Fiitjee - Jee (Main) : Physics, Chemistry Mathematics

FIITJEE – JEE (Main)
Physics, Chemistry & Mathematics

BATCHES –CTY 2123 A LOT(Phase -2)
QP Code:00000
Time Allotted: 3 Hours Maximum Marks: 300
▪ Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
▪ You are not allowed to leave the Examination Hall before the end of the test.
Important Instructions
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR
sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. Each Section is further divided into Two Parts: Part-A & B in the OMR.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be provided
for rough work.
6. No candidate is allowed to carry any textual material, printed or written, bits of papers, clip boards, log
tables, slide rule, calculator, cellular phones, pagers and electronic devices ext. except the Admit Card
inside the examination hall / room.
B. Filling of OMR Sheet:

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR
sheet.
2. On the OMR sheet, darken the appropriate bubble with Blue/Black Ball Point Pen for each
character of your Enrolment No. and write in ink your Name, Test Centre and other details at the
designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
4. Do not fold or make any stray marks on the Answer Sheet.
C. Marking Scheme for All Two Parts:

(i) Part-A (01-20) – Contains Twenty (20) multiple choice objective questions which have four (4) options
each and only one correct option. Each question carries +4 marks which will be awarded for every correct
answer and -1 mark will be deducted for every incorrect answer.
(ii) Part-B (01-05) contains five (05) Numerical based questions, the answer of which maybe positive or negative
numbers or decimals (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) and each question carries +4 marks for correct
answer and there will be no negative marking.
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Batch :_______________________ Date of Examination :____________________
Enrolment Number :___________________________________________________
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Two Year CRP (2123)-(A-LOT) PH-II-(PCM) JEE MAIN
2
Section – I Physics
PART – A
Straight Objective Type
This part contains 20 multiple choice questions. Each question has 4 choices (A), (B), (C) and
(D), out of which ONLY ONE is correct.
1. For the same total mass, which of the following will have largest moment of inertia about an axis
passing through the centre of mass and perpendicular to the plane of the body?
(A) Disc of radius a (B) ring of radius a
(C) Square lamina of side 2a (D) four rods forming a square of side
2. An orbiting satellite will escape if:

(A) Its speed is increased by 41%
(B) Its speed in the orbit is made ( )
1.5 limes of its initial value
(C) Its kinetic energy is tripled
(D) It stops moving in the orbit
3. Two particles of masses m1 and m2 in projectile motion have velocities v1 and v 2 respectively at
time t = 0. They collide at time t0. Their velocities become v 1' and v '2 at time 2t0 while still moving in
air. The value of | (m1v1' + m2 v'2 ) − (m1v1 + m2 v 2 ) | is

(A) Zero (B) [m1 + m2 ]gt0
1
(C) 2(m1 + m2 )gt0 (D) (m1 + m2 )gt 0
2
4. Choose the correct alternative regarding pure rolling of a solid sphere on v/R
horizontal surface.
Upper half
(A) KE of upper half portion of sphere is more than that of lower half as
shown. Lower half
(B) KE of upper half portion of sphere is less than that of lower half as
shown
(C) KE of any two half portions of sphere are equal.
(D) Can’t be determined
5. Two particles each of mass M, are connected by a rigid rod of L

negligible mass and length L. The system is lying on a horizontal M M
frictionless surface. An impulse Mv, perpendicular to the rod, is
Mv
given at one end of the rod as shown in the figure. The angular
velocity acquired by the rod is
(A) 4v/L (B) 2v/L
(C) v/L (D) v/4L
6. Two blocks of masses 10 kg and 4 kg and are connected by a spring of negligible mass and placed on a
frictionless horizontal surface. An impulse gives a horizontal velocity of 14 m/s to the heavier block
towards the lighter block. The velocity of the centre of mass of the two block system is:
(A) 30 m/s (B) 20 m/s
(C) 10 m/s (D) 5 m/s

3
7. A uniform ladder of length 5 m is placed against the smooth wall as shown

in the figure. If coefficient of friction for the ground is , what is the
minimum value of  for it not to slip? 5m 4m
(A) =1/2 (B) =1/4
(C) =1/3 (D) 3/8 3m
k
8. The gravitational field due to a mass distribution is f = in the x-direction where k is a constant taking
x3
the gravitational potential to be zero at infinity. The value of potential at the distance X is:
k k
(A) (B)
x 2x
k k
(C) 2 (D)
x 2x 2
9. A ball of mass M collides elastically with a identical ball at rest y

A
as shown in the figure. Initially velocity of ball is u m/s. After
collision. M
u
(A) Speed of ball B is u cos  
x
(B) Velocity of ball A is usin  cos ˆi + usin2 ˆj
(C) Speed of ball A is u cos  sin  B
(D) Velocity of ball B is u cos  sin  ˆi + 4cos2  ˆj M
10. Two particles are executing SHM in a straight line. Amplitude A and time period T of both the particles
−A
are equal. At time t = 0, one particle is at displacement x 1 = +A and the other at x 2 = and they are
2
approaching towards each other. The time they cross each other is:
(A) T/3 (B) T/4
(C) 5T/6 (D) T/6
11. Two masses M and m are suspended together by a massless spring of force constant k. When the
masses are in equilibrium, M is removed without disturbing the system. The amplitude of oscillation is:
Mg mg
(A) (B)
k k
(M + m ) g (M − m ) g
(C) (D)
k k
12. When two simple harmonic motions of same periods, same amplitude, having phase difference of 3/2,
and at right angles to each other are super imposed, the resultant wave form is a :
(A) circle (B) parabola
(C) ellipse (D) None of these
13. A uniform rod of mass M is hinged at its centre of mass so that it can rotate in
a vertical plane. Two springs each of stiffness K are connected at its ends, as
L, M
shown in the figure. The time period of small oscillations is:
Hinge
M M
(A) 2 (B) 2
6K 3K
M M
(C) 2 (D) 2
2K K

4
14. A light particle moving horizontally with a speed of 12 m/s strikes a very 10 m/s
heavy block moving in the same direction at 10 m/s. The collision is one- 12 m/s
dimensional and elastic. If the speed of the block does not change after the
collision, the particle will:
(A) Move at 2 m/s in its original direction
(B) Move at 8 m/s in its original direction
(C) Move at 8 m/s opposite to its original direction
(D) Move at 12 m/s opposite to its original direction
15. A particle is moving with constant velocity uiˆ + ˆj. Torque on the particle, about origin, when the
particle is at (a, b) is:
(A) uaiˆ + vbjˆ (B) ubiˆ + vajˆ
(C) (ub + va)kˆ (D) 0
16. A ring of mass M and radius R is released on an inclined plane as shown. If

the friction is sufficient then:
gsin 
(A) Acceleration of the ring =
2
(B) Acceleration of the ring = g cos  
gcos 
(C) Acceleration of the ring =
2
(D) None of these
17. A cubical blocks of mass M and edge ‘a’ slides down a rough inclined plane of inclination  (with
horizontal) with a uniform velocity. The torque of the friction force on the block about its centre of
mass has a magnitude:
(A) zero (B) Mga
a
(C) Mg sin  (D) None of these
2
18. What is the change in potential energy in upturning a thin

hemispherical bowl as shown in the figure? The mass of the bowl is M
and the radius of the bowl is R.
(A) mgh (B) MgR/2
3
(C) MgR (D) zero
2
19. A uniform circular disc has radius R. A square portion of diagonal R is cut from y
it. The centre of mass of the remaining portion (from the centre) is at :
R −R
(A) (B)
−2 2 − 2 R
x
R −R
(C) (D)
4 − 2 4 − 2

5
20. A solid sphere is rolling with slipping on a ground with the =2v/R,  = 2a/R
velocities and accelerations as shown. Acceleration of point P will v
a
have O
P
(A) only x-component (B) only y-component
(C) both x and y components (D) zero
SECTION – B
(Numerical Answer Type)
This section contains 05 questions. The answer to each question is a NUMERICAL VALUE. For each
question, enter the correct numerical value (in decimal notation, truncated/rounded‐off to the second decimal
place; e.g. XXXXX.XX).
1. If the period of revolution of an artificial satellite just above the earth’s surface is T and the density of
3
earth is . Then T2 is a universal constant whose value is n ( ). Then find the value of n
2G
2. A smooth sphere of mass 1 kg is moving on a horizontal plane with a velocity (in m/s) 3iˆ + ˆj . It ( )
1
collides with a vertical wall which is parallel to the vector ĵ. If e = then the magnitude impulse (J)
2
that acts on the sphere is (in kg-m/s) :
3. A physical pendulum has time period of 4 sec. If the density of the material used to make the
physical pendulum is doubled and everything else remains the same, the time period of the
pendulum will be (in sec).
4. How many time the kinetic energy should be increased of a satellite orbiting around the earth so
that it can escape the gravitational field of the earth.
5. The time period of a simple harmonic oscillator is 2 seconds. What is the time period of variation of
its kinetic energy (in sec) .
space for rough work

6
Section – II Chemistry
PART – B
This part contains 20 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D),
out of which ONLY ONE is correct.
1. A weak acid HX has the dissociation constant 1 × 10–5 M. It forms a salt NaX on reaction with alkali.
The degree of hydrolysis of 0.1 M solution of NaX is
(A) 0.0001% (B) 0.01%
(C) 0.1% (D) 0.15%
2. The correct order of acidic strength of the following is:

OH OH COOH COOH
Cl CH3
I II III IV
(A) III>IV>II>I (B) IV>III>I>III
(C) III>II>I>IV (D) II>III>IV>I
3. Which of the following contains nucleophiles only?

(A) PH3 , ROH , CH 2 = CH 2 (B) SnF4 , BeF2 , NH 3
(C) Cr 3+ , NH 2− , H 2O (D) CCl2 , I − , H +
4. Which of the following is least stable?

(A) Me − O − CH 2− (B) -
H2C CH2
-
CH2
(C) PhCH 2− (D)
OMe
5. The most stable carbocation is:
PhCH 2+
+
(A) (B) Me CH2
Me Me
+ +
(C) CH2 (D) CH2
Me Me Me

7
6. Which of the following are diasteromers?

Me Me
H Br Br H
(I) H Br (II) H Br
COOH COOH
COOH COOH
H Br Br H
(III) (IV)
H Br H Br
Me Me
(A) ( I ) and ( III ) (B) ( II ) and ( IV )
(C) ( I ) and ( II ) (D) none of these
7. Which among the following is likely to show geometrical isomerism?

(A) CH3CH = CH 2 (B) CH3CH = N − OH
(C) CH 3C ( Cl ) = C ( CH 3 )2 (D) CH2 = CH − CH = CCl2
8. M 2SO4 ( M + is a monovalent metal ion) has a K sp of 3.2 10−5 at 298K . The maximum
concentration of SO42− ion that could be attained in a saturated solution of this solid at 298K is
(A) 3 10−3 M (B) 7 10−2 M
(C) 2.89 10−4 M (D) 2 10−2 M
9. A substance undergoes first order decomposition and follows two parallel first order reactions as
B
k1
A , k1 = 1.26  10 −4 s−1 and k 2 = 3.8  10 −5 s−1

k2
C
The percentage distribution of B and C are
(A) 80% B and 20% C (B) 76.83% B and 23.17% C
(C) 90% B and 10% C (D) 60% B and 40% C
10. What is the molarity of F- ions a saturated solution of BaF2? (Ksp=1.010−6)

(A) 1.010−2 (B) 1.010−3
(C) 1.2610−2 (D) 6.310−3
11. For the reaction

2A + B 3C at 298K , Kc = 40
A 4L vessel contains 2, 1 and 4 mol of A, B and C, respectively. The reaction at the same temperature.
(A) Must proceed in forward direciton (B) Must proceed in backward direction
(C) Must be in equilibrium (D) Cannot be predicate.

8
12. Which one of the following is true of any diprotic acid, H 2 X ?

(A) K a2  K a1 (B) K a1  K a2
1
(C) K a2 = (D) K a2 = K a1
K a1
13. The vapour density of PCl5 is 104.25 but when heated to 230C its vapour density is reduced to 62.
the degree of dissociation of PCl5 at this temperature will be
(A) 6.8% (B) 68%
(C) 46% (D) 64%
14. Consider a gaseous reaction, the rate of which is given by k[A] [B], the volume of the reaction vessel
containing these gases is suddenly reduced to 1/4th of the initial volume. The rate of reaction relative
to the original rate would be
(A) 16/1 (B) 1/16
(C) 8/1 (D) 1/8
15. For the reaction

PCl5(g) PCl3(g) + Cl2(g), the forward reaction at constant temperature is favored by
(1) Introducing an inert gas at constant volume
(2) Introducing chlorine gas at constant volume
(3) Introducing an inert gas at constant pressure
(4) Introducing PCl5 at constant volume
(5) Introducing PCl3 gas at constant volume
(A) 1, 2 (B) 4, 5
(C) 3, 4 (D) 3, 4, 5
16. A solution is 0.09 M in HCl and 0.09 M in CH2ClCOOH. The pH of the solution is 1. What is the
Ka for CH2ClCOOH?
(A) 1.8  10−5 (B) 1.25  10−2
(C) 3.6  10−3 (D) 2.8  10−4
17. Which of the following is NOT true?

4 b
3 N
3
1 2 a
1 2 N N
N
H H
Pyridine ( I ) Pyrrol ( II ) Imidazol ( III )

(A) (I) and (III) are modest Bronsted bases whereas (II) is not.
(B) In (III) N a is more basic than N b .
(C) When (II) is protonated in the presence of a strong acid, protonation occurs at C – 2.
(D) All the nitrogen present in (I), (II), and (III) is sp 2 hybridised.
18. Among the following statements which is true?

(A) K w is independent of temperature (B) At 65°C, pH of water is not equal to 7
(C) pK w increases with temperature (D) pH + pOH = 14, at all temperatures

9
19. Which of the following show stable or major form of tautomerism?
O O O
(A) (B)
O
O
(C) (D) All of these
20. A catalyst lowers the activation energy of a reaction from 20 kJmole–1 to 10 kJmole–1. The
temperature at which the uncatalysed reaction will have the same rate as that of the catalysed at
27C is
(A) –123C (B) 327C
(C) - 327C (D) + 123C
SECTION – B
1. The number of meso from of the given compound is:

H3C CH CH CH CH3
OH OH OH
2. The pH of a solution containing 0.4 M HCO3− and 0.2 M CO32− is:

(Ka1(H2CO3)2=410−7, Ka2 (HCO3−) = 410−11) (log2 = 0.30)
3. A mixture of NH3(g) and N2H4(g) is placed in a sealed container at 27oC, 0.5 atm. After complete
decomposition of NH3 and N2H4 at 927oC according to following reaction,
2NH3 → N2 + 3H2 , N2H4 → N2 + 2H2
The total pressure reached to 4.5 atm. The percentage of NH3 (by mole) in the original mixture
is_____
U ⎯⎯→82 Pb , the sum of number of - and - particle released is__

235 207
4. In the nuclear reaction, 92
5. A reaction takes plane in three steps. The rate constants are k1 , k2 , and k3 . The overall rate constant
k1k3
k= . If E1 , E2 and E3 (energy of activation) are 60, 30, and 10kJ, respectively, the overall
k2
energy of activation (in kJ) is___.

10
Section – III Mathematics

PART – C
This part contains 20 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D),
out of which ONLY ONE is correct.
1. Two parabola y2=16(x-k) and x2=16(y−l) always touch each other (where k, l are variable parameters).
Their point of contact lies on:
(A) a straight line (B) a parabola
(C) a circle (D) none of these
2. If the line y = x + k is a normal to the parabola y2=4x, then k can have the value:
(A) 2 2 (B) 4
(C) −3 (D) 3

3. Double ordinate AB of the parabola y2=4ax subtends an angle at the vertex of the parabola, then
2
tangents drawn to parabola at A and B will intersect at:
(A) (−4a, 0) (B) (−2a, 0)
(C) (−3a, 0) (D) none of these
4. Mutually perpendicular tangents TA and TB are drawn to y2=4ax, minimum length of AB is equal to:
(A) 4a (B) 6a
(C) 8a (D) 2a
5. Equation of parabola having it’s focus at S(2,0) and one extremity of it’s latus rectum as (2,2) is:
(A) y2=4(3−x) (B) y2=4(1−x)
2
(C) y =8(3−x) (D) none of these
6. If x= (2 5 )(5 2 ), then log10 x = ( A − B )(log10 2) + B . Then value of A+B=

(A) 7 (B) 9
(C) 11 (D) 13
7. If log 2 2 (32 5 4) =  +  where  is an integer and β  0,1) then  is

(A) 3 (B) 4
(C) 5 (D) 6
4 z z
8. If a complex number z satisfies | z |2 + − 2 + − 16 = 0 , then the maximum value of |z| is
|z|2
z z 
(A) 6 + 1 (B) 4
(C) 2 + 6 (D) 6
9. If z2 + (p + iq)z + r + is = 0 where p, q, r, s are non-zero, has real roots, then

(A) pqs = s2 + q2r (B) pqr = r2 + p2s
(C) prs = q2 + r2p (D) prs = p2 + s2q

11
10. If z1 , z2 , z3 are three complex numbers and a, b, c are three positive real numbers such that
a b c a2 b2 c2
= = then + + is
z2 − z3 z3 − z1 z1 − z2 z2 − z3 z3 − z1 z1 − z2
(A) 3 (B) 0
(C) abc (D) a + b + c
11. Number of imaginary complex number satisfying the equation, z2 = z.21−|z| is

(A) 0 (B) 1
(C) 2 (D) 3
   2 
12. Let z  C and if A = z,arg(z) =  and B = z,arg(z − 3 − 3i) =  . Then n(A  B) is equal to
 4  3 
(A) 1 (B) 2
(C) 3 (D) 0

2 
i

1
13. If k = and Si = , then S1 + S2 is equal to
(36k )
2 i
k =1 6 k =1
2
−1
2
1 2
1
(A) − (B) +
9 2 12 2
2 1 2 1
(C) + (D) −
15 2 18 2
14. Let a series be defined such that its rth term t r is given by tr = ( r − 1) Sr −1 for r > 1, where S r is sum
of its first r terms, also t1  0 . Then for n  1, ( n  N )
(A) Sn = ( n + 1)!t1 (B) ( n + 1) tn+1 + Sn = nSn+1
(C) ntn+1 + Sn = ( n + 1) Sn+1 (D) ( n + 2) tn+1 + Sn = ( n + 1) Sn+1
15. The equation x2+ax−a2−1=0 will have roots of opposite signs, if:
(A) a(−, ) (B) a[−1,1]
(C) a(,−1)(1, ) (D) none of these
16. The sum of 1st n terms of a A.P., where 1st term is an integer and common difference is 2, is equal to
270. If n > 1, then number of possible values of n is
(A) 11 (B) 12
(C) 15 (D) 16
9 9
17. If  ( xi − 5) = 9 and  ( xi − 5)2 = 45 , then the standard of the 9 items x1, x2 ,.....x9 is:
i =1 i =1
(A) 3 (B) 9
(C) 4 (D) 2
18. The values of a for which both roots of the equation (1−a2)x2+2ax−1=0 lie between 0 and 1 are given
by:
(A) a > 2 (B) 1 < a < 2
(C) − < a <  (D) none of these

12
19. If  ,   C are the roots, of the equation x2 − x + 1 = 0 then  101 +  107 is equal to:
(A) 2 (B) -1
(C) 0 (D) 1
20. If a, b, c are odd integers and ax2+bx+c=0 has real roots, then:
(A) both roots are rational (B) both roots are irrational
(C) both roots are positive (D) roots are of opposite signs
SECTION – B
1 1 2 3  1
1. If  + 4 + 4 + ............ is equal to , then k is equal to ______
3 1 + 4 2 + 4 3 + 4
4
 k
2. The normal to the parabola y 2 = 8 x at the point ( 2, 4 ) meets it again at (18, − 12 ) . If length of
normal chord is  , then the value of  2 must be____
3. If  is the imaginary cube root of unity, then the number of pairs of integers (a, b) such that
| a + b |= 1 is _____
4. Let 1, w and w2 be the cube roots of unity. The least possible degree of a polynomial, with real
coefficients, having 2w2, 3 + 4w, 3 + 4w2, and 5 – w – w2 as roots is _____
4 1
5. Value of 5
log1/5 (1/2)
+ log + log1/2
2
7+ 3 10 + 2 21
space for rough work

13
FIITJEE COMMON TEST

BATCHES: Two Year CRP (2123) (A-LOT)
PHYSICS, CHEMISTRY & MATHEMATICS
JEE MAIN-PHASE-II Paper Code
ANSWER KEY SET-A
PART – A PART – B PART – C

(PHYSICS) (CHEMISTRY) (MATHEMATICS)
1. D P110701 1. B C110503 1. D M110901
2. A P110905 2. A C111302 2. C M110915
3. C P110605 3. A C111302 3. A M110901
4. A P110710 4. A C111303 4. A M110912
5. C P110709 5. B C111301 5. D M110902
6. C P110605 6. C C111404 6. A M110201
7. D P110704 7. B C111403 7. A M110201
8. D P110903 8. D C110501 8. C M110302
9. A P110606 9. B C110606 9. A M110305
10. D P111102 10. C C110501 10. B M110303
11. A P111104 11. A C110401 11. C M110307
12. A P111102 12. B C110506 12. D M110303
13. A P111104 13. B C110401 13. D M110504
14. B P110605 14. A C110601 14. D M110504
15. D P110704 15. C C110403 15. A M110101
16. A P110711 16. B C110502 16. C M110501
17. C P110704 17. B C111302 17. D M110102
18. D P110601 18. B C110502 18. A M110103
19. D P110603 19. B C111402 19. D M110106
20. C P110710 20. B C110404 20. B M110101
1. 2 1. 2 1. 8
2. 4.50 2. 10.10 2. 512
3. 4 3. 75 3. 6
4. 2 4. 11 4. 5
5. 1 5. 40 5. 6

14
FIITJEE COMMON TEST

BATCHES: Two Year CRP (2123) (B-LOT)
JEE MAIN-PHASE-II
HINTS & SOLUTIONS
PART-A : PHYSICS
1. D
 M ( 2a )2 M 
Sol. Moment of inertia of four rod forming a square of side 2a   = 4   + a2 
 4 12 4 

4 4
 =  4Ma2 = Ma2
3 3
2. A
3. C
3. C
4. A
4. A
Sol. Particles in upper half will have more speed than particles in lower half.
5. C
6. C
6. C
m1v1 + m2v 2 10  14 + 4  0
Sol. v cm = = = 10 m/s
m1 + m2 14
7. D
Sol. f = N' N’
N = mg
mg cos  = f sin  mg
2

f = minN
N
8. D
9. A
9. A
10. D
11. A
12. A
13. A
14. B
14. B
12 − 10
Sol. e=  10 − v = 2  v = 8 m/s
10 − V
15. D
15. D
Sol. V=constant a = 0  Fnet = 0
 = r F   = 0
15
16. A
17. C
17. C
18. D
Sol. Position of COM remains same.
19. D
20. C
Sol. Point C will have following acceleration. R2=4v2/R
p a
2a=R
PART - B
1. 2
2. 4.50
3. 4
4. 2
5. 1
PART-B : CHEMISTRY
1. B
Sol. NaX ⎯⎯→Na+ + X−
X− + H2O HX + OH−
t=0 1.0 excess 0 0
1−   
t = eq. 0.1(1 −  ) 0.1 0.1
[HX] [OH− ]
Kh =
[X− ]
[HX] [H+ ][OH− ]
= 
[H+ ] [X− ] 1
K w 0.1  0.1
= = 0.1 2 1 −   1 as 1  for weak acid
Ka 0.1(1 − )
10−14
 = 0.1 2
10−5
  = 1 10−4 = 0.01%
2. A
3. A
Sol. H = 2H1 + 2H20 − H30
4. A
5. B
6. C
7. B
8. D
9. B
16
K1
%B =  100
K1 + K 2
Sol.
K2
%C =  100
K1 + K 2
10. C
1/3
 10−6 
Sol. Ksp = 4s , S = 
3
 = 0.63  10−2
 4 
Molarity of F− = 2S = 20.6310−2 = 1.2610−2
11. A
12. B
13. B
14. A
n  nB 
k A  
=  1  v1 
r1 v
Sol.
r2 n  nB 
k A  
 v2  v 2 
15. C
16. B
Sol. CH2ClCOOH CH2ClCOO− + H+
0.09
(0.09 – x) x (0.09 + x)
+ −1
[H ] in the solution = 10
0.09 + x = 10−1
x = 0.01
0.01 0.01
K a for CH2ClCOOH = = 1.25  10−2
(0.09 − 0.01)
17. B
18. B
Sol. pH of water=7 at 25°C. With increase in temperature Kw value increases (i.e. pKw decreases)
and pH of water becomes less than 7
19. B
20. B
Ea E'a
Sol. =
T1 T2
1. 6
2. 10.10
CO32− 
Sol. pH = pKa2 + log
HCO3− 
 0.2 
= (11−log 4) + log   = 10.1
 0.4 
3. 75
Sol. Let, NH3 = x mole
17
N2H4 = y mole
2NH3 → N2 + 3H2
x 0 0
x 3x
0
2 2
N2H4 → N2 + 2H2
y 0 0
0 y 2y
Initial total mole = x + y
Final total mole = 2x + 3y
2x + 3y 4.5
=
x+y (0.5)  (4)
 x = 3y  %x = 75
4. 11
Sol. C
Sol. 92 →82 Pb207 + 72 He4 + 4−1
U235 ⎯⎯
5. 40
PART-C: MATHEMATICS
1. D M110901
2. C M110915
3. A M110901
4. A M110912
5. D M110902
6. A M110201
7. A M110201
8. C M110302
Sol. Let z = r(cos  + isin )
4
Then the equation r 2 + − 2.2cos2 - 16 = 0
r2
r 4 − 4r 2 (cos2 + 4) + 4 = 0
By solving we get
For maximum value of r, cos2 = 1
r = 2+ 6
9. A M110305
Putting z = x + iy, we get
(x + iy)2 + (p + iq)(x + iy) + r + is = 0
Solving for Real and imaginary part we get x = - s/q
s2 ps
Now putting the value we get − +r = 0
q2 q
 pqs = s2 + rq2
10. B M110303
a a2
= k ; z2 − z3 = 2
2
Sol.
z2 − z3 k
( z2 − z3 ) ( z2 − z3 ) =
a2
k2

18
a2
z2 − z3
(
= k 2 z 2 − z3 )
11. C M110307
Sol. z2 = z.21−|z|
 z3 =| z2 | 21−|z|
By taking modulus both sides
z3 = 1
12. D M110303
13. D M110504
1    1 1 

Soln: S1 + S2 =   + 
2  k =1  ( 6k − 1)2 ( 6k + 1)2 
  
1 1 1 1
 2 ( S1 + S2 ) + 1 = 2 + 2 + 2 + 2 + ........ --------------- (1)
1 5 7 11
 2
1 1 1
Let  = = 2 + 2 + 2 + ....... ----------------- (2)
6 1 2 3
 1 1
= + + ....... ------------------ (3)
22 22 42
 1 1
= + + ....... ------------------ (4)
32 32 62
 1
2
= 2 + ....... ------------------ (5)
6 6
Now, (2) – { (4) – (5) + (3)} gives
2
= 2 ( S1 + S2 ) + 1
3
14. D M110504
Soln: tr +1 = rSr = r tr + Sr −1  = r 2 Sr −1 = r 2 ( r − 1) Sr −2
 tr +1 = r ( r !) t1 ( S1 = t1 )
 Sr = ( r !) t1
tr +1 + Sr = ( r + 1) Sr +1 − ( r + 1) tr +1
15. A M111106
16. C M110501
Soln: n ( a + n − 1) = 270 = 2  33  5
Hence, n take 15 values.
17. D M110102
2
45  9 
Sol: = − 
9 9
= 5 −1
=2
18. A M110103
19. D M110106
Sol: put x = −, − 2
 101 +  107

19
(
= − 101 + ( 2 )
107
)
= − ( 2 +  )
= − ( −1) = 1
20. B M110101
1. 00008.00 M110605

k 1   1 1  3
Sol. 
k =1 k + 4
4
=   − =
4 k =1  k ( k − 2 ) + 2 ( k + 2 ) k + 2  8
2. 00512.00 [M110904]
3. 00006.00 M110305
Sol. We have | a + b |= 1
 (a + b)(a + b) = 1  a2 − ab + b2 = 1
 (a − b)2 + ab = 1
4. 00005.00 M110305
Sol. If  = 2w 2 is a root then 2w has to be a root too. Minimum 5 roots, hence minimum degree → 5 .
5. 00006.00 M110201


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FIITJEE – JEE (Main)

Physics, Chemistry & Mathematics

Time Allotted: 3 Hours Maximum Marks: 300

B. Filling of OMR Sheet:

C. Marking Scheme for All Two Parts:

Name of the Candidate :_______________________________________________

Batch :_______________________ Date of Examination :____________________

Enrolment Number :___________________________________________________

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2. An orbiting satellite will escape if:

air. The value of | (m1v1' + m2 v'2 ) − (m1v1 + m2 v 2 ) | is

5. Two particles each of mass M, are connected by a rigid rod of L

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7. A uniform ladder of length 5 m is placed against the smooth wall as shown

9. A ball of mass M collides elastically with a identical ball at rest y

(D) Velocity of ball B is u cos  sin  ˆi + 4cos2  ˆj M

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16. A ring of mass M and radius R is released on an inclined plane as shown. If

18. What is the change in potential energy in upturning a thin

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space for rough work

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2. The correct order of acidic strength of the following is:

3. Which of the following contains nucleophiles only?

4. Which of the following is least stable?

(C) PhCH 2− (D)

5. The most stable carbocation is:

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6. Which of the following are diasteromers?

7. Which among the following is likely to show geometrical isomerism?

A , k1 = 1.26  10 −4 s−1 and k 2 = 3.8  10 −5 s−1

10. What is the molarity of F- ions a saturated solution of BaF2? (Ksp=1.010−6)

11. For the reaction

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12. Which one of the following is true of any diprotic acid, H 2 X ?

15. For the reaction

17. Which of the following is NOT true?

Pyridine ( I ) Pyrrol ( II ) Imidazol ( III )

18. Among the following statements which is true?

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19. Which of the following show stable or major form of tautomerism?

1. The number of meso from of the given compound is:

2. The pH of a solution containing 0.4 M HCO3− and 0.2 M CO32− is:

U ⎯⎯→82 Pb , the sum of number of - and - particle released is__

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Section – III Mathematics

6. If x= (2 5 )(5 2 ), then log10 x = ( A − B )(log10 2) + B . Then value of A+B=

7. If log 2 2 (32 5 4) =  +  where  is an integer and β  0,1) then  is

9. If z2 + (p + iq)z + r + is = 0 where p, q, r, s are non-zero, has real roots, then

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11. Number of imaginary complex number satisfying the equation, z2 = z.21−|z| is

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FIITJEE COMMON TEST

ANSWER KEY SET-A

PART – A PART – B PART – C

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