Safety Data Sheet: 3M™ Neoprene High Performance Contact Adhesive 1357
Safety Data Sheet: 3M™ Neoprene High Performance Contact Adhesive 1357
Safety Data Sheet: 3M™ Neoprene High Performance Contact Adhesive 1357
SECTION 1: Identification
1.1. Product identifier
3M™ Neoprene High Performance Contact Adhesive 1357
Recommended use
Adhesive, Industrial use
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Signal word
Danger
Symbols
Flame | Exclamation mark | Health Hazard |
Pictograms
Hazard Statements
Highly flammable liquid and vapor.
Precautionary Statements
Prevention:
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Ground/bond container and receiving equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Keep container tightly closed.
Use explosion-proof electrical/ventilating/lighting equipment.
Do not breathe dust/fume/gas/mist/vapors/spray.
Use only outdoors or in a well-ventilated area.
Wear protective gloves and eye/face protection.
Do not eat, drink or smoke when using this product.
Wash thoroughly after handling.
Response:
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention.
If skin irritation occurs: Get medical advice/attention.
Wash contaminated clothing before reuse.
IF exposed or concerned: Get medical advice/attention.
In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to
extinguish.
Storage:
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Keep cool.
Keep container tightly closed.
Store locked up in a well-ventilated place.
Disposal:
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.
*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.
Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.
Skin Contact:
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms
develop, get medical attention.
Eye Contact:
Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical
attention.
If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1. Information on toxicological effects.
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
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Closed containers exposed to heat from fire may build pressure and explode.
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Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Indirect Vented Goggles
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
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substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity.
Gloves made from the following material(s) are recommended: Polymer laminate
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part
of a full respiratory protection program. Based on the results of the exposure assessment, select from the following
respirator type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
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Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.
Skin Contact:
Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain.
Eye Contact:
Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the
cornea, and impaired vision.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
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Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears.
Peripheral Neuropathy: Signs/symptoms may include tingling or numbness of the extremities, incoordination, weakness of
the hands and feet, tremors and muscle atrophy.
Olfactory Effects: Signs/symptoms may include decreased ability to detect odors and/or complete loss of smell.
Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or
numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate.
Reproductive/Developmental Toxicity:
Contains a chemical or chemicals which can cause birth defects or other reproductive harm.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
Name Route Species Value
Overall product Dermal No data available; calculated ATE >5,000 mg/kg
Overall product Inhalation- No data available; calculated ATE >50 mg/l
Vapor(4 hr)
Overall product Ingestion No data available; calculated ATE >5,000 mg/kg
Petroleum Distillate Dermal Rabbit LD50 > 2,000 mg/kg
Petroleum Distillate Inhalation- Rat LC50 259 mg/l
Vapor (4
hours)
Petroleum Distillate Ingestion Rat LD50 > 5,000 mg/kg
n-Hexane Dermal Rabbit LD50 > 2,000 mg/kg
n-Hexane Inhalation- Rat LC50 170 mg/l
Vapor (4
hours)
n-Hexane Ingestion Rat LD50 > 28,700 mg/kg
Acetone Dermal Rabbit LD50 > 15,688 mg/kg
Acetone Inhalation- Rat LC50 76 mg/l
Vapor (4
hours)
Acetone Ingestion Rat LD50 5,800 mg/kg
Methyl Ethyl Ketone Dermal Rabbit LD50 > 8,050 mg/kg
Methyl Ethyl Ketone Inhalation- Rat LC50 34.5 mg/l
Vapor (4
hours)
Methyl Ethyl Ketone Ingestion Rat LD50 2,737 mg/kg
Polychloroprene Dermal LD50 estimated to be > 5,000 mg/kg
Polychloroprene Ingestion Rat LD50 > 20,000 mg/kg
Magnesium Resinate Dermal LD50 estimated to be 2,000 - 5,000 mg/kg
Magnesium Resinate Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg
Toluene Dermal Rat LD50 12,000 mg/kg
Toluene Inhalation- Rat LC50 30 mg/l
Vapor (4
hours)
Toluene Ingestion Rat LD50 5,550 mg/kg
Zinc Oxide Dermal LD50 estimated to be > 5,000 mg/kg
Zinc Oxide Inhalation- Rat LC50 > 5.7 mg/l
Dust/Mist
(4 hours)
Zinc Oxide Ingestion Rat LD50 > 5,000 mg/kg
Rosin Dermal Rabbit LD50 > 2,500 mg/kg
Rosin Ingestion Rat LD50 7,600 mg/kg
ATE = acute toxicity estimate
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Skin Corrosion/Irritation
Name Species Value
Skin Sensitization
Name Species Value
Petroleum Distillate Guinea Not classified
pig
n-Hexane Human Not classified
Toluene Guinea Not classified
pig
Zinc Oxide Guinea Not classified
pig
Rosin Guinea Sensitizing
pig
Respiratory Sensitization
Name Species Value
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Zinc Oxide In vivo Some positive data exist, but the data are not
sufficient for classification
Carcinogenicity
Name Route Species Value
n-Hexane Dermal Mouse Not carcinogenic
n-Hexane Inhalation Mouse Some positive data exist, but the data are not
sufficient for classification
Acetone Not Multiple Not carcinogenic
Specified animal
species
Methyl Ethyl Ketone Inhalation Human Not carcinogenic
Toluene Dermal Mouse Some positive data exist, but the data are not
sufficient for classification
Toluene Ingestion Rat Some positive data exist, but the data are not
sufficient for classification
Toluene Inhalation Mouse Some positive data exist, but the data are not
sufficient for classification
Reproductive Toxicity
Target Organ(s)
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n-Hexane Ingestion endocrine system | Not classified Rat NOAEL Not 13 weeks
hematopoietic available
system | liver |
immune system |
kidney and/or
bladder
Acetone Dermal eyes Not classified Guinea NOAEL Not 3 weeks
pig available
Acetone Inhalation hematopoietic Not classified Human NOAEL 3 6 weeks
system mg/l
Acetone Inhalation immune system Not classified Human NOAEL 1.19 6 days
mg/l
Acetone Inhalation kidney and/or Not classified Guinea NOAEL 119 not available
bladder pig mg/l
Acetone Inhalation heart | liver Not classified Rat NOAEL 45 8 weeks
mg/l
Acetone Ingestion kidney and/or Not classified Rat NOAEL 900 13 weeks
bladder mg/kg/day
Acetone Ingestion heart Not classified Rat NOAEL 13 weeks
2,500
mg/kg/day
Acetone Ingestion hematopoietic Not classified Rat NOAEL 200 13 weeks
system mg/kg/day
Acetone Ingestion liver Not classified Mouse NOAEL 14 days
3,896
mg/kg/day
Acetone Ingestion eyes Not classified Rat NOAEL 13 weeks
3,400
mg/kg/day
Acetone Ingestion respiratory system Not classified Rat NOAEL 13 weeks
2,500
mg/kg/day
Acetone Ingestion muscles Not classified Rat NOAEL 13 weeks
2,500 mg/kg
Acetone Ingestion skin | bone, teeth, Not classified Mouse NOAEL 13 weeks
nails, and/or hair 11,298
mg/kg/day
Methyl Ethyl Ketone Dermal nervous system Not classified Guinea NOAEL Not 31 weeks
pig available
Methyl Ethyl Ketone Inhalation liver | kidney and/or Not classified Rat NOAEL 14.7 90 days
bladder | heart | mg/l
endocrine system |
gastrointestinal tract
| bone, teeth, nails,
and/or hair |
hematopoietic
system | immune
system | muscles
Methyl Ethyl Ketone Ingestion liver Not classified Rat NOAEL Not 7 days
available
Methyl Ethyl Ketone Ingestion nervous system Not classified Rat NOAEL 173 90 days
mg/kg/day
Toluene Inhalation auditory system | Causes damage to organs through Human NOAEL Not poisoning
nervous system | prolonged or repeated exposure available and/or abuse
eyes | olfactory
system
Toluene Inhalation respiratory system Some positive data exist, but the Rat LOAEL 2.3 15 months
data are not sufficient for mg/l
classification
Toluene Inhalation heart | liver | kidney Not classified Rat NOAEL 11.3 15 weeks
and/or bladder mg/l
Toluene Inhalation endocrine system Not classified Rat NOAEL 1.1 4 weeks
mg/l
Toluene Inhalation immune system Not classified Mouse NOAEL Not 20 days
available
Toluene Inhalation bone, teeth, nails, Not classified Mouse NOAEL 1.1 8 weeks
and/or hair mg/l
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Aspiration Hazard
Name Value
Petroleum Distillate Aspiration hazard
n-Hexane Aspiration hazard
Toluene Aspiration hazard
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
Incinerate in a permitted waste incineration facility. Combustion products will include halogen acid (HCl/HF/HBr). Facility
must be capable of handling halogenated materials. As a disposal alternative, utilize an acceptable permitted waste disposal
facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical
substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated
& disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective
regulating authorities to determine the available treatment and disposal facilities.
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EPA Hazardous Waste Number (RCRA): D001 (Ignitable), D035 (Methyl ethyl ketone)
Health Hazards
Reproductive toxicity
Serious eye damage or eye irritation
Skin Corrosion or Irritation
Specific target organ toxicity (single or repeated exposure)
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
Ingredient C.A.S. No % by Wt
Toluene 108-88-3 Trade Secret < 10
n-Hexane 110-54-3 Trade Secret 5 - 20
n-Hexane (Hexane) 110-54-3 5 - 20
This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
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the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued.3MMAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE.User is responsible for determining whether the3Mproduct is fit for a particular purpose and suitable for
user's method of use or application.Given the variety of factors that can affect the use and application of a3Mproduct, some of
which are uniquely within the user's knowledge and control,it is essential that the user evaluate the3Mproduct to determine
whether it is fit for a particular purpose and suitable for user's method of use or application.
3Mprovides information in electronic form as a service to its customers. Due to the remote possibility that electronic
transfer may have resulted in errors, omissions or alterations in this information,3Mmakes no representations as to its
completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the
SDS available directly from3M
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