Hydro Carbon
Hydro Carbon
Hydro Carbon
Types of hydrocarbons
The classifications for hydrocarbons defined by IUPAC nomenclature of organic
chemistry are as follows:
Hydrocarbons can be gases (e.g. methane and propane), liquids (e.g. hexane and
benzene), waxes or low melting solids (e.g. paraffin wax and naphthalene) or
polymers (e.g. polyethylene, polypropylene and polystyrene).
General properties
Generally, with catenation comes the loss of the total amount of bonded
hydrocarbons and an increase in the amount of energy required for bond cleavage
due to strain exerted upon the molecule; in molecules such as cyclohexane, this is
referred to as ring strain, and occurs due to the "destabilized" spatial electron
configuration of the atom.
In simple chemistry, as per valence bond theory, the carbon atom must follow the
"4-hydrogen rule", which states that the maximum number of atoms available to
bond with carbon is equal to the number of electrons that are attracted into the
outer shell of carbon. In terms of shells, carbon consists of an incomplete outer
shell, which comprises 4 electrons, and thus has 4 electrons available for covalent
or dative bonding.
Some hydrocarbons also are abundant in the solar system. Lakes of liquid methane
and ethane have been found on Titan, Saturn's largest moon, confirmed by the
Cassini-Huygens Mission[12].
Number of
Alkane Alkene Alkyne Cycloalkane Alkadiene
carbon atoms
1 Methane — — — —
2 Ethane Ethene Ethyne — —
3 Propane Propene Propyne Cyclopropane Allene
Butane Cyclobutane
4 Butene Butyne Butadiene
Isobutane Methylcyclopropane
Pentane Cyclopentane
Pentadiene
5 Isopentane Pentene Pentyne Methylcyclobutane
Isoprene
Neopentane Ethylcyclopropane
Cyclohexane
Methylcyclopentane
6 Hexane Hexene Hexyne Hexadiene
Ethylcyclobutane
Propylcyclopropane
Cycloheptane
7 Heptane Heptene Heptyne Heptadiene
Methylcyclohexane
8 Octane Octene Octyne Cyclooctane Octadiene
9 Nonane Nonene Nonyne Cyclononane Nonadiene
10 Decane Decene Decyne Cyclodecane Decadiene
Usage
Hydrocarbons are one of the Earth's most important energy resources. The
predominant use of hydrocarbons is as a combustible fuel source. In their solid
form, hydrocarbons take the form of asphalt [13]
Methane [1C] and ethane [2C] are gaseous at ambient temperatures and cannot be
readily liquified by pressure alone. Propane [3C] is however easily liquified, and
exists in 'propane bottles' mostly as a liquid. Butane [4C] is so easily liquified that
it provides a safe, volatile fuel for small pocket lighters. Pentane [5C] is a clear
liquid at room temperature, commonly used in chemistry and industry as a
powerful nearly odorless solvent of waxes and high molecular weight organic
compounds, including greases. Hexane [6C] is also a widely used non-polar, non-
aromatic solvent, as well as a significant fraction of common gasoline.
The [6C] through [10C] alkanes, alkenes and isomeric cycloalkanes are the top
components of gasoline, naptha, jet fuel and specialized industrial solvent
mixtures. With the progressive addition of carbon units, the simple non-ring
structured hydrocarbons have higher viscosities, lubricating indices, boiling
points, solidification temperatures, and deeper color. At the opposite extreme from
[1C] methane lie the heavy tars that remain as the lowest fraction in a crude oil
refining retort. They are collected and widely utilized as roofing compounds,
pavement composition, wood preservatives (the creosote series) and as extremely
high viscosity sheer-resisting liquids.
Burning hydrocarbons
Hydrocarbons are currently the main source of the world’s electric energy and heat
sources (such as home heating) because of the energy produced when burnt. Often
this energy is used directly as heat such as in home heaters, which use either oil or
natural gas. The hydrocarbon is burnt and the heat is used to heat water, which is
then circulated. A similar principle is used to create electric energy in power
plants.
Common properties of hydrocarbons are the facts that they produce steam, carbon
dioxide and heat during combustion and that oxygen is required for combustion to
take place. The simplest hydrocarbon, methane, burns as follows:
Petroleum
Oil reserves in sedimentary rocks are the source of hydrocarbons for the energy,
transport and petrochemical industry.
Hydrocarbons are economically important because major fossil fuels such as coal,
petroleum and natural gas, and its derivatives such as plastics, paraffin, waxes,
solvents and oils are hydrocarbons. Hydrocarbons — along with NOx and sunlight
- contribute to the formation of tropospheric ozone and greenhouse gases.