Durability of Some Glass Fiber Reinforced Cement Composites
Durability of Some Glass Fiber Reinforced Cement Composites
Durability of Some Glass Fiber Reinforced Cement Composites
by J_ Bijen
A number of glass fiber reinforced cement composites currently on pounds under moist conditions. This discovery has ini-
the market were investigated with regard to the alteration of mechan- tiated new research aimed at the elimination of this
ical properties over time. Among these were several so-called alkali-
resistant glass fibers (AR-GFRC) and a system consisting of £-glass
problem.
fibers with a polymer-modified cement matrix [Forton (P)GFRC]. In 1979 a polymer-modified glass fiber reinforced ce-
Properties such as strain at ultimate tensile stress, bending strength, ment system, developed in the laboratories of the
and impact strength were initially higher for the AR-GRFC than for Building Materials Division of the Dutch company
the (P)GFRC. However, the AR-GFRC system showed a consider- DSM, was commercialized under the name of Forton:
able decrease of these properties over time, resulting over the long
term in a lower level than for (P)GFRC. Various alkali-resistant glass
a polymer-modified glass fiber reinforced cement (P-
fiber reinforced cements showed a difference in the level of deterio- GFRC). s-w This cement composite contains E-glass fi-
ration. bers instead of AR-glass fibers and a thermoplastic
polymer in the form of water-dispersed particles (la-
Keywords: alkalies; cements; ductility; durability; glass fibers; impact strength; tex). This polymer emulsion is mixed with cement and
reinforcing materials; tensile properties. sand to form a mortar. It is claimed that when the glass
fiber bundles are mixed with this mortar, the glass fi-
ber filaments are surrounded by the polymer particles
Research significance
and thus are screened off and protected against the mi-
The research presented is believed to be the first pub-
gration of cement hydration products, as well as possi-
lished direct comparison of the durability of commer-
ble chemical attack. The Forton system was patented by
cially available GFRC systems.
DSM and is exclusively marketed by Forton B. V. and
BACKGROUND affiliated companies worldwide. Also in 1979, Pilking-
It was not until 1972, when the British company,
ton Brothers Ltd. introducted a second-generation AR-
Pilkington Brothers Ltd., introduced to the market a glass fiber, Cem-FIL 2. This glass fiber has an organic
glass fiber with a better alkaline resistance than previ- coating that contains chemical groups that interfere
with the accretion of calcareous compounds. 11 • 12
ously available, that the use of glass fiber reinforced
In the examination presented here, a comparison was
cement composites gained acceptance. Pilkington's AR-
made between the durability of Forton E-glass fiber (P-
glass fiber was patented by the British Research Estab-
GFRC and AR-GFRC using Cem-FIL 1, Cem-FIL 2,
lishment and marketed under the tradename Cem-FIL
and Minelon-L glass fibers). Although from a scientific
1. Subsequently, Japanese companies introduced simi-
viewpoint the phenomena occurring at and in the glass
lar glass fibers on the market.
Although it was demonstrated in numerous publica- fibers are interesting, and indirect durability testing, as
tions that these fibers have a better alkali-resistance 1•4 in the pullout test (SIC test) described in Reference 13
than A- and E-glass fibers, it has been shown that ten- may be useful, the performance of a product should b~
sile strength, flexural stren~th, deformation capacity, evaluated in terms of the properties of the composite
and impact resistance decrease in AR-glass fiber rein- itself. Therefore, the goal of the examination was to
determine the degree to which strength and deforma-
forced cement as a function of time. For example, the
literature reports a loss of bending strength from 35 to bility change with time under different climatological
40 MPa (5075 to 5800 psi) after one month to 15 to 19 conditions.
MPa (2175 to 2755 psi) after 10 years of exposure in the
British climate. 5
Received May 3, 1982~ and reviewed under Institute publication policies.
Research has established that this deterioration is at- Copynght © 1983: Amencan Concr_ete Institute. All rights reserved, including
tributable to gradual "filling-up" of the interfilament the makm~ of cop1es unless perm1ss1on IS obtained from the copyright propri-
etors. Pertment d1scuss1on will be published in the May-June 1984 ACI JouR-
spaces of the glass fiber bundles with calcareous com- NAL if received by Feb. I, 1984.
dards NEN 3550. The coefficient of variation in the Total 98.9 98.5 98.0 98.0
glass fiber percentage was 0.3 percent. LOI 1.0 1.5 1.2 1.1
To obtain a similar workability for the AR-GFRC as
the (P)GFRC at the same water-cement ratio, a super- testing machine, Type 1474. The clamp-to-clamp dis-
plasticizer at 4 percent by weight of the cement was tance was 130 mm (5.11 in.). Displacement was mea-
added. The superplasticizer was Melment L10, a 20 sured with a type 1400.651 strain meter (Zwick), of
percent m/m solution of a sulfonated melamine form- which the measurement points were 100 mm (3.94 in.)
aldehyde condensate. apart. The cross head speed was 0. 5 mm/min.
Behavior in flexure was determined on test speci-
Curing
mens of 150 x 50 x 8 mm (5.91 x 1.97 x 0.31 in.),
After production the AR-GFRC specimens were
subjected to four-point bending in accordance with
cured for 7 days at 20 C (68 F) and 95 percent relative
Reference 16. Half the specimens were loaded with the
humidity and for the next 21 days at 20 C (68 F) and 65
top face in tension and the other half with the bottom
percent relative humidity. The (P)GFRC was cured 28
face in tension. The cross head speed was 2 mm/min
days at 20 C (68 F) and 65 percent relative humidity, in
(0.08 in./min).
accordance with the requirements of Forton B. V.
Impact resistance was determined following the
On the basis of the results obtained over three years,
method described in ASTM D 256 (Charpy) with un-
no definitive conclusion can be drawn as to the long-
notched specimens. Dimensions of the specimens were
term behavior of the material. To gain more informa-
120 x 25 x 8 mm (4.72 x 0.98 x 0.31 in.). The span
tion on this point, an accelerated aging test program
length was 70 mm (2.76 in.).
was conducted on the various GFRC's under investiga-
Before testing all the specimens were ground on both
tion.
sides to obtain a smooth surface. Test results discussed
The test was developed by Pilkington. 13 •15 For GFRC
are the average for six samples.
with Cem-FIL 1 AR-glass fiber, this test was supposed
to provide some indication of the effects of aging of the
Results
material over longer periods of natural weathering,
Fig. 1 shows typical stress-strain curves for Cem-FIL
e.g., 30 years. In these tests, 28 day old specimens
I AR-GFRC and Forton (P)GFRC after 28 days (a) and
cured at 20 C (68 F) are submerged in water at 50 (122
after further aging of ten weeks at 50 C (122 F) (b). Fig.
F). The specimens are tested after 1, 4, 10, and 26
2 and 3 give comparative values for tensile and bending
weeks of submersion. The AR-GFRC composites in-
strength of composites aged submerged at 20 C (68 F)
corporating Cem-FIL 2 and Minelon-L fibers are only
water temperature and at 20 C (68 F) and 65 percent
considered in the accelerated aging tests because of their
relative humidity. Fig. 4 shows the results concerning
recent introduction to the market and their present ag-
impact strength.
ing periods at 20 C (68 F) are too short to draw conclu-
Results of the accelerated tests where the specimens
sions.
had been submerged in 50 C (122 F) water are shown in
Mechanical testing Fig. 5 through 10. Shown in these charts as a function
Tensile tests were performed on strips of 300 x 25 x of time under these aging conditions are the tensile
8 mm (11.8 x 0.98 x 0.31 in.) with a Zwick universal strength, strain at ultimate tensile strength, limit of
I
I WATEl 50 c <122 Fl.
I CEM-FI L 1 AR-<FRC 12-1
I 7 DAYS 20'C (l)g'F) £5% Rf', 1750....., FoRTON (p)~fRC
I
I 21 DAYS 20'C (ffi'F) 65% RH,
~
'
I i
I
/
I ~lSOC -110~
I
I
I
-'
!21250 j ;
8--: I
I
I ::: !
I
I:sJJ- /
1
1CCO ~ 6~
; I
I
1- CEM-FIL l
~~ I I I
5'))-
25:-
I'
2-.-,//
~
500-
250.,
.
4-i
· z...;
I I
1
I
I
I
I
I
0 -1
10
---STRAIN ~Q/oo]
Fig. 1-Typica/ tensile stress-strain curve for Cem-FIL AR-GFRC and Forton
(P)GFRC after (a) 28 days curing at 20 C (68 F) and (b) the next 26 weeks under
water at 50 C (122 F)
~ ~ ri\lC~Rj_ffj~ i<i ~~
CUJ-FJL 1 ~P.-G."RC:7 DAYS 20 C (f>'l f) 95~ RH, f'Rl.CUR!lfl:_
21 DAYS 20 C (OIJ FJ G57, RH. WJ-FIL ] M-Q''lC: 7 DAYS 20 ( (68 f) %% RH,
f/JXJ ftHTW (PJGFRC: Zl Jl•\YS 70 C ((8 F) G5'; ~l. fiD 21 DAYS 20 C (68 Fl 654 RH
40 4D FORTON (PJffRC:23 DAYS 20 C (68 FJ 65% !1/i,
00 00
~
\1
~5UIJ ~SITU
\1 \1
!? 30 2 30
ill ill
1~ 14lD
00 00
\1
~2000 ~2ITU
~ ~ FORTON (P)~ ___ _
FoRTON (~~- __ !1
\1 10 --- ---- 10
::: :::
11ITU CEI+FIL 1 M-{fR( 11ITU
0 0
12 24 36 424 12
- - - M)tflHS
- - - - rorm-ts
Fig. 2-Bending and tensile strength development as a Fig. 3-Bending and tensile strength development as a
function of time, curing under water at 20 C (68 F) function of time, curing at 20 C (68 F) and 65 percent
relative humidity
proportionality in tensile testing, Young's modulus de- slight decrease is observed. The tensile strength of the
duced from the tensile stress-strain curve, bending AR-GFRC decreases with time. Under conditions of
strength, and the impact strength. accelerated aging, this decline is found to proceed much
faster than for Forton (P)GFRC (Fig. 5). As a loga-
DISCUSSION rithmic function of time, the tensile strength (Fig. 5) of
Behavior under tensile loading Cem-FIL 2 decreases more or less the same as that of
The AR-GFRC and Forton (P)GFRC tested have al- Cem-FIL 1 AR-GFRC but on a higher level. A remark-
most the same tensile strength after curing for 28 days able difference observed under accelerated aging con-
(Fig. 2). When aged under conditions of 20 C (68 F), ditions is that Forton (P)GFRC does not show a signif-
the Forton (P)GFRC shows a slight increase in tensile icant change in properties after one week, while most
strength, while under accelerated aging conditions, a properties in the AR-GFRCs have not obtained a con-
ACI JOURNAL I July-August 1983 307
-- - - 70 C H.S I l (.',: Ril. fFEC_URJ_IiG__;_
22 --- --- LU ( ((>') F) UIVlR I·J\TLR, FoRTON<P>GFRC:23 DAYS 20 c (ffi r> 6S% RH.
g;
M-GFRC:l DAYS 20 C <&3 F) 95~ Rli,
21 DAYS 20 c <63 F) 65% RH.
20
Cu-rFIL 1 M-GF~: 7 DAYS 20 C (ffi F) ~X ~
71 lli\YS 20 ( (h') F) 65: aJ, 1G
13 FoRTON (P)(ii-RC: 28 lli\YS 20 ( <l8 F) 6~~ ~1.
'"i
~
2000 14
,z:~
16
I
~ 12
~-1'\
~ 14
~
~
~
~ 1500
10
:
I
., •
l <P>GFRC
":1 I
I
'\
•
it 12
~ ~:~1
~ ~ ~I ' •
§I
0:1 ' .
10 1£1
1000
OL--L------t----~~--~--+---
0 10 26
04-----_J__________~----~~----~--~~ ---WEEKS
1 12 36 4S
- - PDITliS
Fig. 4-lmpact strength development as a function of Fig. 5-Tensi/e strength development under accelerated
time aging at 50 C (122 F) under water
f'R_~_CJ.!Bj_Nli:_ fB.LCV.'\1/!:i.:..
FoRTON <P>GFRC: 28 DAYS 20 C (ffi F> liS% RH. FORrorl <P>GFRC: 28 DAYS 20 C (ffi' F> 6S7. RH.
AR-GFRC: 7 DAYS 20 c (ffi Fl 95% PJJ, P.HIIlC: 7 DAYS 20 c (&:J F) 95~ RH,
21 DAYS 20 c (68 Fl 654 RH. 2i r>ws 20 C (li) F> tiS% RH.
1200
-
010
~
~
-...... ...............
~
I
8 I.
~ 1\
~
I
6
I
I \
~
~
._ \
5·~ 4 ~I' ' , \
~I
.
1-
z
§I
&'I
'", ,
~
I .
I
I
I
\ FoRlON <PlGFRC
I
I
I
0
0 1
AR--GFRC
----WEEKS
200
Fig. 6-Development strain at ultimate tensile stress
under accelerated aging at 50 C (122 F) under water
o- oL_~-------+------~----~--~----
0 10
---WEEKS
4lD 28 ~
+=..:.-::,.
''
3 30 : ""-.
i3
~
24 :
I
"':.,,
•
I
~:
V>
-!:!
~
300J
20
I
I
I
I
20 a: (EM-FILl
I
::! I .4R-GFRC
I "-I
I l
I I 11! NELON P.R-GFRC
lo I 1500 10 I
I I
!!!I l
2000 -I I
"'I l
12 §I FORmN lPlGFf( l
&I
I 0 0 -'---'-----+---~--+---1--
~------ 10 26
I ---WEEKS
I
1000 I
I
I Fig. 9-Bending strength development under acceler-
I ated aging at 50 C (122 F) under water
I
I
I
I
I
I
ID 26 ~
0
---WEEKS 15 !\ FoRmN <PlGFRC: Zl DAYS 20 C lf8 Fl 65% RH.
\\\ /\Hflle: 7 DAYS 20 c <6.~ Fl 9){; RH,
Fig. 8-Tensile Young's modulus development under \ 2J DAYS 2fl ( ((3 f) 65! ~!.
accelerated aging at 50 C (122 F) under water \
\
\
stant level even after 26 weeks of accelerated aging (Fig.
\
5 through 10). \
At 28 days, the deformation capacity (Fig. 6) of the \ Ce-1-m 2 A.R-GFRC
\
AR-GFRC is about twice as high as that of Forton \ \
- CEM\< 1L AR-GCRC
(P)GFRC. However, under conditions of accelerated \ \
aging, the deformation capacity of the AR-GFRC de-
clines faster than that of Forton (P)GFRC. The ulti- .l_
!!! 11INELON
mate level of the Forton (P)GFRC is higher. Thus, af-
~WI AR-GCRC
ter 26 weeks in accelerated aging the deformation ca- &I
pacity of the Forton (P)GFRC is about five times
higher than that of AR-GFRC. For Forton (P)GFRC,
~ ........ _.... '·
: ...............
the deformation capacity declines from 5 to 2.3°/ oo• that
of AR-GFRC from 9 to 0.4°/00' This decline is more I FORTON (PlGFRC
rapid for the Minelon AR-GFRC than for the Cem-FIL
1 or Cem-FIL 2, which shows a relatively small de- 1 10 26
crease in the first week. The difference in the deforma- ---WEEKS