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Engineering: Materials Science and

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Materials Science and

Engineering
A First Course

FIFTH EDITION

V. Raghavan
Formerly Professor of Materials Science
Indian Institute of Technology Delhi

PHI Learning Ptofe MgJ(M


Delhi-110092
2013
Contents

Preface IX

Preface to the First Edition x

SI Units XI

Physical Constants

Conversion Factors xv

Greek Alphabets xvu

1 Introduction 1-8
1.1 Materials Science and Engineering 1
1.2 Classification of Engineering Materials 2
1.3 Levels of Structure 3

1.4 Structure-Property Relationships in Materials 7


Suggestions for Further Reading 8

2 Equilibrium and Kinetics 9-22

2.1 Stability and Metastability 10

2.2 Basic Thermodynamic Functions 12


2.3 The Statistical Nature of Entropy 14

2.4 The Kinetics of Thermally Activated Processes 16


Summary 18

Problems 19

Multiple Choice Questions 20


Sources for Experimental Data 22

Suggestions for Further Reading 22

3 Crystal Geometry and Structure Determination 23-52


GEOMETRY OF CRYSTALS 24
3.1 The Space Lattices 24

3.2 Space Lattices and Crystal Structures 29


3.3 Crystal Directions and Planes 31

STRUCTURE DETERMINATION BY X-RAY DIFFRACTION 37


3.4 The Bragg Law of X-ray Diffraction 37
3.5 The Powder Method 41
3.6 Structure Determination 42

iii
iv Contents

Summary 45
Problems 46
Multiple Choice Questions 49

Sources for Experimental 52 Data

Suggestions for Further Reading 52

4 Atomic Structure and Chemical Bonding 53-80


STRUCTURE OF THE ATOM 54
4.1 The Quantum States 54
4.2 The Periodic Table 55

4.3 Ionization Potential, Electron Affinity and Electronegativity 60


CHEMICAL BONDING 63
4.4 Bond Energy, Bond Type and Bond Length 63

4.5 Ionic Bonding 65


4.6 Covalent Bonding 68
4.7 Metallic Bonding 71

4.8 Secondary Bonding 72


4.9 Variation in Bonding Character and Properties 74

Summary 76
Problems 77
Multiple Choice Questions 78

Suggestions for Further Reading 80

5 Structure of Solids 81-119


5.1 The Crystalline and the Noncrystalline States 82
INORGANIC SOLIDS 83
5.2 Covalent Solids 83

5.3 Metals and Alloys 88

5.4 Ionic Solids 97


5.5 The Structure of Silica and the Silicates 103

POLYMERS 706
5.6 Classification of Polymers 106

5.7 Structure of Long Polymers 107


Chain
5.8 Crystallinity of Long Chain Polymers 111
Summary 112

Problems 113
Multiple Choice Questions 116

Sources for Experimental Data 119


Suggestions for Further Reading 119

6 Crystal Imperfections 120-147


6.1 Point Imperfections 121
6.2 The Geometry of Dislocations 126
6.3 Other Properties of Dislocations 131
6.4 Surface Imperfections 137
Contents v

Summary 142

Problems 143
Multiple Choice Questions 146
Sources for Experimental Data 147
Suggestions for Further Reading 147

7 Phase Diagrams 148-177


7.1 The Phase Rule 148
7.2 Single-component Systems 150

7.3 Binary Phase Diagrams 151


7.4 Microstructural Changes during Cooling 157

7.5 The Lever Rule 159

7.6 Summary of Phase Diagram Rules 161


1.1 Some Typical Phase Diagrams 163

7.8 Other Applications of Phase Diagrams 170


Summary 171
Problems 171

Multiple Choice Questions 175


Sources for Experimental Data 177

Suggestions for Further Reading 177

8 Diffusion in Solids 178-200


8.1 Fick's Laws of Diffusion 779
8.2 Solution to Fick's Second Law 181
8.3 Applications Based on the Second Law Solution 182
8.4 The Kirkendall Effect 189
8.5 The Atomic Model of Diffusion 190
8.6 Other Diffusion Processes 193
Summary 196
Problems 196

Multiple Choice Questions 199


Sources for Experimental Data 200

Suggestions for Further Reading 200

9 Phase Transformations 201-237


9.1 Time Scale for Phase Changes 202
NUCLEATION AND GROWTH 204

9.2 The.Nucleation Kinetics 205


9.3 The Growth and the Overall Transformation Kinetics 211
APPLICATIONS 213
9.4 Transformations in Steel 214

9.5 Precipitation Processes 220


9.6 Solidification and Crystallization 224
9.7 The Glass Transition 226
9.8 Recovery, Recrystallization and Grain Growth 228
vi Contents

Summary 232

Problems 232
Multiple Choice Questions 235
Sources for Experimental Data 237
Suggestions for Further Reading 237

10 Elastic, Anelastic and Viscoelastic Behaviour 238-259

ELASTIC BEHAVIOUR 239


10.1 Atomic Model of Elastic Behaviour 239
10.2 The Modulus as a Parameter in Design 243

10.3 Rubber-like Elasticity 246

ANELASTIC BEHAVIOUR 249


10.4 Relaxation Processes 249

VISCOELASTIC BEHAVIOUR 252

10.5 Spring-Dashpot Models 252


Summary 255

Problems 256
Multiple Choice Questions 257
Sources for Experimental Data 258

Suggestions for Further Reading 259

11 Plastic Deformation and Creep in Crystalline 260-297


Materials
PLASTIC DEFORMATION 261
11.1 The Tensile Stress-Strain Curve 261

11.2 Plastic Deformation by Slip 263

11.3 The ShearjStrength of Perfect and Real Crystals 266


11.4 The Stress jto Move a Dislocation 269

11.5 The Effect of Temperature on the Stress to Move

a Dislocation 271

11.6 Multiplication of Dislocations during Deformation 274

11.7 Work Hardening and Dynamic Recovery 275


11.8 The Effect of Grain Size on Dislocation Motion 278

11.9 The Effect of Solute Atoms on Dislocation Motion 281

11.10 The Effect of Precipitate Particles on Dislocation Motion 283


11.11 Review of Strengthening Methods 285

CREEP 257
11.12 Mechanisms of Creep 287
11.13 Creep Resistant Materials 289

Summary 290
Problems 291

Multiple Choice Questions 294


Sources for Experimental Data 297
Suggestions for Further Reading 297
Contents vii

12 Fracture 298-314

12.1 Ductile Fracture 298

12.2 Brittle Fracture 300

12.3 Fracture Toughness 304


12.4 The Ductile-Brittle Transition 305

12.5 Fracture Mechanism Maps 307

12.6 Methods of Protection against Fracture 308


12.7 Fatigue Fracture 310

Summary 31J
Problems 312

Multiple Choice Questions 313

Suggestions for Further Reading 314

13 Oxidation and Corrosion 315-331

OXIDATION 316
13.1 Mechanisms of Oxidation 316
13.2 Oxidation Resistant Materials 318

CORROSION 319
13.3 The Principles of Corrosion 320
13.4 Protection against Corrosion 325

Summary 329

Problems 329
Multiple ChoiceQuestions 330
Sources for Experimental Data 331
Suggestions for Further Reading 331

14 Conductors and Resistors 332-354

14.1 The Resistivity Range 333


14.2 The Free Electron Theory 334
14.3 Conduction by Free Electrons 338

14.4 Conductor and Resistor Materials 341

14.5 Superconducting Materials 344

Summary 349
Problems 349

Multiple Choice Questions 351

Sources for Experimental 354Data

Suggestions for Further Reading 354

15 Semiconductors 355-392
15.1 The Energy Gap in Solids 356

15.2 Intrinsic Semiconductors 361


15.3 Extrinsic Semiconductors 364
15.4 Semiconductor Materials 368
15.5 Fabrication of Integrated Circuits 369
15.6 Some Semiconductor Devices 379
viii Contents

Summary 384
Problems 385
Multiple Choice Questions 387
Sources for Experimental Data 392
Suggestions for Further Reading 392

16 Magnetic Materials 393-411


16.1 Terminology and Classification 394
16.2 Magnetic Moments due to Electron Spin 395
16.3 Ferromagnetism and Related Phenomena 397
16.4 The Domain Structure 399
16.5 The Hysteresis Loop 400
16.6 Soft Magnetic Materials 402
16.7 Hard Magnetic Materials 405
Summary 407
Problems 407
Multiple Choice Questions 409
Sources for Experimental Data
411

Suggestions for Further Reading 411


17 Dielectric Materials 412-426
17.1 Polarization 413
17.2 Temperature and Frequency Effects 416
17.3 Electric Breakdown 419
17.4 Ferroelectric Materials 420
Summary 423
Problems 424

Multiple Choice Questions 424


Sources for Experimental Data 426
Suggestions for Further Reading 426

Appendix I—Properties of Elements 427-429


Appendix II—Properties of Engineering Materials 430

Index 431-439

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