Iit Jee 2010 s0ln
Iit Jee 2010 s0ln
Iit Jee 2010 s0ln
INSTRUCTIONS
A. General :
1. This question Paper contains 43 pages having 84 questions
2. The question paper CODE is printed on the right hand top corner of this sheet and also on the
back page (page no 32 of this booklet)
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y
No additional sheets will be provided for rough work
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electronic gadgets in any form are not allowed
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separately.
IIT
6.
ya
Do not Tamper/multilate the ORS or this booklet
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a
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invigilators.
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B. Filling the bootom half of the ORS :
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The ORS has CODE printed on its lower and upper Parts.
Make sure the CODE on the ORS is the same as that on this booklet. If the Codes do not
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Sri Chaitanya IIT Academy.A.P. Ø2× :: IIT JEE 2010 Paper - I ::
1. The bond energy (in kcal mol1) of a CC single bond is approximately
A) 1 B) 10 C) 100 D) 1000
Ans : C
Sol : C C bond energy is 100 kcal/mol approximately
2. The species which by definition has ZERO standard molar enthalpy of formation
at 298K is
m y
A) Br2(g) B) Cl2(g)
a d e
C) H2O(g)
D) CH (g)
c
4
Ans : B
IT= 0A
Sol : ∆H 0f for Cl2 g ;
y I
( ) which is in nativeastate
a n
3. Plots showing the variationtof the rate constant (k) with temperature (T) are given
i Arrhenius equation is
below. The plot thath
C a
follows
S r i
A) k B) k
T T
C) k D) k
T T
Ans : A
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Sri Chaitanya IIT Academy.A.P. Ø3× :: IIT JEE 2010 Paper - I ::
A) Br OCH3 and H
2
B) Br and CH Br
3
C) Br and CH OH
3
D) OH and CH Br
3
Ans : D
H
Sol : +
y
O CH3
H
→ O CH3
d e m
Br-(SN2)
A c a
II T
a
OH + CH3 - Br
a n y
a it
5.
i C h
The correct statement about the following disaccharide is
CH2OH
oS r CH2OH O H
H H (a) H (b)
H OH
OH H OCH2CH2O CH2OH
OH OH H
H OH
Ans : A
Sol : Pyranose is six membered ring and furanose is five membered ring. Ring(a) is
attached with α − linkage
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6. The synthesis of 3-octyne is achieved by adding a bromoalkane into a mixture of
sodium amide and an alkyne. The bromoalkane and alkyne respectively are
A) BrCH2CH2CH2CH2CH3 and CH3 CH2C ≡ CH
B) BrCH2CH2 CH3 and CH3CH2CH2C ≡ CH
C) BrCH2CH2CH2CH2CH3 and CH3C ≡ CH
D) BrCH2CH2CH2CH3 and CH3CH2C ≡ CH
Ans : D
Sol : R Br + sodamide + Alkyne → CH3 CH2 C ≡ C CH2 CH2 CH2 CH3
possiblities
1) CH3 CH2 Br + CH3 CH2 CH2 CH2 C ≡ C H
y
(or)
e m
2) CH3 CH2 CH2 CH2 Br + CH3 CH2 C ≡ CH ∴ D is correct
7. The ionization isomer of [Cr(H O) Cl (NO )]Cl is ad
A
2
c
T[Cr(H O) Cl ](NO )
4 2
A) [Cr(H O) (O N)] Cl
a II
B)
y
2 4 2 2 2 4 2 2
C) [Cr(H O) Cl(ONO)] Cl
2 4
Ans : B
h a
C of coordination sphere are Cl and . The ionisation
r i
S O) Cl(NO )] Cl is [Cr(H O) Cl ] (NO )
Sol : Ions present outside
isomer of [Cr(H
NO 2−
2 4 2 2 4 2 2
A) B)
C) D)
Ans : C
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Sri Chaitanya IIT Academy.A.P. Ø5× :: IIT JEE 2010 Paper - I ::
SECTION - II (Multiple Correct Choice Type)
This section contains 5 multiple choice questions. Each question has four choices A), B), C), D) out of whihc ONE OR
MORE may be correct.
OH
O O O
O
Br
A) B) C) D)
Br Br Br Br Br
Ans : A,B,C
y
Sol : Phenol react with NaOH gives phenoxide ion which is ortho,para directing group
m
hence Br+ attack at ortho, para positions
a de
10.
A c
In the Newman projecttion for 2, 2 dimethylbutane
T
a IXI
a n
H3 C
y CH3
a it
h
H H
r i C be Y
A) H and H
S
X and Y can respectively
B) H and C H 2 5
CH3(X)
H3C CH3
Sol : Rotation between C2 and C3
H H
CH3(Y)
H(X)
H3C CH3
Rotation between C1 and C2
H H
C2H5(Y)
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Sri Chaitanya IIT Academy.A.P. Ø6× :: IIT JEE 2010 Paper - I ::
11. Aqueous solutions of HNO3, KOH, CH3COOH, and CH3COONa of identical con-
centrations are provided. The pair(s) of solutions which form a buffer upon mix-
ing is (are)
A) HNO3 and CH3COOH B) KOH and CH3COONa
C) HNO3 and CH3COONa D) CH3COOH and CH3COONa
Ans : D
Sol : Weak acid and its salt with strong base
12. The reagent(s) used for softening the temporary hardness of water is (are)
A) Ca3(PO4)2 B) Ca(OH)2 C) Na2CO3 D) NaOCl
Ans : B,C
Sol : Calcium hydroxide and Sodium carbonate are used to softening the temporary
y
hardness of water
d e m
13. Among the following, the intensive property is (properties are)
A) molar conductivity
A c a
B) electromotive force
C) resistance
II
D)Theat capacity
n y a
Ans : A,B
a i a
t of quantity
i C h
Sol : Intensive property is independent
Sr
SECTION - III (Paragraph Type)
This section contains 2 paragraphs. Based upon the first paragraph 2 multiple choice questions and based upon the
second paragraph 3 multiple choice questions have to be answered. Each of these questions has four choices A), B), C)
The concentrationof potassium ions inside a biological cell is at least twenty times
higher than the outside. The resulting potential difference across the cell is impor-
tant in several processes such as tramsmission of nerve impulses and maintaining
the ion balance. A simple model for such a concentration cell involving a metal M is :
For the above electrolytic cell the magnitude of the cell potential |Ecell| = 70 mV.
14. For the above cell
A) Ecell < 0 ; ∆G > 0 B) Ecell > 0 ; ∆G < 0 C) Ecell < 0 ; ∆G 0 > 0 D) Ecell > 0 ; ∆G 0 < 0
Ans : B
Sol : Cell reaction is spontaneous reaction
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Sri Chaitanya IIT Academy.A.P. Ø7× :: IIT JEE 2010 Paper - I ::
15. If the 0.5 molar solution of M is replaced by a 0.0025 molar M+ solution, then the
+
0.0591 1
Sol : For given cell, Ecell = log (0.05 )
1
given Ecell = 70 mV
0.0591 1
hence Ecell = log
1 0.0025
0.0591 1
Ecell = log (0.05 )2
y
1
= 140 mV
e m
Paragraph for Questions 16 toa 18d
A c
T metals and occurs in small
Copper is the most noble of the first rowItransition
deposits in several countries. Oresyofa
I
a n copper include chalcanthite (CuSO .5H O),
t (Cu O), copper glance (Cu S) and malachite
atacamite (Cu Cl(OH) ),icuprite
4 2
C
2
2 2
Sr(CuFeS ). The extraction of copper from chalcopyrite involves par-
chalcopyrite
3
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Sri Chaitanya IIT Academy.A.P. Ø8× :: IIT JEE 2010 Paper - I ::
SECTION - IV (Integer Type)
This section contains TEN questions. The answer to each question is a single digit integer ranging from 0 to 9. The
correct digit below the question number in the ORS is to be bubbled
19. Based on VSEPR theory, the number of 90 degree FBrF angles in BrF5 is
Ans : 0 F
F F
Sol : Br
F F
Repulsion b/w lone pair of e and bond pair of electrons. Because of this bond
angle less than 900
20. The value of n in the molecular formula BenAl2Si6O18 is
Ans : 3
m y
a d e
21. A student performs a titration with different burettes and finds titre values of
T A c
25.2 mL, 25.25 mL, and 25.0 mL. The number of significant figures in the average
titre value is
a II
Ans : 3
a n y
a i t
Sol : Average titre value is 25.15 which is round of as number of significant figures as
C h
small as in the individual titre values
i of R in the reaction R P was measured as a function of time
S r
22. The concentration
and the following data is obtained.
→
Ans : 0
x
Sol : k =
t
Ans : 4
Sol : 235
U 92 + 1n 0 → 142
Xe 54 + 90Sr38 + 4 1n 0
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24. The total nuber of basic groups in the following form of lysine is
Ans : 2
25. The total number of cyclic isomers possible for a hydrocarbon with the molecular
formula C4H6 is
m y
e
Ans : 5
c a d
CH3 CH2 CH3
IT A
Sol : , , , ,
y a I
it a n
C h a
r i
26. In the scheme given below, the total number of intramolecular aldol condensa-
S formed from Y is
tion products
1. O 3
2. Zn ,H 2O
→Y
1. NaOH (aq )
2. heat
→
Ans : 1
H HH H
O
Y= O
Sol :
H HH H
Y is symmetrical diketone. All α − H atoms are identical ∴ only one type of con-
densation is possible
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Sri Chaitanya IIT Academy.A.P. Ø10× :: IIT JEE 2010 Paper - I ::
27. Amongst the following, the total number of compounds soluble in aqueous NaOH is
OH
NO2 CH2CH3 COOH
CH2CH3
N
H3C CH3
Ans : 4
m y
OH
a d e
COOH OH
T Ac COOH
a I I
y
Sol : , , ,
i t a n N
a
H3C CH3
i C h
r paper blue is
28. Amongst the following, the total number of compounds whose aqueous solution
S
turns red litmus
KCN K SO 2 4
(NH ) C O NaCl 4 2 2
Zn(NO )
4 3 2
FeCl3 K2CO3 NH4NO3 LiCN
Ans : 2
S .B W .A
}
+ HCN → solution becomes alkaline
K 2CO 3
H 2O
S .B W .A
}
→ KOH + H 2CO 3 → solution becomes alkaline
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Sri Chaitanya IIT Academy.A.P. Ø11× :: IIT JEE 2010 Paper - I ::
PART - II : MATHEMATICS
SECTION - I (SINGLE CORRECT CHOICE TYPE)
This section contains 8 multiple choice questions. Each question has four choices A), B), C) and D) out of which ONLY
ONE is correct
29. Let f, g and h be real - valued functions defined on the interval [0, 1] by
f ( x ) = e x + e − x , g( x ) = xe x + e − x and h( x ) = x 2 e x + e − x . If a, b and c denote, respec-
2 2 2 2 2 2
Ans : D
my
Sol : f ( x ) = e x + e − x
2
ade2
T Ac
II
f (0) = 2 and f (1) = e + e −1
a
any
t
f 1 ( x ) = 2 x( e x − e − x ) ≥ 0∀x ∈ [0, 1]
2 2
hai
absolute max. of
r i C a = e + e −1
S 2
g( x ) = x e x + e − x
2
g(0) = 1, g(1) = e + e −1
2
h( x ) = x 2 e x + e − x
2
h(0) = 1, h(1) = e + e −1
h ’( x ) = 2 x[ e x + x 2 ex 2 − e − x ] ≥ 0∀x ∈ [0, 1]
2 2
∴a = b = c
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Sri Chaitanya IIT Academy.A.P. Ø12× :: IIT JEE 2010 Paper - I ::
30. Let p and q be real numbers such that p ≠ 0, p 3 ≠ q and p 3 ≠ −q. If α and β are non-
zero complex numbers satisfying α + β = − p and α 3 + β 3 = q , then a quadratic equa-
α β
tion having β and α as its roots is
A) ( p 3 + q )x 2 − ( p 3 + 2 q )x + ( p 3 + q ) = 0 B) ( p 3 + q )x 2 − ( p 3 − 2 q )x + ( p 3 + q ) = 0
C) ( p 3 − q )x 2 − (5 p 3 − 2 q )x + ( p 3 − q ) = 0 D) ( p 3 − q )x 2 − (5 p 3 + 2 q )x + ( p 3 − q ) = 0
Ans : B
Sol : α + β − p , α 3 + β 3 = q
α β α 2 + β 2 p 3 − 2q
Sum of the roots = + =
β α αβ
my= 3
p +q
ade
Product of the roots =
T Ac
α β
. =1
a II β α
any
t
p 3 − 2q
∴ Req. equation.
hai x2 − 3
p + q
x + 1 = 0
r i C
S
⇒ ( p 3 + q )x 3 − ( p 3 − 2 q )x + ( p 3 + q ) = 0
1 t An(1 + t )
x
1 1 1
A) 0 B) C) D)
12 24 64
Ans : B
t log(1 + t )
x
∫
Sol : Lt 0 t + 4
4
dt
x →0 x3
32. The number of 3 x 3 matrices A whose entries are either 0 or 1 and for which the
x 1
system A y = 0 has exactly two distinct solutions, is
z 0
A) 0 B) 2 9 − 1 C) 168 D) 2
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Ans : A
Sol : A system of equations in 3 unknowns cant have two distinct solutions.
33. Let P, Q, R and S be the points on the plane with position vectors
−2iˆ − ˆj , 4iˆ , 3iˆ + 3 ˆj and − 3iˆ + 2 ˆj respectively. The quadrilateral PQRS must be a
my
ade
T Ac
a II
any
ait
Ch
Sri
Therefore AB, CD are equal AD, BC are equal. Therefore ABCD is a parallelo-
gram but not rhombus or rectangel.
34. Let ω be a complex cube root of unity with ω ≠ 1. A fair die is thrown three times.
If r1 , r2 and r3 are the numbers obtained on the die, then the probability that
ω r1 + ω r2 + ω r3 = 0 is
1 1 2 1
A) B) C) D)
18 9 9 36
Ans : C
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Sri Chaitanya IIT Academy.A.P. Ø14× :: IIT JEE 2010 Paper - I ::
Sol :
y
2c .2c .2c .3! 2
∴p( A) = 1 1 1 = .
6c1.6c1.6c1. 9
dem
A ca
Equation of the plane containing thea I IT line x y z
35.
a n y straight = =
and perpendicular to
2 3 4
a it
h
x y z x y z
the plane containing the straight lines = = and = =
is
r i C 3 4 2 4 2 3
A) S B)
x + 2y − 2z = 0 3x + 2 y − 2 z = 0
C) x − 2y + z = 0
D) 5x + 2 y − 4 z = 0
Ans : C
x y 2 x y z
Sol : d.rs of the normal to the plane containing = = & = = are 8, -1, -10
3 4 2 4 2 3
x y z
Now d.rs of the normal of the plane containing = = & above normal are
2 3 4
x − 2y + z = 0
1 3
A) B) C) 1 D) 3
2 2
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Ans : D
a c
Sol : 2 sin c.cos c + 2 sin A cos A
c a
a c
= .2 sin c cos c + .2 sin A cos A
2 R sin c 2 R sin A
π
37. Let ABC be a triangle such that ∠ACB = and let a, b and c denote the lengths of
y
6
dem
the sides opposite to A, B and C respectively. The values (s) of x for which
a = x + x + 1, b = x − 1 and c = 2 x + 1 is (are)
ca
2 2
IT A
A) − (2 + 3 ) B)
a
1+ 3
y IC) D) 2+ 3 4 3
Ans : A,B
itan
Ch a
Sri
π 3 ( x 2 + x + 1)2 + ( x − 1)2 − (2 x + 1)2
Sol : cos = =
6 2 2( x 2 + x + 1)( x 2 − 1)
3 (x 4 + x 3 + x 2 − x 2 − x − 1 ) = x 4 + x 2 + 1 + 2 x 3 + 2 x 2 + 2 x + x 4 − 2 x 2 + 1 − 4 x 2 − 4 x − 1
3 (x 4 + x 3 − x − 1 ) = 2 x 4 + 2 x 3 − 3x 2 − 2 x + 1
( ) ( )
⇒ 2 − 3 x 4 + 2 − 3 x 3 − 3x 2 − 2 − 3 x + 1 + 3 = 0( ) ( )
x = −1(2 + 3), x = 1 + 3 , x = ±1
38. Let z1 and z2 be two distinct complex numbers and let z = (1 − t )z1 + tz2 for some real
number t with 0 < t < 1. If Arg(w) denotes the principal argument of a nonzero
complex number w, then
z − z1 z − z1
C) =0 D) Arg( z − z1 ) = Arg( z2 − z1 )
z2 − z1 z2 − z1
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Ans : A,B,C,D
Sol : Z lie on the line joining the points z1, z2
AB + BC = AC
Therefore |z − z1 |+|z − z2 |=| z1 − z2 |
ABC collinear therfore argument of AB, argument of AC equal and also argu-
ment of AC, argument of AB equal. So B, D is correct.
m y
e
Complex slope of AB = complex slope of BC
cad
A
z − z1 z − z2
T
= = − − − (c )
z − z1 z − z2
a II
ais n
y
t
x 4 (1 − x )4
1
C
0
A)
22
−π r
S B) i 2
C) 0 D)
71 3π
−
7 105 15 2
Ans : A
Sol : (1 − 4 x + 6 x 2 − 4 x 3 + 2 4 ) x 4
x 2 + 1 )x 8 − 4x 7 + 6x 6 − 4x 5 + x 4 ( x 6 − 4x 5 + 5x 4 − 4x 2 + 4
x8 + x6
−4x 7 + 5x 6 − 4x 5
−4 x 7 − 4x 5
5x 6 + x 4
5x 6 + 5 x 4
−4 x 4
−4 x 4 − 4 x 2
4x 2
4x 2 + 4
−4
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Sri Chaitanya IIT Academy.A.P. Ø17× :: IIT JEE 2010 Paper - I ::
1
x 7 4x 6 x 5 4x 3 −1
Given integral = 7 − 6 + 5 5 − 3 + 4 x − 4 tan x
0
22
= −π = 0 .
7
40. Let A and B to two distinct points on the parabola y 2 = 4 x. If the axis of the pa-
rabola touches a circle of radius r having AB as its diameter, then the slope of the
line joining A and B can be
1 1 2 −2
A) − B) C) D)
r r r r
Ans : C,D
m y
e
2 2
Sol : A = t1 , t , B = t2 , t
cad
A
1 2
II Tis 2(t1 + t2 )
y a
Mid.point of A,B is center of the circle that
n
. Because circle touches
2
=r
x -axis
a it a
i C h 2(t2 − t1 ) 2(t 2 − t1 )
Sr
Slope of AB = =
t 2 − t1
2 2
(t2 − t1 )(t2 + t1 )
2 2
= in first quadrant, in fourth quadrant it is −
r r
x
f ( x ) = An x + ∫ 1 + sin t dt. Then which of the following statement(s) is (are) true?
0
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Sri Chaitanya IIT Academy.A.P. Ø18× :: IIT JEE 2010 Paper - I ::
Ans : B, C
x
1
f 1 (x) = + 1 + sin x . exists ∀x ∈ (0, ∞)
x
∴ f 1 ( x )exists
Hence f 1 ( x ) is continuous
−1 1
f "(x) = + (cos x)
x 2 1 + sin x
2
IT A
is not differential for sinx = - 1
f 1 (x)
y a I
So (B) correct.
it a n
∫ i Ch
x
a
Sr
f ( x ) = log x + 1 + sin t.dt
0
1
f 1 (x ) = + 1 + sin x
x
1
If x > 1 then ∈ (0, 1)
x
x2 y2
The circle x + y − 8x = 0 and hyperbola
2 2
− = 1 intersect at the points
9 4
A and B.
42. Equation of a common tangent with positive slope to the circle as well as to the
hyperbola is
A) 2 x − 5y − 20 = 0 B) 2 x − 5y + 4 = 0 C) 3x − 4 y + 8 = 0 D) 4x − 3y + 4 = 0
Ans : B
my
Sol : Tangent for hyperbola
ade
c
y = mx ± 9m 2 − 4
IT A
If it touches the circle then
ya I
r=d
i tan
( )Cha
4m ± 9m2 − 4
Sri
4= .
m2 + 1
16m 2 + 16 = 16 m 2 + 9m 2 − 4 ± 8m 9 m 2 − 4
9m 2 − 20 = ±8m 9m 2 − 4
= 576m 4 − 256m 2
m2 = 4 /5, m = 2 / 5
A) x 2 + y 2 − 12 x + 24 = 0 B) x 2 + y 2 + 12 x + 24 = 0
C) x 2 + y 2 + 24 x − 12 = 0 D) x 2 + y 2 − 24 x − 12 = 0
Ans : A
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Sri Chaitanya IIT Academy.A.P. Ø20× :: IIT JEE 2010 Paper - I ::
Sol : x + y − 8x = 0 − −(1)
2 2
4 x 2 − 9 y 2 = 36 − −(2)
−6
x = 6,
13
∴if x = 6 , y = ±2 3
( )
A = 6, 2 3 , B = 6, −2 3 ( )
Equation of circle with A, B as ends of diameter
(x − 6 )(x − 6 ) + (y + 2 3 )(y − 2 3 ) = 0
m y
a d e
x 2 + y 2 − 12 x + 24 = 0 − − − ( A)
A c
T 44 to 46
a I I
Paragraph for Questions
a y
nand be the following set of 2 x 2 matrices:
it
Let p be an odd prime number
a
Tp
i C h
S
Tp = A =
r
a b
c a
: a , b , c ∈ {0, 1, 2,....., p − 1}
A) ( p − 1)2 B) 2( p − 1) C) ( p − 1)2 + 1 D) 2 p − 1
Ans : D
a b
Sol : Tp = A = c a ; a , b , c ∈ 0, 1, 2.....p − 1}
case. 1 AT = − A ⇒ a = b = c = 0
a b
case. 2 A = A ⇒ b = c and| A|= c a = a − b
T 2 2
∴ a − b is divisible by a + b is divisible by P
a = b ⇒ a - b is divisible P. ∴ there are P ways of choosings
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a + b is divisible by P when (a, b) = (1, P - 1) or (2, 1, -2).....(P-1, 1)
∴ there are P - 1 ways of choosing
45. The number of A in Tp such that the trace of A is not divisible by p but det (A) is
divisible by p is
[Note:- The trace of a matrix is the sum of its diagonal entries.]
Ans : C
Sol : Trace of A = 2a is divisible by p only is a = 0
my
d e
Since each of b and c is less than P let b = p - r and c = p - k.
a
Then
A c
Tp -r and c = p - k
I
| A|= a2 − bc
y a
Since each of b and c is less than P. Let I
b =
i t a n
Then
a
| A|= a 2 − ( p − r )( p − k )
h
C p is a = rk
ri
S k can be selected is p - 1 ways
now |A| is divisible 2
each of r and
∴ Ans. (P - 1)2.
A) 2p 2 B) p 3 − 5 p C) p 3 − 3 p D) p 3 − p 2
Ans : B
Sol :
47. For any real number x, let [x] denote the largest integer less than or equal to x.
Let f be a real valued function defined on the interval [-10, 10] by
x − [ x ] if [ x ] is odd ,
f (x) =
1 + [ x ] − x if [ x ] is even
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π 2 10
Then the value of 10 ∫ f ( x )cos π x dx is.
−10
Ans : 4
x − [ x ]; if [ x ] is odd
Sol : f ( x ) =
1 − (x − [ x ]) ; if [ x ] is even
π 2 10 π2 2
10 −∫10 ∫0 f ( x ). cos π x
∴ f ( x ). cos π x = × 10 ×
10
1 2
2 2
= π ∫ (1 − x)cos π xdx + ∫ x − 1cos π x.dx = π 2 2 + 2 = 4.
y
2
π π
0 1
d e m
Ac a
IIT Then the number of distinct
2π 2π
48. Let be the complex number
w
nya cos
3
+ i sin
3
.
a it a z+1 ω ω2
zh
complex numbersC
S r i satisfying
ω
is equal to
z + ω2
ω2 1
1 =0
z+ω
Ans : 1
z w w2
z z + w2 1 =0
Sol :
z 1 z+w
1 w w2 1 w w2
z 1 z + w2 1 =0 z 0 z + w2 − w 1 − w2 =0
;
1 1 z+w 0 1−w z+w−w 2
z (z 2 − ( w − w 2 ) − (1 − w 2 .w + w 3 ) = 0
2
z z 2 − (w + w − 2 ) − 1 + w 2 + w − 1 = 0
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z (z 2 − 2 w + 2 − 2 ) = 0
z( z 2 − 2 w ) = 0 → z = 0
49. Let Sk , k = 1, 2,....., 100, denot the sum of the infinite geometric series whose first
k −1 1
term is and the common ratio is . Then the value of
k! k
100 2 100 2
+ ∑ ( k − 3 k + 1)Sk is
100! k =1
Ans : 4
k −1
k −1 k
y
k 1
Sol : Sk = = =
k k−1 k−1
m
1
e
1−
k
cad
IT A
k−1
= ∑ +
a I
100 2 100 ( k 2 − 3 k − 1 100 2 100 ( k − 1)2 − ( k − 1) − 1
+∑
100 k = 1
y k−1
n
100 k = 1
aita
+∑
Ch
100 2 100 ( k − 1)( k − 2) − 1 100 2 100 1
∑
1
Sri
= = + −
100 k = 1 k−1 100 k =1 k − 3 k − 1
100 2 1 1
= − − +4
100 98 99
100 1 1 1 100 1
= − = + 4; = −1− + 4 = 4
99 98 99 98 99 99
50. The numebr of all possible value of θ , where 0 < θ < π , for which the system of
equations
( y + z)cos 3θ = ( xyz)sin 3θ
2 cos 3θ 2 sin 3θ
x sin 3θ = +
y z
( xyz)sin 3θ = ( y + 2 z) cos 3 θ + y sin 3 θ
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Ans : 8
cos 3θ 1 1
cos 3θ 2 sin 3θ 2 1 =0
cos 3θ − sin 3θ 0 0
my
ade
cos 3θ . (cos 3θ − sin 3θ = 0
)
T Ac
a I
cos 3θ = 0, tan 3θ = 1 j , sin 3θ = 0I
any
π
3θ = (2 n + 1 ) , θ =
nπ π
ait
h
+
2
C
3 12
π π 5π
∴θ = , ,
6 2 6
Sri
π 5π 11π π 2π
, , ; θ= ,
2 12 12 3 3
51. Let f be a real-valued differentiable function on R (the set of all real numbers)
such that f(1) = 1. If they y-intercept of the tangent at any point P(x, y) on the
curve y = f(x) is equal to the cube of the abscissa of P, then the value of f(-3) is
equal to
Ans : 9
Sol : Tangent at P(x1, y1) is y - y1 = m (x - x1)
dy dy y − x 3
− .x + y = x . ⇒
3
=
dx dx x
dy 1 1
= .y = − x 2 is DE with I.F = and so
dx x x
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1 −x 2
G.S is y. = ∫ −x.dx = +c
x 2
3 x (−x 2 + 3 )
f (1) = 1 ⇒ c = ⇒y=
2 2
( −3)( −6)
f ( −3) = =9
2
π π nπ
52. The number of values of θ in the interval − , scuh that θ ≠ for
2 2 5
n = 0, ± 1, ± 2 and tan θ = cot 5θ as well as sin 2θ = cos 4θ is
Ans : 3
my
Sol : θ = nπ +
π
− 5θ
ade
c
2
IT A
π
6θ = (2 n + 1 ) ; ( )
θ = 2n + 1
ya I π
n
2 12
n =a ita
h
π π
C
n = 0, θ = ; 1, θ=
Sri
12 4
−π 5π
n = 2, θ = ; n = 2, θ =
12 12
π −5π
n = 2, θ = − ; n = - 3, θ =
4 12
π π
4θ = 2 nπ ± − 2θ ; 4θ = 2 nπ + − 2θ
2 2
π π
6θ = (4n + 1) ; θ = (4n + 1)
2 12
π π
4θ = 2 nπ − + 2θ ; 2θ = (4n − 1)
2 2
π π π
θ = (4 n − 1 ) n = 0, ,−
4 12 4
5π 3π π −5π
n = 1, , ; n = -1, − ,
12 4 4 4
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3π 7π
n = 2, ,
4 4
π 5π π
Common ans. for both , ,−
12 12 4
1
53. The maximum value of the expression is
sin θ + 3 sin θ cos θ + 5 cos 2 θ
2
Ans : 2
1 2
=
Sol : 1 − cos 2θ + 3 sin 2θ + 5 1 + cos 2θ 6 + (3sin 2θ + 4 cos 2θ )
2 2 2
d e
6 + 3sin 2θ + 4 cos 2θ 11
a
G
are vectors in space given by IT
G A c G iˆ − 2 ˆj G 2iˆ + ˆj + 3kˆ
54. If a and b
y a I a=
then the value
5
and b =
14
,
) ( ) ( ) istan
G G G G G G
of (
h i
2 a + b . a × b × a − 2b
a
Ans : 5
r i C
Sol :
S
are unit vectors and mutually perpendicular. Let
a, b a×b = c
2 1 0
( )( (
∴ 2 a + b . c × a − 2b )) = 0 0 1 abc
1 −2 0
x2 y2
55. The line 2x + y = 1 is tangent to the hyperbola 2 − 2 = 1. If this line passes
a b
throught the point of intersection of the nearest directrix and the x-axis, then
the eccentricity of the hyperbola is.
Ans : 2
1 a 1
Sol : Tangent 2x + y = 1 . Cuts x-axis at , 0 ⇒ = ⇒ e = 2a
2 e 2
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Tangent y = −2 x + 1 ⇒ e = a m − b ⇒ 1 = a .4 − b ⇒ b = 4 a − 1 = e 2 − 1
2 2 2 2 2 2 2 2
e2
+ e2 − 1
a +b
2 2
4 5e 2 − 4
∴e = = =
a2 e2 e2
4
So e 4 − 5 e 2 + 4 = 0 ⇒ (e 2 − 1 )(e 2 − 4 ) = 0 ⇒ e = 2.
56. If the distance between the plane Ax − 2 y + z = d and the plane containing the
x−1 y −2 z−3 x−2 y−3 z−4
lines = = and − = is 6 , then |d| is
2 3 4 3 4 5
Ans : 6
m y
e
Sol : Given lines have direction ratios (2, 3, 4) and (3, 4, 5).dSo
a
D.Rs (1, -2, 1). Plane through the point (1, 2, 3) isc
normal of plane has
I T A x - 2y + z = 0. It is parallel to
Ax - 2y + z = d
y a I
i
|d|
ta n
⇒ distance
C
=
h a
1+ 4+1
= 6 ⇒|d|= 6
S r i
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m y
ade
2GM
( ) B) ( ) C)IT Ac
2GM GM 2GM
( )
A)
7R
4 2 −5
ya I−
7R
4 2 −5
D)
4R 5R
2 −1
Ans : A
ita n
h a
( ) ri C
Gdm
Sol : dv = V 4 / 2 2 + r 2
S p
dr
M
where dm = × 2π rdr
7π r 2
2 Mrdr
=
7R2
−G (dm )
∴ dv =
r + (4 R )
2
−2 Mrdr
dv =
7 R 2 16 R 2 + r 2
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∴ Total gravitational potential at pt. p (VP)
= ∫ dv
4R
2M rdr
=− 2
7R ∫
3R 16 R 2 + r 2
−2 MG
= 16 R 2 + r 2
7R 2
−2 MG
= 4 2 − 5
7R
V∞ − VP
m y
( ) a d e
c
2GM
A
=+ 4 2 −5
a I
isy and
58. A block of mass m is on an inclined plane θ
between the block and the planen
a it a µ . The block is held stationary by
tan θ > µ
beh
applying a force P parallel to the plane. The direction of force pointing up the
plane is taken to C
r i positive. As P is varied from P = (
S) , the frictional force f versus P graph will look like.
1
) to P =
sin θ − µ cos θ 2
(sin θ + µ cos θ
A) B)
C) D)
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ANS : A
my
de
a D)
C) A
T c
I
IBL IBL IBL
A) IBL B)
π
ya I 2π 4π
Ans: C
itan
Ch a
Sri
Fmag
dθ / 2 dθ / 2 dθ / 2
dθ / 2
Sol :
T T
Tdθ = iR (dθ ) B
T = i RB
iBL
=
2π
60. An AC voltage source of variable angular frequency ω and fixed amplitude V0 is
connected to series with a capacitance C and an electric bulb of resistance R (in-
ductance zero). When ω is increased
A) the bulb glows diammer
B) the bulb glows brighter
C) total bulb glows brighter
D) total impedance of the circuit increases
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Ans : B
C R
V0
i0 =
Sol : R2 +
1
w2 c 2
~
2
V0 R
( Pbulb )0 = i02 R = 1
R2 + 2 2
ω C
I I
1 2 1 2
ny a
a it a
i C h
S r
A) B)
C) D)
Ans : C
Sol : Theoretical
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62. Incandescent bulbs are designed by keeping in mind that the resistance of their
filament increases with the increase in temperature. If at room temperature, 100
W, 60 W and 40 W bulbs have filament resistance R100, R60 and R40, respectively,
the rlation between these resistance is.
1 1 1 1 1 1
A) R = R + R B) R100 = R40 + R60 C) R100 > R60 > R40 D) R > R > R
100 40 60 100 60 40
ANS : D
V2
SOL : p =
R
V2 V2 V2
⇒100 = , 60 = , 40 =
R100 R60 R40
y
1 1 1
∴ > >
R100 R 60 R40
d e m
63. A real gas behaves like an ideal gas if its
A c a
T
A) pressure and temperature are both high
a
B) pressure and temperature are both low I I
a n y
t is high
C) pressure is high and temperature is low
h a i
D) pressure is low and temperature
Ans: D
i C
r and high temperature, the interaction between molcules is
S
Sol : At low pressure
approaces to zero. Therefore real gas is behaves as ideal gas.
64. Consider a thin square sheet of side L and thickness t, made of a material of resis-
tivity ρ . The resistance between two oppositive faces, shown by the shaded areas
in the figure is .
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SECTION - II (Multiple Correct Choice Type)
This section contains 5 multiple choice questions. Each question has four choices A), B), C), D) out of whihc ONE OR
MORE may be correct.
65. A student uses a simple pendulum of exactly 1m length ot determine g, the accel-
eration due to gravity. He uses a stop watch with the least count of 1 sec for this
and records 40 seconds for 20 oscillations. For this observation, which of the fol-
lowing statement(s) is (are) true ?
A) Error ∆T in measuring T, the time period, is 0.05 seconds
B) Error ∆T in measuring T, the time period , is 1 second
C) Percentage error in the determination of g is 5%
D) Percentage error in the determination of g is 2.5%
Ans : A,C
Sol : (40 ± 1) s = 20T
my
∆T =
1
= 0.05 sec
ade
c
20
IT A
I
T = 2π l / g
nya
a
4π 2 A
g=
T2
ait
Ch
Sri
∆g 2∆T
∴ ×100 = × 100
g T
0.05
= 2× × 100
2
= 5%
66. A point mass of 1 kg collides elastically with a stationary point mass of 5 kg. After
their collision, the 1 kg mass reverses its direction and moves with a speed of 2 ms1.
Which of the following statements(s) (are) correct for the system of these two
masses ?
A) Total momentum of the system is 3 kg ms1
B) Momentum of 5 kg mass after collision is 4 kg ms1
C) Kinetic energy of the centre of mass is 0.75 J
D) Total kinetic energy of the system is 4 J
Ans : A,C
Sol : 1× u1 + 0 = −2 ×1 + 5v2 ....(1)
v2 + 2
1= ⇒ v2 + 2 = u1 ....(2)
u1 − 0
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⇒ v2 = u1 − 2
(1) ⇒ u1 = −2 + 5v2
u1 = −2 + 5 (u1 − 2 ) = −2 + 5u1 − 10
⇒ −4u1 = −12
u1 = 3 m/s
v2 = u1 − 3 = 0
1 1
total KE of the system = m1u1 + m2u2
2 2
2 2
my
1
= × 9 = 4.5 J
ade
2
T Ac
1
(m1 + m2
)( )
a II 2
y
KE of com= vcm
n
2
ai
m1u1 + m2u2 1× 3 + 0 1 ta
Vcm = =
Ch =
ri
m1 + m2 6 2
S
KE of COM
1 1
2
6 3
= 6 × = = = 0.75 J
2 2 8 4
67. One mole of an ideal gas in initial state A undergoes a cyclic process ABCA, as
shown in the figure. Its pressure at A is P0. Choice the correct option(s) from the
following.
A) Interval enerhgies at A and B are the same
B) Work done by the gas in process AB is P0V0 An 4
T0
C) Pressure at C is
4
T0
D) Temperature at C is
4
Ans : A,B,C,D
Sol : (i) A to B temperature is same ∴ A is correct
(ii) A to B isothemal process
V2
∴ W = nRT ln V
1
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4V
= nRT0 ln . 0
V0
= P0 V0 ln 4
∴ B is correct
(iii) B to C isobaric process
V1 T1 4V0 T0 T
= = ⇒ T2 = 0
V2 T2 V0 T2 4
T0
∴ temperature at C is
4
∴ D is correct
(iv) C to A isochoric process
m y
a d e
c
P1 T1 PC TC PC T P0
= = = 0 PC =
P2 T2 PA TA P0 4 × T0 4
I T A
∴ C is correct
y a I
68.
i ta n
A few electric field for a system of two charges Q and Q fixed at two different
a
1 2
i C h
points on the x-axis are shown in the figure. These lines susggest that
Sr
A) Q1 > Q2 B) Q1 < Q2
C) at a finite distance to the left of Q1 the electric field is zero
D) at a finite distance to the right of Q2 the electric field is zero
Ans : A,D
Sol : Number of lines of force is directly proportional to the magnitude of the charge
so Q1 > Q2
At null point where E = 0, there will be no lines of force of only the given two
charges are considered, there is a chance of getting E = 0 to the right of Q2 (Null
point will be closer to the charge having small magnitude)
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69. A ray OP of monochromatic light is incident on the face AB of prism ABCD near
vertex B at an incident angle of 60º (sec figure). The refractive index of the mate-
rial of the prism is 3 , which of the following is (are) correct ?
60º
C
60º N 135º
r
P θ N'
r’ Q
45º
r ’’ θ ’ 75º
D
A
i ’’
60º
r = 30º
in quadrilateral PBCQ
θ = 45º
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60º
as θ = 45º r = 45º
θ ' = 60º
m y
i = 60º
a d e
angle of deviation = 180 (60 + 30) = 90
T A c
a II
SECTION - III (Paragraph Type)
a n y
t
This section contains 2 paragraphs. Based upon the first paragraph 2 multiple choice questions and based upon the
h a i
second paragraph 3 multiple choice questions have to be answered. Each of these questions has four choices A), B), C)
S
Electrical resistance of certain materials, know as superconductors, changes
abruptly from a nonzero value to zero as their temperature is lowered below a
critical temperature TC(0). An interseting property of supercondeuctors is that
their critical temperature becomes smaller than TC(0)if they are placed in a mag-
netic field, i.e., the critical temperature TC(B) is a function of the magnetic field
strength B. The dependence of TC(B) on B is shown in the figure.
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A) B)
C) D)
Ans : A
y
Sol : Under magnetic field, the critical temperatures decreases as given in the data
m
d e
therefore the super conductors become conductors for higher magnetic field at
n y a one
A) B = 5 Tesla, T (B) = 80 K
C) B = 10 Tesla, 75 K < T i
C
h
(B)
C
C C
Ans : B
Sol : When B S
i
r T (B) decreased where solid becomes super conductor. If B
is increased, C
= 7.5 tesla given that T (0) decreased from 100 K to 75 K. If B is less than 7.5 then
C
TC(B) stightly increases, it should be in between 75 K and 100 K so if B = 5 Tesla, 75
K < TC(B) < 100 K
Paragraph for Questions 72 to 74
When a particle of mass m moves on the x-axis in a potential of the form V(x) =
kx2, it performs simple harmonic motion. The corresponding time period is pro-
m
portional to , as can be seen easily using dimensional analysis. However, the
k
motion of a particle can be periodic even when its potential energy increases on
both sides of x = 0 in a way different from kx2 and its total energy is such that the
particle does not escape to infinity. Consider a particle of mass m moving on the
x-axis. Its potential energy is V(x) = α x 4 (α > 0 ) for |x| near the origin and be-
comes a constant equal to V0 for x ≥ X 0 (sec figure).
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72. If the total energy of the particle is E, it will perform periodic motion only if
A) E < 0 B) E > 0 C) V0 > E > 0 D) E > V0
Ans : C
73. For periodic motion of small amplitude A, the time period T of this particle is
proportional to
my
d
a D) e
A) A
m
B)
1 m
C)
T A c A
α 1 α
I
α A α
I
m A m
Ans : B
ya
nfor is
a it a
74. The acceleration of this particle x > x0
i C h
S r
A) proportional to V 0
B) proportional to
V0
mX 0
V0
C) proportional to mX 0 D) zero
Ans : D
Sol : For x > x0 the force is zero, therefore acceleration is zero.
For x0 > x > − x0 the force is F = −4α x 3 which act as restoring force, therefore the
particle perform osscilation for V0 > E > 0 .
for small amplititude, curvature variation for curve x4 and x2 is identical. There-
m
fore T ∝ where kA2 = α A4
k
1 m
T∝
A α
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SECTION - IV (Integer Type)
This section contains TEN questions. The answer to each question is a single digit integer ranging from 0 to 9. The
correct digit below the question number in the ORS is to be bubbled
75. A 0.1 kg mass is suspended from a wire of negligible mass . The length of the wire
is 1 m and its cross-sectinla area is 4.9 ×10−7 m2 . If the mass is pulled a little in the
vertically downward direction and released, it performs simple harmonic motion
of angular frequency 140 rad S1. If the Youngs modulus of the material of the
wire is n ×109 Nm −2 , the value of n is
Ans : 4
m 1 m FL KL
Sol : T = 2π ⇒ 2 = , k = mω 2 , Y = =
k ω k Ae A
YA
= mω 2
L
m y
⇒ n=4
a d e
T A c
76. A binary star consists of two stars A (mass 2.2M ) and B (mass 11 M ), where M is
S S S
I
centre of mass, which is stationary. TheIration of the total angular momentum of
the mass of the sun. They are separated by distance
a
d and are rotating about their
a n y
the binary star to the angular momentum of star B about the centre of mass is
a it
h
Ans : 6
r i
L1 M 1 + M 2 C
Sol : L2
=
S
M1
=6
6
77. Gravitational acceleration on the surface of a planet is g , where g is the gravi-
11
tational acceleration on the surface of the earth. The average mass density of the
2
planet is times that of the earth. If the escape speed on the surface of the earth is
3
taken to be 11 kms1 the escape speed on the surface of the planet in kms1 will be
Ans : 3
GM 4
Sol : g = = π Gρ R
R2 3
2GM 8π
Ve = = Gρ R2
R 3
g 2 V2
Veα =3
ρ V1
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78. A piece of ice (heat capacity = 2100 J kg ºC and latent heat = 3.36 × 105 J kg1) of
1 1
− 5º C 0º C (m − 1 ) g ic e
1g water
Given 420 = Q1 + Q2
MC ∆T + igL
a
two cars approaching the source. The difference between the frequencies of sound
S
much smaller than 1
Ans : 7
Sol : Let v is the speed of car approaching towards a stationary source emitty wave of
speed υ
frequency of the sound appeared to stationary observer is
υ + v
f = f0
υ − v
change of frequency is
υ + v1 (υ + v2 )
∆f = − f0
υ − v1 (υ − v2 )
∆f v −v
= 2 1 2 = 12.×10−2
f0 υ
v1 − v2 7.128
nearest integer is 7
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80. The focal length of thin biconvex lens is 20 cm. When an object is moved from a
distance of 25 cm in front of it to 50 cm, the magnification of its image changes
m25
from m25 to m50 . The ration m is
50
Ans : 6
Sol : case-I u = 25 cm f = + 20 cm
v1 = 100 m
⇒ m1 = 4
case - II u = 50 cm f = +20 cm
100
V2 = cm
3
m2 = 2 / 3
m y
a d e
c
m1
∴ =6
m2
I A
Tfrom rest by a potential difference of
81. An
y I
a are
and a proton are acceleration
α − particle
100V. After this, their de Broglienwavelength
a i ta λα and λ p
respectively. The ratio
λp
to the nearestC
i h is
r integer,
,
λα
Ans : 3
S
h
Sol : λ = 2mqV
λp mα q
= × α
λα mp qp
= 4× 2
= 2 2 = 2 × 1.414
= 2.828
∴ nearest answer is 3
82. When two identical batteries of interval resistance 1Ω each are connected in se-
ries across a resistor R, the rate of heat produece in R is J1. When the same batteries
are connected in parallel across R, the rate is J2. If J1 = 2.25 J2 then the value of R in
Ω is
Ans : 4
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Sol : in case -I
ε 1Ω ε 1Ω
i1
R
2ε 2ε
2
i1 = ∴ J1 = R
R+2 R+2
case-II
ε 1Ω
my
ade
ε
T Ac
II
1Ω
R
nya
aita
2ε 2ε
Ch
2
i
I2 = ∴J 2 =
r
R
2R + 1 2R + 1
S
given that J = 1 2.25 × J 2 ∴ R = 4 Ω
83. Two spherical bodies A (radius 6 cm) and B (radius 18 cm) are at temperatures T1
and T2, respectively. The maximum intensity in the emission spectrum of A is at
500 nm and in that of B is at 1500 nm. Considering them to be black bodies, what
will be the ratio of the rate of total energy radiated by A to that of B ?
Ans : 9
Sol : E = eσ AT 4
E1 (R1 / R2 )
2
π
84. When two progressive waves y1 = 4 sin (2x 6t) and y2 = 3 2 x − 6t − are super-
2
imposed, the amplitude of the resultant wave is
Ans : 5
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