JEE MAINS MODEL PRACTICE TEST

GRAND TEST - 4
(KEY SHEET)

PHYSICS

01) 2 02) 2 03) 1 04) 1 05) 2

06) 4 07) 3 08) 2 09) 1 10) 1

11) 4 12) 4 13) 2 14) 3 15) 2

16) 2 17) 3 18) 3 19) 1 20) 4

21) 1 22) 2 23) 1 24) 2 25) 1

CHEMISTRY

26) 3 27) 2 28) 1 29) 3 30) 3

31) 4 32) 2 33) 2 34) 3 35) 2

36) 3 37) 2 38) 2 39) 1 40) 1

41) 1 42) 2 43) 2 44) 4 45) 1

46) 3 47) 3 48) 1 49) 4 50) 1

MATHEMATICS

51) 2 52) 2 53) 4 54) 1 55) 3

56) 3 57) 3 58) 1 59) 2 60) 3

61) 4 62) 2 63) 2 64) 2 65) 3

66) 4 67) 2 68) 4 69) 1 70) 1

71) 2 72) 4 73) 1 74) 3 75) 3

 PHYSICS HINTS & SOLUTIONS
k c ds Tx  T2
 
01. Sol: I 
14  10
 2A k s dc T1  Tx ........ (i)
2
Substituting the given values in equation (i),
14V, 1 we have

9.2  102 125  Tx  0

I  (or) Tx  93.3C
1.1  102 75 100  Tx
10V, 1 (or) Thus the temperature of the junction is
93.3°C. The heat flowing through the junction
The rate at which energy is consumed by per second is
battery of smaller emf is,
dQ k c A(T1  T)
P  (10  I  1)  I  20  4  24 W  ....... (2)
dt dc
Out of this 24 W, 20 W is the rate at which
electrical energy is converted to chemical dc  75cm  0.75m and
energy.
A  r2   (10  2 m)2  3.14  104 m2 .
02. Sol:  Edq  x  I
Also T1  100C and T  93.3C . Using these
 values in (ii) we have
1
 E  dx  x  3 m
2
 
x 0 dQ 9.2  102  3.14  104  (100  93.3)

dt 0.75

 x2  1
 E     m2   2.58  104 J / s .
 2 0 3
ORIGINAL

A
LEVEL

2y
x
y

30cm

dqE 04. Sol:

dx

Figure shows a U-tube of uniform cross-sectional

2 1 3 E
 E   m2     . area A. Let the liquid be depressed through the
2 3 2m distance y in a limb, the difference of levels
03. Sol: Let Tx be the temperature of the junction between two limbs will be 2y as shown in figure.
of the copper and steel bars (figure 4.9). In The liquid now oscillates about the initial
the steady state, the rate of flow of heat in positions. Excess pressure on whole liquid =
the copper bar must be the same as that in (excess height of the liquid column) (density)
the steel bar, i.e., (since their cross-sectional (g)  2y  1  g [As density of water =1]
areas are equal) Restoring Force on the liquid = pressure ×
kc T ks
area of cross section = 2ygA
Due to this force the liquid accelerates and if
its acceleration is a, we have
T1=100°C Copper Steel T2=0°C
ma  2ygA
dc ds
(or) (2  30  A )a  2ygA (or)
Figure 4.9 g
a y
dQ k c A(T1  Tx ) k s A(Tx  T2 ) 30
  (or)
dt dc ds Hence acceleration is directly proportional to
 displacement, so the motion is simple
4 4 4 
harmonic motion. Thus the time period T is P  r 3   r13  r22 
3 3 3 
2  2  30   2  30 
given by T      4T
  g   980   [4 r2  {4 r12  4 r22 }]  0 (or)
3
 g  3PV  4TS  0 .
 As     1.098 s .
 30  08. Sol: The relation between potential and field
will be given by
05. Sol. The center of mass of the system would be
at the center of the disk only. The FBD of the  dV  V  V  V  
E   i j k
system is as shown in figure. Writing the dr  x y z 
equation for motion of system,

E    2 i  2 j  2 k   E  i  j  k
5mg sin   f  5ma and fR  I  1 1 1 
x y z  x 2 y 2 z2
a
  i j k
f
 E at (1, 1, 1) will be   .
1 1 1
09. Sol. The FBD of the block is as shown in figure.
5mg sin
80 sin 37°


mR 2 5mR 2 80 N
Where I   2m  R 2  and a  R
2 2
[for pure rolling] Solving above equation 80 cos 37°
5mg sin 
we have, f  . For pure rolling f  fL f
3
4g
fL  N    5mg cos 
N  80cos37  64N
5mg sin  tan 
    5mg cos     . So, fL  0.2  64  32N
3 3
As 4g  80sin37 , so friction force will act
GM downward equal to 4g. Net applied force in
06. Sol. Orbital speed of satellite is, v 
r upward direction (excluding friction force) is

mv 2 GMm 80 sin37  40  48  40  8N as Fapplied in vertical

Initial KE, K i  
2 2r direction is  f2 so block won’t move in vertical
From work energy theorem, direction and value of static friction force is
f  8N .
mv 2f mv 2i     GMm  GMm   W
   air friction
3Mg Mg 3Mg
2 2  RE r 
10. Sol. f    3
4 4 4
mv 2f GMm GMm GMm Work done by friction force for the duration
 Wair friction    
2 2r RE r as chain completely slips off from the table.
L/4
 1.67  1011 Joule . M
dW  df x    L dx gx
07. Sol. Under isothermal condition PV  P1V1  P2 V2 0

3Mg
L/4
 4T  4 3  Mg  x 2 
P   r  (or) Wf  3   
 4  3  L  2 0 32

 4T   4 3   4T   4 3 
 P    r1    P    r2 
 r1   3   r2   3 
 nE photon 20
x Initial momentum/sec   towards
c c
dx
the plane surface. Let n1 photons reflected/
x sec, so n1  Ephoton  4W . Final Momentum/
n1Ephoton 4
sec   away from the plane
c c

K  Wf  Wgr p 20 4 24
surface     8  108 N .
t c c c
Mv 2 3Mg  Mg  9Mg   
0         13. Sol. KE  TE  3.4 eV
2 32  2  32   
h 6.634  1034
1 4Mg 1  
Mv 2  v g . 2mK 2  9.1  1031  3.4  1.6  1014
2 32 2
 6.6  1010 .
C' C 14. Sol. Let at any time t, N nuclei are present. Then
dN N dN t
 200  N     dt
11. Sol. O 10 cm dt 0 200  N 0

200
N [1  e t ]
5/ D' D 
5  5 For N  100 , t  n (2)sec .
15. Sol.
Mirror can be shifted to new position C' D' .
Distances are shown in figure. Image will be 2 80.6N
16. Sol. f 
at equal distance from the mirror C' D' as the cos2 i
object is. Image distance from Where i is angle of incidence and N is electron
density. For the wave not reflected from
5 10 40 ionosphere.
C'D'  10   10   cm
3/2 3 3
80.6N
Separation between object and image is  f2   80.6N or
cos2 0
80
cm . f2
6 2
(10  10 ) 100
3 N    1012  1.24  1012 m 3 .
80.6 80.6 80.6
12. Sol. Let wavelength of incident radiation is  , 17. Sol.
hc 18. Sol. In series LCR ac circuit, current is maximum
so energy of photon, Ephoton 
 1
when L  where  is the supply angular
C
20W frequency i.e., in resonance condition.
1 1 1000
4W   
LC 0.3  30  10 6 3 .
19. Sol. The angular radius of the central bright disc
in a diffraction pattern from circular aperture
is given by
h E photon
Momentum of photon   . 1.22
  sin  
Let n photons are emitted per sec, so b
n  E photon  20W 1.22  590  10 9 m
  1.4  105 rad .
5.0  102 m
 The radius of the bright disc is 23. Sol. Pmax  VzIz (max)
5 4
 1.4  10  20cm  2.8  10 cm
Pmax 364  103
The diameter of the disc image  5.6  104 cm . Iz (max)    40 mA .
Vz 9.1
20. Sol. At a height 5m; v 2  2  2gh 24. Sol. Conceptual/Basic Question

v 2   2  2gh  10 3ms1 25. Sol. v x  5cos37 , v y  5sin37

 
Horizontal component of velocity v1  v x i , v 2   sin37j  5j
 cos   20cos60
m1v x  m2  0
v xcm 
 tan   2 . m1  m2
21. Sol. We know that,   o (1   ) m1v y  m2 v y
v ycm  .
 4 m1  m2
  1  6.3  10  1  500.6
o 4   107 CHEMISTRY HINTS & SOLUTIONS
Intensity of magnetisation, 26. Sol. ( NH2 ) is close to –COOH, in ( NH ) ,
I  H  500.6  1000  5  105 Am1 the lone pair of electrons is involved in
 Magnetic moment, resonance, and the lone pair on ( N  ) is
intact on N-atom.
M  I  V  I  r2
27. Sol. Conceptual/Basic Question.
 5  105  3.14  (102 )2  (10  102 )  17.70 A  m2 .
G G
22. Sol: For an adiabatic change P1V1  P2 V2  28. Sol.1)  S , is slope in Ellingham
T T

diagram. Which is same below the boiling
V  point.
(or) P2  P1  1 
 V2  2) Below the boiling point slope is same as
factor TS is same.
Here P1  105 N/m2 , V1  6 litre , V2  2 litre
3) Above G  0 line free energy becomes
and for a monoatomic gas, we have positive so oxide decomposes.
3R 3R 5R 4) Random increases i.e., S increases, so
CV  and CP  R 
2 2 2 slope also increases.

CP 5R/2 5 29. Sol.   n(n  2)

(or)    
CV 3R/2 3 Number of unpaired electrons are:
5/3 (i) [Cr(NH3 )6 ]3 Cr3 (3d4 ) , n  3
6
5 5 5/3
Thus P2  10     10  (3)
2
We know that work done on gas W in (ii) [Co(NH3 )6]2 Co2 (3d7 ) , n  3

P2 V2  P1V1 (iii) [Fe(H2O)6 ]2 Fe2 (3d7 ) , n  4

adiabatic change is given by W 
 1
(iv) [Mn(H2O)6 ]2 Mn2 (3d5 ) , n  5
105  (3)5/3  (2  103 )  105  (6  103 )
 (v) [Co(H2O)6 ]3 Co3 (3d6 ) , n  0 (d2sp3 )
(5 / 3)  1
Thus, Cr 3 and Co2 have same number of
3 3
[Here V2  2 litre  2  10 m and unpaired electrons. Hence, in pair (C), both
V1  6 litre  6  103 m3 ] species will have same magnetic moment.
30. Sol. Terylene contains ester linkage, i.e.,
2  102[(3)5/3  3] 2  102 [6.19  3] OCH2  CH2  O  CO  and not ketone
 
(2 / 3) (2 / 3) linkage.
 3  102  (3.19)  957 J . 31. Sol. In basic medium acid looses H .
 :O: :O: :O: 2H2O2 
 2H2O  O2
Br 112 Br C 110 C F 103 F . 2 mol 1 mol
32. Sol.
(3) (2) (1) 2  34 g  68 g 22400 cm3 (at STP)

33. Sol. Conceptual/Basic Question Then 68 g of H2O 2 gives 22400 cm3 of oxygen
34. Sol. Conceptual/Basic Question
22400 cm 3
35. Sol. Ampicillin is synthetic modification of 1 g of H2O 2 gives of oxygen
penicillin. 68

36. Sol. 0.068 g of H2O 2 gives

2H2( g )  O2( g )  2H2O( g )
Thus, 5 cm3 of H2O 2 gives 22.4 cm3 of oxygen
Initial mole 2a a 0
22.4
Final mole (2a  2x ) (a  x ) 2x at STP. So, 1 cm 3 of H2O 2 gives cm3 of
5

80 oxygen at STP  4.48 cm3 at STP

Given 2x  2a   1.6a
100 Therefore, strength of the given H2O 2 sample
 x  0.8a = 4.48 volumes.
38. Sol. I. Molar entropy of gas is much greater than
Thus, after the reaction H2
that of solid and liquid.
left  2a  1.6a  0.4a mole O2 left  0.2a mole
II. Entropy change is positive if ng is positive.
H2O formed  1.6a mole
III. Molar entropy of a crystalline solid will be
 Total mole at 120°C in gaseous phase zero at absolute zero.
 0.4a  0.2a  1.6a  2.2a IV. In irreversible process both system and
surroundings are not restored if path is
Now, given at initial conditions P  0.8 atm
reversed.
T  293 K V. Refractive index and molarity are intensive
P  V  nRT  0.8V  3a  R  293 properties.

3a  R  293 39. Sol. NaBH4

CH3 CH  CHCHO  CH3CH  CHCH2OH
 V
0.8 (X)
HC  ZnC 2
The volume of container remains constant.
Using, P  V  nRT (i ) KCN
CH3 CH  CHCH2COOH 
(ii ) H
 CH3 CH  CHCH2C
(Z) (Y)
3a  R  293
 P  2.2a  R  393 [T  393 K]
0.8 40. Sol. Conceptual/Basic Question
41. Sol. Addition of KSCN increases the colour
393  0.8  2.2
P  0.787 atm . intensity of the solution as it shifts the
3  293 equilibrium to right. Addition of reagents like
37. Sol. The reaction between H2O 2 and the acidified oxalic acid or Hg2 ions which remove F e 3
KI solution is or SCN– ions shift the equilibrium to the left
and colour intensity decreases.
2KI  H2SO4  H2O2 
 K 2SO4  2H2O  I2
34 g 254 g
42. Sol. Conceptual/Basic Question
5.0 cm3 0.508 g 43. Sol. Conceptual/Basic Question
Then, Mass of H2O 2 that liberates 0.508 g of CH3 CH3
44. Sol. I)
34 
C CH2 C CH2
I2   0.508  0.068 g
254 CH3 CH3 
O CH3 O CH3
3
This much H2O 2 is present in 5.0 cm .
Hydrogen peroxide decomposes as follows: Stabilised by resonance and
hyperconjugation having six H-atoms
 CH3 CH3 hC 12400
III)

CH 3  CH  O  HC CH3  CH  O   HC 49. Sol.     2.4     0  516.7 nm
0 0
CH3 CH3
For PEE,  0   0 . So, 5 sources (A, B, C, D, E)
Stabilised by resonance and
hyperconjugation having three H-atoms will exhibit protoelectric effect.
50. Sol. Equivalent weight of Ag  108 / 1  108
CH 3
 Equivalent weight of Cu  63.5 / 2  31.75
II) CH 3  C H  CH 2  HC
CH 3 Eq. wt. of Ag Mass of Ag deposited

Eq. wt.of Cu Mass of Cu deposited
Stabilised by hyperconjugation
having five H-atoms 108 15.28 15.28  31.75
 W  4.49 g .
31.75 W 108
 CH3
IV) CH2  CH2  CH2  HC
CH3 MATHEMATICS HINTS & SOLUTIONS
51. Sol. Conceptual/Basic Question
Stablised by hyperconjugation 52. Sol. Conceptual/Basic Question
having two H-atoms
53. Sol. Conceptual/Basic Question
Stability of the given species depends upon 54. Sol. Conceptual/Basic Question
the hyperconjugation having higher number
55. Sol: sin1(sin10)  sin1 (sin(3  10))  3  10 .
of   hydrogens as well as resonance. Hence
the correct stability order will be 56. Sol: Given, c  2 2 , A  30 , R  2
(I)  (III)  (II)  (IV) .
a  2R sinA  4sin30  2
45. Sol. BeO - Insoluble, BeSO 4 - Soluble
c  2R sinC
BaO - Soluble, BaSO 4 - Insoluble  2 2  4 sinC  C  45 .
Be(OH)2 - Soluble in NaOH 57. Sol: The sides are y  1 and the pair
Be(OH)2 - Insoluble in NaOH. x 2  7xy  2y 2  0 .
46. Sol. For fcc, Clearly, one vertex is (0, 0) and the y co-
ordinate of each of the other two vertices is 1.
2 2 1.414  361
r a   361   127 pm . Putting y  1 in the second equation, we get
4 4 4
x 2  7x  2  0 .
0 0 0 0 0
47. Sol. P  X P  X P  (P  P ) X A  P
A A B B A B B
If x1 , x 2 are the roots then x 1  x 2  7 .
0
So, P  265
B
 The centroid  
0  x1  x 2 0  1  1 
0 0 0 , 
P  P  130
A B P  135
A  3 3 
PA0  PB0  400 .  7 2
  ,  .
48. Sol. Moles of P atom in Ca 3 (PO)4  4  2  8  3 3

Moles of P atom in P4O10  5  4  20 58. Sol: Let x  cos 

Moles of P atom in H3PO3  6  1  6 1 1

Then y  cosec  cosec 1 (sec2 )
Total moles of p-atoms = 34 2x 2  1

 Number of moles of P4 molecule    

 cosec1 cosec   2    2
 2  2
34
  8.5 .
4
z  1  cos2   sin 
 dy
dy d 2 2 nd
  dz
   (a1  a 2n )  .
dz d cos  x d( a1  a n 1 )

1 dy  4 64. Sol: Total number of letters  8

At x  , .
2 dz Number of consonants  5
59. Sol: At x  1 , Number of vowels  3
1
y  e , x 1 0 y  e x Two consonants can be arranged at the two ends
in 5 P2 ways. Remaining 6 places can be filled up
dy  dy  1
 e  x     by the remaining 6 digits in 6! ways.
dx  dx x 1 e
 Required number  5P2  6!  20 720  14400 .
1 65. Sol: Probability of showing different numbers
Equation, y  e 1   (x  1)
e
( 6 C3 )(3!) 5
 ey  1  x  1  x  ey  2 . on a single trial   .
63 9
60. Sol: 5x  (2 3 )2x  132  5x  12x  132 Thus, required probability
2
We know that 52  122  132 .  5  4 100
 3C2      .
 9  9 243
So, for x  2 , 5x  12x  52  122  132 .
  
66. Sol. a  5b  3c  0
61. Sol: Let f(x)  x 6  4x 5  3x 4  2x 3  x  1
     
Thus, a  b  c are coplanar. Hence a  (b  c) .
Hence, f( )  6  45  34  23    1
2 sinx  log(1  x )
 1  42  3  2    1  4(     1)  0 67. Sol: lim
x 0 x2
Hence, f(x) is divisible by x   . Then f(x) is
also divisible by x  2 (as complex roots  x3 x5   x2 x3 
x    .....     x    ..... 
occur in conjugate pairs). 3! 5! 2 3
 lim   
2

x 0 x
f()  ( )6  4( )5  3( )4  2( )3  ( )  1
 x x 3   1 x 
 6  45  34  23    1 x 2     .....       .....  
3 ! 5 !   2 3  1
 1  42  3  2    1  0 .  lim   .
x0 x2 2

62. Sol:       and    3 1

68. Sol: I   x d(tan x )
From second relation   0
x3  x 
  1  2
dx    x   dx
1 x  1  x2 
From first relation,   2
x2 1
Hence,   1 and   2 .   ln(1  x 2 )  C .
2 2
63. Sol: a1  a 2n 2
69. Sol: y dx  x dy  xy dx  0
 a 2  a 2n1  ...  a n  a n1  k (say).
y dx  x dy x
 a  a2 a n  a n 1    x dx  0  d    x dx  0
Expression  k  1  ...   y2 y
 a1  a 2 a n  a n 1 
x x2
k   c.
 ( a1  a n 1 ) , y 2
d
where d = common difference a
70. Sol: Any tangent to y 2  4ax is y  mx  .
m
k a1  a n 1

d a1  a n1 2  a
It touches x 2  4ay if x  4a  mx   ,
 m
 4a 2 Required area  4  2  8 sq. units .
i.e., x 2  4amx   0 has equal roots.
m 2 2
73. Sol: p  q  pq  p  q  1  0
So, m 3  1  0 , i.e., m  1 . Hence, the common  2p2  2q2  2pq  2p  2q  2  0
tangent is y  x  a .
 (p  q)2  (p  1)2  (q  1)2  0
3 6 10
71. Sol: General term in ( 2  3  5 ) is
 p  q 1
10!
( 2 ) ( 3 3 ) ( 6 5 ) 1 cos  cos 
 !!  !
Now,   cos  1 cos 
10! cos  cos  1
or (2)(  /2 ) (3) /3 (5) /6
 ! !  !
 sin2   cos2   2cos   cos   cos   cos2   0
Where       10 for rational terms
[      0
  0, 2, 4, 6, 8, 10
 cos(    )  cos 
  0, 3, 6, 9 and r  0, 6
or (cos  cos   cos  )2  sin2  sin2 
  and  are even numbers, then  should
also be an even number  (1  cos2  )(1  cos2  )] .
(       10 ) 2 2
74. Sol: 2sin   (r  1)  2  2
   0, 6
But max sin   1
For   0 ,     10 , then   4 ,   6 and  The equation implies sin   1 , r 2  1 ,
  10 , r  0 sin   1
For   6 ,   r  4 , then   4 , r  0  5 9
 , , (from the question)
 Number of rational terms  3 . 2 2 2
72. Sol: Graph of f 1 (x ) is the mirror image of f(x) r2  1  r  1,  1
about the line y  x .  The number of values of the pair (r,  )
 2 3  6 .
Y 75. Sol: For x 2  y 2  9 , the centre  (0, 0) and the
yx radius  3 .
f 1 (x )
2 For x 2  y 2  8x  6y  n2  0 ,
The centre  (4, 3) and the radius

f(x)  4 2  3 2  n2
 42  32  n2  0 or n2  52
f 1 (x ) or 5  n  5
X
Circles should cut to have exactly two common
O  2 tangents.
So, r1  r2  d
Required area  4 A ––––– (1)  3  25  n2  4 2  32
 1 or 25  n2  2 or 25  n2  4
Where A   f(x)dx     
0 2
 n2  21 or  21  n  21

 2  x 2  2 Therefore, common values of n should satisfy
  (x  sin x )dx     cos x  
0 2 2 0 2  21  n  21 . But n  Z , so, n  4,  3,...,4 .

 2  2
   ( 1)   (0  1) 
 2  2  2 sq. units ***THE END***