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Dipole Moment: Ii) Magnitude of Charge

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Dipole Moment

Introduction:
The degree of polarity of a molecule is expressed in terms of dipole moment.

Definition:
“The product of magnitude of charge on a molecule and the distance between charges of equal magnitude with opposite sign is
called dipole moment.”

Mathematically:
Dipole moment = charge × distance

µ =e×d

Unit:
Debye OR Coulomb × meter OR E.S.U. × cm (E.S.U : electro static unit of electric charge)

Factors affecting on Dipole Moment:


i) Polarity of molecules:
Dipole moments arise from differences in electronegativity. The larger the difference in electronegativity, the larger the dipole
moment. The dipole moment is a measure of the polarity of the molecule.

ii) Magnitude of Charge:


Dipole moment is directly proportional to the magnitude.

iii) Geometry of Molecule:


a) Homo-nuclear diatomic molecules (Non-polar molecules), polyatomic molecules of linear structure and polyatomic molecules
of symmetrical structure have zero dipole moment

Homo-nuclear diatomic molecules Poly atomic molecules of linear structure Poly atomic molecules of symmetrical structure
H2, O2,Cl2 CO2 , CS2 CH4, CCl4 and C6H6

b) Diatomic molecules of different atom (Polar molecules) and molecules having angular structure have particular values of
dipole moment.

Diatomic polar molecules Poly atomic molecules of angular structure


i) HF 1.9 Debye i) H2O 1.84 Debye
ii) HCl 1.03 Debye ii) NH3 1.46 Debye

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