Phase 5 Mains

FIITJEE – JEE (Main)
Physics, Chemistry & Mathematics

QP Code:
BATCHES –1820 (XII) PHASE-V
Time Allotted: 3 Hours Maximum Marks: 300
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
You are not allowed to leave the Examination Hall before the end of the test.
Important Instructions
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR
sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. Each Section is further divided into Two Parts: Part-A & C in the OMR. Part-B of OMR to be left unused
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be provided
for rough work.
6. No candidate is allowed to carry any textual material, printed or written, bits of papers, clip boards, log
tables, slide rule, calculator, cellular phones, pagers and electronic devices ext. except the Admit Card
inside the examination hall / room.
B. Filling of OMR Sheet:

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR
sheet.
2. On the OMR sheet, darken the appropriate bubble with Blue/Black Ball Point Pen for each
character of your Enrolment No. and write in ink your Name, Test Centre and other details at the
designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
4. Do not fold or make any stray marks on the Answer Sheet.
C. Marking Scheme for All Two Parts:

(i) Part-A (01-20) – Contains Twenty (20) multiple choice objective questions which have four (4) options
each and only one correct option. Each question carries +4 marks will be awarded for every correct
answer and -1 mark will be deducted for every incorrect answer.
(i) Part-C (01-05) contains Five (05) Numerical based questions with single digit integer as answer, ranging
from 0 to 9 (both inclusive). Each question carries +4 marks will be awarded for every correct answer and
NO MARKS will be deducted for every incorrect answer.
Name of the Candidate :_______________________________________________
Batch :_______________________ Date of Examination :____________________
Enrolment Number :___________________________________________________
Faridabad (Delhi-NCR), FIITJEE Ltd, Sector-15A Market, Near Vidya Mandir Public School, Ajrounda Chowk, Faridabad, Ph-
0129-4174582, Website:www.fiitjee.com
IITJEE-2020- PT-V—PCM-SET-A/13
2
SECTION-I: PHYSICS
Part–A: Only One Option Correct Type
This section contains 20 Multiple Choice Questions. Each question has 4 choices (A), (B), (C) and (D), out of
which Only One Option is correct.
1. 1 gm of a radioactive substance takes. 50 sec to loose 0.01 gm then the half life of the
sample will be
50 ln (2) 50 ln (2) 50 ln (2) 50 ln (2)
(A) (B) (C) (D)
 100  ln (100) ln (99) ln (0.99)
ln  
 99 
2. In a hypothetical system a particle of mass m and charge –3q is moving around a very heavy
particle having charge q. Assuming Bohr’s model to be true to this system, the orbital velocity
of mass m when it is nearest to heavy particle is
3q2 3q2 3q 3q
(A) (B) (C) (D)
2ε o h 4ε o h 2εoh 4εoh
3. An intensity vs frequency graph for the x-ray emission is given in the figure, the kα
wavelength will be
I
L1 L2 L3 ν
C C C C
(A) (B) (C) (D)
L1 L2 L1 + L2 L 2 + L3
4 3
4. The lens combination having refractive indices & as shown in the figure, is silvered. The
3 2
velocity of image will be?
3
2
4
3
O
vo = −5 î
R = 20 cm
40 cm
(A) 1.8 î (B) 3 î (C) 3.6 î (D) 5 î
Space for rough work
3
5. There is a uniform time varying magnetic field in a circular region as shown in the figure. Find
out the potential difference across 2 point along an elliptical path as shown in figure.
x x B = Bot
x x x
x x x x
A B
x x x x
x R/2 x
Rx Elliptical
path
x x
πR2 πR2 πR2 πR2

(A) Bo (B) Bo (C) Bo (D) Bo
2 2 4 5
6. A ray incident at an angle 53° on prism emerges at an angle 37° as shown in the figure. If
the angle of incidence is made 50°, which of the following is a possible value of angle of
emergence
53° 37°
(A) 35° (B) 42° (C) 40° (D) 38°
7. A parallel beam of light 500 nm is incident at an angle 30° with the normal to the slit plane in
a Young’s Double Slit Experiment. The intensity due to each slit is Io. Point O is equidistant
from S1 and S2. The distance between slits is
1 mm then
O
30° D = 3m
d
Screen
(A) the intensity at O is 4Io.
(B) the intensity at O is zero.
(C) the intensity at a point on the screen 4 mm from O is 4Io.
(D) None of these
4
8. Figure shows the variation of photocurrent with anode potential for a photosensitive surface for
three different radiations. Let Ia,Ib and Ic be the intensities and fa,fb and fc be the frequencies for
the curves a, b and c respectively. Which of the following facts is correct?
Photo current
c
a
b
Anode potential
(A) fa = fb and Ia ≠ lb
(B) fa = fc and Ia = lc
(C) fa = fb and Ia = lb
(D) fb = fc and Ib = lc
1 1
9. vs graph for a spherical mirror is shown in the figure. The focal length of the mirror will
v u
be
1/v
 1 −1 1 −1 
 2 cm ; cm 
 3 
1/u
6 6
(A) 5 cm (B) –5 cm (C) cm (D) − cm
5 5
10. In a Young’s double slit experiment, the slit separation is 1 mm and the screen is 1 m from
the slit. For a monochromatic light of wavelength 500 nm, the distance of 3rd minima from the
central maxima is
(A) 0.50 mm (B) 1.25 mm (C) 1.50 mm (D) 1.75 mm
11. The Kα X-ray emission line of tungsten occurs at λ = 0.021 nm. The energy difference
between K and L levels in this atom is about
(A) 0.51 MeV (B) 1.2 MeV (C) 59 KeV (D) 13.6 Ev
5
12. A silver sphere (work function 4.6 eV) is suspended in a vacuum chamber by an insulating
thread. Ultraviolet light of wavelength 0.2 µm strike on the sphere. The maximum electric
potential of the sphere will be (hc = 12400 eVÅ)
(A) 4.6 V (B) 6.2 V (C) 1.6 V (D) 3.2 V
13. Photoelectric effect experiments are performed using three different metal plates p, q and r
having work functions φp = 2.0 eV, φq = 2.5 eV and φr = 3.0 eV, respectively. A light beam
containing wavelengths of 550 nm, 450 nm and 350 nm with equal intensities illuminates
each of the plates. The correct I-V graph for the experiment is
(A) I P
(B) I
p q
r
V
(C) I r
q
p
(D) I
r q
p
V
6
14. A rod PQ is connected to the capacitor plates. The rod is placed in a magnetic field (B)
directed downwards perpendicular to the plane of the paper. If the rod is pulled out of
magnetic field with velocity v as shown in figure.
× ×× × × ×
× × ×P × × ×
××× × × × M
v
× ×× × × × N
× × ×Q × × ×
××× × × ×
(A) Plate M will be positively charged
(B) Plate N will be positively charged
(C) both plates will be similarly charged
(D) no charge will be collected on plates.
15. A conducting ring of radius r is rolling without slipping with a constant angular velocity ω in
figure. If the magnetic field strength is B and is directed into the page then the e.m.f. induced
across PQ is
× ×× × × ×
× × × ω× × ×
× × ×i × ×P ×
× ×× × × ×
× × × Q× × ×
2 B ωr 2 2 π2 r 2Bω
(A) B ωr (B) (C) 4Bωr (D)
2 8
7
16. A square loop of side α and a straight infinite conductor are placed in the same plane with the
two sides of a square parallel to the conductor. The inductance and the resistance are equal
to L and R. The frame is turned through 180o about axis OO’. Find the charge that flows in
the square loop.
O
b a
O’
µ0 a + b µ0  2a + b 
(A) In (B) In
πR b πR  b 
µ0Ia 2a + b  a + b  µ0 I
(C) In (D) In  
2 πR b  b  2 πR
17. A metal disc of radius a rotates with a constant angular velocity ω about its axis. The
potential difference between the centre and the rim of the disc is (m = mass of electrone, e =
charge on electron)
mω2 a2 1 mω2a2
(A) (B)
e 2 e
eω2 a2 eω2 a2
(C) (D)
2m m
18. A long conducting wire AH is moved over a conducting triangular wire CDE with a constant
velocity v in a uniform magnetic field B directed into the plane of the paper. Resistance per
unit length of each wire is r. Then
D ×B
F G
A H
v
C E
(A) A constant clock wise induced current will flow in the closed loop
(B) An increasing anticlockwise induced current will flow in the closed loop
(C) A decreasing anticlockwise induced current will flow in the closed loop
(D) A constant anticlockwise induced current will flow in the closed loop
8
19. A beam of light propagates through a medium 1 and falls onto another medium 2, at an angle
α1 as shown. After that, it propagates in medium 2 at an angle α2 as shown. The light’s
wavelength in medium 1 is λ1 . What is wavelength of light in medium 2?
α1
Medium 1
Medium 2
α2
sin α1 sin α 2 cos α1 cos α 2

(A) (B) λ1 (C) λ1 (D) λ1
sin α 2 sin α1 cos α 2 cos α1
20. What is the angle of incidence for an equilateral prism of refractive index 3 so that the ray
is parallel to the base inside the prism?
(A) 30 o (B) 45 o (C) 60 o (D) Either 30 o or 60 o
9
Part – C (Integer Type)

This section contains 05 questions. The answer to each question is a single-digit integer, ranging from 0 to
9. The correct digit below the question number in the ORS is to be bubbled.
1. A beam of light having wavelength 5000 A0 is incident on a plane metallic surface. The intensity
of the incident beam of light is 40 watt and its cross-sectional area is 2mm2. What will be
pressure (in dyne/ cm2) exerted by radiation on the metallic surface if 50% of it is reflected back
by metallic surface.
2. Initially two radio active nucleus have same no of active nucleus their half life are 3 years and 4
years respectively after years, number of nucleus of one of the radioactive element is half the
number of active nucleus of other radioactive element. Then
3. In the figure the refractive index of the medium in which 10 cm

observer is present is µm and the observer sees the object at
µ2 = 4/3
8 cm. If the refractive index µm = (4/15) × P, then find the Observer
value of P. (µ
µm)
• object
Thin slab of Thin slab of

µ3 = 2 µ1 = 3/2
4. Light of wavelength 627 nm illuminates two slits. The minimum path difference (in nm)
between the waves from the slits for the resultant intensity to fall to 25% of the central
maximum is given by 200+(x). Find the value of x?
5. A circular loop of radius 2.0 meters has total resistance of 5.0 ohms. A variable current flows
in the loop given by I=2.0 t amperes, where t is time in seconds. A small circular loop of
radius 1.0 cm and having resistance of 0.5 ohm is placed coaxially with the larger loop at a
distance of 2 3 meters from the centre of larger loop. If the induced current in smaller loop is
µ0π
mA, then the value of p is.
10 p
10
SECTION-II: CHEMISTRY
1. For the non- stoichiometric reaction: 2 A + B  → C + D, the following kinetic data were
obtained in three separate experiments, all at 298 K.
Initial Concentration [A] Initial Concentration [B] Initial rate of formation of C

(mol L-1sec-1)
0.1M 0.1M 1.2 × 10−3
0.1M 0.2M 1.2 × 10−3
0.2M 0.1M 2.4 × 10 −3
The rate law for the formation of C is:
dc 2 dc
(A) = k [ A][B ] (B) = k [ A]
dt dt
dc dc 2
(C) = k [ A ][B ] (D) = k [ A ] [B ]
dt dt
2. How much Faraday’s of electricity should be passed through enough water in order to obtain
32 kg of dioxygen (O2) gas as a product of electrolysis?
(A) 400F (B) 4000F
(C) 2000F (D) 200F
3. The molality of a urea solution in which 0.0100g of urea, [(NH2)2CO] is added to 0.3000 dm3
of water at STP is:
(A) 3.33 × 10 −2 m (B) 0.555m (C) 5.55 × 10 −4 m (D) 33.3m
4. Resistance of a conductivity cell with a solution of an electrolyte of concentration 0.1M is

100Ω . The conductivity of this solution is 1.29 S m-1. Resistance of the same cell when
filled with 0.2 M of the same solution is 520Ω . The molar conductivity of 0.2 M solution of
the electrolyte will be
(A) 124 × 10−4 S m 2 mol −1 (B) 1240 × 10 −4 S m 2 mol −1
(C) 1.24 × 10−4 S m 2 mol −1 (D) 12.4 × 10−4 S m 2 mol −1
11
5. Given the data at 25°C,

→ Agl + e − ; E ° = 1.152V
Ag + I − 
→ Ag + + e − ;
Ag  E ° = −0.800V
What is the value of log Ksp for Agl
 RT 
 2.303 = 0.059 
 F 
(A) -8.12 (B) +8.612 (C) -37.83 (D) -16.13
6. Which of the following complex can form maximum amount of white ppt. when reacts with
aqueous AgNO3 solution?
(A) [Cr(NH3)4(Cl)2]Cl (B) [Cr(NH3)3(Cl)3]
(C) [Cr(NH3)5Cl]Cl2 (D) [Cr(NH3)6]Cl3
7. The color of KMnO4 is due to:

(A) d – d transition
(B) L → M charge transfer transition
(C) σ − σ *transition
(D) M → L charge transfer transition
8. The value of the ‘spin only’ magnetic moment for one of the following configurations is 2.84
BM. The correct one is
(A) d4 (in strong ligand filed)
(B) d4 (in weak ligand field)
(C) d3 (in weak as well as in strong field)
(D) d5 (in strong ligand field)
9. The partial pressure of ethane over a solution containing 13.12 × 10−3 g of ethane is 1
bar. If the solution contains 0.10 g ethane, then partial pressure is
(A) 1.312 bar (B) 1.0 bar (C) 7.62 bar (D) 0.762 bar
10. The value of Henry’s constant KH is is ________.

(A) greater for gases with higher solubility
(B) greater for gases with lower solubility
(C) constant for all gases
(D) not related to the solubility of gases
12
11. In a parallel reaction at 23°C
−1
k1 B E1 = 20 Kcal mol
A
k2 C E2 = 40 Kcal mol −1
Ration of concentration of the product ([B] : [C]) is

(A) 2 (B) 4.67 × 1014 (C) 4.67 × 10 −14 (D) 222 × 10−14
12. Which of the following is the most likely structure of CrCl3.6H2O, if 1/3 of total chlorine of the
compound is precipitated by adding AgNO3 to its aqueous solution :
(A) CrCl3.6H2O (B) [Cr(H2O)3Cl3](H2O)3
(C) [CrCl2(H2O)4]Cl.2H2O (D) [CrCl.(H2O)5]Cl2.H2O
13. For the half-cell,
OH O
+2H + + 2e − ; E ° = 1.30V
OH O
At pH = 2, electrode potential is
(A) 1.36 V (B) 1.30 V (C) 1.42 V (D) 1.20 V
14. Conductivity (k) of 0.01 NaCl solution is

0.00145 S cm-1. What happens to the conductivity if extra 100 mL of H2O be added to the
above solution?
(A) Increases
(B) Decreases
(C) Remains unchanged
(D) First increase and then decreases
15. Which is the strongest field ligand :

(A) CN– (B) NO2– (C) NH3 (D) En
13
16. The electrode potential of which of the following hydrogen electrode is assumed to be zero?
(A) Pt | H2(1 atm) | H+(10 M) (B) H+(1 M) | H2(1 atm) | Pt
+
(C) Pt | H2(1 atm) | H (pH = 1) (D) H+(pH = 1) | H2(10 atm) | Pt
17. For 1 molal aqueous solution of the following compounds, which one will show the highest
freezing point?
(A) [Co(H2O)3 Cl3].3H2O (B) [Co(H2O)6] Cl3
(C) [Co(H2O)5 Cl] Cl2.H2O (D) [Co(H2O)4 Cl2] Cl.2H2O
18. Total number of possible isomers for square planar [Pt(Cl)(NO2)(NO3)(SCN)]-2 is:
(A) 24 (B) 16 (C) 8 (D) 12
22. Which of the following solution is isotonic with 0.4 M CaCl2?

(A) 0.4 M glucose(C6H12O6) (B) 0.4 M NaCl
(C) 0.3 M AlCl3 (D) 0.2 M Na2SO4
20. Choose the incorrect statement:

(A) n-Hexane and n-Heptane form nearly ideal solution.
(B) Pyridine and formic acid can form maximum boiling point azeotrope.
(C) Heptane and Ethanol shows positive deviation from Raoult’s law.
(D) Chloroform and methanol can form maximum boiling point azeotrope
14

1. An element with (Z = 69) emits 2α and 1β particles in succession. What will be the group
number of new element formed?
2. Total number of isomers having formula [Co(en)2 (NH3 )Cl]2+ are :
3. Calculate CFSE value for d5 high spin octahedral.
4. The vapour pressure of a mixture of two volatile liquids ‘A’ & ‘B’; is expressed as
Pmix = 6.0 + 1.5 X B , where XB is the mole fraction of B in the mixture. The vapour pressure
of ‘A’ at the same temperature is __________.
5. E 0 (in volt) of cell A + B + n  0 0

→ A + n + B if E An+ /A = −2.5V and E Bn+ /B = +0.5V …….
15
SECTION-III: MATHEMATICS
1. A pair of dice is rolled together till a sum of either 5 or 7 is obtained. Then, the probability that
5 comes before 7 is:
1 4 2 2
(A) (B) (C) (D)
5 7 3 5
2. 7 white balls and 3 black balls are placed in a row at random. The probability that no two
black balls are adjacent is:
1 7 2 1
(A) (B) (C) (D)
2 15 15 3
x1 x2 x3
3
3. If x1, x 2 , x 3 are the roots of x + ax + b = 0, then the value of x 2 x3 x1 is equal to:
x3 x1 x2
2 2
(A) –a (B) 3b − a (C) 3b − b (D) none of these
4. The minimum number of zero elements in an upper triangular matrix of order n × n is:
(A)
n ( n − 1)
(B)
n ( n + 1)
(C)
n2 − 1 ( )
(D)
n2 + 1 ( )
2 2 2 2
5. Ifa ⋅ iˆ = a ⋅ (2iˆ + ˆj ) = a ⋅ (iˆ + ˆj + 3kˆ ) = 1, then a is equal to

(3iˆ + 3 ˆj + kˆ )
(A) iˆ − kˆ (B)
3
(iˆ + jˆ + kˆ ) (3iˆ − 3 ˆj + kˆ )
(C) (D)
3 3
6. The area of the portion enclosed by the curve x + y = a and the axes of reference is:
2
a a2 a2
(A) (B) a2 (C) (D)
6 2 4
16
7. The maximum area of a rectangle whose two consecutive vertices lie on the x – axis and
−x
another two lie on the curve y = e , is equal to
2 1
(A) 2e sq. units (B) sq. units (C) e sq. units (D) sq. units
e e
8. General solution of ( xy sin xy + cos xy ) y dx + ( xy sin xy − cos xy ) x dy = 0 , is equal to

(A) y.sin ( xy ) = cx (B) x.sec ( xy ) = cy (C) y. tan ( xy ) = cx (D) y.cot ( xy ) = cx
1
9. If a and b be two non – collinear unit vectors such that a × a × b = ( ) 2
b then the angle
between a and b is equal to:

π
(A)
2
π
(B)
4
(C) information are inconsistent
(D) none of the above
10. The equation of the right bisecting plane of the line segment joining the points A ≡ ( a,a,2a )
and B ≡ ( −a, − a,a ) is
(A) x + y + z = a
(B) 4x + 2y + z = 3a
(C) 4x − 2y + z = 3a
(D) 4x + 4y + 2z = 3a
11. The shortest distance of the plane 12x + 4y + 3z = 327, from the sphere
x 2 + y 2 + z 2 + 4x − 2y − 6z = 155, is equal to:
(A) 39 units (B) 26 units (C) 13 units (D) none of these
12. If a + b = p and a − b = q , then

2 2
(A) a + b = p + q
2 2
( 2
(B) 2 a + b
2
)= p 2
+q
2
(
(C) 2 a − b
2 2
)= p 2
−q
2
(D) none of the above
17
1 − t2
13. Area enclosed by the curve y = f(x) defined parametrically as x = and
1 + t2
2t
y= is equal to
1 + t2
π 3π 3π
(A) π sq units (B) sq units (C) sq units (D) sq units
2 4 2
14. If A is a diagonal matrix of order 3 × 3 is commutative with ever square matrix of order 3 × 3
under multiplication and trace (A) = 12, then
(A) |A| = 64 (B) |A| = 16 (C) |A| = 12 (D) |A| = 0
15. The area bounded by the curve xy 2 = 4a2 (2a − x ) and its asymptotes, is
(A) a2 sq units (B) πa2 sq units 2
(C) 4 πa sq units (D) None of these
dx dy
16. The solution of the differential equation + = 0 , is
x y
1 1
(A) + =C (B) log x log y = C (C) xy = C (D) x + y = C
x y
dy
17. The solution of the differential equatin + 1 = e x + y , is
dx
(A) ( x + y ) e x+y = 0 (B) ( x + C ) e
x+y
=0
(C) ( x − C ) e ( x + C ) e x+y + 1 = 0
x+y
=1 (D)
dy
18. The integrating factor of the differential equation cos x + y sin x = 1 , is
dx
(A) sin x (B) sec x (C) tan x (D) cos x
18
19. If a = b , then
(A) (a + b ) is parallel to ( a − b ) (B) (a + b ) is perpendicular to ( a − b )

(C) ( a + b ) . ( a − b ) = 2 a
2
(D) None of the above
20. If a , b and c are the position vectors of three non-collinear points A, B and C respectively,
then the shortest distance of A from BC is
2
 a.b 
2
(A) (
a. b − c ) (B) b −a −
 c 

(C) b −a (D) None of the above

19
FIITJEE COMMON TEST

PHYSICS, CHEMISTRY & MATHEMATICS
PHASE-V (SET-A)
JEE MAINS
QP CODE:
PHYSICS CHEMISTRY MATHEMATICS
Concept Q. Concept Q. Concept
Q.No ANSWER ANSWER ANSWER
Codes No Codes No Codes
1. A P120634 1. B C122101 1. D M121317
2. A P120615 2. B C123404 2. B M121317
3. A P120620 3. D C124402 3. D M121813
4. A P120521 4. C C120603 4. A M121803
5. C P120414 5. D C120507 5. D M121006
6. D P120526 6. D C120504 6. A M121005
7. A P120544 7. C C120504 7. B M121006
8. A P120609 8. C C120706 8. B M122412
9. C P120524 9. B C120104 9. C M121122
10. B P120539 10. A C120107 10. D M121114
11. C P120620 11. D C120104 11. C M121241
12. C P122206 12. C C120602 12. B M121114
13. A P120608 13. B C120604 13. A M121005
14. A P120406 14. B C122101 14. A M121006
15. D P120409 15. A C122109 15. C M121004
16. C P125705 16. B C121301 16. C M122412
17. B P121705 17. D C123703 17. D M122415
18. D P121705 18. C C123510 18. B M122415
19. B P120509 19. C C123606 19. B M121115
20. C P120527 20. B C123506 20. D M121114
1 1 P120609 1 3 C122104 1 4 M121006

2 1 P120632 2 5 C120102 2 1 M121244
3 4 P120529 3 0 C120107 3 1 M122412
4 9 P120537 4 6 C120604 4 4 M121317
5 8 P120413 5 3 C120501 5 1 M122415
20
Hind and Solution

Part - Physics
1. A P120634
Sol. N = Noe–λt
 100 
0.99 = 1 e–λt ⇒ λt = ln  
 99 
 100 
ln  
99 
50 sec = t = 
λ
50 ln(2)
⇒ t1/2 =
ln(100 / 99)
2. A P120615
Sol. By Bohr’s model.
3Kq2 mv 2 3Kq2
I. = ⇒ r =
r2 r mv 2
h
Then mvr = (put n = 1)
2π
mv 3Kq2 h
2
=
mv 2π
3Kq2 (2π) 3q2
⇒ v= =
h 2εoh
3. A P120620
hc  C
Sol. hL1 = ⇒  λkα = 
λkα  L1 
4. A P120521
Sol. v I = −m2 v o
9 ˆ = 1.8 î
= − × ( −5i)
25
5. C P120414
dφ dB πR  R 
Sol. ∆V = = (Area) × = (Bo )
dt dt 2  2 
πR 2
∆VAB = Bo
4
6. D P120526
Sol. By the δ vs i graph if i is decreased e will increase less i.e. it may increase by (2° or 1°).
7. A P120544
Sol. Path diff. at O = d sin 30°
1
= (1× 10−3 ) × = 0.5 × 10–3 = 103 λ.
2
⇒ At 0 there is max having I = 4Io.
8. A P120609
Sol. fA = fB (same stopping potential)
Ia ≠ Ib
21
9. C P120524
1 1 1 1 1 1 6
Sol. + = ⇒ = + ⇒f =
v u f f 2 3 5
10. B P120539
Sol. Distance of nth minima from central bright fringe
(2n − 1)λD
xn =
2d
For n = 3, i.e. 3rd minima
(2 × 3 − 1) × 500 × 10 −9 × 1
x3 = = 1.25 × 10 −3 m = 1.25 mm
2 × 1× 10 −3
11. C P120620
hc (6.6 × 10 −34 ) (3 × 108 )
Sol. EK − EL = = eV = 59 KeV
λ (0.021× 10 −9 ) (1.6 × 10 −19 )
12. C P122206
Sol. From Einstein equation
hc 12400
hv = −ϕ= − 4.6 = 6.2 − 4.6 = 1.6 eV
λ 2000
So the electron will be ejected till sphere will get a potential of 1.6 V
13. A P120608
Sol. As λ increases saturation current also increases.
14. A. P120406
Consider the force on an electron in PQ. This electron experiences a force towards Q.
Clearly, all free electrons in PQ tend to move towards Q.
15. D. P120409
E = Magnitude of induced e.m.f
Bl 2
= ω (i)
2
π l
θ= = (ii)
2 r
Using (ii) in (i), we get
2
π 
 2 r  ω π2 r 2 Bω
∴E =B  =
2 8
16. C. P125705
17. B. P121705
Let E be the electric field at a distance r from the centre of the disc. Then
eE = mω2 r
mω2 r
or E =
e
r =a
∴ P.D. = ∫ E dr
r =0
22
α mω2 r mω2 a2
=∫ =
0 e 2e
18. D. P121705
Magnetic flux in ⊗ direction through the coil is increasing. Therefore, induced current will
produce magnetic field in ⊙ direction. Thus the current in the loop is anticlockwise.
Magnitude of induced current at any instant of time is
e
i=
R
Bu ( FG )
=
ρ ( FG + GD + DF )
When the wire AH moves downwards FG, GD and DF all increase in the same ratio.
Therefore, i is constant.
19. B. P120509
µ1 sin α = µ2 sin α 2
α1 µ1
µ2
α2
c c
sin α1 = sin α 2
v1 v2
sin α1 sin α 2
=
f λ1 f λ2
20. C. P120527
 60 o + δm 
sin  
 2 
3=
 60 o 
sin  
 2 
 60 o + δm 
3 = sin  
 2 
 60 o + δm 
sin 60 o = sin  
 2 
60 o + δm
Or = 60 o
2
A + δm 60 o + 60 o
Or δm = 60 ⇒ i =
o
= = 60 o
2 2
23
INTEGER TYPE
1. 1
2. 1
Let = and = and
t =12 so x=1
3. 4
dactual
= dapp
µrel
4. 9
I = I0 cos2 (φ/2) = I0/4
∴ φ = 2π/3
Now 2π/λ (∆x) = 2π/3
∴ ∆ x = 209 nm
5. 8
Chemistry
1. B C122101
x y
R = k [ A] [B ]
x y
1.2 × 10 −3 = k [0.1] [0.1]
x y
1.2 × 10 −3 = k [0.1] [0.2]
x y
2.4 × 10 −3 = k [0.2] [0.1]
Solving x = 1, y = 0
R = k [ A]
2. A C123404
k = Ae −Ea / RT
k1 A e − Ea / RT k E / RT
= 1 − Ea2 /RT ⇒ 1 = Ae − Ea 1 / RT e a2
k 2 A2e k2
1
k1 [− Ea1 +Ea2 ]
= Ae RT
k2
1
k1 ( − Ea1 + 2Ea1 )
⇒ = Ae RT
k2
k1
= AeEa1 / RT
k2
⇒ k1 = Ak 2eEa1 / RT
Hence, (1) is the correct answer.
24
3. D C124402
 −dN 
 dt  ∝ N
 
2
 1
N = N°  
2
2
N  1
= 
N°  2 
n
1  1
= ⇒ 10 = 2n
10  2 
Activity log10 = n log2
1
⇒n= = 3.32
0.301
t = n × t112
= 3.32 × 30 = 99.6 days
Hence, ( 4 ) is correct.
4. C C120603
C
NH2
H2N
0.01gm
0.01
Moles taken =
60
Moles = 0.000167
0.000167
Molality of solution = = 5.55 × 10 −4
0.3
5. D C120507
There is one mistake in question paper

Assuming concentration of solution is 0.2 M instead of 0.02 M. Since resistance of 0.2 M is
520Ω
25
R = 100Ω
1ℓ
k=
R  a 
1 ℓ
1.29 =  
100  a 
ℓ −1
 a  = 129 m
 
R = 520Ω,C = 0.2M
1ℓ 1
K=   = (129 ) Ω −1m −1
R  a  520
µ = K × Vin cm3
1 1000
= × 129 × × 10 −6 m 3
520 0.2
129 1000
= × × 10−6
520 0.2
= 1.24 × 10 −3
= 12.4 × 10 −4
6. D C120504
Agl ( s ) + e − Ag ( s ) + I − ; E ° = −0.152
→ Ag + + e − ;
Ag ( s )  E ° = −0.8
→ Ag + + I − ;
Agl ( s )  E ° = −0952
0.059
°
Ecell = log K
n
0.059
−0.952 = log K sp
1
0.952
log K sp = − = −16.135
0.059
7. C C120504
n
log K = Ecell
°
×
0.059
2
log K = 0.295 × = 10
0.059
⇒ K c = 1× 1010
8. C C120706
* 2AI2O3 +3C 
→ 4AI+3CO2
* Na3 AIF6 or CaF2 is mixed with purified AI2O3 tolower themelting point and brings
* Oxygen librated at anode reacts with carbon anode to librate CO and CO2.
26
9. B C120104
L→ M charge transfer transition
10. A C120107
d4 in strong field, so unpaired electrons = 2
11. D C120104
Zn2 [Fe(CN)6] is bluish white and rest are yellow colored compounds.
12. C C120602
Solubility ∝ pressure
S2 p2 S 
= ⇒ p2 = p1  2 
S1 p1  S1 
 0.10 
p2 = 1.0  −3 
= 7.62 bar
 13.12 × 10 
13. C C120604
14. B C122101
15. B C122109
16. C C121301
The adsorption of a gas is directly proportional to the pressure of the gas
17. D C123703
Lyophilic sols are reversible, not easily coagulated because it is self-stabilising.
18. C C123510
19. B C123606
20. B C123506
Specific conductance
Molar conductance =
Molarity
On dilution molarity decreases and molar conductance increases. Hence, specific
conductance decreases.
INTEGER TYPE
1. Atomic mass of Z decreases by 8 and atomic number decreases by 3 units. So new atomic
number is 66 which belongs to lanthanide series. So new group number = 3
2. It is [M(AA)2 Ab] type compound.

Geometrical isomer = 2(Cis & trans)
27
C is isomer is optically active & hence can be resolved into d & l. Trans isomer has plane of
symmetry ( meso isomer)
3. CFSE = ( −0.4 × t 2 g + 0.6 × eg)∆ 0

= ( −0.4 × 3 + 0.6 × 2)∆ 0
=0
4. 6
5.
E 0 = E0A/An+ + E0Bn+ /B
= 2.5 + 0.5 = 3V
Mathematics
1. D
Sol. Let A and B denote the events of occurrence of a total of 5 and 7 respectively.
Then, A = {(1,4 ) , ( 2,3 ) , ( 3,2 ) , ( 4,1)}
B = {(1,6 ) , ( 2,5 ) , ( 3,4 ) , ( 4,3 ) , ( 5,2 ) , ( 6,1)}
4 1
P(A) = =
36 9
n ( A ∪ B ) = 10
10 5
∴ Probability that the sum of numbers coming up is either 5 or 7 = = = P ( C ) (say).
36 18
13
Then P ( C' ) = probability that the sum of numbers coming up is neither 5 nor 7 = .
18
∴ Required probability
1 13 1 13 13 1
= + . + . . + .....to ∞
9 18 9 18 18 9
1
9 2
= =
13 5
1−
18
2. B
B B B BB B B BB B
Sol. l W l l W l l W l ....... l W l l W l
10!
n (S) =
( 7!)( 3!)
8!
n (E ) = 8 C3 = , because there are 8 places for black balls.
( 3!)( 5!)
8!
∴P (E ) =
( 3!)( 5!)
10!
( 7!)( 3!)
=
( 8!)( 7!) = 7.6 = 7
(10!)( 5!) 10.9 15
3. D
Sol. Clearly, x1 + x 2 + x 3 = 0
28
From R1 → R1 + R2 + R3 , we get
x1 + x 2 + x 3 x1 + x 2 + x 3 x1 + x 2 + x 3
x2 x3 x1 which is clearly zero, as all entries in the first row are
x3 x1 x2
zero.
4. A
Sol. All the elements below the main diagonal have to be necessarily zero.
Thus, minimum number of zero elements
= 1 + 2 + 3...... ( n − 1)
n ( n − 1)
=
2
5. D
a = a1iˆ + a2 ˆj + a3 kˆ
Let
∴ a ⋅ iˆ = 1 ⇒ a1 = 1
∴ a ⋅ 2iˆ + jˆ = 1 ⇒ 2a1 + a2 = 1
( )
⇒ a2 = 1 − 2
⇒ a2 = −1
a ⋅ (iˆ + ˆj + 3kˆ ) = 1
And
⇒ a1 + a2 + 3a3 = 1
⇒ 1 − 1 + 3a3 = 1
1
⇒ a3 =
3
1 1
∴ a = iˆ − ˆj + kˆ = 3iˆ − 3 ˆj + kˆ ( )
3 3
Hence, (D) is the correct answer.
6. A
a Y
Sol. Area = ∫ y dx
0
a
2
=∫
0
( a− x ) dx
O x
a
29
7. B
Sol. ( ) ( )
Let the rectangle be ABCD, with A ≡ ( t,0 ) ,B ≡ t,e − t ,C ≡ −t, e − t ,D ≡ ( − t,0 ) , where t ∈ R +
Y
y = ex y = e− x
C B
D O A
Area of rectangle
ABCD = 2t.e − t = f ( t ) (say)
df
Now,
dt
{( ) }
= 2 t −e− t + e− t = 2e− t (1 − t )
df df
Clearly, > 0, for t ∈ ( 0, 1) and < 0 for t ∈ (1, ∞ )
dt dt
Thus, t = 1 is the point of maxima for f ( t ) .
2
Thus, maximum area = f (1) = .
e
8. B
Sol. ( xy sin xy + cos xy ) y dx + ( xy sin xy − cos xy ) x dy = 0
⇒ xy .sin xy ( y dx + x dy ) + cos xy ( y dx − x dy ) = 0
dx dy
⇒ tan xy.d ( xy ) + − =0
x y
x
⇒ ln sec xy + ln = c'
y
⇒ x sec ( xy ) = cy
9. C
1
Sol. ( )
a× a×b = b
2
1
⇒ ( a.b ) a − ( a.a ) b = b
2
⇒ a.b = 0
−1
a.a = (which is not possible)
2
Thus information are inconsistent.
10. D
Sol. Direction ratio of segment AB are (2a, 2a, a)
 3a 
Mid – point of AB is  0,0, 
 2 
Required plane will be in the form
x.2a + y.2a + z.a = p
30
 3a 
It should pass through  0,0, 
 2 
2
3a
⇒ =p
2
Thus, equation of the plane is
3a
2x + 2y + z =
2
i.e. 4x + 4y + 2z = 3a
11. C
Sol. Centre and radius of given sphere are (–2, 1, 3) and 13 unit respectively.
Now, distance of centre of the sphere from the given plane
−24 + 4 + 9 − 327
= = 26 units.
122 + 42 + 32
∴ shortest distance = (26 – 13) = 13 units.
12. B
Sol. a+b =p
2 2
⇒ a+b = p
2
(
⇒ a+b . a+b = p )( )
2 2 2
⇒ a + b + 2a.b = p
Also, a − b = q
2 2
⇒ a−b = q
2
(
⇒ a −b . a−b = q)( )
2 2 2
⇒ a + b − 2a.b = q
thus 2 a + b( 2 2
)= p 2
+ q
2
13. A
Clearly, t can be any real number.
1 − tan2 θ
Let t = tan θ ⇒ x =
1 + tan2 θ
⇒ x = cos 2 θ
2 tan θ
And y= = sin 2 θ
1 + tan2 θ
∴ x2 + y 2 = 1
Thus, required area = π sq units
Hence, (a) is the correct answer.
14. B
15. D
The given curve is symmetrical about x-axis and meet it at (2a, 0). The line x = 0 i.e. Y-axis is
an asymptote.
31
X’ X
O A(a, 0)
Y’
2a 2a 2a − x
∴ Required area, A = 2 ∫ y dx = 2 ∫ 2a dx
0 0 x
Put x = 2a sin θ ⇒ dx = 4a sin θ cos θ d θ
2
π /2
∴ A = 16a2 ∫ cos2 θ d θ = 4 πa2 sq units
0
16. C
1 1
We have, dx + dy = 0
x y
On integrating both sides, we get
log x + log y = logC
⇒ xy = C
17. D
dy
We have, + 1 = e x+y
dx
dy dv
Let x + y = v. Then, 1 + =
dx dx
dy
∴ + 1 = e x+y
dx
dv
∴ = ev
dx
⇒ e −v dv = dx
⇒ ∫ e dv = ∫ e
−v v
⇒ −e − v = x + C
⇒ −e − ( x + y ) = x + C
⇒ ( x + C ) e x+y + 1 = 0
18. B
We have,
dy
+ (tan x )y = sec x
dx
IF = e ∫
tan x dx
∴ = elogsec x = sec x
19. B
2 2
We have, (a + b ).(a − b ) = 2 a − b
32
⇒ (a + b ).(a − b ) = 0 [∴ a = b ]
⇒ (a + b ) ⊥ (a − b )
20. D
The vector equation of the line BC is
r = b + λ(c − b )
A(a)
C(c)
(b)B M a
Clearly, BM = Projection of BA on BC
BA ⋅ BC
=
BC
(a − b ) ⋅ (c − b )
=
(c − b )
∴Required distance = AM = AB 2 − BM 2
2
 (a − b ) ⋅ (c − b ) 
2
= b−a − 
 (c − b ) 
Hence, (D) is the correct answer.
Integer Type
1.
Sol. Since, bounded figure ABCD is a rectangle.
Y
y= x −2
B
X’ X
–1 0
–2 1 2
–1
D –1 y = 1− x − 1
–2
C
Y’
AB = 1 + 1 = 2
BC = 4 + 4 = 2 2
33
∴ Bounded area = ( 2 )( 2 2 ) = 4 sq. Units

2. Given planes are
x − cy − bz = 0 ...(i)
cx − y + az = 0 ...(ii)
And bx + ay − z = 0...(iii)
Equation of plane passing through the line of intersection of planes (i) and (ii) may be taken
as
( x − cy − bz ) + λ(cx − y + bz ) = 0
Or (1 + λc )x − (c + λ )y + (aλ − b )z = 0 ...(iv)
Now, planes (iii) and (iv) are same.
1 + λc −(c + λ )
∴ = = b − aλ
b a
− ( a + bc )
⇒ λ=
ac + b
And λ=−
( ab + c )
1 + a2
a + bc ab + c
∴ =
ac + b 1 + a2
⇒ a − a3 + bc − a2 bc = a2 bc + ac 2 + ab2 + be
⇒ a(2abc + c 2 + b2 + a2 − 1) = 0
⇒ a2 + b2 + c 2 + 2abc = 1
dy dz
3. Let y = sin2 x and z = cos2 x ⇒ = sin2x and = − sin 2x
dx dx
dy
∴ = −1
dx
4. Let X denotes the number of aces.

4 1
Probability of selecting aces, = p=
52 13
1 12
Probability of not selecting aces, q = 1 − =
13 13
 1   12  24
P ( X = 1) = 2 ×   ×   =
 13   13  169
2 0
 1   12  1
P( X = 2 ) =   ×   =
 13   13  169
24 2 2
Mean = ∑ Pi X i = + =
169 169 13
5. Here, xf '( x ) = 1 + x 2 f 2 ( x ) − f ( x )
xf '( x ) + f ( x )
⇒ =1
1 + x2f 2 (x )
34
Integrating both sides

( x f '( x ) + f ( x ))dx
∫ 1 + ( x f ( x ))2 = x + C
π 4
⇒ tan−1 ( xf ( x ) = x + C, as f   =
4 π
π
⇒ tan−1 1 = + C
4
⇒ C =0
∴ xf ( x ) = tan x
tan x
⇒ f (x) =
x
tan x
And lim f ( x ) = lim =1
x →0 x →0 x

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FIITJEE – JEE (Main)

Physics, Chemistry & Mathematics

Time Allotted: 3 Hours Maximum Marks: 300

B. Filling of OMR Sheet:

C. Marking Scheme for All Two Parts:

Name of the Candidate :_______________________________________________

Batch :_______________________ Date of Examination :____________________

Enrolment Number :___________________________________________________

(A) 1.8 î (B) 3 î (C) 3.6 î (D) 5 î

Space for rough work

πR2 πR2 πR2 πR2

(A) 35° (B) 42° (C) 40° (D) 38°

Space for rough work

sin α1 sin α 2 cos α1 cos α 2

Part – C (Integer Type)

3. In the figure the refractive index of the medium in which 10 cm

Thin slab of Thin slab of

Initial Concentration [A] Initial Concentration [B] Initial rate of formation of C

4. Resistance of a conductivity cell with a solution of an electrolyte of concentration 0.1M is

Space for rough work

5. Given the data at 25°C,

7. The color of KMnO4 is due to:

10. The value of Henry’s constant KH is is ________.

Space for rough work

11. In a parallel reaction at 23°C

Ration of concentration of the product ([B] : [C]) is

13. For the half-cell,

(A) 1.36 V (B) 1.30 V (C) 1.42 V (D) 1.20 V

14. Conductivity (k) of 0.01 NaCl solution is

15. Which is the strongest field ligand :

Space for rough work

22. Which of the following solution is isotonic with 0.4 M CaCl2?

20. Choose the incorrect statement:

Part – C (Integer Type)

2. Total number of isomers having formula [Co(en)2 (NH3 )Cl]2+ are :

3. Calculate CFSE value for d5 high spin octahedral.

5. E 0 (in volt) of cell A + B + n  0 0

Space for rough work

Part–A: Only One Option Correct Type

5. Ifa ⋅ iˆ = a ⋅ (2iˆ + ˆj ) = a ⋅ (iˆ + ˆj + 3kˆ ) = 1, then a is equal to

8. General solution of ( xy sin xy + cos xy ) y dx + ( xy sin xy − cos xy ) x dy = 0 , is equal to

between a and b is equal to:

12. If a + b = p and a − b = q , then

Space for rough work

(A) (a + b ) is parallel to ( a − b ) (B) (a + b ) is perpendicular to ( a − b )

(C) b −a (D) None of the above

Part – C (Integer Type)

FIITJEE COMMON TEST

1 1 P120609 1 3 C122104 1 4 M121006

Hind and Solution

There is one mistake in question paper

d4 in strong field, so unpaired electrons = 2

The adsorption of a gas is directly proportional to the pressure of the gas

Lyophilic sols are reversible, not easily coagulated because it is self-stabilising.

2. It is [M(AA)2 Ab] type compound.

3. CFSE = ( −0.4 × t 2 g + 0.6 × eg)∆ 0

∴ Bounded area = ( 2 )( 2 2 ) = 4 sq. Units

4. Let X denotes the number of aces.

Integrating both sides

Batch :___ Date of Examination :