BEC1(CHEM & PHY)

1. The system shown is in static equilibrium. Find W. c. 1500 N

2. What is the force in member AF? d. O
3. A ball is dropped from rest at a point 12 m above the ground into a smooth, frictionless chute.
The ball exist the chute 2 m above the ground and at angle 45o from the horizontal. Air
resistance is negligible. Approximately how far will the ball travel in the horizontal direction
before hitting the ground? a. 22 m
4. The structure shown is formed of three separate solid aluminum cylindrical rods, each with a
1 cm diameter. What is the -coordinate of the centroid of volume for the structure?
Select one: d. 14.0 cm
5. A projectile has an initial velocity of 110 m/s and a launch angle of 20o from the horizontal.
The surrounding terrain is level, and air friction is to be disregarded. What is the maximum
elevation achieved by the projectile? b. 72 m
6. What are R1 and R2? (insert question #11)a. 1250 N
7. What is the reaction at point Ab. O
8. A turntable capable of angularly accelerating at 12 rad/s2 needs to be given an initial angular
velocity if it is to rotate through a net 400 radians in 6 seconds. What must its initial angular
velocity be? b. 21 rad/s
9. A 550 kg mass initially at rest acted upon by a force of 50 et N. What are the acceleration,
speed, and displacement of the mass at t = 4 s?
a. 4.96 m/s2,4.87 m/s,19.5 m
10. A constant force of 750 N is applied through a pulley system to lift a mass of 50 kg as
shown. Neglecting the mass and friction of the pulley system, what is the acceleration of the 50
kg mass? a. 20.2 m/s2
11. A child keeps a 1 kg toy airplane flying horizontally in a circle by holding onto a 1.5 m long
string attached to its wing tip. The string is always in the plane of the circular flight path. If the
plane flies at 10 m/s, what is the tension in the string? d. 67 N
12. One newton is the force required to b. accelerate a 10 kg mass at a rate of 0.10 m/s2.
13. What is the approximate centroidal polar moment of inertia of the area? b. 25.6 cm4
14. A 4-A current is maintained in a simple circuit with a total resistance of 2 ?. How much
energy is delivered in 3 seconds d. 96J
15. In the pin-jointed truss shown, what is the force in member DE? c. O
16. Link AB of the linkage mechanism shown in the illustration rotates with an instantaneous
counterclockwise angular velocity of 10 rad/s. What is the instantaneous angular velocity of link
BC when link AB is horizontal and link CD is vertical? c. 12.5 rad/s (clockwise)
17. Why does a spinning ice skater's angular velocity increase as she brings her arms in toward
her body? c. Her mass moment of inertia is reduced.
18. A flywheel rotates at 7200 rev/min when the power is suddenly cut off. The flywheel
decelerates at a constant rate of 2.1 rad/s2 and comes to rest 6 min later. How many
revolutions does the flywheel make before coming to rest? c. 22 000 rev
19. Two 2 kg block are linked as shown. Assuming that the surfaces are frictionless, what is the
velocity of block B if block A is moving at a speed of 3 m/s?c. 5.20 m/s
20. Find the distance between position B and C. b. 10.1 m
21. A weekend plumber, unable to loosen a pipe fitting, slips a piece of scrap pipe (a "cheater")
over his wench handle. He then applies his full mass of 100 kg to the end of the cheater by
standing on it. The distance from the center of the fitting on the point where the weight acts is
0.80 m and the wrench handle and cheater make an angle of 19° with the horizontal. Find the
magnitude and direction of the torque he applies about the center of the pipefitting. a. 740 N
22. A 1530 kg car is towing a 300 kg trailer. The coefficient of friction between all tires and the
road is 0.80. How fast can the car and trailer travel around an unbanked curve of radius 200 m
without either the car or trailer skidding?a. 143 km/h
23. A rope passes over a fixed sheave as shown. The two rope ends are parallel. A fixed load
on one end of the rope is supported by a constant force on the other end. The coefficient of
friction between the rope and the sheave is 0.30. What is the ratio of tensile forces in the two
rope ends? a. 2.6
24. If the sum of the forces on a particle is not equal to zero, the particle is. c. accelerating in the
same direction as the resultant force.
25. What is the -coordinate of the centroid of the perimeter line? d. 1.80 cm
26. An angle bracket is subjected to the forces and couple shown. Determine the equivalent
force-couple system at point A
a. 292 N at -5.9o ; 103 N.m
27. In the figure, a very small toy race car of mass m is released from rest on the loop-the-loop
track. If it is released at a height 2R above the floor, how high is it above the floor when it leaves
the track, neglecting friction? c. 1.67 R
28. Find the acceleration of block A after the blocks are released. c. 1.4 m/s
29. Where can a couple be moved on a rigid body to have an equivalent effect? c. anywhere on
the rigid body
30. What is the reaction at point B? a. 20 000 N
31. Find the -and y-coordinates of the centroid of wire ABC d. 0.64 m ; 2.83 m
32. For a force to do work it must be ____ the displacement c. paralllel or antiparallel to
33. For which of the following situation is the net force acting on a particle necessarily equal to
zero? a. The particle has constant linear momentum.
34. A perfect sphere moves up a frictionless incline. Which of the following quantities increases?
a. potential energy
35. A single force (not shown) is applied at point B in the y-direction, in line with points A and B.
What should this force bein order for the frame to be in equilibrium in that direction?. d. -250 N
(down)
36. A cable passes over a stationary sheave and supports a 60 kg bucket, as shown. The
coefficient of friction between the cable abd the sheave is 0.10. The cable has a uniform mass
per unit length of 0.4 kg/m. The cable is in the shape of a catenary due to its own weight. The
tension of the cable at the pulley is given by T = wy, where w is the weight per unit length and
the constant y (for this configuration) is known to be 151 m. How much more mass can be
added to the4 bucket before the cable slips over the pulley?
a. 12.1 kg

37. The moment of inertia about the -axis of the cross section shown is 245833 cm4. If the
cross-sectional area is 250 cm2 and the thickness of the web and the flanges are the same,
what is the moment of inertia about the centroidal axis? a. 2.1 x 104 cm4
38. Assume that the centroidal moment of inertia of area A2 with respect to the composite
centroidal -axis is 73.94 cm4. The moment of inertia of area A2 with respect to the composite
centroidal horizontal axis is 32.47 cm4. What is the moment of inertia of the composite area with
respect to its centroidal -axis? a. 560 cm4
39. Find the tension, T, that must be applied to pulley A to lift the 1200 N weight.c. 100 N
40. What are the - and y-coordinates of the centroid of the area? d. 3.0 cm ; 3.8 cm
41. Determine the force in member FH for the pi-connected truss shown. d. 3840 N (tension)
42. What is the period of a pendulum that passes the center point 20 times a minute. c. 6 s
43. A 2kg block rests on 34o incline. If the coefficient of static friction is 0.2, how much
additional force, F, must be applied to keep the block from sliding down the incline? c. 7.7 N
44. A uniform rod (AB) of length L and weight W is pinned at point C. An initial impulse starts the
rod accelerating with an initial angular acceleration (in rad/s2) of g/L. What is the initial reaction
at point C? a. w/3
45. What is the radius of gyration about a horizontal axis passing through the centroid? a. 1.7
cm
46. A 153 kg car is towing a 300 kg trailer. The coefficient of friction between all tires and the
road is 0.80. The car and trailer are traveling at 100 km/h around a banked curve of radius 200
m. What is the necessary banking angle such that tire friction will not be necessary to prevent
skidding? c. 21o
47. A 47.2-kg child is standing on the outer edge of a merry-go-round that has moment of inertia
543 kg m2 and radius 2.40 m. The entire system is initially rotating at 0.180 rev/s. Find the
angular velocity if the child moves to a final position 1.10 m from the center of the merry-go-
round. c. 0.244 rev/s
48. A hollow cylinder has a mass of 2 kg, a height of 1 m, an outer diameter of 1 m, and an
inner diameter of 0.8 m. What is the cylinders mass moment of inertia about an axis
perpendicular to the cylinders longitudinal axis and located at the cylinders end? b. 0.87 kg m2
49. Rigid link AB is 12 m long. It rotates counterclockwise about point A at 12 rev/min. A thin
disk with radius 1.75 m is pinned at its center to the link at point B. The disk rotates
counterclockwise at 60 rev/min with respect to point B. What is the maximum tangential velocity
seen by any point on the disk? b. 28 m/s
50. A car is pulling a trailer at 100 km/h. A 5 kg cat riding on the roof of the car jumps from the
car to the trailer. What is the change in the cat's momentum? b. 0 N s
X51. What is the magnitude of the couple that exactly replaces the moment that is removed? a.
2.5 N m
52. Refer to a particle for which the position is defined by s(t) = 2 sin tj [tin radians]. What is the
magnitude of the particles velocity at t = 4 rad?
Select one: a. 3.30
53. A 2 kg mass swings in a vertical plane at the end of a 2 m cord. When = 30o, the
magnitude of the tangential velo9city of the mass is 1 m/s. What is the tension in the cord at this
position? c. 18.0 N
54. What total torque is applied to the pulley? b. 230 N m
55. A fisherman cuts his boats engine as it is entering a harbor. The boat comes to a dead stop
with its front end touching the dock. The fisherman's mass is 80 kg. He moves 5 m from his seat
in the back to the front of the boat in 5 s, expecting to be able to reach the dock. if the empty
boat has a mass of 300 kg, how far will the fisherman have to jump to reach the dock?
Select one: a. 1.3 m
56. A cannonball of mass 10 kg is fired from a cannon of mass 250 kg. The initial velocity of the
cannonball is 1000 km/h. All of the cannon's recoil is absorbed by a spring with a spring
constant of 250 N/cm. What is the maximum recoil distance of the cannon?
Select one: d. 0.77 m
57. The cylinder shown is acted on by couple M. Wall A is frictionless (&#181s = 0), but the
coefficient of static friction between the cylinder and wall B is &#181s = 0.3. The cylinder has a
weigh of 200 N. What is the largest value of the couple M for which the cylinder will not turn?
b. 31 N m
58. What is the polar radius of gyration? b. 4.9 m
59. Three concurrent forces act as shown.
If the forces are in equilibrium, and F2 is 11 N, what is the magnitude of F1? a. 10 N
60. If the car described in Prob.72 moves along a track that is banked 5o, what is the smallest
radius it can travel without skidding? c. 26 m
61. Find the force in member BC .c. 52 700 N (compression)
62. A projectile is fired from a cannon with an initial velocity of 1000 m/s and at an angle of 30o
from the horizontal. What distance from the cannon will the projectile strike the ground if the
point of impact is 1500 m below the point of release? a. 90 800 m
63. Quantity of inertia possessed by an object or the proportion between force and acceleration
Select one: a. Mass
64. A varying force acts on a 40 kg weight as shown in the following force versus time diagram.
What is the object's velocity at t = 4 s if the object start from c. 0.15 m/s
65. A I kg uniform rod 1 m long is suspended from the ceiling by a frictionless hinge. The rod is
free to pivot. What is the product of inertia of the about the pivot point? a. 0 kg m2
66. Three forces act on a hook. Determine the magnitude of the resultant of the forces. Neglect
hook bending. c. 1510 N
67. The support force exerted on an object in contact with another stable object a. Normal force
68. Refer to a particle whose curvilinear motions is represented by the equation s = 20t + 4t2 -
3t3. What is particles initial velocity?
b. 20 m/s
69. What is the tension in cable AB? d. 500 N
70. A 100 kg block is pulled along a smooth, flat surface by an external 500 N force. If the
coefficient of friction between the block and the surface is 0.15, what acceleration is
experienced by the block due to the external force? b. 3.23 m/s2

71. A motorist is travelling at 70 km/h when he sees a traffic light in an intersection 250 m ahead
turn red. The light's red cycle is 15 s. The motorist wants to enter the intersection without
stopping his vehicle, just as the light turns green. What uniform deceleration of the vehicle will
just put the motorist in the intersection when the light turns greens? c. 0.37 m/s2
72. The nuts on a collar are each tightened to 18 N m torque. 17% of this torque is used to
overcome screw thread friction. The bolts have a nominal diameter of 10 mm. The threads are a
simple square cut with a pitch angle of 15o. The coefficient of friction in the threads is 0.10.
What is the approximate tensile force in each bolt? b. 1620 N
73. During the time a compact disc (CD) accelerates from rest to a constant rotational speed of
477 rev/min, it rotates through an angular displacement of 0.250 rev. What is the angular
acceleration of the CD b. 794 rad/s2
74. A 6.0-kg block is released from rest 80m above the ground. When it has fallen 60m its
kinetic energy is approximately:
Select one: c. 3528 J
75. A particle starting from rest experienced an acceleration of 3 m/s2 for 2 s. The particle then
returned to rest in a distance of 8 m. Assuming all accelerations were uniform, what was the
total time elapsed for the particles motion? b. 4.67 s
76. A rope passes over a fixed sheave as shown. The two rope ends are parallel. A fixed load
on one end of the rope is supported by a constant force on the other end. The coefficient of
friction between the rope and the sheave is 0.30. What is the ratio of tensile forces in the two
rope ends? d. 2.6
77. In an isolated system it does not change with time when there are no forces acting on the
system c. momentum
78. The coefficient of friction between the brake pad and drum is 0.3. Assuming that the beam
supporting the cable drum is more than adequate for the loads involved, what load,W, can be
held stat5ionary?(Insert question #12)b. 180 N
79. The elevator in a 12-story building has a mass of 1000 kg. Its maximum velocity and
maximum acceleration are 2 m/s and 1 m/s2, respectively. A passenger with a mass of 75 kg
stands on a bathroom scale in the elevator as the elevator ascends at its maximum
acceleration. What is the scale reading just as the elevator reaches its maximum velocty? d.
811 N
80. The braced frame shown is constructed with pin-connected members and supports. All
applied forces are horizontal. What is the force in the diagonal member AB?(Insert question
#10)b. 250 N
81. An automobile travels on a perfectly horizontal, unblanked circular track of radius r. The
coefficient of friction between the tires and the track is 0.3. If the car's velocity is 10 m/s, what is
the smallest radius it may travel without skidding? c. 34 m
82. A 10 kg block is resting on a horizontal circular disk (e.g., turntable) at a radius of 0.5 m form
the center. The coefficient of friction between the block and disk is 0.2. the disk begins to rotate
with a uniform angular acceleration. What is the minimum angular velocity of the plate that will
cause the block to slip? b. 1.98 rad/s
83. A rigid body is subjected to three concurrent, coplanar forces. What is the minimum number
of independent equations that are necessary to establish the equilibrium conditions? b. 2
84. Two meshing spur gears are arranged such that neither gear is turning and both are in
equilibrium. Gear 1 has a radius of 4 cm. Gear 1's shaft carries a torsional moment of 65 N m
from an external motor. Gear 2 has a radius of 6 cm. Assuming a 100% transmission efficiency,
what torque is transmitted by the shaft of gear 2?a. 97.5 N m
85. Determine the force in member AG for the pin-connected truss shown .a. 37 500 N (tension)
86. What are the -and y-coordinates of the centroid of the area? b. 3.93 cm ; 4.79 cm
87. An ideal spring is hung vertically from the ceiling. When a 2.0-kg block hangs at rest from it
the spring is extended 6.0 cm from its relaxed length. A upward external force is then applied to
the block to move it upward a distance of 16 cm. While the block is moving upward the work
done by the spring is c. -1.05 J
88. Refer to a particle for which the position is defined by s(t) = 2 sin tj [tin radians]. What is the
magnitude of the particle's acceleration at t = p?c. 4.00
89. A satellite is placed in a circular orbit to observe the surface of Mars from an altitude of 144
km. The equatorial radius of Mars is 3397 km. If the speed of the satellite is 3480 m/s, what is
the magnitude of the centripetal acceleration of the satellite? c. 3.42 m/s2
90. A motorist is travelling at 70 km/h when he sees a traffic light in an intersection 250 m ahead
turn red. The light's red cycle is 15 s. The motorist wants to enter the intersection without
stopping his vehicle, just as the light turns green. What uniform deceleration of the vehicle will
just put the motorist in the intersection when the light turns greens? a. 0.37 m/s2
91. The location of a particle moving in the -y plane is given by the parametric equations = t2 +
4t and y =(1/4)t4 - 60t, where and y are in meters and t is in seconds. What Is the particles
velocity at t = 4 s? d. 12.6 m/s
92. The two cables shown carry a 100 N vertical load. What is the tension in cable AB? b. 60 N
93. The pedestrian bridge truss shown has 10 000 N applied loads at points I,J, and K. What is
the force in member IJ? a. 18 000 N (compression)
94. A projectile whose mass is 10 g is fired directly upward from ground level with an initial
velocity of 1000 m/s. Neglect the effects of air resistance, what will be speed of the projectile
when it impacts the ground? c. 1000 m/s
95. The 285 kg plate shown is suspended horizontally by four wires of equal length, and the
tension of each wire is equal. If wire D snaps, the tension in the three remaining wires is
redistributed. Determined the tension in each wire after wire D snaps.
e. TA = 699 N ; TB = 1398 N ; TC = 699 N
96. Identify the zero-force members in the truss shown. a. AB,GH,GI,HI,EG
97. Three coplanar forces are in equilibrium on the surface of a steel plate, as shown. Two of
the forces are known to be 10 N. What is the angle, , of the third force? a. 82.5o
98. A signal arm carries two traffic signals and a sign, as shown. The signals and sign are rigidly
attached to the arm. Each traffic signal is 0.2 m2 in frontal area and weighs 210 N. The sign
weighs 60 N/m2. The design wind pressure is 575 N/m2. The maximum moment that the
connection between the arm and pole can withstand due to wind is 6000 N m , and the
maximum permitted moment due to the loads is 4000 N m. As limited by moment on the
connection, what is the maximum area of the sign? d. 1.04 m2
99. A uniform thin disk has a radius of 30 cm and a mass of 2 kg. A constant force of 10 N is
applied tangentially at a varying, but unknown, distance from the center of the disk. The disk
accelerates about its axis at 3t rad/s2. What is the distance from the center of the disk at which
the force is applied at t = 12 s? b. 32.4 cm
100. Four bolts (not shown) connect support A to the ground. Determine the design load for
each of the four bolts.
b. 50 000 N (tension)
101. A projectile has an initial velocity of 110 m/s and a launch angle of 20o from the horizontal.
The surrounding terrain is level, and air friction is to be disregarded. What is the horizontal
distance traveled by the projectile? c. 800 m
102. Figure shows a uniform disk, with mass M = 2.5 kg and radius R = 20 cm, mounted on a
fixed horizontal axle. A block with mass m = 1.2 kg hangs from a massless cord that is wrapped
around the rim of the disk. Find the acceleration of the falling block. The cord does not slip, and
there is no friction at the axle. a. -4.8 m/s2
103. Find the velocity of block A 2.5 s after the blocks are released. a. 3.5 m/s
104. A box has uniform density and a total weight of 600 N. It is suspended by three equal-
length cables, AE,BE, and CE, as shown. Point E is 0.5 m directly above the center of the box's
top surface. What is the tension in cable CE? d. 370 N
105. The five forces shown act at point A. What is the magnitude of the resultant force? a. 234
N
106. Determine the reaction at point C. b. + 83 N (down)
107. A 50 kg cylinder has a height of 3 m and a radius of 50 cm. The cylinder sits on the -axis
and is oriented with its major axis parallel to the y-axis. What is the mass moment of inertia
about the -axis? c. 150 kg mo
108. A rope is wrapped over a 6 cm diameter pipe to support a bucket of tools being lowered.
The coefficient of friction between the rope and the pipe is 0.20. The combined mass of bucket
and tools is 100 kg. What is the range of force that can be applied to the free end of the rope
such that the bucket remains stationary? d. 670 N to 1440 N
109. A model T-beam is constructed from five balsa boards. Refer to the illustration for the as-
built dimensions. What is the approximate centroidal moment of inertia about an axis parallel to
the -axis? d. 560 cm4
110. A 3 kg disk with a diameter of 0.6 m is rigidly attached at point B to 1 kg rod 1 m in length.
The rod-disk combination rotates around point A. What is the mass moment of inertia about A
for the combination d. 3.7 kg m2
111. A 2.5-kg ball and a 5.0-kg ball have an elastic collision. Before the collision, the 2.5-kg ball
was at rest and the other ball had a speed of 3.5 m/s. What is the kinetic energy of the 2.5-kg
ball after the collision?_____" a. 27 J
112. A spring has a constant of 50 N/m. The spring is hung vertically, and a mass is attached to
its end. The spring end displaces 30 cm from its equilibrium position. The same mass is
removed from the first spring and attached to the end of a second (different) spring, and the
displacement is 25 cm. What is the spring constant of the second spring? c. 60 N/m
113. What is the polar moment of inertia about the composite centroid? c. 2410 m4
114. An area is a composite of a semicircle and a triangle, as shown. What is the distance
between the -axis and the centroid?d. 4.28 mm
115. Find the velocity at position B .a. 9.83 m/s
116. In the structure shown, the beam is pinned at point B. Point E is a roller support. The beam
is loaded with a distributed load from point A to point B of 400 N/m, a 500 N m couple at point C,
and a vertical 900 N force at point D. If the distributed load and the vertical load are removed
and replaced with a vertical upward force of 1700 N at point F, what moment at point F would be
necessary to keep the reaction at point E at the same? b. 12 000 N m (clockwise)
117. What is the magnitude of the forces that constitute the moment? d. 2.1 N
118. A 28 mm diameter circuit area is reduced by a 21 mm diameter circular area that is cut out.
Both circles are tangent to the y-axis. What is the moment of inertia about the y-axis of the
remaining (shaded) area? a. 103 000 mm4
119. What is the coefficient of friction between the plane and the block? b. 0.78
120. Two blocks are connected over a pulley. The mass of block A is 10 kg and the coefficient
of kinetic friction between A and the incline is 0.20. Angle ? of the incline is 30°. Block A slides
down the incline at constant speed. What is the mass of block Bd. 3.3 kg
121. The center of gravity of a roller coaster car is 0.5 m above the rails. The rails are 1 m part.
What is the maximum speed that the car can travel around an unbanked curve of radius 15 m
without the inner wheel losing contact with the top of the rail? d. 12.1 m/s
122. Two particles are fixed to an x axis : particle 1 of charge -2.00 x 10-7 C at x=6.00 cm and
particle 2 of charge +2.00 x 10-7 C at x=21.0 cm. Midway between the particles, what is their
net electric field in unit vector notation? b. -6.39 x 105 N/C i ^
123. Find the force in member DE. a. 8800 N (tension)
124. A force is defined by the vector A = 3.5 i - 1.5 j + 2.0k. i, j, and k are unit vectors in the -,y-,
and z-direction, respectively. What is the angle that the force makes with the positive y-axis? c.
110o
125. The position (in radians) of a car travelling around a curve is described by the following
function of time (in seconds). What is the angular velocity at t = 3 s? d. 11 rad/s
126. A stone is dropped down a well. 2.47 s after the stone is released, a splash is heard. If the
velocity of sound in air is 342 m/s, find the distance to the surface of the water in the well. c. 28
m
127. The maximum kinetic and potential energy of a spring when stretched at various
displacements is equal to a. 1 /2Kx2
128. A car with a mass of 1530 kg tows a trailer (mass of 200 kg) at 100 km/h. What is the total
momentum of the car-trailer combination?
d. 48 000 N s
129. If W = 80 N, what are the reactions
at pont A? b. -27 i N - 100j N
130. A parallel-plate air capacitor is made from two plates 0.070 m square, spaced 6.3 mm
apart. What must the potential difference between the plates be to produce an energy density of
0.037 J/m3d. 570 V
131. Block d side freely on the homogeneous bar and experiences a gravitation force of 50 N.
Homogeneous bar AB experiences a gravitational force of 25 N. What is the force between the
bar and block D? d. 28 N
132. A motorist is travelling at 70 km/h when he sees a traffic light in an intersection 250 m
ahead turn red. The light's red cycle is 15 s. The motorist wants to enter the intersection without
stopping his vehicle, just as the light turns green. If the vehicle decelerates at a constant rate of
0.5 m/s2, what will be its speed when the light turns green? c. 43 km/h
133. Which of the structures shown is statically determinant and stable? c. I only

134. The rotor of a steam turbine is rotating at 7200 rev/min when the steam supply is suddenly
cut off. The rotor decelerates at a constant rate and comes to rest after 5 min. What was the
angular deceleration of the rotor? a. 2.5 rad/s2
135. A 6 kg sphere moving at 3m/s collides with a 10 kg sphere traveling 2.5 m/s in the same
direction. The 6 kg ball comes to a complete stop after the collision. What is the new velocity of
the 10 kg ball immediately after the collision? d. 4.3 m/s
136. Which type of load is not resisted by a pinned joint? b. moment
138. If the frame is pinned so that it rotates around point B, what counteracting moment must be
applied at point A to put the frame in equilibrium? b. 1240 N m
140. An isolated parallel-plate capacitor (not connected to a battery) has a charge of Q = 2.9 ×
10-5 C. The separation between the plates initially is d = 1.2 mm, and for this separation the
capacitance is 3.1 × 10-11 F. Calculate the work that must be done to pull the plates apart until
their separation becomes 5.3 mm, if the charge on the plates remains constant. The capacitor
plates are in a vacuum b. 46 J
141. A wheel with a radius of 80 cm rolls along a flat surface at 3 m/s. If arc AB on the wheels
perimeter measures 90o, what is the velocity of point A when point B contacts the ground? c.
4.24 m/s
142. A disk-shaped boy with a 4 cm radius has a 320 N force acting through the center at an
unknown angle , and two 40 N loads acting as a couple, as shown. All of these forces are
removed and replaced by a single 320 N force at point B, parallel to the original 320 N force.
What is the angle ?c. 15o
143. A block with a mass of 150 kg is pulled over a horizontal surface by a cable guided by a
pulley as shown. The coefficients of friction are 0.58 between the surface and the block, and
0.90 between the cable and the pulley. What force, F, must be applied to the cable for the block
to move? d. 2200 N
144. Refer to a particle whose curvilinear motions is represented by the equation s = 20t + 4t2 -
3t3. What is the acceleration of the particle at time t = 0? d. 8 m/s2
145. A playground merry-go-round has a radius of 3.0m and a rotational inertia of 600 kg m2.It
is initially spinning at 0.80 rad/s when a 20-kg child crawls from the center to the rim. When the
child reaches the rim the angular velocity of the merry-go-round is d. 0.62 rad/s
146. Traffic travels at 100 km/h around a banked high-way curve with a radius of 1000m. What
banking angle is necessary such that friction will not be required to resist the centrifugal force?
c. 4.5o
147. Resolve the 300 N force into two components, one along line p and the other along line Q.
(F, P and Q are coplanar.)
b. Fp = 226 N ; FQ = 135 N

148. Determine the force in member BC .b. 2500 N (tension)

149. The statement An object with constant momentum is in a state of equilibrium is d. True
150. The velocity (in m/s) of a falling ball is described by the equation v = 32 + t + 6t2. What Is
the acceleration at time t = 2 s?
a. 25 m/s2
151. A particle has a tangential acceleration of at (represented by the equation given) when it
moves around a point in a curve with instantaneous radius of 1 m. What is the instantaneous
angular velocity ( in rad/s) of the particle? d. t2+cost+ 3 In |sint|
152. A golfer on level ground attempts to drive a golf ball across a 50 m wide pond, hitting the
ball so that it travels initially at 25 m/s. The ball travels at an initial angle of 45o to the horizontal
plane. How far will the golf ball travel, and does it clear the pond?
d. 64 m ; the ball clears the pond
153. A 2000 kg car pulls a 500 kg trailer. The car and trailer accelerates from 50 km/h to 75
km/h at rate of 1 m/s2. What linear impules does
b. 3470 N s
154. What are R1 and R2? (insert question #11)
g. 3750 N; R2 /
155. Two blocks are connected over a pulley. The mass of block A is 10 kg and the coefficient
of kinetic friction between A and the incline is 0.20. Angle ? of the incline is 30°. Block A slides
down the incline at constant speed. What is the mass of block Bb. 3.3 kg
156. A mass of 10 kg is suspended from a vertical spring with a spring constant of 10 N/m.
What is the period of vibration?
a. 6.3 s

157. What is the reaction at point A for the simply supported beam shown? woL/2
158. A bent beam is acted upon by a moment and several concentrated forces, as shown. Find
the missing force F and distance that will maintain equilibrium on the member shown.a. F = 20
N ; = 0.2 m
159. A car travels around an unbanked 50 m radius curve without skidding. The coefficient of
friction between the tires and road is 0.3. What is the car's maximum speed? c. 44 km/h
160. A force that is directed away or towards the origin c. Central force
161. The small piston of a hydraulic lift has a cross-sectional area of 3.00 cm2, and its large
piston has a cross-sectional area of 200 cm2 . What force must be applied to the small piston
for it to raise a load of 15.0 kN? (In service stations, this force is usually generated with the use
of compressed air.) d. 225 N
162. A disk rolls along a flat surface at a constant speed of 10 m/s. Its diameter is 0.5 m. At a
particular instant, point P on the edge of the disk is 45o from the horizontal. What is the velocity
of point P at that instant? b. 18.5 m/s

163. For the reciprocating pump shown, the radius of the crank is r = 0.3 m, and the rotational
speed is n = 350 rpm. What is the tangential velocity of point A on the crank corresponding to
an angle of = 35o from the horizontal? d. 11 m/s
164. What is the -coordinate of the centroid of the curve y = cos between = 0 = /2? c. 1 2/pi
165. Two particles are fixed to an x axis : particle 1 of charge -2.00 x 10-7 C at x=6.00 cm and
particle 2 of charge +2.00 x 10-7 C at x=21.0 cm. Midway between the particles, what is their
net electric field in unit vector notation? a. -6.39 x 105 N/C i ^
166. Refer to a particle whose curvilinear motions is represented by the equation s = 20t + 4t2 -
3t3. What is the maximum speed reached by the particle? d. 21.8 m/s
167. A torsional pendulum consists of a 5 kg uniform disk with a diameter of 50 cm attached at
its center to a rod 1.5 m in length. The torsional spring constant is 0.625 N.m/rad. Disregarding
the mass of the rod, what is the natural frequency of the torsional pendulum? d. 2.0 rad/s
168. The position (in radians) of a car travelling around a curve is described by the following
function of time (in seconds). What is the angular acceleration at t = 5 s? b. 26 rad/s2
** 2.0 rad/s"A torsional pendulum consists of a 5 kg uniform disk with a diameter of 50 cm
attached at its center to a rod 1.5 m in length. The torsional spring constant is 0.625 N.m/rad.
Disregarding the mass of the rod, what is the natural frequency of the torsional pendulum?"
** 3.0 cm ; 3.8 cm What are the - and y-coordinated of the centroid of the perimeter line?
** 12m "If the angle of inclination is 45°, how far has the block traveled after 4 s?"
=====================================================================

CHEM
***2.9 L "When active metals such as magnesium are immersed in acid solution, hydrogen gas
is evolved. Calculate the volume of H2(g) at 30.1°C and 0.85 atm that can be formed when 275
mL of 0.725 M HCI solution reacts with excess Mg to give hydrogen gas and aqueous
magnesium chloride."
***0.0164 M A 250. mL sample of 0.0328 M HCI is partially neutralized by the addition of 100.
mL of 0.0245 M NaOH. Find the concentration of hydrochloric acid in the resulting solution.
***110 A solution is adjusted from pH 8 to pH 9. The relative concentration of the hydrogen [H?]
ion has changed by a factor of what?
***Mg is the reducing agents; O2 is the oxidizing agent. "In the following reaction, which
elements are the reducing and oxidizing agents?"
***H (hydrogen) Which of the following elements has the largest first ionization energy?
***Upper right. The elements that display the greatest non-metallic character are located toward
which corner of the periodic table?
***2. An atom has eight electrons in a 3d subshell. How many orbitals in this subshell have an
unpaired electron?
***alkali metals. "The group of metals that includes lithium, sodium, potassium, rubidium, and
cesium forms a closely related family known as the"
***a mole. What is the term for a quantity of a substance to which a chemical formula can be
assigned and whose mass is equal to its formula weight?
***accelerating in the same direction as the resultant force.. "If the sum of the forces on a
particle is not equal to zero, the particle is"
***Normal force. The support force exerted on an object in contact with another stable object
***0 What is the reaction at point A?
***0 kg m². A 1 kg uniform rod 1 m long is suspended from the ceiling by a frictionless hinge.
The rod is free to pivot. What is the product of inertia of the about the pivot point?
***1.7 cm What is the radius of gyration about horizontal axis passing through the centroid?
***the remaining portion of an alkane after it loses a hydrogen atom. An alkyl radical is best
defined as
***"AI(NO3)3,Mg(OH)2,CaO,CuCO3" "What are the chemical formulas for the following
compounds: aluminum nitrate, magnesium hydroxide, calcium oxide, and cupric carbonate?"
***always increases. "As the pressure of a gas increases, the solubility of that gas in a liquid"
***valence electrons "Assuming the ground state, all of the elements located in the group 12 of
the periodic table will have the same number of"
***Liquid to solid is called freezing. Which phase change is described correctly?
***different by about 11.2 L. At STP the volume of 1.5 mole N2as compared to 1.0 mole O2 is
***2.27 m. A copper wire has a diameter of 2.00 mm. What length of this wire contains exactly
1.00 mol of copper? [Given: density of Cu = 8.92 g/cm3]
***2.1x109 kg "Americans combined drive about 4.0x109 miles per day and their vehicles get an
average of 20 miles per gallon of fuel used. For each 1kg of gasoline that is burned, about 3.0kg
of carbon dioxide are produced. How many kilograms of CO2 are emitted into the atmosphere
each day by cars in the U.S.? One gallon of gas weighs about 3.5 kg."
***70 g/ mol. 6 g of a substance are dissolved in 1000 g of water. The solution freezes at
-0.16°C. What is the molecular weight of the substance?
***160 kg "Hydrogen and chlorine gas combine in a 35 m3 reaction vessel to produce hydrogen
chloride. The masses of hydrogen and chlorine are 4.5 kg and 160 kg, respectively. How much
hydrogen chloride gas is produced?"
***moment. Which type of load is not resisted by a pinned joint?
***2. "A rigid body is subjected to three concurrent, coplanar forces. What is the minimum
number of independent equations that are necessary to establish the equilibrium conditions?"
***6 s. What is the period of a pendulum that passes the center point 20 times a minute?
***100 N. Find the tension, T, that must be applied to pulley A to lift the 1200 N weight.
***parallel or antiparallel to. For a force to do work it must be ____ the displacement
***0. What us the force in member AF?
***1.3 x 10-3. It has been determined that 1.0 L of solution contain 52.7 g H2SO4, 240.8 g
KMnO4, 11.3 g K2SO4, and 5.5 g Mn2O7. The reaction equation is The molecular weights of
the compounds are What is the equilibrium constant for the reaction?
***N². "An ideal gas occupies a volume of 4L and has a pressure of 283.71kPa
(1atm=101.325kPa). Under 22.5°C, what most likely is the identity of the gas if 0.01293 Kg of
gas is used."
***4.2 x 10² cm3 "How many cubic centimeters of ore containing 0.22% by mass gold must be
processed to obtain $100 worth of gold? The density of the ore is 8.0 g/cm3 and the price of
gold is $418 pre troy ounce. (14.6 troy oz = 1.0 ordinary pound, called an avoirdupois pound;
1lb = 454g)"
***The water momentarily stops boiling. Which of the following occurs when table salt (NaCI) is
added to continuously heated boiling water?
***second order with respect to E; second order overall. What is the order of reaction with
respect to reactant E and the overall order of the reaction described by the following rate law?
***12.00 grams of ^12 C. The mole (mol) is the amount of a substance that contains as many
elementary entities as there are atoms in exactly
***Rb / Rb1- Which atom is not paired with its correct ion and ionic charge?
***Raise the temperature and add more water "Consider a solution of water and a nonvolatile
solute at some temperature. What combination of conditions would be sure to increase the
vapor pressure of the solution? _____"""
***0.107 What is the molarity of a solution obtained by dis-solving 25 g of NaCI in enough water
to produce 4 L of solution?
***0.33 What is the gravimetric (i.e.m.,mass) percentage of oxygen in K2CrO4?
***3 The pH of a 0.001 M HCI solution is
***6 What is the oxidation number for chromium (Cr) in the compound BaCro?
***its vapor pressure is equal to the surrounding pressure A liquid will boil when
***740 N "A weekend plumber, unable to loosen a pipe fitting, slips a piece of scrap pipe (a
""cheater"") over his wench handle. He then applies his full mass of 100 kg to the end of the
cheater by standing on it. The distance from the center of the fitting on the point where the
weight acts is 0.80 m and the wrench handle and cheater make an angle of 19° with the
horizontal. Find the magnitude and direction of the torque he applies about the center of the
pipefitting."
***Calorie and joule. Which units could be used to express the account absorbed or released
during chemical reaction?
***different arrangement of the same atoms. What is an isomer?
***0.067 What is the percentage (by mass) of hydrogen in glucose (C6H12O6)?
***ester. What family of compounds is produced from the reaction between an alcohol and a
carboxylic acid?
***ester. What family of compounds is produced from the reaction between an alcohol and a
carboxylic acid?
***1.12 L Calculate the volume of H2(g) at 273 K and 2.00 atm that will be formed when 275 mL
of 0.725 M HCI solution reacts with excess Mg to give hydrogen gas and aqueous magnesium
chloride
***0.85 "A 2.50-L flask contains a mixture of methane (CH2) and propane (C3H8) at a pressure
of 1.45 atm and 20°C.When this gas mixture is then burned in excess oxygen, 8.60g of carbon
dioxide is formed.(The other product is water.)What is the mole fraction of methane in the
original gas mixture?"
***0 kcal/ mol How much energy is needed to convert ozone to oxygen?
***becomes moist "When a deliquescent substance is exposed to air, it"
***1. In period 3 of the periodic table the atom with the largest atomic radius is located in group
***Protons and electrons. Uranium-235 and uranium-238 have the same number of which of the
following?
***Pure iron is a heterogeneous mixture. Which sentence below is incorrect?
***CO2(g) Which sample demonstrate particles arranged in regular geometric pattern?
***7.7 N A 2 kg block rests on 34° incline. If the coefficient of static friction is 0.2, how much
additional force F, must be applied to keep the block from sliding down the incline?
***4.00 Refer to a particle for which the position is defined by s(t) = 2 sin tj [tin radians]. What is
the magnitude of the particle's acceleration at t = p?
***28 m "A stone is dropped down a well. 2.47 s after the stone is released, a splash is heard. If
the velocity of sound in air is 342 m/s, find the distance to the surface of the water in the well."
***22 m A ball is dropped from rest at a point 12 m above the ground into a smooth, frictionless
chute. The ball exist the chute 2 m above the ground and at angle 45° from the horizontal. Air
resistance is negligible. Approximately how far will the ball travel in the horizontal direction
before hitting the ground?
***Concentration have no effect on the direction of the reaction. Which of the following
statements concerning reversible reactions is false?
***64.9 g "How many grams of glucose, C6H12O6, are necessary to prepare 656 mL of a
solution with a concentration that is 0.550 molar? _____"""
***3528 J. A 6.0-kg block is released from rest 80m above the ground. When it has fallen 60m
its kinetic energy is approximately:
***2.19 L An object will float at the surface of a liquid if the mass of the object is less than the
mass of the liquid that it displaces. A spherical vessel (diameter =2.00 cm) when empty has a
mass of 2.00 g. What is the greatest volume of water that can be placed in the vessel and still
have the vessel float at the surface of the water? (Given: density of water = 1.00
***1.42 g What is the mass of 0.01 gram-moles of Na2SO4?
***22.8 torr "What is the vapor pressure of 1000.0 g of a water solution at 25°C that contains
124.0 g of the nonvolatile solute ethylene glycol, C2H6O2? The vapor pressure of pure water at
this temperature is 23.76 torr. Assume an ideal solution"
***8490 L "The mole fraction of oxygen molecules in dry air is 0.2029.What volume of dry air at
1.00 atm and 25°C is required for burning 1.00 L of hexane (C6H14, density = 0.660 g/mL)
completely, yeilding carbon dioxide and water?"
***21 rad/s A turntable capable of angularly accelerating at 12 rad/s2 needs to be given an initial
angular velocity if it is to rotate through a net 400 radians in 6 seconds. What must its initial
angular velocity be?
***2.6 A rope passes over a fixed sheave as shown. The two rope ends are parallel. A fixed load
on one end of the rope is supported by a constant force on the other end. The coefficient of
friction between the rope and the sheave is 030. What is the ration tensile forces in the two rope
ends?
***52 700 N (compression)...
***3.93 cm ; 4.79 cm...
***3470 N s A 2000 kg car pulls a 500 kg trailer. The car and trailer accelerates from 50 km/h at
rate of 1 m/s2. What linear does the car impart on the trailer?
2***200 N A block whit a mass of 150 kg is pulled over a horizontal surface by a cable guided by
a pulley as shown. The coefficient of friction are 0.58 between the surface and the block, and
0.90 between the cable and the pulley. What force F must be applied to the cable for the block
to move?
***32 mg What mass of lead nitrate, Pb(NO3)2, must be dis-solved in 1 L of water to produce a
solution that contains 20 mg of lead ions? Assume 100% ionization.
***4.5 g/cm3 "The radius of the Earth is approximately 6370 km. If one could dig down straight
towards the center of the Earth, one would find that the innermost 3480 km (the core) has an
average of density of about 11 g/cm3. Above that are the mantle and crust. If the average
density of the Earth is 5.5 g/cm3, what is the average density of the Earth's mantle and crust?
(Recall that the volume of a sphere is given V=(4/3)?r3.)"
***1s²2s²3s1 Which electron configuration demonstrates an atom in the excited state?
***0.77 m A cannonball of mass 10 kg is fired from a cannon of mass 250 kg. The initial velocity
of the cannonball is 1000 km/h. All of the cannon's recoil is absorbed by a spring with a spring
constant of 250 N/cm. What is the maximum recoil distance of the cannon?
***-27 i N - 100j N If W = 80 N, what are the reactions at point A?
***21° A 153 kg car is towing a 300 kg trailer. The coefficient of friction between all tires and the
road is 0.80. The car and trailer are traveling at 100 km/h around a banked curve of radius 200
m. What is the necessary banking angle such that tire friction will not be necessary to prevent
skidding?
***+ 83 N (down) Determine the reaction at point C.
***potential energy A perfect sphere moves up a frictionless incline. Which of the following
quantities increases?
***20 000 N What is the reaction at point B?
***accelerate a 10 kg mass at a rate of 0.10 m/s²....
***0 In the pin-jointed truss shown, what is the force in member DE?
***10 N Three concurrent forces act as shown.
***[Xe]6s25d104f146p2. Which of the following is the correct electron configuration of Pb?
***More ammonia (NH3) would be generated. "Given the following reversible chemical reaction,
assume all reactants and products are ideal gases."
***14 L A transportation company specializes in the shipment of pressurized gaseous materials.
An order is received for 100 L of a particular gas at STP (0°C and 1 atm). What minimum
volume tank is necessary to transport the gas at 25°C and a maximum pressure of 8 atm?
***0.1 g "The solubility constant of stronyium sulfate, SrSO4, is 2.8 x 10-7. How many grams of
SrSO4 must be dissolved in water to produce 1 L saturated solution?"
***4.3 m/s. A 6 kg sphere moving at 3 m/s collides with a 10 kg sphere traveling 2.5 m/s in the
same direction. The 6 kg ball comes to a complete stop after the collision. What is the new
velocity of the 10 kg ball immediately after the collision?
***8 m/s2. Refer to a particle whose curvilinear motions is represented by the equation s = 20t +
4t2 - 3t3. What is the acceleration of the particle at time t = 0?
***"A 2.5-kg ball and a 5.0-kg ball have an elastic collision. 27 J...
***18.0 N A 2 kg mass swings in a vertical plane at the end of a 2 m cord. When 30°, the
magnitude of the tangential velocity of the mass is 1 m/s. What is the tension in the cord at this
position?
***1/2 Kx². The maximum kinetic and potential energy of a spring when stretched at various
displacements is equal to
***nitrogen, and 3 kg of xenon. What is the mole fraction of the oxygen gas?"
***0.24 "A gaseous mixture consists of 2 kg of oxygen, 5 kg of ...
***63 . 2.00 g of a substance dissolved in 250 g of water produces a boiling point elevation of
0.065°C. What is the molecular weight of the substance?
***Bases have a sour taste. Which of the following statements pertaining to acids and bases is
incorrect?
***Mn3O4. "The mineral hausmannite is a compound of manganese-55 and oxygen-16. If 72%
of the mass of hausmannite is due to manganese, what is the empirical formula of
hausmannite?"
***I only. Which of the structures shown is statistically determinant and stable?
***accelerate a 10 kg mass at a rate of 0.10 m/s². One newton is the force required to
***8800 N (tension). Find the force in member DE.
***44 km/h. A car travels around an unbanked 50 m radius curve without skidding. The
coefficient of friction between the tires and road is 0.3. What is the car's maximum speed?
***Mass. Quantity of inertia possessed by an object or the proportion between force and
acceleration
***anywhere on the rigid body. Where can a couple be moved on a rigid body to have an
equivalent effect?
***230 N m. What total torque is applied to the pulley?
***153 g. "A sample of mercury(II) oxide is placed in a 5.00 L evacuated container and heated
until it decomposes entirely to mercury metal and oxygen gas. After the container is cooled to
25°C, the pressure of the gas inside is 1.73 atm. What mass of mercury(II) oxide was originally
placed into the container?"
***0.22 g. An unknown quantity of hydrogen gas has a volume of 2.5 L at STP (0° and 1 atm).
What is the mass of hydrogen?
***1.78 L. How much water must be added to 100 mL of a 0.75 molar solution of KCI to make a
0.04 molar solution?
***3s²3p5. An atom in the ground state has seven valence electrons. Which electron
configuration could represent the valence electron configuration of this atom in the ground
state?
***gained potential energy. A book is lifted off of the floor and placed on a table that is one
meter above the floor. The book has
***H (hydrogen). Which of the following elements has the largest first ionization energy?
***sulfur. Which of the following elements does not exists as a diatomic molecule under normal
(ambient) conditions?
***794 rad/s². "During the time a compact disc (CD) accelerates from rest to a constant
rotational speed of 477 rev/min, it rotates through an angular displacement of 0.250 rev. What is
the angular acceleration of the CD"
***0.244 rev/s. A 47.2-kg child is standing on the outer edge of a merry-go-round that has
moment of inertia 543 kg m2 and radius 2.40 m. The entire system is initially rotating at 0.180
rev/s. ***Find the angular velocity if the child moves to a final position 1.10 m from the center of
the merry-go-round.
***"1,3,1,1,3,1" "Nitroglycerin is made by combining glycerol, nitric acid, and sulfuric acid. What
are the minimum coefficients needed to balance the equation of this reactions?"
***KCI "Which of the following compounds would be ionic, considering the electro negativities of
the elements?"
***3.2x103 kg. A method of producing pure copper metal involves the reaction of copper(I)
sulfide with oxygen gas to give copper metal and sulfur dioxide. Suppose the yield of this
reaction is 87%. What mass of a copper ore consisting of 46% copper(I) sulfide must be mined
in order to produce 1.0x103 kg (1.0 metric ton) of copper metal?
***5.17 L "During a laboratory experiment at 1.0 atm and 25°C, a student observed that oxygen
gas was produced by de-composition of 15 g of sodium chlorate. What was the volume of
oxygen?"
***320 kPa. The final temperature of the hydrogen and chlorine described in Prob. 8 is 30°C.
What is the final pressure in the reaction vessel?
***The amount of I2 will have increased. "The reaction shown occurs in a gaseous phase. Once
equilibrium has been achieved in a particular reaction vessel, additional HI gas is injected
directly into the reaction vessel. Compared to the initial conditions, which of the following
statements is correct after the new equilibrium has been achieved?"
***An atom has a negatively charged nucleus....
***CH3OH(aq) Which sample represent a homogeneous mixture?
***AB, GH, GI, HI, EG. Identify the zero-force members in the truss shown.
***3.3x 109 yr "The decay of U-238 to Pb-206 can be used to estimate the age of inorganic
matter. The half-life of U-238 is 4.5 x 10^9 years. In a particular rock sample, the ratio of the
numbers of Pb-206 to U-238 atoms is 0.66. Assume all of the Pb-206 present is due to the
decay of U-238. What is the age of the rock?"
***-340 kcal/mol(exothermic) What is the enthalpy of reaction at 25°C for the combustion of
ethane (C2H6)?
***38.3 "A 0.850-mole sample of nitrous oxide, a gas used as anasthetic by dentists, has a
volume of 20.46 L at 123°C and 1.35 atm. What would be its volume [in L] at 468°C and 1.35
atm?"
***272 g. What mass of KCIO3 must be decomposed to produce 126 L of oxygen gas at 133°C
and 0.880 atm? (The other reaction product is solid KCI.)
***An atom has a negatively charged nucleus. Which of the following is not a conclusion
Rutherford made from his experiment with alpha particles being shot at a thin sheet of gold foil?
***Litium and potassium. Which two elements will display the most similar chemical properties?
***Ammonia . Which substance can be decomposed chemical?
***the activation energy of a reaction. Which of the following does a catalyst change?
***MnO2 "The mineral pyrolusite is a compound of manganese-55 and oxygen-16. If 63% of the
mass is pyrolusite is due to manganese, what is the empirical formula of pyrolusite?"
***0 N s A car is pulling a trailer at 100 km/h. A 5 kg cat riding on the roof of the car jumps from
the car to the trailer. What is the change in the cat's momentum?
***1.4 m/s. Find the acceleration of block A after the blocks are released.
***103 000 mm4. A 28 mm diameter circuit area is reduced by a 21 mm diameter circular area
that is cut out. Both circles are tangent to the y-axis. What is the moment of inertia about the y-
axis of the remaining (shaded) area?
***3.6 g. How many grams of copper will be deposited at an electrode if a current of 1.5 A is
supplied for 2 hours to a CuSO4?
***1.7 x 10-2mol/L. "The reaction shown proceeds in a gaseous state. At equilibrium, the
concentration of the components X,Y, and Z are measured to be 5.73 x 10-2 mol/L, 2.67 x 10-2
mol/L and 4.59 x 10-2 mol/L, respectively. What is the equilibrium constant for this reaction?"
***22.5 M. Calcium nitrate tetrahydrate dissolves in cold water to the extent of 266 g per 100
cm3. What is the concentration of nitrate ions in this slution?
***4.28 mm. An area is a composite of a semicircle and a triangle, as shown. What is the
distance between the -axis and the centroid?
***143 km/h. A 1530 kg car is towing a 300 kg trailer. The coefficient of friction between all tires
and the road is 0.80. How fast can the car and trailer travel around an unbanked curve of radius
200 m without either the car or trailer skidding?
***3.5 m/s. Find the velocity of block A 2.5 s after the blocks are released.
***4.5° Traffic travels at 100 km/h around a banked high-way curve with a radius of 1000m.
What banking angle is necessary such that friction will not be required to resist the centrifugal
force?
***3.1 x 10-5 atm "A waste water treatment plant uses chlorine gas as a reactant. A tank is filled
with 800 m3 of 20°C water, and chlorine is added at a dosage of 125 g per cubic meter of water.
(Assume all of the chlorine dissolves and none initially reacts chemically.) If the atmospheric
pressure is 1.0 atm, what is the theoretical partial pressure of the chlorine gas at the tank
surface immediately after the gas is added?"
***2.43 x 10-2 M "When 20.0 mL of a 0.250 M (NH4)2S solution is added to 150.0 mL of a
solution of Cu(NO3)2, CuS precipitate forms. The precipitate is then filtered from the
solution,dried, and weighed. If the recovered CuS found to have a mass of 0.3491 g, what was
the concentration of copper ions in the original Cu(NO3)2 solution?"
***HCI "An unknown gas with a temperature of 25°C and a pressure of 740 mm Hg is collected
in a sampling bag. The volume and mass of the gas are 24.0 L and 34.9 g, respectively. Which
chemical formula could represent the gas?"
***98.51 Kpa. Macro Vee collected hydrogen gas using water displacement method. He
measured the temperature of water using a thermometer and found out that it is 230C with the
correponding pressure of 21.1 mmHg. Calculate the pressure of hydrogen gas under standard
atmospheric pressure.
***Energy has a mass and takes up space. Which statement is incorrect regarding energy?
***96 J. A 4-A current is maintained in a simple circuit with a total resistance of 2 ?. How much
energy is delivered in 3 seconds
***64 m ; the ball clears the pond "A golfer on level ground attempts to drive a golf ball across a
50 m wide pond, hitting the ball so that it travels initially at 25 m/s. The ball travels at an initial
angle of 45° to the horizontal plane. How far will the golf ball travel, and does it clear the pond?"
***12.6 m/s. "The location of a particle moving in the -y plane is given by the parametric
equations = t² + 4t and y = (1/4) t? - 60t, where and y are in meters and t is in seconds. What is
the particles velocity at t = 4 s?"
***28 N. Block D side freely on the homogeneous bar and experiences a gravitational force of
50 N. Homogeneous bar AB experiences a gravitational force of 25 N. What is the force
between the bar and block D?
***F = 20 N ; =0.2 m. A bent beam is acted upon by a moment and several concentrated forces,
as shown. Find the missing force F and distance that will maintain equilibrium on the member
shown.
***28 The probability for the ECE board examinees from a certain school to pass the
Mathematics subject is 3/7 and that for the Communication subject is 5/7. If none of the
examinees failed in both subjects, how many examinees from the school took the examination.
***3hrs . A tank is filled with an intake pipe that fills it in 2 hours and an outlet pipe that empty it
in 6 hours. If both pipes are left open, how long will it take to fill the empty tank.
***2.5miles. A man rows downstream at the rate of 5mph and upstream at the rate of 2mph.
How far downstream should he go if he is to return in 7/4 hours after leaving
***5. How many significant digits do 10.097 have?
*** 6.8 x 10-4 mol/Latm. The solubility of nitrogen gas at 25°C and a nitrogen pressure of 522
mmHg is 4.7 ´ 10-4 mol/L. What is the value of the Henry's Law constant in mol/Latm?
***0.24. "A gaseous mixture consists of 2 kg of oxygen, 5 kg of nitrogen, and 3 kg of xenon.
What is the mole fraction of the oxygen gas?"
*** "4, 0, 0, ½". "Select the correct set of quantum numbers (n, l, ml, ms) for the highest energy
electron in the ground state of potassium, K. "
*** 16 p, 15 n, 16 e. An atom of the isotope sulfur-31 consists of how many protons, neutrons,
and electrons?(p = proton, n = neutron, e = electron)
***Mg. Select the element with the highest first ionization energy.
***Chloric Acid. The chemical name for ClO3- is "chlorate ion". Therefore, the name of HClO3 is
***125.9. Use Hess's Law to calculate the enthalpy change for the reaction
WO3(s) + 3H2(g) ? W(s) + 3H2O(g)
from the following data:
2W(s) + 3O2(g) ? 2WO3(s) ?H = -1685.4 kJ
2H2(g) + O2(g) ? 2H2O(g) ?H = -477.84 kJ
***0.33. ""The first step in the Otswald process for producing nitric acid is 4NH3(g) + 5O2(g) -->
4NO(g) + 6H2O(g). If the reaction of 150 g of ammonia with 150 g of oxygen gas yields 87 g of
nitric oxide (NO), what is the percent yield of this reaction?"

*** 0.2 M Na2SO4. Which of the following aqueous solutions has the highest osmotic pressure
at 25°C?
*** n and l. The ____________________ quantum numbers are associated with the energy of
an electron in a many-electron atom.
*** Calcium carbonate is heated to form calcium oxide and carbon dioxide in a container with
variable volume. In which of the following processes is ?H = ?E?
*** "For a fission reaction the mass defect (Dm) is negative, whereas for fusion Dm is positive."..
Which one of the following statements about fission and fusion is false?
*** -602 kJ/mol. A 0.1326 g sample of magnesium was burned in an oxygen bomb calorimeter.
The total heat capacity of the calorimeter plus water was 5,760 J/°C. If the temperature rise of
the calorimeter with water was 0.570°C, calculate the enthalpy of combustion of magnesium.
Mg(s) + 1/2 O2(g) --> MgO(s)
*** 470. Phosphine, an extremely poisonous and highly reactive gas, will react with oxygen to
form tetraphosphorus decaoxide and water.

PH3(g) + O2(g) ? P4O10(s) + H2O(g) [unbalanced]

Calculate the mass in grams 40of P4O10(s) formed when 225 g of PH3 reacts with excess
oxygen.
***The rate at 75°C will be greater than the rate at 50°C because the number of molecules with
enough energy to react increases with increasing temperature. The kinetics of the
decomposition of dinitrogen pentaoxide is studied at 50°C and at 75°C. Which of the following
statements concerning the studies is correct?
***Have a properly balance chemical equation. In order to write the correct mass-action
expression for a reaction one must
***CO2(s) ? CO2(g). In which one of the following reactions would you expect ?H to be
substantially greater than ?E (i.e., ?H > ?E)
***alters the reaction mechanism. Complete the following statement: A catalyst
*** 50.0 mL. how manu millimiters of 0.100M H2SO4 are required to neutralize 50.0 mL of 0.200
KOH?
***californium-249.Which isotope, when bombarded with oxygen-18, yields the artificial isotope
seaborgium-263 plus 4 neutrons?

*** 0.15 mol. How many moles of Pb(NO3)2 must be added to 0.10L of a solution that is 1.0M in
MgCl2 and 1.0M in KCl to precipitate all of the chloride ion? The compound PbCl2 precipitates.
*** 0.89 kW. Assuming all of the energy goes into the reaction, what electrical power is required
to produce oxygen gas at a rate of 50 mg/s?
***146 g/mol. Lysine is an amino acid that is an essential part of nutrition but which is not
synthesized by the human body. What is the molar mass of lysine if 750.0 mL of a solution
containing 8.60 g of lysine has an osmotic pressure of 1.918 atm? T = 25.
*** 5 ´ 10-3 pm. A typical radius of an atomic nucleus is about
*** Amonton's.. The pressure of an ideal gas is directly proportional to its absolute temperature
at constant volume and number of moles" is a statement of ________________ Law
***The products will be favored because the hydrogen sulfate ion is a stronger acid than the
ammonium ion. The acid dissociation constant Ka equals 1.26 × 10-2 for HSO4- and is 5.6 ×
10-10 for NH4+. Which statement about the following equilibrium is correct?
***45. For a given isotope of an element, the atomic number plus the atomic weight is 148, and
their difference is 58. How many protons does an atom of the isotope contain
***helium gas. If a sample of methane gas effuses at a rate of 9.0 mole per hour at 35 deg C,
which of the gases below will effuse at approximately twice the rate under the same conditions
***663. 0.102 g of an unknown compound dissolved in 100. mL of water has an osmotic
pressure of 28.1 mmHg at 20°C. Calculate the molar mass [g/mol] of the compound.
***Einstein. Who proposed a model that successfully explained the photoelectric effect?
***the volume of the molecules. The true volume of a real gas is larger than that calculated from
the ideal gas equation. This occurs because the ideal gas equation does consider which of the
following?
***the entropy of the solution must be greater than that of its pure components.If a solute
dissolves in an endothermic process
***dipole-dipole forces. In hydrogen iodide __________________ are the most important
intermolecular forces.
*** 1.86. Calculate the molality of a 15.0% by mass solution of MgCl2 in H2O. The density of
this solution is 1.127 g/mL.
*** 0.123M. Calcium chloride is used to melt ice and snow on roads and sidewalks and to
remove water from organic liquids. Calculate the molarity of a solution prepared by diluting 165
mL of 0.688 M calcium chloride to 925.0 mL
***As equilibrium is reestablished, the partial pressure of hydrogen decreases. The reaction
system
*** HI. Which of the following is the strongest acid?
*** 26.0 g Fe. Which of these quantities does not represent 1.00 mol of the indicated
substance?
*** He. The position of the equilibrium 2CO(g) + O2(g)
***37.1 L. A sample of propane, a component of LP gas, has a volume of 35.3 L at 315 K and
922 torr. What is its volume at STP?
***1.05 M. the mole fraction of potassium nitrate in an aqueous solution is 0.0194. The solution
density is 1.0627 g/mL. calculate the molarity of the solution.
*** 4.97 M. Potassium hydrogen phosphate is used in the preparation of non-dairy powdered
creamers. Calculate the molarity of a solution prepared by dissolving 238 g of K2HPO4 in
enough water to produce 275 mL of solution.
*** the attraction by an atom for electrons in a chemical bond. Electronegativity is a measure of
*** visible. Electromagnetic radiation of 500 nm wavelength lies in the ________ region of the
spectrum.
*** change in temperature. Which of the following has an effect on the magnitude of the
equilibrium constant?
*** there is an increase in entropy. When two pure substances are mixed to form a solution
***true. Although a system may be at equilibrium, the rate constants of the forward and reverse
reactions will in general be different.
*** It is doubled. A sample of argon gas is sealed in a container. The volume of the container is
doubled. If the pressure remains constant, what happens to the absolute temperature
*** ?Hsoln ? 0, entropy of system increases. Which of the following sets of conditions could exist
when two liquids which are completely miscible in one another are mixed?
*** DG° = nFE°. The relation connecting DG° and E° is _____.
***"radio, infrared, ultraviolet, gamma rays". Select the arrangement of electromagnetic radiation
which starts with the lowest energy and increases to greatest energy
*** 60.0 g. How many grams of MgSO4 (MW 120.4) are in 100.0 mL of a 5.0 molar solution?
*** 82.6°C. Carbon tetrachloride, once widely used in fire extinguishers and as a dry cleaning
fluid, has been found to cause liver damage to those exposed to its vapors over long periods of
time. What is the boiling point of a solution prepared by dissolving 375 g of sulfur (S8)?

*** 74.2. Methane, CH4(g), reacts with steam to give synthesis gas, a mixture of carbon
monoxide and hydrogen, which is used as starting material for the synthesis of a number of
organic and inorganic compounds.
***Zn. Galvanized iron is steel coated with _____.
*** describe regions of space in which one is most likely to find an electron. Atomic orbitals
developed using quantum mechanics
*** Rutherford. Who was the first scientist to propose that the atom had a dense nucleus which
occupied only a small fraction of the volume of the atom?
*** [Zn2+] / [Ag+]2. Write the mass-action expression, Qc , for the following chemical reaction.
*** volt. The unit of electromotive force is the _____.
*** 54 kJ. A common laboratory reaction is the neutralization of an acid with a base. When 50.0
mL of 0.500 M HCl at 25.0°C is added to 50.0 mL of 0.500 M NaOH at 25.0°C in a coffee cup
calorimeter, the temperature of the mixture rises to 28.2°C. What is the heat of reaction per
mole of acid? Assume the mixture has a specific heat capacity of 4.18 J/(gK) and that the
densities of the reactant solutions are both 1.00 g/mL.
***116. What volume [mL] of water should be added to 600. mL of ethanol in order to have a
solution that boils at 95.0°C?
[For ethanol, Kb = 1.22°C/m, density = 0.789 g/cm3, boiling point = 78.4°C]
***it lowers the activation energy for the reaction.
A catalyst accelerates a reaction because

*** He. Which gas under a high temperature and a low pressure behaves most like an ideal
gas?
*** HClO3. Which of the following is the strongest acid?
*** Pure iron is a heterogeneous mixture. Which sentence below is incorrect?
*** CaCI. Which of the following chemical formulas is incorrect?
*** 0.528 M. What is the molarity of a solution of 10% by mass cadmium sulfate, CdSO4 (molar
mass = 208.46 g/mol) by mass? The density of the solution is 1.10 g/mL.
*** 695 torr. A flask containing neon gas is connected to an open-ended mercury manometer.
The open end is exposed to the atmosphere, where the prevailing pressure is 745 torr. The
mercury level in the open arm is 50. mm below that in the arm connected to the flask of neon.
What is the neon pressure, in torr?
*** 87.0 g. Lead (II) nitrate is a poisonous substance which has been used in the manufacture of
special explosives and as a sensitizer in photography. Calculate the mass of lead in 139 g of
Pb(NO3)2.
*** 2.543. Sodium hydroxide, also known as caustic soda, is used to neutralize acids and to
treat cellulose in making of cellophane. Calculate the number of moles of solute in 1.875 L of
1.356 M NaOH solution.
*** 151. Lead(II) sulfide was once used in glazing earthenware. It will also react with hydrogen
peroxide to form lead(II) sulfate and water. How many grams of hydrogen peroxide are needed
to react completely with 265 g of lead(II) sulfide?
*** [H2O] = [CO]. Which statement is correct with respect to the above equilibrium when 0.30
moles of CO and 0.30 moles of H2O are heated to 700°C and allowed to reach equilibrium.
*** CaCl2. Select the correct formula for a compound formed from calcium and chlorine.
*** "?H > 0, process is endothermic". Cold packs, whose temperatures are lowered when
ammonium nitrate dissolves in water, are carried by athletic trainers when transporting ice is not
possible. Which of the following is true of this reaction?
***nitrogen. Which element forms compounds which are involved in smog and acid rain?
*** PbCO3 + 2 H+ + 2 Cl- --> PbCl2 + CO2 + H2O. Which of the following best an the balanced
net ionic equation for the reaction of lead (II) carbonate with concentrated hydrochloric acid? In
this reaction, all lead compounds are insoluble
*** 2.76. What is the molality [m] of a solution prepared by dissolving 86.9 g of diethyl ether,
C4H10O, in 425 g of benzene, C6H6?
*** 84.30 mm Hg. A solution is 40.0% by volume benzene (C6H6) in carbon tetrachloride at
20°C. The vapor pressure of pure benzene at this temperature is 74.61 mmHg and its density is
0.87865 g/cm3; the vapor pressure of pure carbon tetrachloride is 91.32 mmHg and its density
is 1.5940 g/cm3. If this solution is ideal, its total vapor pressure at 20°C is
*** 417 g of 36% acetic acid in 583 g of distilled water. The chemist, Anna Lytic, must prepare
1.00 kg of 15.0% (w/w) acetic acid using a stock solution which is 36.0% (w/w) acetic acid (? =
1.045 g/mL). Which of the following combinations will give her the solution she wants?
*** 150 J. A system receives 575 J of heat and delivers 425 J of work. Calculate the change in
the internal energy, ?E, of the system.
*** "5, 1, 0, ½". "5, 1, 0, ½" Select the correct set of quantum numbers (n, l, ml, ms) for the
highest energy electron in the ground state of tin, Sn
*** sulfur. Which of the following elements does not exists as a diatomic molecule under normal
(ambient) conditions?
*** The partial pressure of carbon dioxide at equilibrium will be unchanged. Magnesium
carbonate dissociates to magnesium oxide and carbon dioxide at elevated temperatures.

MgCO3(s) ? MgO(s) + CO2(g)

A reaction vessel contains these compounds in equilibrium at 300°C. What will happen if the
volume of the container is reduced by 25% at 300°C?
*** 11.2 atm. What is the osmotic pressure of a solution that contains 13.7 g of propyl alcohol
(C3H7OH) dissolved in enough water to make 500. mL of solution at 27°C?
*** 168 g/mol. An ideal gas sample weighing 1.28g at 127 deg C and 1.00 atm has a volume of
0.250L. Determine the molar mass of the gas.
*** the frequency of molecular collisions increases. When the concentrations of reactant
molecules are increased, the rate of reaction increases. The best explanation for this
phenomenon is that as the reactant concentration increases
*** Decreasing pressure. The equilibrium 2SO2(g) + O2(g) <==> 2 SO3(g) can shifted to the
reactant side by _____. DH = 198.2 Kj
*** S > As > Ca > Rb. Arrange calcium, rubidium, sulfur, and arsenic in order of decreasing
electronegativity.
***log [X] versus time. For the reaction whose rate law is rate = k[X], a plot of which of the
following is a straight line?
***10.3. Potassium chlorate (used in fireworks, flares and safety matches) forms oxygen and
potassium chloride when heated.

KClO3(s) ? KCl(s) + O2(g) [unbalanced]

How many grams of oxygen are formed when 26.4 g of potassium chlorate is heated?
*** 0.12. What is the pH of a 0.75 M HNO3 solution?
*** K+(aq) + H2(g) + OH-(aq). What are the products of the reaction of potassium hydride and
water? KH(s) + H2O(l) ?
*** Graham's. The rate of effusion of a gas is inversely proportional to the square root of its
molar mass is a statement of _________________ Law
*** 7.503%. Lithium forms compounds which are used in dry cells and storage batteries and in
high-temperature lubricants. It has two naturally occurring isotopes, 6Li (isotopic mass =
6.015121 amu) and 7Li (isotopic mass = 7.016003 amu). Lithium has an atomic mass of 6.9409
amu. What is the percent abundance of lithium-6?
*** 0.4446. Cadmium bromide is used in photography and lithography. Calculate the molality
[m] of a solution prepared by dissolving 45.38 g of CdBr2 in 375.0 g of water
*** 2900 kJ. Solid sodium peroxide (Na2O2) reacts with liquid water yielding aqueous sodium
hydroxide and oxygen gas. How much heat is released when 250.0 L of oxygen gas is produced
from the reaction of sodium peroxide and water if the reaction is carried out in an open container
at 1.000 atm pressure and 25°C?
(Given: heat of formation
[Na2O2(s)] = -510.9 kJ/mol; [NaOH(aq)] = -469.2 kJ/mol; [H2O(l)] = -285.8 kJ/mol)

***0.030 mol. 3 Cu(s) + 8 HNO3(aq) --> 3 Cu(NO3)2(aq) + 2 NO(g) + 4 H2O(l) Copper metal
reacts with nitric acid according to the above equation. A 0.30 mol sample of copper metal and
10.0 mL of 12 M nitric acid are mixed in a flask. How many moles of NO gas will form?
***90. The executioner in charge of the lethal gas chamber at the state penitentiary adds excess
dilute sulfuric acid to 196 g of sodium cyanide. What volume [L] of HCN gas is formed at STP?
The reaction is: H2SO4 + 2 NaCN --> 2 HCN + Na2SO4
*** chlorine. Which of the following elements is a reactive gas?
*** They can be used as fungicides.. Tin reacts to form several organic compounds. Which of
the following is a use for organotin compounds?
*** SrF2. Which of the following contains ionic bonding?
*** Po. A radioisotope decays to give an alpha particle and Pb-208. What was the original
element?
*** Cl2(g). The species _____ can oxidize water to oxygen under standard state conditions.
***The energy of a given orbital increases as the nuclear charge Z increases. Which one of the
following statements about orbital energies is incorrect?
*** True. For a gas-phase equilibrium, a change in the pressure of any single reactant or
product will affect the amounts of other substances involved in the equilibrium.
*** True. Unless ?H°rxn = 0, a change in temperature will affect the value of the equilibrium
constant Kc.
*** Mg. Which of the following elements is present in chlorophyll?
*** C4H3O2. Terephthalic acid, used in the production of polyester fibers and films, is composed
of carbon, hydrogen, and oxygen. When 0.6943 g of terephthalic acid was subjected to
combustion analysis it produced 1.471 g CO2 and 0.226 g H2O. What is its empirical formula?
***0.510 atm. A gas mixture of N2(g) and CO2(g) contained in a volume of 10.0 L has a total
pressure of 0.750 atm at a temperature of 273K. The mixture is known to contain 3.00 g N2(g).
What is the partial pressure of CO2(g) in the mixture?
*** London dispersion forces. Neon condenses due to
*** 5.30 g. How many grams of nitrogen are in 25.0g of (NH4)2SO4?
*** 0.24 atm. A reaction produces a gaseous mixture of carbon dioxide, carbon monoxide, and
water vapor. After one reaction, the mixture was analyzed and found to contain 0.60 mol of
carbon dioxide, 0.30 mol of carbon monoxide, and 0.10 mol of water vapor. If the total pressure
of the mixture was 0.80 atm, what was the partial pressure of the carbon monoxide
*** The solution is basic.. A solution is prepared by adding 0.10 mol of sodium fluoride, NaF, to
1.00 L of water. Which statement about the solution is correct
*** 13.9 J/K. "A piece of copper metal is initially at 100.0°C. It is dropped into a coffee cup
calorimeter containing 50.0 g of water at a temperature of 20.0°C. After stirring, the final
temperature of both copper and water is 25.0°C. Assuming no heat losses, and that the specific
heat (capacity) of water is 4.18 J/(gK), what is the heat capacity of the copper in J/K?
*** 381°C. At what temperature in 0C will O2 has under a pressure of 2.4 atm?
***320 g. There are 500 g of zinc sulfide (ZnS) in a load of zinc ore. The ZnS is roasted in
excess air to form zinc oxide (ZnO) and sulfer dioxide (S)?. How many grams of zinc can be
subsequently recovered if 5% of the zinc is lost in the roasting process?
*** 4. How many valence electrons are in a atom with the configuration 1s²2s²2p?3s²3p²
*** Cu3(PO4)2. Which is the correct formula for copper(II) phosphate?
*** Robert Millikan. The scientist who determined the magnitude of the electric charge of the
electron was
*** 11.7 L. How many liters of oxygen gas at 153°C and 0.820 atm can be produce by the
decomposition of 22.4 g of solid KCIO3? (The other decomposition product is solid potassium
chloride.)

***84 neutrons. A commonly occurring isotope of tin is tin-118, while most oxygen occurs in
nature as oxygen-16. A molecule of tin(IV) oxide formed from thesse isotopes contains
Select one:
*** 3.11 x 10-3 M. When 38.0 mL of 0.1250 M H2SO4 is added to 100. mL of a solution of Pbl2,
a precipitate of PbSO4 is then filtered from the solution, dried, and weighed. If the recovered
PbSO4 is found to have a mass of 0.0471 g, what was the concentration of iodide ions in the
original solution?
*** solubility. In order to separate two substances by fractional crystallization, the two
substances must differ in which of the following?
*** Dissolve 120 g of urea in enough distilled water to produce 1.00 L of solution. Which of the
following statements describes the correct method of preparation of 1.00 L of a 2.0 M urea
solution? (MW urea = 60.06 g/mol )
***Oxidation occurs at the anode. The correct statement is: _____.
***21.8L. Nitrogen dioxide is a red-brown gas that is responsible for the color of photochemical
smog. A sample of nitrogen dioxide has a volume of 28.6 L at 45.3°C and 89.9 kPa. What is its
volume at STP?
*** "n = 3, l = 2, ml = -2". Which of the following is a correct set of quantum numbers for an
electron in a 3d orbital?
*** dispersion. Which word best describes the phenomenon which gives rise to a rainbow?
*** a strong Arrhenius base. The substance Ba(OH)2 is considered
*** a weak Arrhenius acid. The substance HOBr is considered
*** 1.09V. The potential of the cell made up of Zn/Zn2+(0.25 M) and Cu/Cu2+(0.15 M) at 25 °C
is _____.
***3.3 x 103 kg. The Hall process for the production of the aluminun involves the reaction of the
aluminum oxide with elemental carbon to give aluminum metal and carbon momoxide. If the
yield of this reaction is 82% and aluminum ore is 71% by mass aluminum oxide,what mass of
aluminum ore must be mined in order to produce 1.0 x 103 kg(1 metric ton) of aluminum metal
by the Hall process?
*** 67 days. The diameter of a spherical mothball is observed to halve in 200
days.approximately how long it will take for its remaining volume to become half of its volume at
200 days?
*** In < Al < P < N. Arrange aluminum, nitrogen, phosphorus and indium in order of increasing
electronegativity
*** Se. This element may form a compound with the formula CaXO4.
*** 1.92 × 102 kcal. Natural gas, or methane, is an important fuel. Combustion of one mole of
methane releases 802.3 kilojoules of energy. How much energy does that represent in
kilocalories?

*** 0.11. A given sample of radioactive material has 80% of the original substance remaining
after 10 years. How much will remain after 90 additional years?
*** 35.8°C. 10.1 g CaO is dropped into a styrofoam coffee cup containing 157 g H2O at 18.0°C.
If the following reaction occurs, then what temperature will the water reach, assuming that the
cup is a perfect insulator and that the cup absorbs only a negligible amount of heat?
[specific heat of water = 4.18 J/g°C]
CaO(s) + H2O(l) --> Ca(OH)2(s) ?Hr = -64.8 kJ/mol
*** 3.3 g. Water and SO3 combine to sulfuric acid (H2SO4) according to the following reaction.
How many grams of water must be added to 100 g of 20% oleum (20% SO3 and 80% H2SO4
by weight) to produce a 95% solution (by weight) of sulfuric acid?
***4.85 × 10-2 g. Sulfur trioxide can react with atmospheric water vapor to form sulfuric acid that
falls as acid rain. Calculate the mass in grams of 3.65 × 1020 molecules of SO3.

*** KI. Which of the following is an ionic compound?

*** X^(-2). The equilibrium constant Kc for the equilibrium A + B <==> C + D is X. The
equilibrium constant for the reaction 2C + 2D <==> 2A + 2B is
*** Limiting reactant is FeCl3; 2 g of Mg remain. Magnesium (used in the manufacture of light
alloys) reacts with iron(III) chloride to form magnesium chloride and iron.

3Mg(s) + 2FeCl3(s) ? 3MgCl2(s) + 2Fe(s)

A mixture of 41.0 g of magnesium ( M= 24.31 g/mol) and 175 g of iron(III) chloride ( M= 162.2
g/mol) is allowed to react.
Identify the limiting reactant and determine the mass of the excess reactant present in the
vessel when the reaction is complete.
*** 2.3 x103 L. The atmosphere on Mars is composed mainly of carbon dioxide. The surface
temperature is 220 K and the atmospheric pressure is about 6.0 mmHg. Taking these values as
Martian STP, calculate the molar volume in liters of an ideal gas on Mars.
*** 209 g. Copper(II) bromide is used as a wood preservative. What mass of CuBr2 is needed to
prepare 750.0 mL of a 1.25 M solution?
*** 0.1356 M. A sample of oxalic acid, H2C2O4, is titrated with standard sodium hydroxide,
NaOH, solution. A total of 45.20 mL of 0.1200M NaOH is required to neutralize20.00 mL of the
acid. What is the concentration of the acid?
*** CH3CH2-OH. Which of the following substances will have hydrogen bonds between
molecules?
*** Ca(OH)2(s). Predict the products for the reaction of the following set of reactants. CaO(s) +
H2O(l) ?
*** The partial pressure of NO will increase..

The reaction of nitric oxide to form dinitrogen oxide and nitrogen dioxide is exothermic.

3NO(g) ? N2O(g) + NO2(g) + heat

What effect will be seen if the temperature of the system at equilibrium is raised by 25°C?
*** Se2-. Which of the following ions and atoms has the greatest radius?
***. 0.197 M .A 350. mL sample of 0.276 M HNO3 is partially neutralized by 125mL of 0.0120 M
Ca(OH)2. Find the concentration of nitric acid in the resulting solution.
***3.1 x 10?5 M. When solid iron (II) hydroxide is added to water, the resulting solution contains
1.4 x 10?3 g of dissolved iron(II) hydroxide per liter of solution. What is the hydoxide ion
concentration in this solution?
***K1 × K2. About half of the sodium carbonate produced is used in making glass products
because it lowers the melting point of sand, the major component of glass. When sodium
carbonate is added to water it hydrolyses according to the following reactions.

CO32-(aq) + H2O(l) ? HCO3-(aq) + OH-(aq); K1

HCO3-(aq) + H2O(l) ? H2CO3(aq) + OH-(aq); K2

These can be combined to yield

CO32-(aq) + 2H2O(l) ? H2CO3(aq) + 2OH-(aq); K3

What is the value of K3?

***sulfur. Which of the following elements does not exists as a diatomic molecule under normal
(ambient) conditions?
*** ClF. In which of these substances are the atoms held together by polar covalent bonding?
*** 27g. A reaction produces a gaseous mixture of carbon dioxide, carbon monoxide, and water
vapor. After one reaction, the mixture was analyzed and found to contain 0.60 mol of carbon
dioxide, 0.30 mol of carbon monoxide, and 0.10 mol of water vapor. If the total pressure of the
mixture was 0.80 atm, what was the partial pressure of the carbon monoxide
*** "5, 0, 0, -½". Select the correct set of quantum numbers (n, l, ml, ms) for the first electron
removed in the formation of a cation for strontium, Sr.
***Raoult's Law works best when applied to dilute solutions. Raoult's Law relates the vapor
pressure of the solvent above the solution to its mole fraction in the solution. Which of the
following is an accurate statement?
*** 2 moles of sodium hydroxide and 1 mole of hydrogen. Two moles of sodium react with 2
moles of water to produce which of the following?
***21.2 kJ. Nitric acid, which is among the top 15 chemicals produced in the United States, was
first prepared over 1200 years ago by heating naturally occurring sodium nitrate (called
saltpeter) with sulfuric acid and collecting the vapors produced.Calculate ?H°rxn for this
reaction.
NaNO3(s) + H2SO4(l) ? NaHSO4(s) + HNO3(g)
?H°f [NaNO3(s)] = -467.8 kJ/mol; ?H°f [NaHSO4(s)] = -1125.5 kJ/mol; ?H°f [H2SO4(l) = -814.0
kJ/mol; ?H°f [HNO3(g)] = -135.1 kJ/mol
***-1.16°C. Calculate the freezing point of a solution made from 22.0 g of octane (C8H18)
dissolved in 148.0 g of benzene. Benzene freezes at 5.50°C and its Kf value is 5.12°C/m
*** 0.5. How many moles of sulfate ions are present in 1.0 L of 0.5 M Li2SO4?
***molarity. For a given solution, which of the following concentration values will change as
temperature changes?
***increasing the temperature. Which one of the following changes would alter the rate constant
(k) for the reaction 2A + B ® products?
*** 200 mL. A sample of oxygen gas has its absolute temperature halved while the pressure of
the gas remained constant. If the initial volume is 400 mL, what is the final volume?
*** -6.2. By how much [in deg] will 50 grams of water have its freezing point depressed if you
add 30 g (MW=80) of glucose to it?
*** 1.89. Calculate the molality of a 20.0% by mass ammonium sulfate (NH4)2SO4 solution. The
density of the solution is 1.117 g/mL.
*** 8.96. Barium reacts with water according to the reaction:
Ba(s) + 2 H2O(l) --> Ba(OH)2 (aq) + H2 (g)
What volume [in L] of hydrogen gas, at STP, is produced from 0.400 mol of barium?
*** one atomic number higher than the original element. As a result of beta decay, the product
nucleus is
*** lower left. The most basic oxides contain elements from the ________________
____________ region of the periodic table.
*** hydrogen bonding.. Ammonia's unusually high melting point is the result of
*** Cu. The cathode in the Daniell cell is _____.
*** 1.78 g/L. Assuming ideal behavior, what is the density of argon gas at STP, in g/L?

*** Ba3N2. Select the correct formula for a compound formed from barium and nitrogen
*** 10^-7 M. The concentration of H+ in pure water at 25°C is _____.
*** is an application of Hess's Law. A Born-Haber cycle applied to the formation reaction of an
ionic solid
*** N-Bi. Which of the following bonds would you expect to be the most polar?
*** 2.48 kg. What mass of ethanol, C2H5OH a nonelectrolyte, must be added to 10.0 L of water
to give a solution that freezes at -10.0°C?
Assume the density of water is 1.0 g/mL. Kf of water is 1.86°C/m.
*** MnO4 oxidizing Fe to Fe2+. The reaction _____ is spontaneous.
*** True. The molar mass of caffeine is 194.19 g/mol and the empirical formula is C4H5N2O;
therefore the molecular formula of caffeine is C8H10N4O2.
*** -304.1 kJ. calculate the enthalpy change for the reactions NO(g) + O(g) ? NO2(g)
from the following data:
NO(g) + O3(g) ? NO2(g) + O2(g) ?H = -198.9 kJ
O3(g) ? 1.5 O2(g) ?H = -142.3 kJ
O2(g) ? 2O(g) ?H = 495.0 kJ

***c. 310L. A method of removing CO2 from a spacecraft is to allow the CO2 to react with
sodium hydroxide. (The products of the reaction are sodium carbonate and water.) What volume
of carbon dioxide at 25°C and 749 mmHg can be removed per kilogram of sodium hydroxide
that reacts?
*** 4. Which principal energy level has exactly four subshells?
*** [CO]12[H2O]6/[C6H6][O2]5 . Write the mass-action expression, Qc, for the following
chemical reaction equation.
*** Rb. Which one of the following elements is likely to exhibit the most violent and rapid
reaction with water?
*** 0.750 mol. Gold(III) oxide, Au2O3, can be decomposed to gold emtal, Au, plus oxygen gas,
O2. How many moles of oxygen gas will form when 221 g of solid gold(III) oxide is
decomposed? The formula mass of gold(III) oxide is 442.
*** the lower oxidation state is more important as one goes down a group. When elements from
a group exhibit more than one oxidation state
*** Ne. Which of the following elements has the smallest atomic radius?
*** 2.26 M. Which of the following gives the molarity of a 17.0% by mass solution of sodium
acetate, CH3COONa (molar mass = 82.0 g/mol) in water? The density of the solution is 1.09
g/mL.
*** 1.3. The osmotic pressure of a 0.010 M MgSO4 solution at 25°C is 0.318 atm. Calculate i,
the van't Hoff factor, for this MgSO4 solution
*** 68 h. A 3.0-L sample of helium was placed in container fitted with a porous membrane. Half
of the helium effused through the membrane in 24 hours. A 3.0-L sample of oxygen was placed
in an identical container. How many hours will it take for half of the oxygen to effuse through the
membrane?
***Mg. Which is the symbol for the element that forms a protective oxide coating?
*** 0.0100. Heating will decompose silver oxide, Ag2O, to silve metal, Ag, plus oxygen gas, O2.
How many moles of oxygen gas will form when 4.64 g of solid silver oxide is decomposed? The
formula mass of silver oxide is 232 g/mol.
*** 146 kJ/mol. Styrene, C8H8, is one of the substances used in the production of synthetic
rubber. When styrene burns in oxygen to form carbon dioxide and liquid water under standard-
state conditions at 25°C, 42.62 kJ are released per gram of styrene. Find the standard enthalpy
of formation of styrene at 25°C.
*** 99 kJ/mol. Given the thermochemical equation 2SO2 + O2 --> 2SO3, dHr= -198 kJ/mol,
what is the standard enthalpy change for the decomposition of one mole of SO3

*** 139. The combustion of butane produces heat according to the equation
2 C4H10(g) + 13 O2(g) ? 8 CO2(g) + 10 H2O(l) ?Hrx = -5,314 kJ

How many grams of butane must be burned to release 6,375 kJ of heat?

*** 4. Which principal energy level has exactly four subshells?
*** isotopes. Atoms of the same element with different mass numbers are called
*** "q < 0, ?E < 0". A system that does no work but which transfers heat to the surroundings has
*** an inert gas that is used as an electrical insulator. Sulfur hexafluoride, SF6, is
*** 5.4. Calculate the concentration [molality] of an alcohol-water mixture which will not freeze
above a temperature of -10 deg C. MW of alcohol = 46; kf water = 1.86 deg C/m
*** True. Changing the amount of reactant or product in an equilibrium reaction will always
change the equilibrium position, regardless of the physical state of the substance involved.
*** He. Which gas is expected to have the highest rate of effusion?
*** 3.6 x 105. An average home in Colorado requires 20. GJ of heat per month. How many
grams of natural gas (methane) must be burned to supply this energy?
*** 0.145. Diethyl ether has a vapor pressure of 400.0 torr at 18°C. When a sample of benzoic
acid is dissolved in ether, the vapor pressure of the solution is 342 torr. What is the mole
fraction of benzoic acid in the solution
***1.840. A flask has a mass of 78.23 g when empty and 593.63 g when filled with water. When
the same flask is filled with concentrated sulfuric acid, H2SO4, its mass is 1026.57 g. What is
the density [g/cc] of concentrated sulfuric acid? (Assume water has a density of 1.00 g/cm3 at
the temperature of the measurement.)
*** False. The rate of a reaction is determined by the rate of the fastest step in the mechanism
*** a charged atom or group of atoms with a net negative charge. An anion is defined as
*** increasing temperature. The equilibrium PCl5(g) <==> PCl3(g) + Cl2(g) can be shifted
toward more product formation by _____. DH = 92.5 kJ
*** 273 K and 760 torr. What are the conditions of STP?
*** Ni. The electronic structure 1s2 2s2 2p6 3s2 3p6 4s2 3d8 refers to the ground state of
*** 45.5 L. An object will float at the surface of a liquid if the mass of the object is less than the
mass of the liquid that it displaces. A spherical vessel (diameter = 5.00 cm) when empty has a
mass of 12.00 g. What is the greatest volume of water that can be placed in the vessel and still
have the vessel float at the surface of benzene? (Given: density of water = 1.00 g/cm3; density
of benzene = 0.879 g/cm3)
***-1.03°C. What is the freezing point of a solution that contains 10.0 g of glucose (C6H12O6) in
100. g of H2O? Kf for water is 1.86°C/m.

***52.3 m. A silver wire has a diameter of 0.500 mm.What length of this wire contains exactly
1.00 mol of silver? [Given: density of Ag = 10.5 g/cm3
***KNO3. Which one of the following substances will give an aqueous solution of pH closest to
7?
*** neutralize the acid with NaHCO3 solution. What should you do if you spill sulfuric acid on the
countertop?
**** the average speed of the molecules. Increasing the temperature of an ideal gas from 50
deg C to 75 deg C at constant volume will cause which of the following to increase for the gas?
**** False. There is a direct correlation between the speed of a reaction and its equilibrium
constant
*** CH4 + 2O2 ? CO2 + 2H2O. Which of the following equations is balanced?
**** 14.8 m. A gold wire has a diameter of 1.00 mm. What length of this wire contains exactly
1.00 mol of gold? [Given: density of Au = 17.0 g/cm3]
***342.15. Aluminum sulfate, Al2(SO4)3, is used in tanning leather, purifying water, and
manufacture of antiperspirants. Calculate its molar mass (g/mol).
*** 267. Ammonia, an important source of fixed nitrogen that can be metabolized by plants, is
produced using the Haber process in which nitrogen and hydrogen combine.

N2(g) + 3H2(g) ? 2NH3(g)

How many grams of nitrogen are needed to produce 325 grams of ammonia?
*** H = E + PV. Which one of the following relationships is always correct?
*** the standard emf of the cell is positive. An electrochemical reaction will be spontaneous if
_____.
*** Reaction yield. Le Châtelier's principle can help to predict how to maximize _____.
*** Rb. Which of the following elements has the greatest atomic radius?
*** 0.0154 g. Small quantities of hydrogen can be prepared by the addition of hydrochloric acid
to zinc. A sample of 195 mL of hydrogen was collected over water at 25°C and 753 torr. What
mass of hydrogen was collected? (Pwater = 24 torr at 25°C)
*** *190. When 24.0 g of glucose (a nonelectrolyte) are dissolved in 500. g of water, the solution
has a freezing point of -0.47°C. What is the molar mass of glucose? Kf of water is 1.86°C/m.
***0.008. The solubility of the oxidizing agent potassium permanganate is 7.1 g per 100.0 g of
water at 25°C. What is the mole fraction of potassium permanganate in this solution?
*** provides a new pathway (mechanism) for the reaction. When a catalyst is added to a
reaction mixture, it
*** 4. _____ Faradays are required to liberate 32 g of O2 in the electrolysis of H2O.
***0.29. Aqueous ammonia is commercially available in a solution that is 28% (w/w) ammonia.
What is the mole fraction of ammonia in such a solution?
*** MgCl2(s). Predict the products for the reaction of the following set of reactants. Mg(s) +
Cl2(g) ?
*** -420 J. A system delivers 1275 J of heat while the surroundings perform 855 J of work on it.
Calculate ?E in J
*** 12 protons and 10 electrons. A magnesium ion, Mg2+, has
*** Hund's rule.. Electrons added to atomic orbitals of the same energy will remain unpaired with
parallel spins until the subshell is more than half-filled"" is a statement of
*** b. 12 g . When octane (C8H18) is burned in a particular internal combustion engine, the yield
of the products (carbon dioxide and water) is 93%. What mass of carbon dioxide will be
produced in this engine when 15.0 g of octane is burned with 15.0 g of oxygen gas?
*** 6.74 kJ. Calculate q when 28.6 g of water is heated from 22.0°C to 78.3°C.
*** Ernest Rutherford. Which of these scientists developed the nuclear model of the atom?
*** 12.5 mol. When the following equation is balanced, it is found that 1.00 mol of C8H18 reacts
with how many moles of O2(g)? ___C8H18(g) + ___O2(g) --> ___CO2(g) + ___H2O(g)
*** Na2SO4 *6H2O. Sodium sulfate froms a number of hydrates. A sample of a hydrate is
heated until all the water is removed. What is the formula of the original hydrate if it loses 43%
of its mass when heated?
*** 100 mL. How many milliters of 1 M NaOH solution will 25 mL of 2 H2SO4 neutralize?
*** 1.56 atm. The equilibrium pressure of NO2 in the equilibrium N2O4(g) <==> 2 NO2(g) is 1.56
atm. Its pressure on the addition of a catalyst will be _____.
*** 153 kg. Dimenthly hydrazine (CH3)2NNH2 has been used as a fuel in space, with nitrogen
tetraoxide (N2O4) as the oxidizer. The products of the reaction between these two in an engine
are H2O, CO2, and N2. What is the mass of nitrogen tetraoxide required to burn 50 kg of
dimenthly hydrazine?
*** Ar. Which of the following elements has the smallest atomic size?
*** lowering the temperature. The following reaction is at equilibrium at a pressure of 1 atm, in a
closed container.
NaOH(s) + CO2(g) ? NaHCO3(s); ?H°rxn < 0
Which, if any, of the following actions will decrease the concentration of CO2 gas present at
equilibrium?
*** lowering the temperature. The following reaction is at equilibrium in a sealed container.
N2(g) + 3H2(g) ? 2NH3(g); ?H°rxn < 0
Which, if any, of the following actions will increase the value of the equilibrium constant, Kc?
*** 47 Mg. Iron has a density of 7.78 g/cm3. What mass of iron would be required to cover a
football playing surface of 120 yds x 60 yds to a depth of 1.0 mm?(1 inch = 2.54 cm)
*** c. 0.33. The first step in the Otswald process for producing nitric acid is 4NH3(g) + 5O2(G) ?
4NO(g) + 6H2O(g). If the reaction of 150 g of ammonia with 150 g of oxygen gas yeilds 87 g of
nitric oxide (NO), what is the percent yeild of this reaction?
***furnace bricks. "Magnesium oxide, MgO, is an important industrial material. Which of the
following is one of its uses? "
***vapor pressure of water. "An experiment to determine the molar mass of a gas begins by
heating a solid to produce a gaseous product. The gas passes through a tube and displaces
water in an inverted, water-filled bottle. Which of the following items may be determined after
the experiment is completed?"
***carbon dioxide. Which of the following gases will be the slowest to diffuse through a room?
*** 7.02 g. Methane has a Henry's Law constant (k)of 9.88 × 10-2 mol/(Latm) when dissolved in
benzene at 25°C. How many grams of CH4 will dissolve in 3.00 L of benzene if the partial
pressure of CH4 is 1.48 atm?
*** 0.05 m CaSO4. Which of the following aqueous solutions will have the lowest osmotic
pressure?
*** Compton. Which scientist demonstrated that photons transferred momentum during
collisions with matter?
***refraction. Contact lenses can focus light due to the ___________ of the waves.
***liquid in a liquid.. An emulsion is a dispersion consisting of a
*** 1s2 2s2 2p6 3s2 3p4. Select the correct electron configuration for sulfur (Z = 16).
***1.8 g/L. "Air contains 78% N2, 21% O2, and 1% Ar, by volume. What is the density of air
1,000. torr and 10°C?"
***Addition of NaOH solution. Which of the following will shift the equilibrium to the right?
CaCO3(s) <==> CaO(s) + CO2(g)
*** MnO2. Manganese, Mn, forms a number of oxides. A particular oxide is 63.2% Mn. What is
the simplest formula for this oxide
*** Kp = RT × Kc. Consider the equilibrium reaction: N2O4(g) ? 2NO2(g)
Which of the following correctly describes the relationship between Kc and Kp for the reaction?
*** -119.0°C. Benzaldehyde ( MW = 106.1 g/mol), also known as oil of almonds, is used in the
manufacture of dyes and perfumes and in flavorings. What would be the freezing point of a
solution prepared by dissolving 75.00 g of benzaldehyde in 850.0 g of ethanol?
Kf = 1.99°C/m, freezing point of pure ethanol = -117.3°C.
*** 71.3. An ideal gas sample weighing 0.548g at 100°C and 0.993 atm has a volume of 0.237
L. Determine the molar mass [g/mol] of the gas

***As equilibrium is reestablished, the partial pressure of carbon disulfide increases. The
reaction system CS2(g) + 4H2(g) ? CH4(g) + 2H2S(g)
is at equilibrium. Which of the following statements describes the behavior of the system if the
partial pressure of carbon disulfide is reduced?
***-0.020 mol L-1 s-1Consider the reaction 2NH3(g) ? N2(g) + 3H2(g) If the rate ?[H2]/?t is
0.030 mol L-1 s-1, then ?[NH3]/?t is
***16.8 L. Aluminum metal reacts with gaseous HCl to produce aluminum chloride and hydrogen
gas . What volume of hydrogen gas, at STP, is produced when 13.5 g of aluminum is mixed with
an excess of HCL?
*** 97.6. The density of a 20.3 M CH3OH (methanol) solution is 0.858 g/mL. What is the molality
of this solution? H2O is the solvent.
*** C2H3NO5. Peroxyacylnitrate (PAN) is one of the components of smog. It is a compound of
C, H, N, and O. Determine the empirical formula from the following percent composition by
mass: 19.8 percent C, 2.50 percent H, 11.6 percent N, 66.1 percent O. What is its molecular
formula given that its molar mass is about 120 g?
*** 27g. "A reaction produces a gaseous mixture of carbon dioxide, carbon monoxide, and water
vapor. After one reaction, the mixture was analyzed and found to contain 0.60 mol of carbon
dioxide, 0.30 mol of carbon monoxide, and 0.10 mol of water vapor. If the total pressure of the
mixture was 0.80 atm, what was the partial pressure of the carbon monoxide?"
*** q > 0. "An ideal gas (the system) is contained in a flexible balloon at a pressure of 1 atm and
is initially at a temperature of 20.°C. The surrounding air is at the same pressure, but its
temperature is 25°C. When the system has equilibrated with its surroundings, both systems and
surroundings are at 25°C and 1 atm. In changing from the initial to the final state, which one of
the following relationships regarding the system is correct? "
*** True. The half-life of a first-order reaction does not depend on the initial concentration of
reactant.
*** H2SO4 . Which one of the following is a strong acid?
*** arsenic (V) sulphide. The Stock system name for As2S5 is
*** "upper right, lower left". The strongest elemental oxidizing agents are found in the
_________ _________ region of the periodic table while the strongest reducing agents are
found in the ________ ________ region of the periodic table.
*** Charles'. "The volume of an ideal gas is directly proportional to its absolute temperature at
constant pressure and number of moles" is a statement of ________________ Law.
***882 °F. "If 1.5 L of an ideal gas at 250C is heated, the new volume increases 2.5 times the
original volume. The pressure and amount of substance are held constant. What is the new
temperature of gas in 0F"
***as a disinfectant.. Sodium hypochlorite is used
*** 92.6 g/mol. What is the molar mass of toluene if 0.85 g of toluene depresses the freezing
point of 100. g of benzene by 0.47°C?
Kf of benzene is 5.12°C/m.
***305. "The gas present in electric bulbs is argon. If a samle of this gas is at a pressure of
101.325 kPa, when the volume is 0.1L and the temperature is 32°C,what must its temperature
[in °C] be if its volumes becomes 200mL and its pressure 96 kPa?"
*** 16.8L which of th Aluminum metal reacts with gaseous HCl to produce aluminum chloride
and hydrogen gas . What volume of hydrogen gas, at STP, is produced when 13.5 g of
aluminum is mixed with an excess of HCL?
"***Ga Which of the following elements is important in the semiconductor industry to improve the
conductivity of germanium, Ge?"
*** Fe(NO3)2The chemical formula for iron(II) nitrate is
*** poor electrical conductor when molten"Which one of the following properties is least
characteristic of substances composed of small, covalently-bonded molecules? "
***35.9 atm. What is the osmotic pressure of a solution prepared from 13.7 g of the electrolyte
HCl and enough water to make 0.500 L of solution at 18°C?
*** 210 kPa. It is known that ozone (O3) will decompose into oxygen (O2) at a temperature of
100°. One mole of ozone is sealed in a container at STP (0°C and 1 atm). What will be pressure
of the container once it is heated to 100°C?
*** Zeff increases across a period and is relatively constant down a group. " e statements about
the effective nuclear charge, Zeff, is correct? "
***0.085 M. A 2.0% (w/v) solution of sodium hydrogen citrate, Na2C6H6O7, which also contains
2.5% (w/v) of dextrose, C6H12O6, is used as an anticoagulant for blood which is to be used for
transfusions. What is the molarity of the sodium hydrogen citrate in the solution?
*** water. "If, as a pioneer, you wished to warm your room by taking an object heated on top of
a pot-bellied stove to it, which of the following 15-pound objects, each heated to 100°C, would
be the best choice? The specific heat capacity (in J/(gK)) for each substance is given in
parentheses. Iron (0.450), copper (0.387), granite (0.79), water (4.18). "
*** Fe3+ oxidizes I The process _____ occurs spontaneously under standard state conditions.
*** 154. An unknown liquid is vaporized in a 273-mL flask by immersion in a water bath at 99°C.
The barometric pressure is 753 torr. If the mass of the liquid retained in the flask is 1.362 g,
what is its molar mass [g/mol]?
*** 3200 torr. A 500-mL sample of argon at 800 torr has its absolute temperature quadrupled. If
the volume remains unchanged what is the new pressure?
*** 0.15 M. A 0.89% (w/v) sodium chloride solution is referred to as physiological saline solution
because it has the same concentration of salts as human blood. What is the molarity of a
physiological saline solution?
*** The reverse reaction will proceed to reestablish equilibrium At 450°C, tert-butyl alcohol
decomposes into water and isobutene.
(CH3)3COH(g) ? (CH3)2CCH2(g) + H2O(g)

A reaction vessel contains these compounds at equilibrium. What will happen if the volume of
the container is reduced by 50% at constant temperature?

*** ClF. In which of these substances are the atoms held together by polar covalent bonding?
*** w = 0. "Two solutions (the system), each of 25.0 mL volume and at 25.0°C, are mixed in a
beaker. A reaction occurs between them, and the temperature rises to 35.0°C. After the
products have equilibrated with the surroundings, the temperature is again 25.0°C and the total
volume is 50.0 mL. No gases are involved in the reaction. Which one of the following
relationships concerning the change from initial to final states (both at 25.0°C) is correct? "
***0.200. Sulfur dioxide reacts with chlorine to produce thionyl chloride (used as a drying agent
for inorganic halides) and dichlorine oxide (used as a bleach for wood, pulp and textiles).
SO2(g) + 2Cl2(g) ? SOCl2(g) + Cl2O(g)
If 0.400 mol of Cl2 reacts with excess SO2, how many moles of Cl2O are formed?
***46.6 kPa. Calculate the pressure of a helium sample at -207.3°C and 768 mL if it exerts a
pressure of 175 kPa at 25.0°C and 925 mL.
*** Ammonia, NH3. All of the substances listed below are fertilizers that contribute nitrogen to
the soil. Which of these is the richest source of nitrogen on a mass percentage basis?
*** 48. Safrole is used as a topical antiseptic. Calculate the vapor pressure [torr] of a solution
prepared by dissolving 0.75 mol of safrole in 950 g of ethanol ( MW = 46.07 g/mol).
***50.0 mL. How many milliliters of 0.100M H2SO4 are required to neutralize 50.0 mL of 0.200M
KOH?
*** 2.03. How many moles of bromide ions are present in 750.0 mL of 1.35 M MgBr2?
*** Sr. Select the element with the lowest first ionization energy.
*** 0.856 g. Chlorine gas can be prepared in the laboratory by the reaction of solid manganese
dioxide with hydrochloric acid. (The other reaction products are aqueous manganese chloride
and water.)How much MnO2 should be added to excess HCI to obtain 275 mL of chlorine gas at
5.0oC and 650 mmHg?
*** 715 mm Hg. A sample of methane gas was collected over water at 35degC. The sample had
a total pressure of 756 mm Hg. Determine the partial pressure of the methane gas in the
sample. The vapor pressure of water at this temperature is 41 mm Hg.
*** controls chain reaction (control rods). What role does cadmium metal (Cd) play in a nuclear
reactor?
***100 degrees Celcius. At which temperature does a water sample have the highest average
kinetic energy?
*** nuclear fusion. The energy released by the sun is the result of
*** Pb. What element is the stable end-product of the uranium radioactive decay series?
*** The final solution is basic. Potassium metal will react with water to release a gas and form a
potassium compound. Which of the following is true?
*** Cl. The species that is not an oxidizing agent is _____.
*** 190 mL. How many mL of concentrated nitric acid (16 M) are needed to prepare 0.500 L of
6.0 M nitric acid?
*** shielding. The effective nuclear charge for an atom is less than the actual nuclear charge
due to
*** K2O. Which of the following oxides will give the most basic solution when dissolved in
water?
*** do not pollute the air with SO2, soot, and fly-ash". Which of the following is an advantage of
nuclear power plants over coal-burning plants? Nuclear power plants
*** 67 days. The diameter of a spherical mothball is observed to halve in 200 days.
Approximately how long will it take for its remaining volume to become half of its volume at 200
days?
*** 403.65. Determine the alumi of iron (III) bromide hexahydrate, a substance used as a
catalyst in organic reactions.
*** lower left. The smallest ionization energies are found in the ____________ ___________
region of the periodic table.
*** 3.88 L. Some commercial drain cleaners contain a mixture of sodium hydroxide and
aluminum powder. When the mixture is poured down a clogged drain, the following reaction
occurs:
2NaOH(aq) + 2Al(s) + 6H2O(l) ® 2NaAl(OH)4(aq) + 3H2(g)
The heat generated in this reaction helps melt away obstructions such as grease, and the
hydrogen gas released stirs up the solids clogging the drain. Calculate the volume of H2 formed
at 0 °C and 1.00 atm if 3.12 g of Al are treated with an excess of NaOH.
*** 346. Calculate the vapor pressure [torr] of a solution prepared by dissolving 0.500 mol of a
non-volatile solute in 275 g of hexane ( MW = 86.18 g/mol) at 49.6°C. P°hexane = 400.0 torr at
49.6°C.
***168 J. A system initially has an internal energy E of 501 J. It undergoes a process during
which it releases 111 J of heat energy to the surroundings, and does work of 222 J. What is the
final energy of the system, in J?
***"n = 5, l = 3, ml = +1". Which of the following is a correct set of quantum numbers for an
electron in a 5f orbital?
*** True. Once a reaction system reaches equilibrium, the concentrations of reactions and
products no longer change
*** gamma. Which is the most penetrating of the three types of nuclear radiation?
*** Rb. has the smallest first ionization energy?
*** 78.73. Ethanol boils at 78.5 °C. If 10 g of sucrose (C12H22O11) is dissolved in 150g of
ethanol, at what temperature [ °C] will the solution boil? Assume Kb=1.20 ° C/m for the alcohol.
***3600 C. One ampere-hour (1Ahr) is _____.
*** -570 kJ/mol. "When 0.560 g of Na(s) reacts with excess F2(g) to form NaF(s), 13.8 kJ of heat
is evolved at standard-state conditions. What is the standard enthalpy of formation () of
NaF(s)?"
***Planck. Who was the first scientist to propose that an object could emit only certain amounts
of energy?
*** electrons. Beta particles are identical to
*** 14500 atoms. "The half-life of radioactive carbon is approximately 5700 years. If a sample is
found to have 7000 atoms after 6000 years, how many atoms were presents initially?"
***200 mL. A sample of oxygen gas has its absolute temperature halved while the pressure of
the gas remained constant. If the initial volume is 400 mL, what is the final volume?
*** 117.2 g isoamyl salicylate in 950.0 mL of ethyl alcohol. Isoamyl salicylate ( MW = 208.25
g/mol) has a pleasant aroma and is used in perfumes and soaps. Which of the following
combinations gives a 0.75 m solution of isoamyl salicylate in ethyl alcohol (? = 0.7893 g/mL)?
***0.049 mol L-1s-1. The compound RX3 decomposes according to the equation
*** Ag2S. Tarnished silver is coated with _____.
**** lithium. Which element forms compounds which are used to treat individuals suffering from
manic-depressive disorders?
*** 1.8 g. Joseph Priestley discovered oxygen in 1774 by heating mercury(II) oxide. The
compound decomposes into its elements. How much oxygen, O2, is produced by the
decomposition of 25 g of HgO?
*** 6. When the reaction Cu + HNO3 --> Cu2+ + NO + H2O is balanced in acidic solution, the
coefficient of H+ is _____.
*** it has the lowest ionization energy of these noble gases. Xenon forms several compounds
with oxygen and fluorine. It is the most reactive non-radioactive noble gas because
*** IBr. Which of the following contains covalent bonds?
*** - 273°C. Charles's Law relates the volume and temperature of a gas sample at constant
pressure. What would be the temperature of a gas sample when its volume is 0 L?
***381°C. At what temperature in °C will O2 has under a pressure of 2.4 atm? ( of O2= 1.43
g/L)
*** The partial pressure of carbon monoxide will decrease. Methanol can be synthesized by
combining carbon monoxide and hydrogen.
*** 117.2 g isoamyl salicylate in 950.0 mL of ethyl alcohol. Isoamyl salicylate ( MW = 208.25
g/mol) has a pleasant aroma and is used in perfumes and soaps. Which of the following
combinations gives a 0.75 m solution of isoamyl salicylate in ethyl alcohol (? = 0.7893 g/mL)?
***0.049 mol L-1s-1. The compound RX3 decomposes according to the equation
*** Ag2S. Tarnished silver is coated with _____.
**** lithium. Which element forms compounds which are used to treat individuals suffering from
manic-depressive disorders?
*** 1.8 g. Joseph Priestley discovered oxygen in 1774 by heating mercury(II) oxide. The
compound decomposes into its elements. How much oxygen, O2, is produced by the
decomposition of 25 g of HgO?
*** 6. When the reaction Cu + HNO3 --> Cu2+ + NO + H2O is balanced in acidic solution, the
coefficient of H+ is _____.
*** it has the lowest ionization energy of these noble gases. Xenon forms several compounds
with oxygen and fluorine. It is the most reactive non-radioactive noble gas because
*** IBr. Which of the following contains covalent bonds?
*** - 273°C. Charles's Law relates the volume and temperature of a gas sample at constant
pressure. What would be the temperature of a gas sample when its volume is 0 L?
***381°C. At what temperature in °C will O2 has under a pressure of 2.4 atm? ( of O2= 1.43
g/L)
*** The partial pressure of carbon monoxide will decrease. Methanol can be synthesized by
combining carbon monoxide and hydrogen.
***The angular momentum quantum number (l)The shape of an atomic orbital is associated with
*** LiNO3. Select the strongest electrolyte from the following set.
**** Ethanol, C2H5OH, is being promoted as a clean fuel and is used as an additive in many
gasoline mixtures. Calculate the ?H°rxn for the combustion of ethanol.
*** Isoamyl salicylate ( MW = 208.25 g/mol) has a pleasant aroma and is used in perfumes and
soaps. Which of the following combinations gives a 0.75 m solution of isoamyl salicylate in ethyl
alcohol (? = 0.7893 g/mL)?
*** 3.06M What is the molarity of a solution that is 26.0% by mass phosphoric acid (H3PO4) and
that has a density of 1.155 g/mL?
**** 0.1 2.3 g ethanol (C2H5OH) is added to 500 g water. Determine the molality, m, of the
resulting solution.
*****15.87 kJ/°C aWhen 0.7521 g of benzoic acid was burned in a calorimeter containing 1,000.
g of water, a temperature rise of 3.60°C was observed. What is the heat capacity of the bomb
calorimeter, excluding the water? The heat of combustion of benzoic acid is -26.42 kJ/g.
***62.7°C"Benzene is a starting material in the synthesis of nylon fibers and polystyrene
(styrofoam). Its specific heat capacity is 1.74 J/(gK). If 16.7 kJ of energy is absorbed by a 225-g
sample of benzene at 20.0°C, what is its final temperature? "
***"The enthalpy of solid barium hydroxide plus pure water is greater than that of the solution, at
the same temperature." The dissolution of barium hydroxide in water is an exothermic process.
Which of the following statements is correct?
****work Which of the following is not a state function?
**7.98 Calculate the molality of 6.0 M H2SO4 solution. The density of the solution is 1.34 g/mL.
**gamma rays, ultraviolet, infrared, radio. Select the arrangement of electromagnetic radiation
which starts with the lowest wavelength and increases to greatest wavelength.
** H2(g) + Br2(g) ? 2HBr(g) For which one of the following reactions will?H be approximately (or
exactly) equal to ?E?
*** 0.33 The first step in the Otswald process for producing nitric acid is 4NH3(g) + 5O2(g) ?
4NO(g) + 6H2O(g). If the reaction of 150 g of ammonia with 150 g of oxygen gas yeilds 87 g of
nitric oxide (NO), what is the percent yeild of this reaction?"
***Zeff increases across a period and is relatively constant down a group "Which of the following
statements about the effective nuclear charge, Zeff, is correct? "
**** strong reducing agents. The elements from Groups 1A(1) and 2A(2) are
***1.01 × 102 J "A system expands from a volume of 1.00 L to 2.00 L against a constant
external pressure of 1.00 atm. The work (w) done by the system, in J, is"
**"w = ?EA system which undergoes an adiabatic change (i.e., q = 0) and has work done on it
by the surroundings has "
***-420 J A system delivers 1275 J of heat while the surroundings perform 855 J of work on it.
Calculate ?E in J.
**95 1 How many moles of solute particles are present in 100.0 mL of 2.50 M (NH4)3PO4?
The highly exothermic thermite reaction, in which aluminum reduces iron(III) oxide to elemental
iron, has been used by railroad repair crews to weld rails together.
2Al(s) + Fe2O3(s) ? 2Fe(s) + Al2O3(s) ?H = -850 kJ
What mass [g] of iron is formed when 725 kJ of heat are released?
*** the Pauli exclusion principle. Each electron in an atom must have its own unique set of
quantum numbers"" is a statement of
***3°C "When Mr. Bean adds chilled grog to his new granite mug, he removes 10.9 kJ of energy
from the mug. If it has a mass of 625 g and was at 25°C, what is its new temperature? Specific
heat capacity of granite = 0.79 J/(gK) "
***180 g/molA sugar solution was prepared by dissolving 9.0 g of sugar in 500 g of water. At 27
deg C, the osmotic pressure was measured as 2.46 atm. Determine the molecular weight of
sugar.
*** 2.26 M"Which of the following gives the molarity of a 17.0% by mass solution of sodium
acetate, CH3COONa (molar mass = 82.0 g/mol) in water? The density of the solution is 1.09
g/mL. "
***CI < CBr < CCl < CFArrange the following bonds in order of increasing bond strength.
*** 168 J "A system initially has an internal energy E of 501 J. It undergoes a process during
which it releases 111 J of heat energy to the surroundings, and does work of 222 J. What is the
final energy of the system, in J? "
***number The modern periodic table is arranged based upon atomic
** Cl2O Which of the following is a covalent compound?
*** 4 What is the valence (oxidation state) of carbon in sodium carbonate (Na2CO3)?
*** 78.73"Ethanol boils at 78.5 deg C. If 10 g of sucrose (C12H22O11) is dissolved in 150g of
ethanol, at what temperature [deg C] will the solution boil? Assume Kb=1.20 deg C/m for the
alcohol."
** 1.5 M CH3OH, methyl alcohol from the following list of aqueous solutions and water, select
the one with the lowest freezing point.
** 0.1 M NaCl Which of the following aqueous solutions should demonstrate the most ideal
behavior
**100.22°C What is the boiling point of an aqueous solution of a nonelectrolyte that has an
osmotic pressure of 10.50 atm at 25°C? Kb of water is 0.52°C/m. Assume the density of the
solution is the same as that of pure water.
**Rydberg Who developed an empirical equation from which the wavelengths of lines in the
spectrum of hydrogen atoms can be calculated?

*** "?H > 0, process is endothermic""Cold packs, whose temperatures are lowered when
ammonium nitrate dissolves in water, are carried by athletic trainers when transporting ice is not
possible. Which of the following is true of this reaction? "
** "n = 3, l = 2, ml = -2" Which of the following is a correct set of quantum numbers for an
electron in a 3d orbital?
**the number of particles dissolved. Colligative properties depend on
** In < Al < P < N "Arrange aluminum, nitrogen, phosphorus and indium in order of increasing
electronegativity. "
** Br- Which of the following ions and atoms has the greatest radius?
**the magnetic quantum number (ml). The orientation in space of an atomic orbital is
associated with.
** O > S > Ca > K > Rb "Arrange oxygen, sulfur, calcium, rubidium and potassium in order of
decreasing electronegativity. "
**H2AsO4 A solution is prepared by mixing 50.0 mL of 0.20M arsenic acid, H3AsO4, and 50.0
mL of 0.20M sodium hydroxide, NaOH. Which anion is present in the highest concentration?

** 769 How many grams of water are needed to dissolve 27.8 g of ammonium nitrate NH4NO3
in order to prepare a 0.452 m solution?
** 0.75 M CuCl2 From the following list of aqueous solutions and water, select the one with the
highest boiling point.
** 5.45 x 10^-19 J "According to the Bohr theory of the hydrogen atom, the minimum energy (in
J) needed to ionize a hydrogen atom from the n = 2 state is "
** London Dispersion Forces Octane is a component of fuel used in internal combustion
engines. The dominant intermolecular forces in octane are

** 6°C A glass containing 200. g of H2O at 20°C was placed in a refrigerator. The water loses
11.7 kJ as it cools to a constant temperature. What is its new temperature? The specific heat of
water is 4.184 J/g°C.
** q = ?E A system that does no work but which receives heat from the surroundings has
** [Ar]4s1 3d10 Select the correct electron configuration for Cu (Z = 29).
** 1.92 × 102 kcal "Natural gas, or methane, is an important fuel. Combustion of one mole of
methane releases 802.3 kilojoules of energy. How much energy does that represent in
kilocalories? "
**the concentration of the solution will remain the same. "A solution of sucrose (sugar) in water
is in equilibrium with solid sucrose. If more solid sucrose is now added, with stirring, "

** 12.6 gHexachlorophene is used as a disinfectant in germicidal soaps. What mass of

hexachlorophene ( MW = 406.9 g/mol) must be added to 125 g of chloroform to give a solution
with a boiling point of 62.60°C?
** 118.8°C Barbiturates are synthetic drugs used as sedatives and hypnotics. Barbital ( MW =
184.2 g/mol) is one of the simplest of these drugs. What is the boiling point of a solution
prepared by dissolving 42.5 g of barbital in 825 g of acetic acid?
** 13.2°C "If 325 g of water at 4.2°C absorbs 12.28 kJ, what is the final temperature of the
water? The specific heat of water is 4.184 J/g°C."
** 2.0 L How many liters of 2M solution (i.e., a molarity of 2) can be produced from 184 g of
ethyl alcohol (CH3CH2OH)?
** 5.80Calculate the molality of a solution containing 14.3 g of NaCl in 42.2 g of water.
**"For n = 4, the largest possible value of ml is 2." Which one of the following statements about
atomic structure and quantum numbers is incorrect?
"-870 J A system delivers 225 J of heat to the surroundings while delivering 645 J of work.
Calculate the change in the internal energy, ?E, of the system. "
** 18 "In the ground state of an atom of silver (Ag), how many electrons will there be with the
quantum number l = 1? (The n, ml and ms quantum numbers may have any appropriate
values.) "
** Cl Which of the following elements is the most electronegative?
** 0.15 m Na2SO4 Which of the following aqueous solutions has the lowest freezing point?

** a. ethanol <Mg(NO3)2 < NaCl.Arrange the following aqueous solutions in order of increasing
boiling points. 0.050 m Mg(NO3)2; 0.100 m ethanol; 0.090 m NaCl
** 0.25M When 50.0 mL of 1.0M AgNO3 is added to 50 mL of 0.50M HCl, a precipitate of AgCl
forms. After the reaction is complete, what is the concentration of silver ions in the solution?
**6.01 M Potassium fluoride is used for frosting glass. Calculate the molarity of a solution
prepared by dissolving 78.6 g of KF in enough water to produce 225 mL of solution.

** It can be doped to form a high temperature semiconductor. Silicon carbide is an important

industrial chemical. Which of the following statements about silicon carbide is true?
** de Broglie Which scientist first proposed that particles of matter could have wave properties?
** 405 J "A system contracts from an initial volume of 15.0 L to a final volume of 10.0 L under a
constant external pressure of 0.800 atm. The value of w, in J, is "
** 1.7C Calculate the freezing point of a solution made by dissolving 3.50 g of potassium
chloride (MW = 74.55 g/mol) in 100.0 g of water. Assume ideal behavior for the solution; Kf =
1.86°C/m.
** uniformly increase. "While moving from left to right across the second row of the periodic
table (i.e., from Li to Ne), the atomic radii tend to"
** 3.64 kJ/°C. Naphthalene combustion can be used to calibrate the heat capacity of a bomb
calorimeter. The heat of combustion of naphthalene is -40.1 kJ/g. When 0.8210 g of
naphthalene was burned in a calorimeter containing 1,000. g of water, a temperature rise of
4.21°C was observed. What is the heat capacity of the bomb calorimeter excluding the water?
** "A chemist dropped a 200 g object into a tank of water. It displaced 60 mL of the water when
it sunk to the bottom of the tank. In a similar experiment, it displaced only 50 g of oil into which it
was dropped. Calculate the density of the oil [g/mL]."

**32 "In a single atom, what is the maximum number of electrons which can have quantum
number n = 4? "
** S > As > Ca > Rb "Arrange calcium, rubidium, sulfur, and arsenic in order of decreasing
electronegativity. "
** "5, 1, 0, ½" "Select the correct set of quantum numbers (n, l, ml, ms) for the highest energy
electron in the ground state of tin, Sn. "
** The alkaline earth salts have much greater lattice energies than the alkali metal salts. Most
of the alkali metal salts are soluble in water while many alkaline earth salts have very low
solubilities. Why is this so?
** first When the reaction A ? B + C is studied, a plot of ln[A]t vs. time gives a straight line with a
negative slope. What is the order of the reaction?
** NH4Br Which one of the following substances will give an aqueous solution of pH < 7?
** Temperature Which an alter the value of the equilibrium constant?
** Kp = Kc Consider the equilibrium reaction: H2(g) + Br2(g) ? 2HBr(g)
Which of the following correctly describes the relationship between Kc and Kp for the reaction?
** 2.71V The standard emf of the cell involving Mg/Mg2+ and Cu/Cu2+ half-cell reactions is
_____.
**0.11 A given sample of radioactive material has 80% of the original substance remaining after
10 years. How much will remain after 90 additional years?
**12.70 What is the pH of a 0.050 M LiOH solution?
** 3DAYS What is the half-life of a substance that decays to 25% of its original amount in six
days?
** True Unless ?H°rxn = 0, a change in temperature will affect the value of the equilibrium
constant Kc.
** "difficult, if not impossible. to prove A reaction mechanism usually is
** As equilibrium is reestablished, the partial pressure of carbon disulfide increases. The
reaction system CS2(g) + 4H2(g) ? CH4(g) + 2H2S(g) is at equilibrium. Which of the following
statements describes the behavior of the system if the partial pressure of carbon disulfide is
reduced?
** it lowers the activation energy for the reaction. A catalyst accelerates a reaction because
** FALSE There is a direct correlation between the speed of a reaction and its equilibrium
constant.
** less than 1.112 The value of Kc for the equilibrium 2SO2(g) + O2(g) <==> 2SO3(g) is
5.6x10^4 at 350 C. The initial pressures of SO2 and O2 are 0.35 and 0.762 atm. The total
pressure at equilibrium will be

** 0.37VThe standard potential for the reduction of Cu+ to Cu is 0.52V. E° at 25 °C for 2Cu+(aq)
--> Cu2+(aq) + Cu(s) is _____.
** FALSE. For a gas-phase equilibrium, a change in the pressure of any single reactant or
product will affect the amounts of other substances involved in the equilibrium.
** FALSE For a gas-phase equilibrium, a change in the pressure of any single reactant or
product will change Kp.
**FALSE For some gas-phase reactions, Kp = Kc.
** helium nuclei Alpha particles are identical to

** the frequency of molecular collisions increases "When the concentrations of reactant

molecules are increased, the rate of reaction increases. The best explanation for this
phenomenon is that as the reactant concentration increases,"
** one atomic number higher than the original element. "As a result of beta decay, the product
nucleus is "
** 0.35V The emf of the concentration cell Cu/Cu2+(0.08 M)||Cu2+(1.2 M)/Cu is _____.
**0.52 "What is the value of Kc for the reaction CO2(g) + H2(g) <==> H2O(g) + CO(g) when the
equilibrium concentrations of CO, H2, CO2, and H2O are 0.050 M, 0.045 M, 0.086 M and 0.040
M respectively?"
** TRUE For a gas-phase equilibrium, a change in the pressure of any single reactant or
product will affect the amounts of other substances involved in the equilibrium.
** TRUE Once a reaction system reaches equilibrium, the concentrations of reactions and
products no longer change.
** Rate = k[H2O2][H+][Br-]Consider the following mechanism for the oxidation of bromide ions
by hydrogen peroxide in aqueous acid solution.
H+ + H2O2 H2O+-OH (rapid equilibrium)
H2O+-OH + Br- ? HOBr + H2O (slow)
HOBr + H+ + Br- ? Br2 + H2O (fast)
Which of the following rate laws is consistent with the mechanism?
** change in temperature products Which of the following has an effect on the magnitude of the
equilibrium constant?
** TEMPERATURE Which can alter the value of the equilibrium constant?
** zeroth order For what order reaction does the half-life get longer as the initial concentration
increases?
** ions and free radicals Gamma-rays cause radiation damage when they interact with matter by
producing

** 1.1 Kc for the formation of one mole of NH3 from H2 and N2 is _____.
** californium-249 Which isotope, when bombarded with nitrogen-15, yields the artificial isotope
dubnium-260 plus 4 neutrons?
** fusion reaction Which type of nuclear process requires an extremely high temperature
(millions of degrees)?
** oxygen is liberated at the anode "In the electrolysis of water, _____."
** 0.7 What is the pH of a 0.20 M HCl solution?
** 0.76V The standard potential of the cell consisting of the Zn2+/Zn half-cell and the SHE is
**Ea/R The Arrhenius equation is k = A e-(Ea/RT). The slope of a plot of ln k vs. 1/T is equal to
_____.
** FALSE. When a reaction system reaches equilibrium, the forward and reverse reactions stop.
** in the reaction equation, the number of moles of gaseous products equals the number of
moles of gaseous reactants. The two equilibrium constants for the same reaction, Kc and Kp,
will always equal one another when
** a. A catalyst increases the rate of the forward reaction, but does not alter the reverse rate.
Which of the following statements is false?
**6 "When the reaction Cu + HNO3 --> Cu2+ + NO + H2O is balanced in acidic solution, the
coefficient of H+ is _____."
*** 0.5 "Kp is 158 for the equilibrium 2NO2(g) <==> 2 NO(g) + O2(g) Starting with NO2 (g) only,
the partial pressure of NO at equilibrium is 0.25 atm. Calculate the partial pressure [atm] of NO2
at equilibrium."
** "0.1 M HBO, pKa = 2.43" Which of the following acids has the lowest pH?
** 6 The number of faradays required to deposit one mole of Cr metal from Cr2O72- is