AFFF 3% M C6 - Version 9 Page 1 of 14

SAFETY DATA SHEET

AFFF 3% M C6

The safety data sheet is in accordance with Commission Regulation (EU) 2015/830 of 28 May 2015 amending Regula-
tion (EC) No 1907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation
and Restriction of Chemicals (REACH)

SECTION 1: Identification of the substance / mixture and of the company /

undertaking
Date issued 18.08.2014
Revision date 16.04.2018

1.1. Product identifier

Product name AFFF 3% M C6
Article no. V-AFFF3M/

1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance / Appliance protection.
preparation

1.3. Details of the supplier of the safety data sheet

Downstream user
Company name Viking S.A.
Postal address Z.I. Haneboesch
Postcode L-4562
City Differdange/Niederkorn
Country Luxembourg
Telephone number +352 58 37 37 1
Fax +352 58 37 36
Website http://www.viking-emea.com

1.4. Emergency telephone number

Emergency telephone Telephone number: +44 1273 289451
Description: NCEC CareChem24
Identification, comments Additional Emergency Phone Number in Section16

SECTION 2: Hazards identification

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2.1. Classification of substance or mixture

Classification according to Eye Irrit. 2; H319; Calculation method
Regulation (EC) No 1272/
2008 [CLP / GHS]

2.2. Label elements

Hazard pictograms (CLP)

Composition on the label Diethylene glycol monobutyl ether 10 -19 %, Sodium decyl sulphate 1 -2,9 %,
Tolyltriazole, sodium salt 0,1 -0,5 %
Signal word Warning
Hazard statements H319 Causes serious eye irritation.
Precautionary statements P264 Wash thoroughly after handling. P280 Wear protective gloves / protective clothing
/ eye protection / face protection. P305+P351+P338 IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing. P337+P313 If eye irritation persists: Get medical advice / attention.

2.3. Other hazards

PBT / vPvB The product does not meet the criteria for PBT (persistent / bioaccumulative / toxic) or
vPvB (very persistent / very bioaccumulative).

SECTION 3: Composition / information on ingredients

3.2. Mixtures
Substance Identification Classification Contents
Diethylene glycol monobutyl CAS No.: 112-34-5 Eye Irrit. 2; H319; 10 -19 %
ether EC No.: 203-961-6
Index No.: 603-096-00-8
Ethanediol CAS No.: 107-21-1 Acute Tox. 4;H302 1 -5 %
EC No.: 203-473-3
Index No.: 603-027-00-1
REACH Reg. No.:
01-2119456816-28
Diethylene glycol CAS No.: 111-77-3 Repr. 2;H361d* 0,1 -0,9 %
monomethyl ether EC No.: 203-906-6
Index No.: 603-107-00-6
REACH Reg. No.:
01-2119475100-52
Methanol CAS No.: 67-56-1 Flam. Liq. 2; H225 0,1 -0,5 %
EC No.: 200-659-6 Acute tox. 3; H331
Index No.: 603-001-00-X Acute tox. 3; H311
REACH Reg. No.: Acute tox. 3; H301
01-2119392409-28 STOT SE1; H370
Alkyl polyglycoside CAS No.: 68515-73-1 Eye Dam. 1;H318 1 -2,9 %
EC No.: 500-220-1
REACH Reg. No.:

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01-2119488530-36-XXXX
Sodium decyl sulphate CAS No.: 142-87-0 Acute tox. 4; H302 1 -2,9 %
EC No.: 205-568-5 Eye Dam. 1; H318
REACH Reg. No.: Skin Irrit. 2; H315
01-2119970328-30 Aquatic Chronic 3; H412
Tolyltriazole, sodium salt CAS No.: 64665-57-2 Acute tox. 4; H302 0,1 -0,5 %
EC No.: 265-004-9 Skin Corr 1B; H314
REACH Reg. No.: Eye Dam. 1; H318
01-2119980062-42 Aquatic Chronic 2; H411

SECTION 4: First aid measures

4.1. Description of first aid measures
General Provide rest, warmth and fresh air. Get medical attention if any discomfort continues.
Inhalation Fresh air and rest. Get medical attention if any discomfort continues.
Skin contact Remove contaminated clothing and launder thoroughly before re-use. Wash skin
thoroughly with soap and water for several minutes. Get medical attention if any
discomfort continues.
Eye contact Immediately rinse with plenty of lukewarm water for at least 5 minutes. Remove any
contact lenses and open eyelids widely. Contact physician if discomfort continues.
Ingestion Immediately rinse mouth and drink plenty of water. Keep person under observation. If
person becomes uncomfortable seek hospital and bring these instructions.
Recommended personal No recommendation given.
protective equipment for first
aid responders

4.2. Most important symptoms and effects, both acute and delayed
General symptoms and ef- Causes eye irritation. After extensive contact, may cause irritation to skin. Ingestion of
fects large quantities may cause nausea, vomiting, dizziness, confusion, lost of
consciousness.

4.3. Indication of any immediate medical attention and special treatment needed
Medical treatment Treat Symptomatically.
Medical monitoring for de- No recommendation given.
layed effects
Separate first aid equipment No recommendation given.

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media This product is not flammable.

5.2. Special hazards arising from the substance or mixture

Fire and explosion hazards None.

5.3. Advice for firefighters

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Fire fighting procedures Follow the general fire precautions indicated by the workplace.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Personal protection mea- Avoid contact with skin and eyes. Do not breathe vapour. For personal protection, see
sures section 8.

6.2. Environmental precautions

Environmental precautionary Prevent discharge of larger quantity to drain. Avoid discharge to the aquatic
measures environment.

6.3. Methods and material for containment and cleaning up

Clean up Absorb in vermiculite, dry sand or earth and place into containers. Flush area clean
with lots of water. Be aware of potential for surfaces to become slippery. Further
handling of waste – see section 13.

6.4. Reference to other sections

Additional information See Sections 8 and 13 for information concerning protective equipment and waste
treatment methods.

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Handling Avoid contact with skin and eyes. Avoid inhalation of vapours. Wash hands before
breaks and before smoking, eating or drinking. Wash hands and contaminated areas
with water and soap after finished work. Container must be kept tightly closed.

7.2. Conditions for safe storage, including any incompatibilities

Storage Store at moderate temperatures in dry, well ventilated area. Keep container tightly
closed. Protect against direct sunlight.

7.3. Specific end use(s)

Specific use(s) See EWC-code under Section 13.

SECTION 8: Exposure controls / personal protection

8.1. Control parameters
Substance Identification Value TWA Year
Diethylene glycol monobutyl CAS No.: 112-34-5
ether
Ethanediol CAS No.: 107-21-1 TWA (8h) : 20 ppm, vapour
TWA (8h) : 52 mg/m3,
vapour
OEL short term value
Value: 40 ppm vapour

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OEL short term value

Value: 104 mg/m3 vapour
Diethylene glycol CAS No.: 111-77-3
monomethyl ether

DNEL / PNEC
Substance Diethylene glycol monomethyl ether
PNEC Comments: Predicted No Effect Concentration
12 mg/L aquatic organisms
100 mg/L microorganisms
1,4 mg/kg terrestrial environment
90 mg/kg predators
Substance Alkyl polyglycoside
DNEL Group: Consumer
Route of exposure: Long term (repeated) – Inhalation – Systemic effect
Value: 124 mg/m3

Group: Worker
Route of exposure: Long term (repeated) – Inhalation – Systemic effect
Value: 420 mg/m3

Group: Worker
Route of exposure: Long term (repeated) – Dermal – Systemic effect
Value: 595000 mg/kg bw/day

Group: Consumer
Route of exposure: Long term (repeated) – Oral – Systemic effect
Value: 35,7 mg/kg bw/day

Group: Consumer
Route of exposure: Long term (repeated) – Dermal – Systemic effect
Value: 357000 mg/kg bw/day

8.2. Exposure controls

Safety signs

Precautionary measures to prevent exposure

Appropriate engineering An eye wash bottle must be available at the work site.
controls

Eye / face protection

Suitable eye protection Wear approved chemical safety goggles where eye exposure is reasonably probable.

Hand protection
Skin- / hand protection, long In cases of prolonged, repeated or extensive exposure, wear protective gloves.
term contact

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Suitable gloves type Rubber or plastic.

Skin protection
Suitable protective clothing Use protective clothes in order to avoid skin contact.

Respiratory protection
Respiratory protection nec- In case of inadequate ventilation and work of brief duration, use suitable respiratory
essary at equipment.

Hygiene / environmental
Specific hygiene measures No specific hygiene procedures noted, but good personal hygiene practices are always
advisable, especially when working with chemicals.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state Clear, yellowish liquid.
Colour Yellowish.
Odour Slight odour.
Odour limit Comments: No information.
pH Status: In delivery state
Value: 6,5 – 8,5
Melting point / melting range Comments: No information.
Freezing point Value: -5 °C
Boiling point / boiling range Comments: No information.
Flash point Comments: Not relevant.
Evaporation rate Comments: No information.
Flammability (solid, gas) Not relevant.
Explosion limit Comments: Product is not explosive.
Vapour pressure Comments: No information.
Vapour density Comments: No information.
Specific gravity Value: ~ 1,03 g/ml
Solubility Comments: Soluble in water.
Partition coefficient: n-oc- Comments: No information.
tanol/water
Spontaneous combustability Comments: Not relevant.
Decomposition temperature Comments: No information.
Viscosity Value: ≤ 20 mPas
Method: Brookfield DV
Explosive properties Product is not explosive.

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Oxidising properties Does not meet the criteria for oxidising.

9.2. Other information

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity Stable product under normal conditions of handling and storage.

10.2. Chemical stability

Stability Stable product under normal conditions of handling and storage.

10.3. Possibility of hazardous reactions

Possibility of hazardous re- Stable product under normal conditions of handling and storage.
actions

10.4. Conditions to avoid

Conditions to avoid Not known under normal conditions of handling and storage.

10.5. Incompatible materials

Materials to avoid Alkali earth metals.

10.6. Hazardous decomposition products

Hazardous decomposition Thermal decomposition or combustion may liberate carbon oxides and other toxic
products gases or vapours.

SECTION 11: Toxicological information

11.1. Information on toxicological effects
Substance Ethanediol
Acute toxicity Type of toxicity: Acute
Effect tested: LD50
Route of exposure: Dermal
Value: = 9530 mg/kg bw
Animal test species: Rabbit
Comments: Non-acute toxic.
Substance Diethylene glycol monomethyl ether
Acute toxicity Type of toxicity: Acute
Effect tested: LC50
Route of exposure: Oral
Value: = 4000 mg/kg bw
Animal test species: Rat
Comments: Non-acute toxic.

Type of toxicity: Acute

Effect tested: LD50

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Route of exposure: Dermal

Value: = 6720 mg/kg bw
Animal test species: Rabbit
Comments: Non-acute toxic.
Substance Alkyl polyglycoside
Acute toxicity Type of toxicity: Acute
Effect tested: LD50
Route of exposure: Oral
Value: > 2000 mg/kg
Animal test species: Rat
Test reference: OECD 401

Type of toxicity: Acute

Effect tested: LD50
Route of exposure: Dermal
Value: > 2000 mg/kg
Animal test species: Rabbit
Test reference: OECD 423
Substance Sodium decyl sulphate
Acute toxicity Type of toxicity: Acute
Effect tested: LD50
Route of exposure: Oral
Value: = 1950 mg/kg bw
Animal test species: Rat
Comments: Hazardous if ingested.
Substance Tolyltriazole, sodium salt
Acute toxicity Type of toxicity: Acute
Effect tested: LD50
Route of exposure: Oral
Value: 630 -1980 mg/kg bw
Animal test species: Rat
Comments: Hazardous if ingested.

Other information regarding health hazards

Skin contact In case of prolonged contact wth skin, may cause irritation.
Eye contact Causes serious eye irritation.
Ingestion In case of ingestion of large quantities may cause nausea, vomiting, dizziness,
confusion, loss of consciousness.
Sensitisation No known chronic or acute health risks.
Mutagenicity No known chronic or acute health risks.
Carcinogenicity, other infor- No known chronic or acute health risks.
mation
Reproductive toxicity No known chronic or acute health risks.

Symptoms of exposure
In case of ingestion Ingestion of large quantities may cause cause nausea, vomiting, dizziness, confusion,

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loss of consciousness.
In case of skin contact Irritation is possible in case of prolonged contact with skin.
In case of eye contact Irritation of eyes and mucous membrane.

SECTION 12: Ecological information

12.1. Toxicity
Substance Ethanediol
Acute aquatic, fish Toxicity type: Acute
Value: = 18500 mg/l
Effect dose concentration : LC50
Exposure time: 96 hour(s)
Species: Oncorhynchus mykiss
Comments: Not hazardous for environment.
Substance Diethylene glycol monomethyl ether
Acute aquatic, fish Toxicity type: Acute
Value: = 1000 mg/l
Effect dose concentration : LC50
Exposure time: = 96 h
Species: Oncorhynchus mykiss
Comments: Not hazardous for environment.
Substance Methanol
Acute aquatic, fish Toxicity type: Acute
Value: = 15400 mg/l
Effect dose concentration : LC50
Exposure time: = 96 hour(s)
Species: Lepomis macrochirus
Comments: Not hazardous for environment.
Substance Alkyl polyglycoside
Acute aquatic, fish Value: ~ 20 mg/l
Test duration: 96 hrs
Species: Cyprinodon Variegatus
Method: OCDE 203
Substance Ethanediol
Acute aquatic, algae Toxicity type: Acute
Value: = 2000 mg/l
Effect dose concentration : IC50
Exposure time: = 72 hour(s)
Comments: Not hazardous for environment.
Substance Diethylene glycol monomethyl ether
Acute aquatic, algae Toxicity type: Acute
Value: > 500 mg/l
Effect dose concentration : IC50
Exposure time: 72 hour(s)
Species: Scenedesmus subspicatus
Comments: Not hazardous for environment.

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Substance Methanol
Acute aquatic, algae Toxicity type: Acute
Value: = 441 mg/l
Effect dose concentration : IC50
Exposure time: = 72 hour(s)
Comments: Not hazardous for environment.
Substance Alkyl polyglycoside
Acute aquatic, algae Value: ~ 21 mg/l
Test duration: 72 hrs
Species: Skeletonerna Costatum
Method: ISO 10253
Substance Ethanediol
Acute aquatic, Daphnia Toxicity type: Acute
Value: = 51000 mg/l
Effect dose concentration : EC50
Exposure time: = 48
Species: Daphina magna
Comments: Not hazardous for environment.
Substance Diethylene glycol monomethyl ether
Acute aquatic, Daphnia Toxicity type: Acute
Value: = 1192 mg/l
Effect dose concentration : EC50
Exposure time: = 48 hour(s)
Species: D. magna
Comments: Not hazardous for environment.
Substance Methanol
Acute aquatic, Daphnia Toxicity type: Acute
Value: = 24500 mg/l
Effect dose concentration : EC50
Exposure time: = 48 hour(s)
Species: D.magna
Comments: Not hazardous for environment.
Substance Alkyl polyglycoside
Acute aquatic, Daphnia Value: ~ 150 mg/l
Test duration: 48 hrs
Species: Acartia Tonsa
Method: ISO 14669
Ecotoxicity The product is not environmentally hazardous to aquatic life.
Aquatic, comments On basis of test data.

12.2. Persistence and degradability

Substance Ethanediol
Biodegradability Value: = 56 %
Method: degradation in 28 days OECD 301C
Comments: Not readily biodegradable.

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Substance Diethylene glycol monomethyl ether

Biodegradability Value: = 100 %
Method: degradation in 7 days OECD 302B
Comments: Readily biodegradable.
Substance Methanol
Biodegradability Value: = 99 %
Method: degradation in 28 days OECD 301D
Comments: Readily biodegradable.
Substance Alkyl polyglycoside
Biodegradability Value: ~ 100 %
Method: OCDE 301E
Test period: 28 days
Persistence and degradabili- The product is expected to be biodegradable.
ty, comments

12.3. Bioaccumulative potential

Bioaccumulative potential Bioaccumulation: Is not expected to be bioaccumulable.
Substance Ethanediol
Bioconcentration factor Value: = 10
(BCF) Comments: No bioaccumulation expected.
Substance Diethylene glycol monomethyl ether
Bioconcentration factor Value: = 0,2
(BCF) Comments: No bioaccumulation expected.
Substance Methanol
Bioconcentration factor Value: = 1
(BCF) Comments: No bioaccumulation expected.

12.4. Mobility in soil

Mobility The product contains substances, which are water soluble and may spread in water
systems.

12.5. Results of PBT and vPvB assessment

PBT assessment results Not Classified as PBT/vPvB by current EU criteria.

12.6. Other adverse effects

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Specify the appropriate Dispose of waste and residues in accordance with local authority requirements.
methods of disposal
EWC waste code EWC waste code: 160305 organic wastes containing dangerous substances
Classified as hazardous waste: Yes

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EU Regulations Directive 2008/98/EC of the European Parliament and of the Council of 19 November
2008 on waste and repealing certain Directives. Annex III to Directive 2008/98/EC.

SECTION 14: Transport information

Dangerous goods No

14.1. UN number
Comments Not applicable. No information required.

14.2. UN proper shipping name

Comments Not applicable. No information required.

14.3. Transport hazard class(es)

Comments Not applicable. No information required.

14.4. Packing group

Comments Not applicable. No information required.

14.5. Environmental hazards

Comments Not applicable. No information required.

14.6. Special precautions for user

14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

Additional information
Additional information The product is not covered by international regulation on the transport of dangerous
goods (IMDG, IATA, ADR/RID).

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations / legislation specific for the sub-
stance or mixture
EEC-directive Commission Directive 2006/15/EC of 7 February 2006 establishing a second list of
indicative occupational exposure limit values in implementation of Council Directive 98/
24/EC and amending Directives 91/322/EEC and 2000/39/EC. Commission Directive
2012/45/EU adapting for the second time the Annexes to Directive 2008/68/EC of the
European Parliament and of the Council on the inland transport of dangerous goods to
scientific and technical progress.
National regulations Deutschland Wassergefährdungsklasse (WGK): 1
Legislation and regulations Commission Regulation (EU) 2015/830 of 28 May 2015 amending Regulation (EC) No
1907/2006 of the European Parliament and of the Council on the Registration,
Evaluation, Authorisation and Restriction of Chemicals (REACH). Regulation (EC) No
1272/2008 on classification, labelling and packaging of substances and mixtures,
amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending

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Regulation (EC) No 1907/2006.

15.2. Chemical safety assessment

Chemical safety assessment Yes
performed

SECTION 16: Other information

List of relevant H-phrases H225 Highly flammable liquid and vapour.
(Section 2 and 3) H301 Toxic if swallowed.
H302 Harmful if swallowed.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H318 Causes Serious eye damage.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H370 Causes damage to organs
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
Classification according to Eye Irrit. 2; H319; Calculation method
Regulation (EC) No 1272/
2008 [CLP / GHS]
Additional information Emergency Phone No
*Europe (English, Dutch, French, German, Italian, Spanish) +44 1273 289451
France (English, French) +33 1 72 11 00 03
Germany (English, German) +49 69 222 25285
Spain (English, Spanish) +34 91 114 2520
Italy (English, Italian) +39 02 3604 2884
Netherlands (English, Dutch) +31 10 713 8195
*Middle East (English, Arabic) +44 1273 289454
United States (English, French, Spanish) +1 866 928 0789
Canada (English, French) +1 800 579 7421
United States and Canada (English) +1 202 464 2554
Mexico (English, Spanish) +52 55 5004 8763
Brazil (Portuguese, Spanish, English) +55 11 3197 5891
Chile (English, Spanish) +56 2 2582 9336
Colombia (English, Spanish) +57 1 508 7337
Argentina (English, Spanish) +54 11 5984 3690
*East/South East Asia (English, Bahasa Malaysia, Hindi, Japanese, Korean, Mandarin,
Tagalog) +65 3158 1412
China (English, Mandarin) +86 512 8090 3042
China (Mainland) (English, Mandarin) **+86 532 8388 9090
Japan (English, Japanese) +81 3 4578 9341
Malaysia (English, Malaysian) +60 3 6207 4347
India (English, Hindi) 000 800 100 7479
Philippines (English, Tagalog) +63 2 231 2149
South Korea (English, Korean) +82 2 3479 8401
Australia (English) +61 2 8014 4558
Australia (English) 18000 74234
New Zealand (English) +64 9 929 1483
New Zealand (English) 0800 446 881

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Last update date 06.11.2017

Version 9

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