOTHING NOT OTHERWISE SPECIFIED; packaging (including separately collected municipal
packaging waste); plastic packaging
Contaminated packaging
Dispose of waste according to applicable legislation.
Completely empty containers
Non-contaminated packages must be recycled or disposed of.
Handle contaminated packages in the same way as the substance itself.

SECTION 14: Transport information

Land transport (ADR/RID)

14.1. UN number: UN 1719
14.2. UN proper shipping name: CAUSTIC ALKALI LIQUID, N.O.S. (sodium hydroxide)
14.3. Transport hazard class(es): 8
14.4. Packing group: III
Hazard label: 8
Classification code: C5

Revision No: 5 GB - EN Revision date: 21.07.2015

 DR.SCHNELL Chemie GmbH
Safety Data Sheet

according to Regulation (EC) No 1907/2006

GLASAN
Print date: 21.07.2015 Product code: 70030_CLP Page 9 of 10

Special Provisions: 274

Limited quantity: 5L
Excepted quantity: E1
Transport category: 3
Hazard No: 80
Tunnel restriction code: E
Inland waterways transport (ADN)
14.1. UN number: UN 1719
14.2. UN proper shipping name: CAUSTIC ALKALI LIQUID, N.O.S. (sodium hydroxide)
14.3. Transport hazard class(es): 8
14.4. Packing group: III
Hazard label: 8
Classification code: C5
Special Provisions: 274
Limited quantity: 5L
Excepted quantity: E1
Marine transport (IMDG)
14.1. UN number: UN 1719
14.2. UN proper shipping name: CAUSTIC ALKALI LIQUID, N.O.S. (caustic soda, sodium hydroxide)
14.3. Transport hazard class(es): 8
14.4. Packing group: III
Hazard label: 8
Special Provisions: 223, 274
Limited quantity: 5L
Excepted quantity: E1
EmS: F-A, S-B
Air transport (ICAO)
14.1. UN number: UN 1719
14.2. UN proper shipping name: CAUSTIC ALKALI LIQUID, N.O.S. (caustic soda, sodium hydroxide)
14.3. Transport hazard class(es): 8
14.4. Packing group: III
Hazard label: 8
Special Provisions: A3 A803
Limited quantity Passenger: 1L
Passenger LQ: Y841
Excepted quantity: E1
IATA-packing instructions - Passenger: 852
IATA-max. quantity - Passenger: 5L
IATA-packing instructions - Cargo: 856
IATA-max. quantity - Cargo: 60 L
14.5. Environmental hazards
ENVIRONMENTALLY HAZARDOUS: no
14.6. Special precautions for user
Persons responsible for the transport of dangerous goods must be trained.
Security provisions must be observed by all persons involved.
Precautions must be taken to avoid injury

Revision No: 5 GB - EN Revision date: 21.07.2015

 DR.SCHNELL Chemie GmbH
Safety Data Sheet

according to Regulation (EC) No 1907/2006

GLASAN
Print date: 21.07.2015 Product code: 70030_CLP Page 10 of 10

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable, as freight is carried as general cargo, not in bulk.
Minimum quantity regulations are not observed here.
Other applicable information
Hazard number and packing code are available on request.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulatory information
2010/75/EU (VOC): 5%
2004/42/EC (VOC): 5%
Additional information
For classification and labelling, see section 2.
Observe trade association/occupational health regulations.
Observe Chemical Ordinance, ChemO
Observe Chemical Risk Reduction Ordinance, ORRChem
Observe Air Quality Control regulation
National regulatory information
Employment restrictions: Observe employment restrictions for young people.
Water contaminating class (D): 2 - water contaminating

SECTION 16: Other information

Changes
Revised sections: 2, 3, 9, 11, 12, 13, 14, 15, 16
Abbreviations and acronyms
vPvB = very persistent very bioaccumulative
PBT = persistent bioaccumulative toxic
Relevant H- and EUH-phrases (Number and full text)
H225 Highly flammable liquid and vapour.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
H412 Harmful to aquatic life with long lasting effects.
Further Information
The above information describes exclusively the safety requirements of the product and is based on
our present-day knowledge. The information is intended to give you advice about the safe handling of
the product named in this safety data sheet, for storage, processing, transport and disposal. The
information cannot be transferred to other products. In the case of mixing the product with other
products or in the case of processing, the information on this safety data sheet is not necessarily valid
for the new made-up material.

(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety
data sheet.)

Revision No: 5 GB - EN Revision date: 21.07.2015