Cape Chem 2010 U2 p2 Ms

Mark Scheme
Unit 2 Paper2 2010
Module I
1 (a) (i) eold alkaline MnO+- / het acidified MnOa- tzl
( ii) HaO(g) - stcam- H3POa phosphoric acid / sioz at 300oc and 60 atm
or conc HzSO+, 180oC tZ]
(b)
B CHs CHa
Hg
HO OH
a CHs Br'
CHs
C H
Br l2l
(c) (i) macromolecule formed from joining many monomers (small molecules)
t1l
(ii) Addition t1l
(i ii) poly(ethene) or poly(propene) or poly(chloroethene) etc t1I
(iv) Hg
Hs t11
(v) No, unlikely because they do not have C=C t21

(d) H
H I
N C €
H
I
o-H
R t1I
(e) They both contain the amide linkage
OH
llr
C-N _ t1l
The amide linkages are separated by one C atom in proteins, but in nylon 6,6
they are separated by several C atoms. t1l
Module 2
2 (a) (i) Electromagnetic radiation - oscillating electric and magnetic fields of

energy which can be transmitted through space'
(ii) Wavelength is the distance between successive peak of waves of

radiation.
(iii) Frequency is the number of waves passing a particular point /sec
t3l
(b) (i) 1x10-5m t1l
(ii) 7,5 x 107 Hz t1I
(iii) tR t1l
(iv) Radiowaves [1]
(c) (i) (a) if sample is solid weigh a small amount in a beaker, if liquid
measure 2 cm3 into a beaker;
(b) add 1o cm3 of solvent usually water to the beaker;
(c)transfer the solution and washings to a 50 cm3 volumetric

flask,
distilled water
add chromogenic agent if necessary and dilute to the mark with
or chosen solvent t3I
(ii) Any two of the following;
- StabilitY
. Ability to develop colour with sample
- Transparency in uv/vis region
- Ability to function in a common solvent
- Freedom from interference by other solvenV constituents [2]
(d) (i) E = 6.63 x 10'3a Js x 1.5 x 101s s-1
= 9.9 x 10-1s J
(ii) Emoh = Emelgrlrh X L
= 9.9 x 1o-le J x 6.02 x 1023 mol-1
= 6 x 105 J mol-1 = 600 kJ mol-1
Module 3
3 (a) (i) COz, NOz, SOz anY two tzl
(ii) COz - respiration, SOz - volcano eruptions; NOz - lightning storm t2I
(iii) COs + HzO = HzCOsi or SO2 + HzO = HzSOs,
or 3NOz + HzO 2HNOo + ) NO 121
(b) (i) electric power generation that relies on burning fossil fuels like coal ,
which can be contaminated with sulphur
Burning of gasoline in vehicles in heavily populated areas- there is often

incomplete combustion of gasoline generation NO, 121
(ii) -destroys aquatic life

- leaches soil nutrients
vegetation
- destroys 121
(c) (i) pipe has no leak t1l
(ii) iodide ions,l-'for Pbz*; t1I

(Brown ring test) or A! (or Zn). NaOH in xs
feSOs/conc HaSO*
and warm -test for NHs- (Devarda's alloy test) t1]
(iii) yellow ppt - Pblz t1l

Brown ring at junction of conc acid and rest of solution; or
red litmus turns blue in Devarda's alloy test I1l
Section B
Module 1
4 (a) A and B have the same molecular formula, CeHsO, but diftrenl
structuraiformulap - atoms are linked differently. t2l
(b) alkene and 10 alcohol 121
(cXi) HHHHHHHH
llA,
H-C
lll
-C{+C-C-C =C-Q -H
I
ttl-tl
HO H CHgH H
I
H
(ii) H H
C eis t1l
,/'
c H3-r H-CHz-e Hz-CHz CHzOH
CHc
H CHeOH
t"=/ trans isomer t1]
,/\
CH3-CT-CHz-CHz-CHz t{
eHs
There is no asymmetric or chiral C therefore no optical isomerism t1I
(d) (i) Cracking is the sptitting of larger alkane molecules to smaller ones together
with the formation of an alkene. This requires high temperature or moderate temp and a
catalyst.
(ii) (a) CsHra * C+Hro + CeHa t1l

(b)
Bubhle eaeh gas separately into brown bromine
in an inert solvent . The
alkanc C+Hro will have ns effeet and the alkene
c+Ho will immediately decolourise it.
[3]
Module 2
5 (a)
r Distinguish between motecules of similar

M,
r prediction of posslble identity of
simple organic morecute based on fragmentation
pattern
o Determination of the number of c atoms in the morecure based on M and
peaks M+1
o Identify the presence of atoms such as
cr or bromine from the M+2 peak
a
abundance
Relative isotopic
any three
t3l
(b) (i) M=78; M+1 =7g
121
(ii) (CH:CHCHs)* = 43 (CHeCH3sCl)* = 63 (CH.CH3TC;)* = 65
lsl
(ii i) M = CHg CH35CICHs M+! = CHs eH3scll3CHs
tzl
Name:2-ehloropropane
t1l
(c) Ar (RAM) = ((7s.77t100) x g4.92) + (24.231100)
x 36.96 = z6.s +8.9s
= 35.85
(d) Any two of the following
. Separation of dyes
. Pesticide analysis
r Forensic testing
. Purification of natural products
Module S
(a) Eractional distiilatisn of

liouid,air
(b) (i) Hydrotysis 121
(ii) CHa(g) + Hzo(g) CO(g) + gHa(9) IU
= balance[1 ] formutae[1
]
(c) conditions of optimum yierd
: High pressure favours row vorume
Low temperature favours fonnrard t1l
exothermic reaction
t1l
(d) The Haber process uses the compromise pressure of 250 atm and
moderate temperature (550oC) with Fe catalyst to increase rate I2l
(e) Table 2
Pollutant Source Polluting Effect
NOs- Fertilizers Eutrophication/ algal
Untreated sewage bloom/ lowers Oz for
u marine life
Eutrophication / algal
t1l
PO4- Detergent
Fertilizers bloom
Untreated sewage tU:- I1l
Pipes, paints, car Carcinogenic, cumulative
Pb2* batteries poison
t1l l1l

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Mark Scheme

Unit 2 Paper2 2010

(v) No, unlikely because they do not have C=C t21

(e) They both contain the amide linkage

2 (a) (i) Electromagnetic radiation - oscillating electric and magnetic fields of

(ii) Wavelength is the distance between successive peak of waves of

(iii) Frequency is the number of waves passing a particular point /sec

(b) (i) 1x10-5m t1l

(ii) 7,5 x 107 Hz t1I

(iv) Radiowaves [1]

(b) add 1o cm3 of solvent usually water to the beaker;

(c)transfer the solution and washings to a 50 cm3 volumetric

(d) (i) E = 6.63 x 10'3a Js x 1.5 x 101s s-1

(ii) Emoh = Emelgrlrh X L

= 9.9 x 1o-le J x 6.02 x 1023 mol-1

= 6 x 105 J mol-1 = 600 kJ mol-1

3 (a) (i) COz, NOz, SOz anY two tzl

which can be contaminated with sulphur

Burning of gasoline in vehicles in heavily populated areas- there is often

(ii) -destroys aquatic life

(c) (i) pipe has no leak t1l

(ii) iodide ions,l-'for Pbz*; t1I

(iii) yellow ppt - Pblz t1l

(b) alkene and 10 alcohol 121

There is no asymmetric or chiral C therefore no optical isomerism t1I

(ii) (a) CsHra * C+Hro + CeHa t1l

r Distinguish between motecules of similar

(a) Eractional distiilatisn of

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