Thermodynamic II PDF
Thermodynamic II PDF
Thermodynamic II PDF
1. Definitions , phase change , pure substance اﻟﻤﺎدة اﻟﻨﻘﻴﺔ/ ﺗﻐﻴﻴﺮ اﻟﻄﻮر/ ﺗﻌﺮﻳﻔﺎت .1
2. = = .2
3. Steam tables ﺟﺪاول اﻟﺒﺨﺎر .3
4. T-s , P v diagrams and h- s chart h-s او ﻣﺨﻄﻂp-v، T-s رﺳﻮﻣﺎت .4
5. Steam process إﺟﺮاءات اﻟﺒﺨﺎر .5
6. = = .6
7. Dryness fraction measurement ﻗﻴﺎس ﻧﺴﺒﺔ اﻟﺠﻔﺎف .7
8. = = .8
9. Steam cycles Carnot cycle دورات اﻟﺒﺨﺎر دورة آﺎرﻧﻮ .9
10. Rankine cycles دورة راﻧﻜﻦ .10
11. Ranking cycle with superheat دورة راﻧﻜﻦ ذو اﻟﺘﺴﺨﻴﻦ اﻟﻌﺎﻟﻲ .11
The effect of steam condition on thermal
12. ﺗﺄﺛﻴﺮ ﺣﺎﻟﺔ اﻟﺒﺨﺎر ﻋﻠﻰ اﻟﻜﻔﺎءة اﻟﺤﺮارة .12
efficiency
13. Reheat cycle دورة اﻋﺎدة اﻟﺘﺴﺨﻴﻦ .13
14. Regenerative cycle , open feed heater ﻣﺴﺨﻦ ﺗﻐﺬﻳﺔ ﻣﻔﺘﻮح/ دورة إﻋﺎدة اﻟﺘﻨﺸﻴﻂ .14
15. Regenerative cycle , closed feed heater ﻣﺴﺨﻦ ﺗﻐﺬﻳﺔ ﻣﻐﻠﻖ/ دورة إﻋﺎدة اﻟﺘﻨﺸﻴﻂ .15
16. Air standard cycle ; Otto cycle دورة اوﺗﻮ: دورات اﻟﻬﻮاء اﻟﻘﻴﺎﺳﻴﺔ .16
17. Air standard cycle ; Diesel cycle دورة دﻳﺰل: دورات اﻟﻬﻮاء اﻟﻘﻴﺎﺳﻴﺔ .17
18. Air standard cycle ; Daul cycle اﻟﺪورة اﻟﻤﺰدوﺟﺔ: دورات اﻟﻬﻮاء اﻟﻘﻴﺎﺳﻴﺔ .18
Mean effective pressure , and comparison ﻣﺘﻮﺳﻂ اﻟﻀﻐﻂ اﻟﻔﻌﺎل واﻟﻤﻘﺎرﻧﺔ ﺑﻴﻦ دورات اﻟﻬﻮاء
19. اﻟﻘﻴﺎﺳﻴﺔ
.19
between air standard cycles
20. Simple gas turbine cycle ; Brayton cycle دورة اﻟﺘﻮرﺑﻴﻦ اﻟﻐﺎزي اﻟﺒﺴﻴﻄﺔ دورة ﺑﺮاﺗﻦ .20
21. Reciprocating compressors اﻟﻀﻮاﻏﻂ اﻟﺘﺮددﻳﺔ .21
22. The condition for minimum work ﺷﺮط اﻟﺸﻐﻞ اﻷدﻧﻰ .22
23. Isothermal efficiency اﻟﻜﻔﺎءة اﻟﺤﺮارﻳﺔ .23
References:-
1. Applied Thermodynamics for Engineering Technologists, by
Estop, T. D. and McConky, A.
2. Engineering Thermodynamics, Work and heat Transfer, by
Rogers, C. F. C. and Mayhew, Y. R.
3. Thermodynamics: An Engineering Approach, 3/e, by Yunus
A. Cengel and Michael A. Boles
Fundamentals:
Steam: is water vapor at or above the boiling point. Steam has the widest
application as working fluid due the following reasonable reasons:-
1. Water is the most widely spread substance in nature.
2. Water and steam possess relatively good thermodynamic properties.
3. Water and steam do not have harmful effect on metal and living
organisms.
Evaporation: - is the process of vapor formation that occurs only from the
surface of the liquid and it takes place at any temperature.
1
Unsaturated water: - water where its temperature is below the saturated
temperature. (T < Ts )
2
Figure (02) phase change due to heating
For engineering purpose, figure (02) is more related then figure (03).
Heating Process (A-B-C-D-E-F-G), which is under constant pressure, can be
repeated for different pressure from a value below triple point
( Tt = 273.16 K , p t = 0.006112 bar ) to a value above critical value
( Tc = 647.3 K , p c = 221.2 bar , v c = 0.00317 m 3 / kg ).
3
Figure (04) shows
different heating processes
under different pressures.
Arrows (1) for
boiling, (2) for sublimation
and (3) for fusion denote
the variation of
temperature under different
pressures, see figure (05).
4
Figure (06): T-v diagram for pure water.
5
T-s and p-v diagrams:
T-v diagram can be transposed into a more useful (T-s) and (p-v)
diagrams.
6
Determining Parameter of State of Steam and Basic Relations
Steam table:- the one used here is arranged by G.F.C. Rogers and
Y.R. Mayhew
7
dry steam mass
Dryness ratio, x =
total steam mass
Steam table cannot contain infinite data, then the between values are
evaluated by interpolation from previous and next values.
8
Unsaturated water:
uw = hw
For entropy:
Δs = s w − s o
dq 1 T T
dT
dq = Tds ⇒ ds = = ∫ c w , p dT = 4.168∫
T T0 0
T
T
s w = 4.187 Ln w , where ( T ) in K.
273.3
Saturated water:
h f = h w ; u f = u w ; s f = s w at saturation temperature.
Wet steam:
h = h f + x h fg
h fg = h g − h f
9
u = u f + x u fg
u fg = u g − u f
u g = h g − (p s v g )
s = s f + x s fg
h fg
s fg =
Ts
( h fg ) is the latent heat for evaporation. At wet steam region, the specific heat
at constant pressure is variable due to gradual phase change. It sound that
( h g ) should be evaluated experimentally.
Saturated steam:
h = h f + h fg
u = u f + u fg
s = s f + s fg
h = h f + h fg + h sup
t sup
t sup
h sup = ∫ c sup,p dt = [c sup,p ] ts × t sup
ts
u = u f + u fg + u sup
s = s f + s fg + s sup
h sup
s sup =
Tsup
10
(h-s) diagram, also called mollier chart:-
11
Reversible non-flow steam processes:-
q12 − w 12 = Δu
dq = du + pdv
q12 = u 2 − u 1
q12 − w 12 = u 2 − u 1
w 12 = pΔv = pv 2 − pv1
∴ q12 = h 2 − h 1
dq = Tds
q12 = T (s 2 − s1 )
w 12 = q12 − Δu
dq = 0
ds = 0 ⇒ s1 = s 2
w 12 = Δu = u 2 − u 1
also
dw = pdv
p1 v1γ = p 2 v 2γ Figure (14): isotropic process
1
p1 v 1 − p 2 v 2
w 12 =
γ −1
At wet region ( γ ≈ 1.125 ) and at superheated region ( γ ≈ 1.3 ).
5) Polytrophic
processes: -
p1 v1n = p 2 v n2
p v − p2v2
w 12 = 1 1
n −1 Figure (15): polytropic process
p v − p2v2
q12 = (u 2 − u 1 ) + 1 1
n −1
Throttling process:-
2
Throttling process is highly irreversible
due friction loses. From steady flow energy
equation (SFEE)
q − w = Δh + Δp.e. + Δk.e.
q=0;w=0
Δp.e. = g(z 2 − z1 ) = 0
Figure 17: flow in throttling valve
Δk.e. = 0.5(C 22 − C12 ) = 0
∴ Δh = 0
i.e. h 2 = h 1
Throttling process is a constant
enthalpy process, which is an
adiabatic irreversible process.
Throttling process is
represented in p-v, T-s and h-s
diagrams as shown in figures (18),
(19) and (20).
3
Measurement of dryness fraction of wet steam
Throttling calorimeter:
Figure 21: throttling calorimeter, where throttling process is drawn on h-s diagram
h1 = h 2
h 1 = h f 1 + x 1h fg1
h − h f1
x1 = 2 , which is the dryness fraction of wert steam in the main.
h fg1
This method can be used only if ( x 1 ≥ 0.95 ), otherwise, the throttling
process is represented by process (3-4), which is not useful.
4
Separating and throttling calorimeter:-
5
p1 = p 2 ; And steam at (2) is still wet after separation but with less
moisture.
h 2 = h 3 = h f 1 + x 2 h fg1
h − h f1
x2 = 3
h fg1
m total = m1 + m 2
m 2 = m3
x 2m2
x1 =
m1 + m 2
Also from heat balance where the calorimeter is treated as a system, then:
m total * h 1 = m 1 h f 1 + m 2 h 2
m1 h f 1 + m 2 h 2
h1 =
m1 + m 2
h1 − h f 1
x2 =
h fg1
6
Non-steady flow energy equation:-
& 1 , u1
m & in
W
c1 , p 1
v1 , z 1 m ′, u ′
m ′′, u ′′ & 2,u2
m
&
Q c2 , p2
in
Figure 24: non-steady flow energy equation. v2 , z2
For the open system shown, the flow is non-steady. This means that
the entered mass of worked fluid and the entered energies to the open system
do not equal to exit mass and energies with time. The difference causes the
mass and the energy of the system to change.
& in + m ⎛ c ⎞
Energy Entering the System = Q & 1 ⎜ u 1 + 1 + gz1 + p1 v1 ⎟
⎝ 2 ⎠
& in + m ⎛ c ⎞
Energy Leaving the System = W & 2 ⎜ u 2 + 2 + gz 2 + p 2 v 2 ⎟
⎝ 2 ⎠
Increase of the Energy of System, E = E ′′ − E ′ = m ′′u ′′ − m ′u ′
&1 −m
m & ′′ − m
&2 =m &′
7
Application of steady flow energy equation:-
⎡& ⎛ c ⎞⎤ ⎡ & ⎛ c ⎞⎤
⎢Q in + m
& 1 ⎜ u 1 + 1 + gz 1 + p1 v1 ⎟⎥ − ⎢ Win + m
& 2 ⎜ u 2 + 2 + gz 2 + p 2 v 2 ⎟⎥ = 0
⎣ ⎝ 2 ⎠⎦ ⎣ ⎝ 2 ⎠⎦
q out = h 1 − h 2 q in = h 2 − h 1
b) Turbines and compressors:-
2
(
1 2
)
c 2 − c12 = h 1 − h 2 (
1 2
2
)
c1 − c 22 = h 2 − h 1
And nozzle efficiency is: And diffuser efficiency is:
c 22 p 2 − p1
ηN = ηD =
c′ 22 p 2 − p1
p 2 − p1 is pressure rise due to acual
c 2 is the final velocity due to actual
process.
process.
p ′2 − p1 is pressure rise due to isentropic
c′2 is the final velocity due to isentropic
process.
process
Isentropic efficiency:-
9
Steam cycles:-
Carnot cycle:-
Although Carnot cycle has the maximum possible efficiency, but its
work ratio is low. Furthermore the pump needed to pump water-steam
mixture from (4) to (1) is complex, expensive and consumes high work., so
it is impractical for steam power plants.
workout put
η carnot =
heat added
w
= net
q in
w out − w in
=
q in
w
work ratio = net
w out
1
Rankin cycle:-
Heat added:
q in = h 1 − h 4
Pump work:
w pump = h 4 − h 3
Heat rejected:
q out = h 2 − h 3
2
Net work out put:
dq = du + pdv = 0
dh = du + pdv + vdp
∫ dh = ∫ vdp ⇒ Δh = vΔp
w pump = v water (p b − p c )
Work ratio:
3
Specific steam consumption:
It is the amount of steam per unit time to produce one unit power. (s.s.c.) is
also a comparison criterion in steam power plants. The lower the value the
best the plant for the same output power. It gives a direct indication to the
relative size of the plant components.
m& s kg h
s.s.c. =
Pout kW
(m& s ) is steam mass flow rate in kilogram per hour required. However,
steam mass flow rate is usually measured in kilogram per second so it should
be multiply by (3600).
( Pout ) is output power in kilowatt.
& s * 3600
m
s.s.c. =
& s w net
m
3600 kg
=
w net kW.h
4
Influence of Steam Condition on Power Plant Performance:-
5
Rankine cycle with superheating:
h1 − h 2
ηR =
h1 − h 4
w net (h1 − h 2 ) − (h 4 − h 3 )
work ratio = =
w out h1 − h 4
3600 kg
s.s.c. =
w net kW.h
6
Rankine cycle with reheater:
w out = (h 1 − h 2 ) + (h 3 − h 4 )
w in = (h 6 − h 5 )
q in = (h 1 − h 6 ) + (h 3 − h 4 )
q out = (h 4 − h 5)
w w − w in
η R = net = out
q in q in
w
work ratio = net
w out
3600 kg
s.s.c. =
w net kW.h
7
Regenerative Rankine Cycle:
8
Regenerative Rankine Cycle with Open Feed Water Heater:
9
Regenerative Rankine Cycle with Closed Feed Water Heater:
For this cycle, no extra fee water pumps are needed. Moreover bled
steam pressure may not equal to incoming water since the open type is a heat
exchanger system and no mixing is occurred. There are two type of
(CFWH). They are :
h 5 + mh 7 = mh 6 + h 4
h − h4
m= 5
h6 − h7
w out = (h 1 − h 6 ) + (1 − m)(h 6 − h 2 )
w in = (h 4 − h 3 )
q in = (h 1 − h 5 )
q out = (1 − m)(h 2 − h 8 ) + (h 8 − h 3 )
10
Cascaded back ward closed feed water heater:
p 7 = p 8 = p bleed
h 7 from (h - s) chart .
h 4 = h 3 + w 34
t5 = t8
h8 ≈ h5
h 9 = h 8 + w 89
(1 − m)h 5 + mh 8 = mh 7 + (1 − m)h 4
h5 − h4
m=
h7 + h5 − h8 − h 4
h 6 = mh 9 + (1 − m)h 5
w out = (h 1 − h 6 ) + (1 − m)(h 6 − h 2 )
w in = (h 4 − h 3 )
q in = (h 1 − h 5 )
q out = (1 − m)(h 2 − h 8 ) + (h 8 − h 3 )
11
Example:
o
The thermal power plant shown operates between (10 MPa , 450 C ) and
( 0.035 bar ) . Draw (T-s) diagram and find plant performance.
12