Safety Data Sheet as per regulation (EC) 1907/2006

Commercial Product Name : FIS V 360/950 S - Component A (Mortar ) ..

Revision Date : 28.03.2017 Replaces version from : 11.01.2017
Version : 5.3 /en Print date : 05.04.2017

SECTION 1: Identification of the substance/mixture and of the company/

undertaking

1.1 Product identifier

Commercial Product Name FIS V 360/950 S - Component A (Mortar )

1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses composite mortar
Recommended restrictions None under normal processing. Observe technical data sheet.

1.3 Details of the supplier of the safety data sheet

Company designation fischerwerke GmbH & Co. KG
Klaus-Fischer-Straße 1
D-72178 Waldachtal
Telephone : +49(0)7443 12-0
FAX : +49(0)7443 12-4222
Email : info-sdb@fischer.de
Internet : www.fischer.de
Marketer Great Britain: Mrs Mirka Valovicova, fischer Fixing (UK) Ltd, Hithercroft
Road, Wallingford, Oxfordshire, OX10 9AT, Tel. 01491 827 920, Fax
01491 827 950

1.4 Emergency telephone number

Emergency telephone number +49(0)6132-84463 (24h)

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Reg- Skin Irrit. 2; H315 Eye Dam. 1; H318 Skin Sens. 1; H317
ulation (EC) No. 1272/2008

2.2 Label elements

Hazard pictogram

GHS05 GHS07

Signal word Danger

Hazardous component(s) to be tetramethylendimethacrylat , Cement , portland , chemicals , 2-hy-
indicated on label droxypropyl methacrylate
H-statement(s) H315: Causes skin irritation.
H317: May cause an allergic skin reaction.

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Safety Data Sheet as per regulation (EC) 1907/2006
Commercial Product Name : FIS V 360/950 S - Component A (Mortar ) ..
Revision Date : 28.03.2017 Replaces version from : 11.01.2017
Version : 5.3 /en Print date : 05.04.2017

H318: Causes serious eye damage.

P-statement(s) P101: If medical advice is needed, have product container or label at
hand.
P102: Keep out of reach of children.
P280: Wear protective gloves/protective clothing/eye protection/face
protection.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.

2.3 Other hazards

Health hazard None known.
Particular information pertain- None known.
ing specific risk for human / en-
vironment
Indication of danger None known.
Hazard precautions None known.

SECTION 3: Composition/information on ingredients

Hazardous ingredients
Ingredient Classification (EC) 1272/2008 Concen-
tration
tetramethylendimethacrylat CAS No. : 2082-81-7 Skin Sens. 1; H317 10.0 -
EC-No. : 218-218-1
25.0 % by
REACH No. :
01-2119967415-30 weight
Cement, portland, chemi- CAS No. : 65997-15-1 Skin Irrit. 2;H315 Eye Dam. 1; H318 10.0 -
EC-No. : 266-043-4
cals STOT SE 3;H335 25.0 % by
REACH No. : The sub-
stance does not require weight
registration according
to Regulation (EC) No
1207/2006 [REACH].
2-hydroxypropyl methacry- CAS No. : 27813-02-1 Skin Sens. 1; H317 Eye Irrit. 2; H319 2.5 -
EC-No. : 248-666-3
late 10.0 % by
REACH No. :
01-2119490226-37 weight

SECTION 4: First aid measures

4.1 Description of first aid measures

General advice If symptoms persist, call a physician.
Remove/Take off immediately all contaminated clothing.
If inhaled IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing.
In case of skin contact IF ON SKIN: Gently wash with plenty of soap and water.

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Safety Data Sheet as per regulation (EC) 1907/2006
Commercial Product Name : FIS V 360/950 S - Component A (Mortar ) ..
Revision Date : 28.03.2017 Replaces version from : 11.01.2017
Version : 5.3 /en Print date : 05.04.2017

In case of eye contact In case of eye contact, remove contact lens and rinse immediately
with plenty of water, also under the eyelids, for at least 15 minutes.
If swallowed If swallowed, seek medical advice immediately and show this contain-
er or label.
Clean mouth with water and drink afterwards plenty of water. Drink 1
or 2 glasses of water.
Do NOT induce vomiting.

4.2 Most important symptoms and effects, both acute and delayed
Symptoms None known.

4.3 Indication of any immediate medical attention and special treatment needed
Immediate medical attention No data available
Special medical treatment No data available

SECTION 5: Firefighting measures

5.1 Extinguishing media

Suitable extinguishing media Carbon dioxide (CO2)
Dry powder
Foam
Water spray jet
Extinguishing media which must High volume water jet
not be used for safety reasons

5.2 Special hazards arising from the substance or mixture

Special exposure hazards arising Heating or fire can release toxic gas.
from the substance or prepara-
tion itself, its combustion prod-
ucts, or released gases

5.3 Advice for firefighters

Special protective equipment for In the event of fire, wear self-contained breathing apparatus.
firefighting In the event of fire and/or explosion do not breathe fumes.
Additional information on fire- Fire residues and contaminated fire extinguishing water must be dis-
fighting posed of in accordance with local regulations.
Keep containers and surroundings cool with water spray.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions Ensure adequate ventilation, especially in confined areas.
Keep people away from and upwind of spill/leak.

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Safety Data Sheet as per regulation (EC) 1907/2006
Commercial Product Name : FIS V 360/950 S - Component A (Mortar ) ..
Revision Date : 28.03.2017 Replaces version from : 11.01.2017
Version : 5.3 /en Print date : 05.04.2017

6.2 Environmental precautions

Environmental precautions The product should not be allowed to enter drains, water courses or
the soil.
Prevent spreading over a wide area (e.g. by containment or oil barri-
ers).

6.3 Methods and material for containment and cleaning up

Methods for cleaning up Use mechanical handling equipment.
Treat recovered material as described in the section "Disposal consid-
erations".

6.4 Reference to other sections

Reference to other sections See chapter 8/13

6.5 Additional information

Other information Dispose of in accordance with local regulations.

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Advice on safe handling None under normal processing.
Caution: During machining in cured state dust is formed.
Advice on protection against fire No special precautions required.
and explosion

7.2 Conditions for safe storage, including any incompatibilities

Storage space and container re- Keep containers tightly closed in a cool, well-ventilated place.
quirements Store in accordance with local regulations.
Keep only in original container.
Hints on storage assembly Store in accordance with the particular national regulations.
German storage class 10-13 (TRGS 510)

7.3 Specific end use(s)

Specific use(s) composite mortar
Further information: see technical data sheet.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Cement, portland, chemicals

Great Britain
Long-term exposure value/ mg/m3 Remarks Source
10 inhalable dust 100
4 respirable dust 100

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Safety Data Sheet as per regulation (EC) 1907/2006
Commercial Product Name : FIS V 360/950 S - Component A (Mortar ) ..
Revision Date : 28.03.2017 Replaces version from : 11.01.2017
Version : 5.3 /en Print date : 05.04.2017

Source : 100 - Company data

Leerzeile

8.2 Exposure controls

Respiratory protection No personal respiratory protective equipment normally required.
Hand protection not required under normal use
Suitable material : butyl-rubber, Chloroprene, Nitrile rubber
Unsuitable material : PVC disposable gloves
Material thickness : adjust to application and duration of use
Break through time : adjust to application and duration of use
Remarks : Take note of the information given by the producer concerning per-
meability and break through times, and of special workplace condi-
tions (mechanical strain, duration of contact).
Reference substance : Replace when worn.
Eye protection Tightly fitting safety goggles
Skin and body protection Wear suitable protective equipment.
Note : Choose body protection according to the amount and concentration
of the dangerous substance at the work place.
General protective and hygiene Smoking, eating and drinking should be prohibited in the application
measures area.
Avoid contact with skin, eyes and clothing.
Take off all contaminated clothing immediately.
Wash hands before breaks and at the end of workday.
Keep away from food, drink and animal feedingstuffs.
Use protective skin cream before handling the product.
Information on environmental No special environmental precautions required.
protection regulations

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Form paste
Colour light grey
Odour characteristic
Odour threshold not determined
pH No data available
Melting point [°C] / Freezing No data available
point [°C]

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Safety Data Sheet as per regulation (EC) 1907/2006
Commercial Product Name : FIS V 360/950 S - Component A (Mortar ) ..
Revision Date : 28.03.2017 Replaces version from : 11.01.2017
Version : 5.3 /en Print date : 05.04.2017

Boiling point [°C] no data available

Flash point [°C] > 100
Evaporation rate [kg/(s*m²)] No data available
Flammability (solid, gas) No data available
Explosion limits [Vol-% ]
Lower limit : not determined
Upper limit : not determined
Vapour pressure [kPa] No data available
Vapour density No data available
Density [g/cm³] 1,7 - 1,8
Temperature : 20 °C
Relative density No data available
Solubility No data available
Water solubility [g/l] not determined
Solubility [g/l] No data available
Partition coefficient n-octanol / No data available
water (log P O/W)
Autoinflammability not auto-flammable
Decomposition temperature [°C] not determined
Viscosity, dynamic [kg/(m*s)] 120 - 160
Temperature : 20 °C
Explosive properties Not explosive
Risk of explosion. Not explosive
Oxidising properties No

9.2 Other information

Relative vapour density (air=1) not determined

SECTION 10: Stability and reactivity

10.1 Reactivity
Thermal decomposition No decomposition if stored and applied as directed.

10.2 Chemical stability

Chemical stability Stable under recommended storage conditions.

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Safety Data Sheet as per regulation (EC) 1907/2006
Commercial Product Name : FIS V 360/950 S - Component A (Mortar ) ..
Revision Date : 28.03.2017 Replaces version from : 11.01.2017
Version : 5.3 /en Print date : 05.04.2017

10.3 Possibility of hazardous reactions

Hazardous reactions No dangerous reaction known under conditions of normal use.

10.4 Conditions to avoid

Conditions to avoid No decomposition if used as directed.

10.5 Incompatible materials

Materials to avoid Not applicable.

10.6 Hazardous decomposition products

Hazardous decomposition prod- No decomposition if used as directed.
ucts

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Hazardous ingredients

Tetramethylen dimethacrylate
Oral toxicity [mg/kg] Test criterion Test species Source
> 2000 LD50 rat 100
Source : 100 - Company data

Dermal toxicity [mg/kg] Test criterion Test species Source

> 3000 LD50 rabbit 100
Source : 100 - Company data

Inhalative toxicity [mg/l] Source

No data available 100
Source : 100 - Company data

Sensitization Skin sensitizer

Carcinogenic effects Contains no ingredient listed as a carcinogen
Mutagenicity Not applicable.
Reproduction toxicity Not applicable.
Caustic effect Not applicable.
Specific target organ toxicity (single expo- Specific effects Source
sure) [mg/kg]
none 100
Source : 100 - Company data

Specific target organ toxicity (repeated expo- Specific effects Source

sure) [mg/kg]
none 100

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Safety Data Sheet as per regulation (EC) 1907/2006
Commercial Product Name : FIS V 360/950 S - Component A (Mortar ) ..
Revision Date : 28.03.2017 Replaces version from : 11.01.2017
Version : 5.3 /en Print date : 05.04.2017

Source : 100 - Company data

Cement, portland, chemicals

Oral toxicity [mg/kg] Test criterion Remarks Source
> 2000 LD50 literature value 100
Source : 100 - Company data

Dermal toxicity [mg/ Test criterion Test species Remarks Source

kg]
> 2000 LD50 rabbit Limit test 2000 mg/kg 100
Source : 100 - Company data

Inhalative toxicity Test criterion Test species Note Source

[mg/l]
>5 LC50 rat Limit Test 5 g/m³ 100
Source : 100 - Company data

Sensitization May cause an allergic skin reaction.

Carcinogenic effects Not applicable.
Mutagenicity Not applicable.
Reproduction toxicity Not applicable.
Caustic effect No data available
Specific target organ toxicity (single expo- Specific effects Source
sure) [mg/kg]
Irritating to respiratory system. (dust) 100
Source : 100 - Company data

Specific target organ toxicity (repeated expo- Remarks Source

sure) [mg/kg]
Not applicable. 100
Source : 100 - Company data

2-hydroxypropyl methacrylate
Oral toxicity [mg/kg] Test criterion Test species Remarks Source
> 2000 LD50 rat OECD 401 Limit Test. 100
Source : 100 - Company data

Dermal toxicity [mg/kg] Test criterion Test species Source

> 5000 LD50 rabbit 100
Source : 100 - Company data

Inhalative toxicity [mg/l] Source

No data available 100
Source : 100 - Company data

Sensitization Skin sensitizer

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Safety Data Sheet as per regulation (EC) 1907/2006
Commercial Product Name : FIS V 360/950 S - Component A (Mortar ) ..
Revision Date : 28.03.2017 Replaces version from : 11.01.2017
Version : 5.3 /en Print date : 05.04.2017

Carcinogenic effects Not applicable.

Mutagenicity Not applicable.
Remarks OECD 471 (Ames Test) / OECD 476.
Reproduction toxicity Not applicable.
Remarks OECD 422.
Caustic effect Not applicable.
Specific target organ toxicity (single expo- Remarks Source
sure) [mg/kg]
Not applicable. 100
Source : 100 - Company data

Specific target organ toxicity (repeated expo- Remarks Source

sure) [mg/kg]
Not applicable. 100
Source : 100 - Company data

Leerzeile
Irritant effect on skin Irritating to skin and mucous membranes
Irritant effect on eyes Irritating to eyes.

11.2 Additional information

Other information (chapter 11.) The product itself has not been tested.

SECTION 12: Ecological information

12.1 Toxicity
Hazardous ingredients

Tetramethylen dimethacrylate
Toxicity to fish [mg/l] Test criterion Measuring method Exposure duration Source
32,5 LC50 DIN 38412 48 h 100
Source : 100 - Company data

Toxicity to algae [mg/ Test criterion Test species Measuring method Source
l]
9,79 EC50 Scenedesmus capricor- OECD Test Guideline 100
nutum (fresh water al- 201
gae)
Source : 100 - Company data

NOEC (daphnia) [mg/l] Test species Measuring method Source

7,51 Daphnia magna (Big water flea). OECD 211 100
Source : 100 - Company data

Biodegradability Readily biodegradable.

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Safety Data Sheet as per regulation (EC) 1907/2006
Commercial Product Name : FIS V 360/950 S - Component A (Mortar ) ..
Revision Date : 28.03.2017 Replaces version from : 11.01.2017
Version : 5.3 /en Print date : 05.04.2017

Ready degradability
Cement, portland, chemicals
Toxicity to fish [mg/l] Test criterion Source
> 100 LC50 100
Source : 100 - Company data

Toxicity to daphnia [mg/l] Test criterion Test species Source

> 100 LC50 Daphnia magna (Water flea) 100
Source : 100 - Company data

Toxicity to algae [mg/l] Test criterion Source

> 100 EC50 100
Source : 100 - Company data

Biodegradability Not applicable. (inorganic)

2-hydroxypropyl methacrylate
Toxicity to fish Test criterion Test species Measuring Exposure dura- Source
[mg/l] method tion
493 LC50 Leuciscus idus DIN 38412 48 h 100
(Golden orfe)
Source : 100 - Company data

Toxicity to daph- Test criterion Test species Exposure dura- Measuring Source
nia [mg/l] tion method
> 130 EC50 Daphnia magna 48 h OECD Test Guide- 100
(Water flea) line 202
Source : 100 - Company data

Toxicity to algae Test criterion Test species Exposure dura- Measuring Source
[mg/l] tion method
> 97,2 EC50 Selenastrum capri- 72 h OECD Test Guide- 100
cornutum line 201
Source : 100 - Company data

NOEC (daphnia) Test criterion Test species Measuring Exposure dura- Source
[mg/l] method tion
24,1 NOEC Daphnia magna OECD 202 21 d 100
(Big water flea).
Source : 100 - Company data

Biodegradability Readily biodegradable.

Ready degradability
Leerzeile

12.2 Persistence and degradability

Elimination and distribution There is no data available for this product.
mechanisms

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Safety Data Sheet as per regulation (EC) 1907/2006
Commercial Product Name : FIS V 360/950 S - Component A (Mortar ) ..
Revision Date : 28.03.2017 Replaces version from : 11.01.2017
Version : 5.3 /en Print date : 05.04.2017

Elimination in purification plant There is no data available for this product.

12.3 Bioaccumulative potential

Bioaccumulation There is no data available for this product.
Bioconcentration factor (BCF) There is no data available for this product.

12.4 Mobility in soil

Distribution in the environment There is no data available for this product.
Mobility
Mobility : There is no data available for this product.

12.5 Results of PBT and vPvB assessment

Results of PBT characteristics This preparation contains no substance considered to be very persis-
determination tent nor very bioaccumulating (vPvB).

12.6 Other adverse effects

Further information on ecology The product itself has not been tested.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Disposal considerations The product should not be allowed to enter drains, water courses or
the soil.
Dispose of waste according to applicable legislation.
Empty remaining contents.
Waste Code According to the European Waste Catalogue, Waste Codes are not
product specific, but application specific.
The following Waste Codes are only suggestions:
Product (Mortar and Curing agent)
200127 - paint, inks, adhesives and resins containing dangerous
substances
080409 - waste adhesives and sealants containing organic solvents
or other dangerous substances
cured material and completely squeezed cartridges
200000 - MUNICIPAL WASTES (HOUSEHOLD WASTE AND SIMILAR
COMMERCIAL, INDUSTRIAL AND INSTITUTIONAL WASTES) INCLUDING
SEPARATELY COLLECTED FRACTIONS

SECTION 14: Transport information

Land transport ADR/RID Marine transport IMDG Air transport ICAO/IATA
14.1 UN-No Not applicable. Not applicable. Not applicable.
14.2 Description of the No dangerous good ac- No dangerous good ac- No dangerous good ac-
goods cording to ADR cording to IMDG cording to IATA
14.2 UN proper shipping Non dangerous good Non dangerous good
name

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Safety Data Sheet as per regulation (EC) 1907/2006
Commercial Product Name : FIS V 360/950 S - Component A (Mortar ) ..
Revision Date : 28.03.2017 Replaces version from : 11.01.2017
Version : 5.3 /en Print date : 05.04.2017

Land transport ADR/RID Marine transport IMDG Air transport ICAO/IATA

14.3 Transport hazard Not applicable. Not applicable. Not applicable.
class(es)
14.4 Packaging group Not applicable. Not applicable. Not applicable.
14.5 Environmental haz- Not applicable. Not applicable. Not applicable.
ards
Danger releasing sub- Not applicable. Not applicable. Not applicable.
stance
Leerzeile
14.6 Special precautions for user
Precautions not required under normal use

14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to not applicable
Annex II of MARPOL and the IBC
Code

14.8 Additional information

Other information (chapter 14.) Not dangerous goods in the meaning of ADR/RID, ADNR, IMDG-Code,
ICAO/IATA-DGR

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
Decopaint regulation Exempt
Carcinogenic hazardous sub- no
stance as per Annex II GefStoffV
Restriction of occupation. Exempt
Water Hazard Class (Ger.) 1
Cassification in compliance with Exempt
the Industrial Safety Regulation

15.2 Chemical safety assessment

Safety assessment Not relevant. Chemical safety assessments for substances in this mix-
ture were not carried out.
Additional regulations Not applicable.

SECTION 16: Other information

Relevant H-phrases H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
H318: Causes serious eye damage.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.

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Safety Data Sheet as per regulation (EC) 1907/2006
Commercial Product Name : FIS V 360/950 S - Component A (Mortar ) ..
Revision Date : 28.03.2017 Replaces version from : 11.01.2017
Version : 5.3 /en Print date : 05.04.2017

Wording of the hazard classes Skin Irrit.: Skin irritation

Eye Dam.: Serious eye damage
Skin Sens.: Skin sensitization
STOT SE: Specific target organ toxicity - single exposure
Eye Irrit.: Serious eye irritation

Classification for mixtures Classification Evaluation

and used evaluation method Skin Irrit. 2; H315 Calculated
Eye Dam. 1; H318 Calculated
according to regulation (EC) Skin Sens. 1; H317 Calculated
1272/2008 [CLP]
Recommended restrictions None under normal processing. Observe technical data sheet.
Modifications of the previous version are denoted with an asterisk (*).
This information is provided in accordance with the current status of our knowledge and experience. The
Safety Data Sheet describes products with a view to relevant safety requirements. This information does
not constitute a warranty of properties, features or qualities.

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Safety Data Sheet as per regulation (EC) 1907/2006
Commercial Product Name : FIS V 360/950 S - Component B (Hardener) ..
Revision Date : 28.03.2017 Replaces version from : 11.01.2017
Version : 6.2 /en Print date : 05.04.2017

SECTION 1: Identification of the substance/mixture and of the company/

undertaking

1.1 Product identifier

Commercial Product Name FIS V 360/950 S - Component B (Hardener)

1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses composite mortar
Recommended restrictions None under normal processing. Observe technical data sheet.

1.3 Details of the supplier of the safety data sheet

Company designation fischerwerke GmbH & Co. KG
Klaus-Fischer-Straße 1
D-72178 Waldachtal
Telephone : +49(0)7443 12-0
FAX : +49(0)7443 12-4222
Email : info-sdb@fischer.de
Internet : www.fischer.de
Marketer Great Britain: Mrs Mirka Valovicova, fischer Fixing (UK) Ltd, Hithercroft
Road, Wallingford, Oxfordshire, OX10 9AT, Tel. 01491 827 920, Fax
01491 827 950

1.4 Emergency telephone number

Emergency telephone number +49(0)6132-84463 (24h)

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Reg- Eye Irrit. 2; H319 Skin Sens. 1; H317 Aquatic Chronic 2; H411
ulation (EC) No. 1272/2008

2.2 Label elements

Hazard pictogram

GHS07 GHS09

Signal word Warning

Hazardous component(s) to be dibenzoyl peroxide
indicated on label
H-statement(s) H319: Causes serious eye irritation.
H317: May cause an allergic skin reaction.

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Commercial Product Name : FIS V 360/950 S - Component B (Hardener) ..
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Version : 6.2 /en Print date : 05.04.2017

H411: Toxic to aquatic life with long lasting effects.

P-statement(s) P101: If medical advice is needed, have product container or label at
hand.
P102: Keep out of reach of children.
P280: Wear protective gloves/protective clothing/eye protection/face
protection.

2.3 Other hazards

Health hazard None known.
Particular information pertain- None known.
ing specific risk for human / en-
vironment
Indication of danger None known.
Hazard precautions None known.

SECTION 3: Composition/information on ingredients

Hazardous ingredients
Ingredient Classification (EC) 1272/2008 Concen-
tration
dibenzoyl peroxide CAS No. : 94-36-0 Org. Perox. B; H241 Eye Irrit. 2; H319 10.0 -
EC-No. : 202-327-6 Skin Sens. 1; H317 Aquatic Acute 1; 25.0 % by
Index-No. :
617-008-00-0
H400 weight
REACH No. :
01-2119511472-50

SECTION 4: First aid measures

4.1 Description of first aid measures

General advice If symptoms persist, call a physician.
Remove/Take off immediately all contaminated clothing.
If inhaled IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing.
In case of skin contact IF ON SKIN: Gently wash with plenty of soap and water.
In case of eye contact In case of eye contact, remove contact lens and rinse immediately
with plenty of water, also under the eyelids, for at least 15 minutes.
If swallowed If swallowed, seek medical advice immediately and show this contain-
er or label.
Clean mouth with water and drink afterwards plenty of water. Drink 1
or 2 glasses of water.
Do NOT induce vomiting.

4.2 Most important symptoms and effects, both acute and delayed
Symptoms None known.

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Safety Data Sheet as per regulation (EC) 1907/2006
Commercial Product Name : FIS V 360/950 S - Component B (Hardener) ..
Revision Date : 28.03.2017 Replaces version from : 11.01.2017
Version : 6.2 /en Print date : 05.04.2017

4.3 Indication of any immediate medical attention and special treatment needed
Immediate medical attention No data available
Special medical treatment No data available

SECTION 5: Firefighting measures

5.1 Extinguishing media

Suitable extinguishing media Carbon dioxide (CO2)
Dry powder
Foam
Water spray jet
Extinguishing media which must High volume water jet
not be used for safety reasons

5.2 Special hazards arising from the substance or mixture

Special exposure hazards arising Heating or fire can release toxic gas.
from the substance or prepara-
tion itself, its combustion prod-
ucts, or released gases

5.3 Advice for firefighters

Special protective equipment for In the event of fire, wear self-contained breathing apparatus.
firefighting In the event of fire and/or explosion do not breathe fumes.
Additional information on fire- Fire residues and contaminated fire extinguishing water must be dis-
fighting posed of in accordance with local regulations.
Keep containers and surroundings cool with water spray.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions Ensure adequate ventilation, especially in confined areas.
Keep people away from and upwind of spill/leak.

6.2 Environmental precautions

Environmental precautions The product should not be allowed to enter drains, water courses or
the soil.
Prevent spreading over a wide area (e.g. by containment or oil barri-
ers).

6.3 Methods and material for containment and cleaning up

Methods for cleaning up Use mechanical handling equipment.
Treat recovered material as described in the section "Disposal consid-
erations".

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Safety Data Sheet as per regulation (EC) 1907/2006
Commercial Product Name : FIS V 360/950 S - Component B (Hardener) ..
Revision Date : 28.03.2017 Replaces version from : 11.01.2017
Version : 6.2 /en Print date : 05.04.2017

6.4 Reference to other sections

Reference to other sections See chapter 8/13

6.5 Additional information

Other information Dispose of in accordance with local regulations.

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Advice on safe handling None under normal processing.
Caution: During machining in cured state dust is formed.
Advice on protection against fire No special precautions required.
and explosion

7.2 Conditions for safe storage, including any incompatibilities

Storage space and container re- Keep containers tightly closed in a cool, well-ventilated place.
quirements Store in accordance with local regulations.
Keep only in original container.
Hints on storage assembly Store in accordance with the particular national regulations.
German storage class 10-13 (TRGS 510)

7.3 Specific end use(s)

Specific use(s) composite mortar
Further information: see technical data sheet.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

dibenzoyl peroxide
Great Britain
Long-term exposure value/ mg/m3 Remarks Source
5 R2, 36, 43 100
Source : 100 - Company data

8.2 Exposure controls

Respiratory protection No personal respiratory protective equipment normally required.
Hand protection not required under normal use
Suitable material : butyl-rubber, Chloroprene, Nitrile rubber
Unsuitable material : PVC disposable gloves
Material thickness : adjust to application and duration of use
Break through time : adjust to application and duration of use

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Safety Data Sheet as per regulation (EC) 1907/2006
Commercial Product Name : FIS V 360/950 S - Component B (Hardener) ..
Revision Date : 28.03.2017 Replaces version from : 11.01.2017
Version : 6.2 /en Print date : 05.04.2017

Remarks : Take note of the information given by the producer concerning per-
meability and break through times, and of special workplace condi-
tions (mechanical strain, duration of contact).
Reference substance : Replace when worn.
Eye protection Tightly fitting safety goggles
Skin and body protection Wear suitable protective equipment.
Note : Choose body protection according to the amount and concentration
of the dangerous substance at the work place.
General protective and hygiene Smoking, eating and drinking should be prohibited in the application
measures area.
Avoid contact with skin, eyes and clothing.
Take off all contaminated clothing immediately.
Wash hands before breaks and at the end of workday.
Keep away from food, drink and animal feedingstuffs.
Use protective skin cream before handling the product.
Information on environmental No special environmental precautions required.
protection regulations

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Form paste
Colour black
Odour characteristic
Odour threshold not determined
pH No data available
Melting point [°C] / Freezing No data available
point [°C]
Boiling point [°C] no data available
Flash point [°C] > 100
Evaporation rate [kg/(s*m²)] No data available
Flammability (solid, gas) No data available
Explosion limits [Vol-% ]
Lower limit : not determined
Upper limit : not determined
Vapour pressure [kPa] No data available

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Safety Data Sheet as per regulation (EC) 1907/2006
Commercial Product Name : FIS V 360/950 S - Component B (Hardener) ..
Revision Date : 28.03.2017 Replaces version from : 11.01.2017
Version : 6.2 /en Print date : 05.04.2017

Density [g/cm³] 1,6 - 1,65

Pressure : 20 °C
Water solubility [g/l] not determined
Solubility [g/l] No data available
Partition coefficient n-octanol / No data available
water (log P O/W)
Autoinflammability not auto-flammable
Decomposition temperature [°C] not determined
Viscosity, dynamic [kg/(m*s)] 100 - 160
Temperature : 20 °C
Risk of explosion. Not explosive

9.2 Other information

Oxidizing properties Oxidising
Relative vapour density (air=1) not determined

SECTION 10: Stability and reactivity

10.1 Reactivity
Thermal decomposition No decomposition if stored and applied as directed.

10.2 Chemical stability

Chemical stability Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

Hazardous reactions No dangerous reaction known under conditions of normal use.

10.4 Conditions to avoid

Conditions to avoid No decomposition if used as directed.

10.5 Incompatible materials

Materials to avoid Not applicable.

10.6 Hazardous decomposition products

Hazardous decomposition prod- No decomposition if used as directed.
ucts

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Safety Data Sheet as per regulation (EC) 1907/2006
Commercial Product Name : FIS V 360/950 S - Component B (Hardener) ..
Revision Date : 28.03.2017 Replaces version from : 11.01.2017
Version : 6.2 /en Print date : 05.04.2017

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Hazardous ingredients

dibenzoyl peroxide
Oral toxicity [mg/kg] Test criterion Test species Source
> 5000 LD50 rat 100
Source : 100 - Company data

Inhalative toxicity Test criterion Test species Note Source

[mg/l]
24300 LC50 rat (dust) 100
Source : 100 - Company data

Irritant effect on skin Irritating to skin and mucous membranes

Irritant effect on eyes Irritating to eyes.

11.2 Additional information

Other information (chapter 11.) The product itself has not been tested.

SECTION 12: Ecological information

12.1 Toxicity
Hazardous ingredients

dibenzoyl peroxide
Toxicity to fish [mg/l] Test criterion Exposure duration Source
0,06 LC50 96 h 100
Source : 100 - Company data

Toxicity to daphnia Test criterion Test species Exposure duration Source

[mg/l]
0,11 EC50 Daphnia magna (Water 48 h 100
flea)
Source : 100 - Company data

Toxicity to algae [mg/l] Test criterion Exposure duration Source

0,06 EC50 72 h 100
Source : 100 - Company data

Ready degradability
NOEC (daphnia) [mg/l]
Value Test species Measuring method Exposure duration
1 Daphnia magna (Big water OECD 202 48 h
flea).

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Safety Data Sheet as per regulation (EC) 1907/2006
Commercial Product Name : FIS V 360/950 S - Component B (Hardener) ..
Revision Date : 28.03.2017 Replaces version from : 11.01.2017
Version : 6.2 /en Print date : 05.04.2017

NOEC (algae) [mg/l]

Value Test species Measuring method Exposure duration
0,5 Pseudokirchneriella sub- OECD 201 72 h
capitata

12.2 Persistence and degradability

Elimination and distribution There is no data available for this product.
mechanisms
Elimination in purification plant There is no data available for this product.

12.3 Bioaccumulative potential

Bioaccumulation There is no data available for this product.
Bioconcentration factor (BCF) There is no data available for this product.

12.4 Mobility in soil

Distribution in the environment There is no data available for this product.
Mobility
Mobility : There is no data available for this product.

12.5 Results of PBT and vPvB assessment

Results of PBT characteristics This preparation contains no substance considered to be very persis-
determination tent nor very bioaccumulating (vPvB).

12.6 Other adverse effects

Further information on ecology The product should not be allowed to enter drains, water courses or
the soil.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Disposal considerations The product should not be allowed to enter drains, water courses or
the soil.
Dispose of waste according to applicable legislation.
Empty remaining contents.
Waste Code According to the European Waste Catalogue, Waste Codes are not
product specific, but application specific.
The following Waste Codes are only suggestions:
Product (Mortar and Curing agent)
200127 - paint, inks, adhesives and resins containing dangerous
substances
080409 - waste adhesives and sealants containing organic solvents
or other dangerous substances
cured material and completely squeezed cartridges

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Safety Data Sheet as per regulation (EC) 1907/2006
Commercial Product Name : FIS V 360/950 S - Component B (Hardener) ..
Revision Date : 28.03.2017 Replaces version from : 11.01.2017
Version : 6.2 /en Print date : 05.04.2017

200000 - MUNICIPAL WASTES (HOUSEHOLD WASTE AND SIMILAR

COMMERCIAL, INDUSTRIAL AND INSTITUTIONAL WASTES) INCLUDING
SEPARATELY COLLECTED FRACTIONS

SECTION 14: Transport information

Land transport ADR/RID Marine transport IMDG Air transport ICAO/IATA
14.1 UN-No 3077 3077 3077
14.2 Description of the ENVIRONMENTALLY HAZ- ENVIRONMENTALLY HAZ- ENVIRONMENTALLY HAZ-
goods ARDOUS SUBSTANCE, ARDOUS SUBSTANCE, ARDOUS SUBSTANCE,
SOLID, N.O.S. (dibenzoyl SOLID, N.O.S. (dibenzoyl SOLID, N.O.S. (dibenzoyl
peroxide) peroxide) peroxide)
14.2 UN proper shipping ENVIRONMENTALLY HAZ- Environmentally haz-
name ARDOUS SUBSTANCE, ardous substance, solid,
SOLID, N.O.S. (dibenzoyl n.o.s. (dibenzoyl peroxide)
peroxide)
14.3 Transport hazard 9 9 9
class(es)
14.4 Packaging group III III III
14.5 Environmental haz- U - Environmentally haz- U - marine pollutant U - Environmentally haz-
ards ardous ardous
Remarks Not dangerous goods in Not dangerous goods in Not dangerous goods in
original packaging (Special original packaging (Special original packaging (Special
Provision 375) Provision 969 ) Provision A197)
Leerzeile
14.6 Special precautions for user
Precautions not required under normal use

14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to not applicable
Annex II of MARPOL and the IBC
Code

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
Restriction of occupation. -
Water Hazard Class (Ger.) 1

15.2 Chemical safety assessment

Safety assessment Not relevant. Chemical safety assessments for substances in this mix-
ture were not carried out.
Additional regulations Not applicable.

SECTION 16: Other information

Relevant H-phrases H241: Heating may cause a fire or explosion.
H317: May cause an allergic skin reaction.

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Safety Data Sheet as per regulation (EC) 1907/2006
Commercial Product Name : FIS V 360/950 S - Component B (Hardener) ..
Revision Date : 28.03.2017 Replaces version from : 11.01.2017
Version : 6.2 /en Print date : 05.04.2017

H319: Causes serious eye irritation.

H400: Very toxic to aquatic life.
H411: Toxic to aquatic life with long lasting effects.
Wording of the hazard classes Eye Irrit.: Serious eye irritation
Skin Sens.: Skin sensitization
Aquatic Chronic: Hazardous to the aquatic environment
Org. Perox.: Organic peroxide
Aquatic Acute: Hazardous to the aquatic environment
Classification for mixtures Classification Evaluation
and used evaluation method Skin Sens. 1; H317 Calculated
Eye Irrit. 2; H319 Calculated
according to regulation (EC) Aquatic Chronic 2; H411 Experimental data
1272/2008 [CLP]
Recommended restrictions None under normal processing. Observe technical data sheet.
Modifications of the previous version are denoted with an asterisk (*).
This information is provided in accordance with the current status of our knowledge and experience. The
Safety Data Sheet describes products with a view to relevant safety requirements. This information does
not constitute a warranty of properties, features or qualities.

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