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    112.1 Exercise 9

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    Julie Ann Felices
    1) Five trials of titrating KIO4 solutions with standardized Na2S2O3 were conducted under various conditions of temperature and solvent. 2) The results, including final and initial buret readings and volumes used, were recorded to calculate the molarity and average molarity of the KIO4 solutions. 3) Additional experiments were performed to determine the solubility product (KSP) values, activity coefficients (γ), and ionic strengths (σ) of KIO4 in different solvents and temperatures.

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    112.1 Exercise 9

    Uploaded by

    Julie Ann Felices
    54 views3 pages
    1) Five trials of titrating KIO4 solutions with standardized Na2S2O3 were conducted under various conditions of temperature and solvent. 2) The results, including final and initial buret readings and volumes used, were recorded to calculate the molarity and average molarity of the KIO4 solutions. 3) Additional experiments were performed to determine the solubility product (KSP) values, activity coefficients (γ), and ionic strengths (σ) of KIO4 in different solvents and temperatures.

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    Data excel

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    112.1-Exercise-9

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    1) Five trials of titrating KIO4 solutions with standardized Na2S2O3 were conducted under various conditions of temperature and solvent. 2) The results, including final and initial buret readings and volumes used, were recorded to calculate the molarity and average molarity of the KIO4 solutions. 3) Additional experiments were performed to determine the solubility product (KSP) values, activity coefficients (γ), and ionic strengths (σ) of KIO4 in different solvents and temperatures.

    Copyright:

    © All Rights Reserved
    Download as XLSX, PDF, TXT or read online from Scribd
    Download as xlsx, pdf, or txt
    54 views3 pages

    112.1 Exercise 9

    Uploaded by

    Julie Ann Felices
    1) Five trials of titrating KIO4 solutions with standardized Na2S2O3 were conducted under various conditions of temperature and solvent. 2) The results, including final and initial buret readings and volumes used, were recorded to calculate the molarity and average molarity of the KIO4 solutions. 3) Additional experiments were performed to determine the solubility product (KSP) values, activity coefficients (γ), and ionic strengths (σ) of KIO4 in different solvents and temperatures.

    Copyright:

    © All Rights Reserved
    Download as XLSX, PDF, TXT or read online from Scribd
    Download as xlsx, pdf, or txt
    of 3

    Standardization Titration of KIO4 solutions with standardized Na2S2O3

    Trial Temperature (C)


    Solution Solvent
    I II I
    Final buret reading, mL 55 61 1 distilled H2O 19
    Initial buret reading, mL 50 55 2 0.20 M NaNO3 31
    Volume used, mL 5 6 3 0.10 M NaNO3 31
    Mass 0.0645 0.0662 4 0.20 M KNO3 19
    Molarity 0.46627 0.3988 5 0.10 M KNO3 19
    average molarity 0.43253
    Activity
    Solvent
    IO4-
    distilled H2O 0.0335210843
    0.20 M NaNO3 0.0435233434
    0.10 M NaNO3 0.0451453313
    0.20 M KNO3 0.0110835843
    0.10 M KNO3 0.0170308735

    Coated with counterion - salting in


    Common ion - lower solubility than distilled water
    ardized Na2S2O3 Volume of Na2S2O3, mL
    Temperature (C) Volume of aliquot, mL Vfinal
    II I II I II
    19 10 10 89.2 95.4
    31 10 10 70.1 57.2
    31 10 10 79.4 66
    19 10 10 54 56.1
    19 10 10 82.8 59

    KSP I gamma sigma


    K+
    0.0335210843 0.0011236631 0.6024023807 0.4026630347 0.055645670
    0.0435233434 0.0018942814 0.8024023807 0.3499882785 0.0542412939
    0.0451453313 0.002038 0.7024023807 0.3744638539 0.0642727482
    0.2110835843 0.0023395627 0.8024023807 0.3499882785 0.0705864962
    0.1170308735 0.001993138 0.7024023807 0.3744638539 0.0792827946
    Vinitial Vol used Average
    I II I II
    82.8 89.4 6.4 6 6.2
    61.2 50 8.9 7.2 8.05
    70.1 58.6 9.3 7.4 8.35
    52 54 2 2.1 2.05
    79.4 56.1 3.4 2.9 3.15

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