Fiitjee Rit 1
Fiitjee Rit 1
Fiitjee Rit 1
Instructions
Note:
1. The question paper contains 3 sections (Sec-1, Chemistry, Sec-II, Physics & Sec-III, Mathematics.)
2. Each section is divided into three parts, PART-A, PART-B and PART-C.
3. Rough spaces are provided for rough work inside the question paper. No additional sheets will be provided
for rough work.
4. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices, in
any form, are not allowed.
Filling of OMR Sheet
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sheet.
2. On the OMR sheet, darken the appropriate bubble with Blue/Black Ball Point Pen for each character of
your Enrolment No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
Enrolment Number :
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Section – I (Chemistry)
PART – A
(Single Correct Choice Type)
This section contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which only
ONE option is be correct.
2. In which molecule the central atom uses d- orbital for bond formation?
(A) SO2 (B) H2S (C) SCl2 (D) S8
4. 1 and 2 are two wavelengths of the visible radiations of hydrogen spectrum. They are emitted by two
adjacent electronic transition in hydrogen atom. If 1 is greater than of 2, what is the ratio of 1 to 2?
(A) 17 : 10 (B) 10 : 17 (C) 27 : 20 (D) 20 : 27
6. The radial wave function of an atomic orbital is represented by Rn,l. The wave function of an orbital is
given below [a0 = 0.529 A ].
− Zr
1 Z
3/2
Zr 2a0
R2,1 = e
2 6 a0 a0
Choose correct statement(s) about the orbital.
(A) It is one of 2p orbitals.
(B) The radial probability versus radial distance curve of this orbital has a maxima at around 2 A .
(C) It has no radial node.
(D) The orbital has two nodal planes.
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10. Which of the following quantum number(s) is/are correct for the unpaired electron of aluminium atom
(Z = 13) in ground state?
1
(A) n = 3 (B) =1 (C) m = –2 (D) s =
2
11. The correct statement(s) regarding the O2 molecule and O atom is/are:
(A) Oxidizing agent : O > O2 (B) Spin-only magnetic moments : O = O2
(Paramagnetism)
12. Which of the following aqueous solutions form a thin solid layer on their surface(s) when they are kept
under air?
(A) NaOH (B) Ca(OH)2 (C) Ba(OH)2 (D) KOH
13. Which of the following statement(s) is / are correct for iron atom and its ions? (Z = 26)
(A) The spin multiplicity of Fe3+ ion is greater than that of Fe2+ ion.
(B) Fe3+ contains more electrons with = 2 than that of Fe2+.
(C) The orbital of Fe atom which wave function is 3, 2, 0 contains no nodal planes.
(D) ‘Fe’ atom contains eight electrons in spherical orbitals.
PART – B
(Matrix Match Type)
1. Match the molecules mentioned in Column-I with their properties mentioned in Column-II.
Column-I Column-II
(A) BF3 (P) Dipole moment is zero.
(B) CO2 (Q) Bond order is greater than one
(C) SO3 (R) Contains sigma as well as pi-bonds
(D) NH3 (S) Contains lone pair on central atom
(T) Contains p–p back bond.
space for rough work
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2. Match the compounds mentioned in Column-I with their properties mentioned in Column-II.
Column-I Column-II
(A) MgCl2 6H2O (P) Undergoes complete dehydration on heating.
(B) Mg(OH)2 (Q) Undergoes partial dehydration on heating
(C) Ca(OH)2 (R) Added to NaCl to decrease its melting point during
preparation of Na through electrolysis
(D) CaCl2 (S) Forms mixed salt when treated with Cl2
(T) Precipitated from sea water by adding lime water
PART – C
This section contains 5 Numerical Based questions. The answer to each question is a single digit integer, ranging from 0
to 9 (both inclusive)
1. The threshold wavelength for the photoelectron emission of molybdenum is 2300 A . Radiation with
wavelength 1682 A is used to release photoelectrons. What is the maximum kinetic energy of the
photoelectrons in eV unit?
2. The wave function describing the resonating structures of hydrogen molecule is given by
H2 = (1 − )cov alent + ionic
Hence, is called the mixing coefficient which measures the extent of contribution of the ionic forms
to the resonating structures.
What is the value of for pure covalent forms of H2(H – H)?
3. An alkaline earth metal which hydroxide is used as an antacid, reacts with carbon to form carbide (P)
at 500°C and carbide (Q) at 700°C. (P) contains two carbon atoms and (Q) has three carbon atoms
X
per molecule. If the molar mass of (P) is X g mol–1 , what is the value of ?
6
4.
2p
How many maximum number of exchange pair(s) is/are possible for the above electron configuration?
5. A s-block metal(P) forms a mixture (Q) when it is heated in air. Reaction of (P) with HCl forms salt(R)
and gas(S). The same treatment of mixture(Q) produces salt(R), gas(T) and water. Reaction of (Q)
with water produces lime water and gas (T). If the number of atoms present in gas(S) and gas(T) are
respectively X and Y, what is (X + Y)?
Section – II (Physics)
PART – A
(Single Correct Choice Type)
This section contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which only
ONE option is be correct.
1. The hour hand of a clock is 6 cm long. The magnitude of the displacement of the tip of hour hand
between 1:00 pm to 5:00 pm is
(A) 6 cm (B) 6 3 cm (C) 12 cm (D) 3 3 cm
space for rough work
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2. Let A + B = C and A − B = D . If C and D are equal in magnitude and perpendicular to each other
then
(A) A = B (B) A B
(C) A is perpendicular to B (D) A is parallel to B
3. The velocity function of an object moving along a straight line is given by v(t) = At 2 + Bt. If at
t = 2s, the velocity is 3 m/s and acceleration is 2 m/s2, find the value of the constant A.
(A) 0.5 m/s3 (B) − 0.5 m/s2 (C) 2.5 m/s3 (D) − 1.5 m/s2
(C) If C A + B then angle between the vectors A and B is between 0° and 90°
2 2 2
7. Which of the following statements are true based on graphs of y-versus x as shown below
y y y y
x x x x
x0 x0 x0 x0
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10. ( )
If A + B is perpendicular to A − B then A and B must represent adjacent sides of
(A) rhombus (B) square (C) rectangle (D) none
11. Let ar and at represent radial and tangential accelerations. The motion of a particle may be circular if:
(A) ar = at = 0 (B) ar = 0 and at 0 (C) ar 0 and at = 0 (D) ar 0 and at 0
x t3
12. A particle moves along positive branch of the curve, y = , where x = , x and y are measured in
2 3
metres and t in seconds, then
1
(A) The velocity of particle at t = 1s is ˆi + ˆj
2
1ˆ ˆ
(B) The velocity of particle at t =1s is i+j
2
(C) The acceleration of particle at t =1s is 2iˆ + ˆj
(D) The acceleration of particle at t = 2 s is ˆi + 2jˆ
PART – B
(Matrix Match Type)
1.
Column I Column II
(A) In one dimensional motion of a particle (P) Acceleration may be along the motion
(B) In projectile motion of a particle (except (Q) Acceleration will never be along the motion
angle of projection with horizontal is
90°)
(C) In uniform circular motion of a particle (R) Acceleration may be perpendicular to motion
(D) In non-uniform circular motion of a (S) Acceleration may be opposite to the
particle displacement
(T) Acceleration must be perpendicular to the
motion
space for rough work
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2. If a particle is projected with speed 5 2 m/s along the angle of elevation of 45° with horizontal from
top of a tower of height 30 m, then match the following (g = 10 m/s2)
Column I Column II
(A) Time taken to reach the ground (P) 1.366 sec
(B) Time taken to reach to the maximum (Q) 1 sec
height
(C) Time taken by the body when its (R) 3 sec
velocity makes an angle 45o with
vertical again
(D) Time taken by the body when its (S) 0.5 sec
velocity makes an angle 60o with
horizontal during its downward motion
(T) 2 sec
PART – C
This section contains 5 Numerical Based questions. The answer to each question is a single digit integer, ranging from 0
to 9 (both inclusive)
1. A passenger is standing 20m behind from a bus. The bus begins to move with constant acceleration
0.9m/s2 . To catch the bus, the passenger runs at a constant speed v towards the bus. What must be
the minimum speed (in m/s)of the passenger so that he may catch the bus?
V0
0
2. In the given figure, the angle of inclination of the inclined 90
plane is 300. Find the horizontal velocity V0 (in m/s) so that H
the particle hits the inclined plane perpendicularly. Given,
H = 4m, g = 10 m/s2
0
30
3. Velocity of a particle at any instant is given by the equation V = (3iˆ + 2t 2 ˆj)m/s. Tangential
acceleration of the particle at t = 2s is 4.1 K m/s2. Find the value of K.
x
4. Given two vectors A = 2iˆ + 3jˆ and B = ˆi + ˆj . The component of vector A along vector B is .
2
Find the value of ‘x’.
v
5 m/s
−5 m/s
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1. (
If f ( x ) = cos−1 x − x 2 + 1 −
) 1
+ 2
1
, then domain of f(x) is (where [.] is the greatest
x x − 1
integer)
1 − 5 1− 5 1+ 5 1 − 5 1 + 5
(A) , 2 (B) − 2, (C) 2, (D) ,
2 2 2 2 2
cot −1
tan x
2. For R, the range of the function f() = tan x + cot x dx is equal to
tan−1
− − 3
(A) , (B) (0, ) (C) , (D) 0,
2 2 4 4 2
3. Which of the following function is surjective but not injective
(A) f : R → R f(x) = x 4 + 2x 3 − x 2 + 1 (B) f : R → R f(x) = x 3 + x + 1
(C) f : R → R+ f(x) = 1 + x 2 (D) f : R → R f(x) = x 3 + 2x 2 − x + 1
6.
5 1
Let f : 0, → , 3 such that f ( x ) =
x + 1
where . represents the greatest integer function
2 2 x + 1
and
. represents the fractional part of x, then which of the following is / are true.
(A) f(x) is injective discontinuous function. (B) f(x) is surjective non – differentiable function.
(
(C) min lim− f ( x ) , lim+ f ( x ) = f (1)
x →1 x →1
) (D) max ( lim f ( x), lim f ( x )) = f (2)
x →2− x →2+
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1 1
(C) min sin, x( ) (D) x + + x − + 2 −x
2 2
( . denotes greatest integer function)
8. Of the following functions defined from −1, 1 to −1, 1 , select those which are not bijective
(
(A) sin sin−1 x ) (B)
2 −1
sin ( sin x ) (C) ( Sgn x ) / In e x ( ) (D) x3 ( Sgn x )
( ))
ax + 1
(A) f ( x ) = x (B) g ( x ) = In x + (x 2
+ a2
a − 1
x
0, if x is rational
(C) h ( x ) = (1 − x ) + 3 (1 + x ) (D) p ( x ) =
2 2
3
1, if x is irrational
10. If x, y and z lie on domain of the equation such that ln(x + z) + ln(x – 2y + z) = 2 ln (x – z), then which
of the following is / are true
2xz x x−y
(A) y = (B) y2 = xz (C) 2y = x + z (D) =
x+z z y−z
2 5
11. Let f : , → 0,4 be a function defined as f ( x ) = 3 sin x − cos x + 2 , then :
3 3
4 5 7
(A) f (1) = (B) f −1 (1) = (C) f ( 2 ) = (D) f ( 2 ) =
−1 −1 −1
3 6 6
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PART – B
(Matrix Match Type)
1. Column B represents the number of solutions of equations given in column A now match the following
where {x} stands for fractional part of x.
Column A Column B
(A) 15{x} = 2x + 3 (P) 7
(B) x (Q) 5
{x} = n
3
(C) | x | =| sin x | x ( −, ) (R) 6
(D) {x} = {− x} x ( −3,3) (S) 11
1. If f : R → R is a function such that f ( x ) = x3 + x2 f ' (1) + xf " ( 2) + f "' (3 ) for all x R, then
f (1) − f ( 2)
2. Let f(x) be a function such that f(x) = x3 and the line x + y = 0 is tangent to the graph of f(x). Find the
value of (4 f(x) – x4).
3. Let x and y be real numbers satisfying the equation x 2 + y2 − 4x + 3 = 0 . If the maximum and
( )
minimum values of x 2 + y2 are M and m respectively, then the numerical value of (M−m) is …….
1 1
4. If f ( x ) is a polynomial satisfying f ( x ) .f = f ( x ) + f , and f ( 3) = 28, then f ( 4 ) is given by
x x
K
K, where equals to
13
x2 − 1
5. If f ( x ) = , for every real number, then minimum value of f is m, where m + 1 is
x2 + 1
space for rough work
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SECTION – II (Physics)
Part – A
1. B 2. C 3. A(marks to all) 4. B
5. D 6. ABCD 7. ABC 8. ABCD
9. ACD 10. AB 11. CD 12. AC
13. AC
Part – B
1. A → PS B → QR C → QRST D → QS
2. A→R B→S C→Q D→P
Part – C
1. 6 2. 4 3. 2 4. 5
5. 0
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