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IIT2020, CPM (RIT-1)-1

FIITJEE INTERNAL TEST


Batches: NWCM820X1R - X4R, NWTR820C01, D01, CAMP820, NWCM820G1W, NWCM820X1W
- X11W, NWTW820D01 - D02, PANINI820-XII G1, PANINI820-XII1 - XII7, PIN820-XII B
RANK IMPROVEMENT TEST – I
IIT- JEE 2020
QP CODE: 122460
Time: 3 hours Maximum Marks: 210
• Please read the instructions carefully. You are allotted 5 minutes specially for this purpose.
• You are not allowed to leave the examination hall before end of the test.
• Use Blue/Black Ball Point Pen only for writing particulars on Side–1 and Side–2 of the
Answer Sheet. Use to Pencil is strictly prohibited.

Instructions
Note:
1. The question paper contains 3 sections (Sec-1, Chemistry, Sec-II, Physics & Sec-III, Mathematics.)
2. Each section is divided into three parts, PART-A, PART-B and PART-C.
3. Rough spaces are provided for rough work inside the question paper. No additional sheets will be provided
for rough work.
4. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices, in
any form, are not allowed.
Filling of OMR Sheet
1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR
sheet.
2. On the OMR sheet, darken the appropriate bubble with Blue/Black Ball Point Pen for each character of
your Enrolment No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.

Marking Scheme For All Three Parts.


1. PART – A (01 – 05) contains 5 Multiple Choice Questions which have Only One Correct answer. Each
question carries +3 marks for correct answer and –1 mark for wrong answer.
2. PART – A (06 – 13) contains 8 Multiple Choice Questions which have One or More Correct answer.
For each question in the group Q. 6 – 13 of PART – A you will be awarded
Full Marks: +4 If only the bubble(s) corresponding to all the correct options(s) is (are) darkened.
Partial Marks: +1 For darkening a bubble corresponding to each correct option, provided NO incorrect
option is darkened.
Zero Marks: 0 If none of the bubbles is darkened.
Negative Marks: −2 In all other cases.
For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three will result
in +4 marks; darkening only (A) and (D) will result in +2 marks; and darkening (A) and (B) will result in −2
marks, as a wrong option is also darkened.
3. PART – B contains 2 Matrix Match Type Questions which have statements given in 2 columns. Statements
in the first column have to be matched with statements in the second column. There may be One or More
Than One Correct choices. Each question carries +4 marks for all correct answer however for each correct
row +1 marks will be awarded. No negative marks will be awarded in this section.
4. PART-C (01 – 05) contains 5 Numerical Based questions with Single Digit Integer as answer, ranging from 0
to 9 and each question carries +3 marks for correct answer. No negative marks will be awarded in this
section.

Name of the Candidate :

Enrolment Number :

FIITJEE Ltd., Punjabi Bagh Centre, 31, 32, 33 Central Market, West Avenue Road, Punjabi Bagh, New Delhi – 110026, Ph: 011 - 45634000
IIT2020, CPM (RIT-1)-2

Section – I (Chemistry)
PART – A
(Single Correct Choice Type)
This section contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which only
ONE option is be correct.

1. In the discharge tube experiment, very low pressure is maintained in order to


(A) increase the formation of electrons from the electrodes.
(B) reduce the scattering of electrons by the gas molecules
(C) increase the velocity of electrons
(D) reduce the number of electrons

2. In which molecule the central atom uses d- orbital for bond formation?
(A) SO2 (B) H2S (C) SCl2 (D) S8

3. Group − 1 metals ⎯⎯⎯⎯


Air
Heating
→ Products
Which product is not formed in the above reaction?
(A) Li3N (B) NaO (C) KO2 (D) RbO2

4. 1 and 2 are two wavelengths of the visible radiations of hydrogen spectrum. They are emitted by two
adjacent electronic transition in hydrogen atom. If 1 is greater than of 2, what is the ratio of 1 to 2?
(A) 17 : 10 (B) 10 : 17 (C) 27 : 20 (D) 20 : 27

5. Which of the following is a polymeric hydride?


(A) KH (B) BeH2 (C) YbH2.25 (B) ZnH2

(Multiple Correct Choice Type)


This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which
ONE OR MORE may be correct.

6. The radial wave function of an atomic orbital is represented by Rn,l. The wave function of an orbital is

given below [a0 = 0.529 A ].
− Zr
1 Z 
3/2
 Zr  2a0
R2,1 =    e
2 6  a0   a0 
Choose correct statement(s) about the orbital.
(A) It is one of 2p orbitals.

(B) The radial probability versus radial distance curve of this orbital has a maxima at around 2 A .
(C) It has no radial node.
(D) The orbital has two nodal planes.

7. The correct statement(s) regarding PH3 and PF3 is/are:


(A) Bond angle : PF3 > PH3
(B) Dipole moment : PH3 > PF3
(C) % s-orbital character in covalent bonds : PF3 > PH3
(D) Basic strength : PH3 > PF3
space for rough work

FIITJEE Ltd., Punjabi Bagh Centre, 31, 32, 33 Central Market, West Avenue Road, Punjabi Bagh, New Delhi – 110026, Ph: 011 - 45634000
IIT2020, CPM (RIT-1)-3

8. Which of the following reaction(s) evolve O2 gas?


(B) NaNO3 ⎯⎯⎯⎯
→ Heating
(A) KO2 + H2O →

(C) LiOH ⎯⎯⎯⎯


→ (D) MgO + H2O ⎯⎯→
Heating

9. Choose correct statement(s) for the compound BaO2.


(A) It is obtained in the following reaction
2BaO + O2 → 2BaO2
(B) It is an ionic peroxide and contains O22− ions in solution state
(C) It’s hydrate, BaO28H2O contains O22− ions to which H2O molecules are hydrogen bonded like
− − − − − − O22− − − − (H2O )8 − − − −O22− − − − − (H2O )8 − − − −
(D) It reacts with dilute acids to form H2O2 and its salt.

10. Which of the following quantum number(s) is/are correct for the unpaired electron of aluminium atom
(Z = 13) in ground state?
1
(A) n = 3 (B) =1 (C) m = –2 (D) s = 
2

11. The correct statement(s) regarding the O2 molecule and O atom is/are:
(A) Oxidizing agent : O > O2 (B) Spin-only magnetic moments : O = O2
(Paramagnetism)

(C) Ionization enthalpy : O2 > O (D) Number of electrons : O2 > O

12. Which of the following aqueous solutions form a thin solid layer on their surface(s) when they are kept
under air?
(A) NaOH (B) Ca(OH)2 (C) Ba(OH)2 (D) KOH

13. Which of the following statement(s) is / are correct for iron atom and its ions? (Z = 26)
(A) The spin multiplicity of Fe3+ ion is greater than that of Fe2+ ion.
(B) Fe3+ contains more electrons with = 2 than that of Fe2+.
(C) The orbital of Fe atom which wave function is 3, 2, 0 contains no nodal planes.
(D) ‘Fe’ atom contains eight electrons in spherical orbitals.

PART – B
(Matrix Match Type)

1. Match the molecules mentioned in Column-I with their properties mentioned in Column-II.
Column-I Column-II
(A) BF3 (P) Dipole moment is zero.
(B) CO2 (Q) Bond order is greater than one
(C) SO3 (R) Contains sigma as well as pi-bonds
(D) NH3 (S) Contains lone pair on central atom
(T) Contains p–p back bond.
space for rough work

FIITJEE Ltd., Punjabi Bagh Centre, 31, 32, 33 Central Market, West Avenue Road, Punjabi Bagh, New Delhi – 110026, Ph: 011 - 45634000
IIT2020, CPM (RIT-1)-4

2. Match the compounds mentioned in Column-I with their properties mentioned in Column-II.
Column-I Column-II
(A) MgCl2  6H2O (P) Undergoes complete dehydration on heating.
(B) Mg(OH)2 (Q) Undergoes partial dehydration on heating
(C) Ca(OH)2 (R) Added to NaCl to decrease its melting point during
preparation of Na through electrolysis
(D) CaCl2 (S) Forms mixed salt when treated with Cl2
(T) Precipitated from sea water by adding lime water

PART – C
This section contains 5 Numerical Based questions. The answer to each question is a single digit integer, ranging from 0
to 9 (both inclusive)


1. The threshold wavelength for the photoelectron emission of molybdenum is 2300 A . Radiation with

wavelength 1682 A is used to release photoelectrons. What is the maximum kinetic energy of the
photoelectrons in eV unit?

2. The wave function describing the resonating structures of hydrogen molecule is given by
H2 = (1 − )cov alent + ionic
Hence,  is called the mixing coefficient which measures the extent of contribution of the ionic forms
to the resonating structures.
What is the value of  for pure covalent forms of H2(H – H)?

3. An alkaline earth metal which hydroxide is used as an antacid, reacts with carbon to form carbide (P)
at 500°C and carbide (Q) at 700°C. (P) contains two carbon atoms and (Q) has three carbon atoms
X
per molecule. If the molar mass of (P) is X g mol–1 , what is the value of ?
6

4.
  
2p
How many maximum number of exchange pair(s) is/are possible for the above electron configuration?

5. A s-block metal(P) forms a mixture (Q) when it is heated in air. Reaction of (P) with HCl forms salt(R)
and gas(S). The same treatment of mixture(Q) produces salt(R), gas(T) and water. Reaction of (Q)
with water produces lime water and gas (T). If the number of atoms present in gas(S) and gas(T) are
respectively X and Y, what is (X + Y)?

Section – II (Physics)
PART – A
(Single Correct Choice Type)
This section contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which only
ONE option is be correct.

1. The hour hand of a clock is 6 cm long. The magnitude of the displacement of the tip of hour hand
between 1:00 pm to 5:00 pm is
(A) 6 cm (B) 6 3 cm (C) 12 cm (D) 3 3 cm
space for rough work

FIITJEE Ltd., Punjabi Bagh Centre, 31, 32, 33 Central Market, West Avenue Road, Punjabi Bagh, New Delhi – 110026, Ph: 011 - 45634000
IIT2020, CPM (RIT-1)-5

2. Let A + B = C and A − B = D . If C and D are equal in magnitude and perpendicular to each other
then
(A) A = B (B) A  B
(C) A is perpendicular to B (D) A is parallel to B

3. The velocity function of an object moving along a straight line is given by v(t) = At 2 + Bt. If at
t = 2s, the velocity is 3 m/s and acceleration is 2 m/s2, find the value of the constant A.
(A) 0.5 m/s3 (B) − 0.5 m/s2 (C) 2.5 m/s3 (D) − 1.5 m/s2

4. A particle is moving in a straight line and graph between (velocity)2 (v2) v2


and displacement (s) are related as shown. Find the acceleration of
particle when its velocity is 3 m/s.
1
(A) 1 m/s2 (B)
2
m/s2 (3m/s)2
3 450
(C) 2 m/s2 (D) m/s2 s
2
5. If A  B = C + D , then select the correct alternative
(A) B is parallel to C + D
(B) A is perpendicular to C
(C) Component of C along A = component of D along A
(D) Component of C along A = – component of D along A

(Multiple Correct Choice Type)


This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which
ONE OR MORE may be correct.

6. Two vectors A and B are drawn from a common point and C = A + B


(A) If C = A + B , the angle between vectors A and B is 90°
2 2 2

(B) If C  A + B , the angle between A and B is greater than 90°


2 2 2

(C) If C  A + B then angle between the vectors A and B is between 0° and 90°
2 2 2

(D) If C = A − B, angle between A and B is 180°

7. Which of the following statements are true based on graphs of y-versus x as shown below
y y y y

(i) (ii) (iii) (iv)

x x x x
x0 x0 x0 x0

(A) Slope at x0 is positive and non-zero in graph (i) and (ii)


(B) Slope is constant in (iii)
(C) Slope at x0 is negative in (iv) at x0
(D) Slope at x0 is negative in (ii)

space for rough work

FIITJEE Ltd., Punjabi Bagh Centre, 31, 32, 33 Central Market, West Avenue Road, Punjabi Bagh, New Delhi – 110026, Ph: 011 - 45634000
IIT2020, CPM (RIT-1)-6

8. The magnitude of component of a vector may be


(A) greater than the magnitude of that vector. (B) equal to the magnitude of that vector
(C) smaller then the magnitude of that vector (D) zero

9. Which of the following statement(s) is/are true about a vector quantity :


(A) A vector quantity always obey law of vector addition.
(B) Two vectors quantities are equal if they have same direction and magnitude even if they
represent two different physical quantities.
(C) The result of scalar product of two vectors is scalar quantity, not another vectors quantity.
(D) Similar to scalar subtraction the order of the terms in vector difference affects the results.

10. ( )
If A + B is perpendicular to A − B then A and B must represent adjacent sides of
(A) rhombus (B) square (C) rectangle (D) none

11. Let ar and at represent radial and tangential accelerations. The motion of a particle may be circular if:
(A) ar = at = 0 (B) ar = 0 and at  0 (C) ar  0 and at = 0 (D) ar  0 and at  0

x t3
12. A particle moves along positive branch of the curve, y = , where x = , x and y are measured in
2 3
metres and t in seconds, then
1
(A) The velocity of particle at t = 1s is ˆi + ˆj
2
1ˆ ˆ
(B) The velocity of particle at t =1s is i+j
2
(C) The acceleration of particle at t =1s is 2iˆ + ˆj
(D) The acceleration of particle at t = 2 s is ˆi + 2jˆ

13. If A 2iˆ 3ˆj and B 2iˆ 3ˆj kˆ then


(A) A.B 5 (B) A.B 5 (C) A B 157 (D) A B 157

PART – B
(Matrix Match Type)
1.
Column I Column II
(A) In one dimensional motion of a particle (P) Acceleration may be along the motion
(B) In projectile motion of a particle (except (Q) Acceleration will never be along the motion
angle of projection with horizontal is
90°)
(C) In uniform circular motion of a particle (R) Acceleration may be perpendicular to motion
(D) In non-uniform circular motion of a (S) Acceleration may be opposite to the
particle displacement
(T) Acceleration must be perpendicular to the
motion
space for rough work

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2. If a particle is projected with speed 5 2 m/s along the angle of elevation of 45° with horizontal from
top of a tower of height 30 m, then match the following (g = 10 m/s2)

Column I Column II
(A) Time taken to reach the ground (P) 1.366 sec
(B) Time taken to reach to the maximum (Q) 1 sec
height
(C) Time taken by the body when its (R) 3 sec
velocity makes an angle 45o with
vertical again
(D) Time taken by the body when its (S) 0.5 sec
velocity makes an angle 60o with
horizontal during its downward motion
(T) 2 sec

PART – C
This section contains 5 Numerical Based questions. The answer to each question is a single digit integer, ranging from 0
to 9 (both inclusive)

1. A passenger is standing 20m behind from a bus. The bus begins to move with constant acceleration
0.9m/s2 . To catch the bus, the passenger runs at a constant speed v towards the bus. What must be
the minimum speed (in m/s)of the passenger so that he may catch the bus?

V0

0
2. In the given figure, the angle of inclination of the inclined 90
plane is 300. Find the horizontal velocity V0 (in m/s) so that H
the particle hits the inclined plane perpendicularly. Given,
H = 4m, g = 10 m/s2
0
30

3. Velocity of a particle at any instant is given by the equation V = (3iˆ + 2t 2 ˆj)m/s. Tangential
acceleration of the particle at t = 2s is 4.1 K m/s2. Find the value of K.

x
4. Given two vectors A = 2iˆ + 3jˆ and B = ˆi + ˆj . The component of vector A along vector B is .
2
Find the value of ‘x’.
v
5 m/s

5. From the velocity-time plot shown in figure. The


average velocity during this period is (N × 6). 0 t (s)
20 40

−5 m/s

space for rough work

FIITJEE Ltd., Punjabi Bagh Centre, 31, 32, 33 Central Market, West Avenue Road, Punjabi Bagh, New Delhi – 110026, Ph: 011 - 45634000
IIT2020, CPM (RIT-1)-8

Section – III (Mathematics)


PART – A
(Single Correct Choice Type)
This section contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which only
ONE option is be correct.

 
1. (
If f ( x ) = cos−1 x − x 2 +  1 −
 ) 1
 + 2
1
, then domain of f(x) is (where [.] is the greatest
 x   x − 1
integer)
1 − 5   1− 5   1+ 5  1 − 5 1 + 5 
(A)  , 2 (B)  − 2,  (C)  2,  (D)  , 
 2   2   2   2 2 

cot −1 
 tan x 
2. For   R, the range of the function f() =   tan x + cot x dx is equal to
tan−1   
 −    − 3   
(A)  ,  (B) (0, ) (C)  ,  (D)  0,
 2 2  4 4   2 
3. Which of the following function is surjective but not injective
(A) f : R → R f(x) = x 4 + 2x 3 − x 2 + 1 (B) f : R → R f(x) = x 3 + x + 1
(C) f : R → R+ f(x) = 1 + x 2 (D) f : R → R f(x) = x 3 + 2x 2 − x + 1

and for n  2, define f n  x  = f1 ( f n −1 ( x ) ) then incorrect statement is


2 3
4. Let f1 ( x ) = −
3 3x + 1
−3x − 7
(A) f 2 ( x ) = f ( f ( x ) ) = (B) f1001 ( x ) = f 2 ( x )
9x − 6
(C) f3 ( x ) = x (D) None of these

5. Let f ( x ) = x3 + x2 and g ( x ) be the inverse of f ( x ) , then the value of g' ( 2 ) =


1 1 1 1
(A) (B) (C) (D)
3 4 5 6
(Multiple Correct Choice Type)
This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which
ONE OR MORE may be correct.

6.
 5 1 
Let f : 0,  →  , 3  such that f ( x ) =
 x + 1
where . represents the greatest integer function
 2 2  x + 1
and 
. represents the fractional part of x, then which of the following is / are true.
(A) f(x) is injective discontinuous function. (B) f(x) is surjective non – differentiable function.

(
(C) min lim− f ( x ) , lim+ f ( x ) = f (1)
x →1 x →1
) (D) max ( lim f ( x), lim f ( x )) = f (2)
x →2− x →2+

space for rough work

FIITJEE Ltd., Punjabi Bagh Centre, 31, 32, 33 Central Market, West Avenue Road, Punjabi Bagh, New Delhi – 110026, Ph: 011 - 45634000
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7. Which of the following function is / are periodic


(A) sgn e
−x
( ) (B) sin x + sin x

 1  1
(C) min sin, x( ) (D)  x +  +  x −  + 2 −x
 2  2
( . denotes greatest integer function)

8. Of the following functions defined from  −1, 1 to  −1, 1 , select those which are not bijective

(
(A) sin sin−1 x ) (B)
2 −1

sin ( sin x ) (C) ( Sgn x ) / In e x ( ) (D) x3 ( Sgn x )

9. Which of the following functions are even?

( ))
 ax + 1
(A) f ( x ) = x   (B) g ( x ) = In x + (x 2
+ a2
 a − 1
x

0, if x is rational
(C) h ( x ) = (1 − x ) + 3 (1 + x ) (D) p ( x ) = 
2 2
3

 1, if x is irrational

10. If x, y and z lie on domain of the equation such that ln(x + z) + ln(x – 2y + z) = 2 ln (x – z), then which
of the following is / are true
2xz x x−y
(A) y = (B) y2 = xz (C) 2y = x + z (D) =
x+z z y−z

 2 5 
11. Let f :  ,  → 0,4 be a function defined as f ( x ) = 3 sin x − cos x + 2 , then :
3 3
4 5 7
(A) f (1) = (B) f −1 (1) =  (C) f ( 2 ) = (D) f ( 2 ) =
−1 −1 −1

3 6 6

12. The function g, defined by g(x)= sin  + cos  − 1, where  = sin


−1
x, where 
. denotes fractional
part then which of the following is / are true for the function g
(A) an even function (B) periodic function (C) odd function (D) neither even nor odd

13. Which of the following function(s) has/have the same range?


1 1 1 1
(A) f(x) = (B) f(x) = (C) f(x) = (D) f(x) =
1+ x 1+ x 2
1+ x 3−x
space for rough work

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PART – B
(Matrix Match Type)

1. Column B represents the number of solutions of equations given in column A now match the following
where {x} stands for fractional part of x.
Column A Column B
(A) 15{x} = 2x + 3 (P) 7
(B) x (Q) 5
{x} = n  
3
(C) | x | =| sin x | x  ( −, ) (R) 6
(D) {x} = {− x} x  ( −3,3) (S) 11

2. Match the following


Column-I Column-II
f ( x ) = x, the fractional part of x
( )
(A) (P) 1 x
f −1 ( x ) = 4 − 4− x
2
(B) 16 x − 1 (Q) f is an even function
f (x) =
4x
(C)
(
f ( x ) = log4 x + x 2 + 1 ) (R) f is a periodic function

(D) 3x − 1 (S) f is an odd function


f (x) = x
3x + 1
PART – C
This section contains 5 Numerical Based questions. The answer to each question is a single digit integer, ranging from 0
to 9 (both inclusive)

1. If f : R → R is a function such that f ( x ) = x3 + x2 f ' (1) + xf " ( 2) + f "' (3 ) for all x  R, then
f (1) − f ( 2)
2. Let f(x) be a function such that f(x) = x3 and the line x + y = 0 is tangent to the graph of f(x). Find the
value of (4  f(x) – x4).

3. Let x and y be real numbers satisfying the equation x 2 + y2 − 4x + 3 = 0 . If the maximum and
( )
minimum values of x 2 + y2 are M and m respectively, then the numerical value of (M−m) is …….

 1  1
4. If f ( x ) is a polynomial satisfying f ( x ) .f   = f ( x ) + f   , and f ( 3) = 28, then f ( 4 ) is given by
x x
K
K, where equals to
13
x2 − 1
5. If f ( x ) = , for every real number, then minimum value of f is m, where m + 1 is
x2 + 1
space for rough work

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IIT2020, CPM (RIT-1)-11

FIITJEE INTERNAL TEST


Batches: NWCM820X1R - X4R, NWTR820C01, D01, CAMP820, NWCM820G1W, NWCM820X1W
- X11W, NWTW820D01 - D02, PANINI820-XII G1, PANINI820-XII1 - XII7, PIN820-XII B
RANK IMPROVEMENT TEST – I
IIT- JEE 2020
ANSWERS
QP CODE: 122460
SECTION – I (Chemistry)
Part – A
1. B 2. A 3. B 4. C
5. B 6. ABC 7. ABCD 8. AB
9. ABCD 10. ABD 11. ABD 12. BC
13. ACD
Part – B
1. A →PQT B → PQR C → PQR D →S
2. A→Q B → PT C → PS D→R
Part – C
1. 2 2. Zero 3. 8 4. 3
5. 6

SECTION – II (Physics)
Part – A
1. B 2. C 3. A(marks to all) 4. B
5. D 6. ABCD 7. ABC 8. ABCD
9. ACD 10. AB 11. CD 12. AC
13. AC
Part – B
1. A → PS B → QR C → QRST D → QS
2. A→R B→S C→Q D→P
Part – C
1. 6 2. 4 3. 2 4. 5
5. 0

SECTION – III (Mathematics)


Part – A
1. C 2. C 3. D 4. D
5. C 6. ABD 7. ABCD 8. BCD
9. ACD 10. AD 11. AD 12. AB
13. BC
Part – B
1 A→R B→Q C→Q D→S
2. A→R B→S C →P D →Q
Part – C
1. 6 2. 3 3. 8 4. 5
5. 0

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