Time: 1 Hrs Max. Marks: 75 Single Correct: - O OH CH CH NH C Me - O
Time: 1 Hrs Max. Marks: 75 Single Correct: - O OH CH CH NH C Me - O
Time: 1 Hrs Max. Marks: 75 Single Correct: - O OH CH CH NH C Me - O
Marks: 75
Single correct [6 × 3=18]
Q.1 Cinnamic acid (Ph–CH=CH–COOH) is nitrated preferably at________ and it is ________ then nitration
of benzene.
(A) m-position, faster (B) o & p-positions, faster
(C) m-position, slower (D) o & p-position, slower
(A) (B)
(C) (D)
2 4 aq. H SO
Q.3 MeCH (CN) CO Me P
(A) P giving +ve iodoform test & –ve test with Fehling solution.
(B) P giving –ve iodoform test & +ve test with NaHCO3 solution.
(C) P gives +ve Lucas test & –ve test with NaHSO3 solution
(D) P gives +ve test with NaHSO3 & cerric ammonium nitrate solution.
Q.4 Compound A (C7H8O) is insoluble in water, dilute HCl & aqueous NaHCO3, it dissolves in dilute
NaOH. When A is treated with Br2 water it is converted into a compound C7H5OBr3 rapidly. The
structure of A is
O
||
Q.5 Me C O CH 2 CH 2 N H 3 NaOH
Q
Q is:
O O
|| ||
(A) Me C O CH 2 CH 2 NH 2 (B) Me C NH CH 2 CH 2 OH
Page No.1
Q.6 Nylon-6 is prepared by linear condensation homopolymerization reaction of:
(A) caprolactum (B) hexamethylene diamine and adipic acid
(C) 6-aminohexanoic acid (D) acrylonitrile
Comprehension [6 × 3 = 18]
O3 KOH N 2H 4 CrO 3
P1 P2 P4
Zn/H 2O EtONa
P3
KOH H2/Pd HBr NH3
P5 excess
P6 excess P7
Q.7 Which of the following statement is correct about P4?
(A) It will not give yellow/orange or red colour with 2, 4-DNP.
(B) It will give red colour with Cerric Ammonia Nitrate
(C) It will not give Fehling test.
(D) It will give Bielstien test
Q.8 Which of the following statement is correct about P7?
(A) It will not give mustard oil reaction.
(B) It will not give carbylamine test or isocyanide test
(C) It will decolourize bromine water.
(D) It will give base soluble product with Hinsburg reagent
Q.9 Which of the following reaction will be useful for conversion of P3 into P4.
(A) Clemmenson's reduction
(B) Oppenauer oxidation
(C) Meerwin Pondorff Verely reduction
(D) Tischenko reaction
NaOH (i)AgOH
(J) C–OH (A) + (B)
O (ii)Br2, CCl4, Major Minor
(X)
Kolbe
Electrolysis Na, EtOH, liq NH3
(I)
On the basis of reactions involved in above interconversions answer the given questions.
Page No.2
Q.10 Find out the incorrect statement?
(A) Product G is a racemic mixture
(B) Product F is 3° halide
(C) Product A, C, F, H, I are optically inactive.
(D) No product ( A to L) can show the geometrical isomerism.
Q.11 Reaction which does not involve free radical mechanism in above reactions is:
(A) X to A, B (B) H to I (C) A to C, D, E (D) X to J
OH
(B) shows Keto-enol tautomerism.
O
(C) Phenol & benzoic acid can be distinguished by NaHCO3.
O O
O
(D) and can be distinguished by iodoform test.
O
Reaction 2— 5HIO
4
Ratio of moles of formaldehyde obtained in the reaction (1) and reaction (2)
(1) Ac O, AcONa ,
Q.19 Reaction 1— 2 (A)
( 2 ) H3O ,
O
|| Al ( OCHMe 2 )3
Reaction 2— Ph – CH CH – C CH 3 (B)
CH 3 CH OH
|
CH 3
OH
| (1) NaOI
Reaction 3— Ph – CH CH CH CH 3 (C)
( 2) H
Degree of unsaturation present in compound (A + B + C) is?
Page No.4
Answers
1. D 2. C 3. A 4. C
5. B 6. C 7. C 8. D