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THERMODYNAMICS
1. Given that bond energies of H-H and Cl-Cl 7. The heat of combustion of C, H2, and CH4
are 430 kJ mol-1 and 240 kJ mol-1 , are 349.0, -241.8 and -906.7 kJ/mol,
respectively and ∆ fH for HCl is -90 kJ mol-1. respectively. The heat of formation of CH4, is
The bond enthalpy of HCl is (A) 74.1 kJ/mole (B) 174.1 kJ/mole
(A) 245 kJ mol-1 (B) 290 kJ mol-1 (C) 274.1 kJ/ mole (D) 474.1 kJ/ mole
-1
(C) 380 kJ mol (D) 425 kJ mol-1
8. The value of ∆ G° for a reaction having Keq =
2. What is the entropy change (in J Kol-1 mol-1) 1 would be
when one mole of ice is converted into water (A) -RT (B) -1
at 0° C ? (The enthalpy change for the (C) 0 (D) +RT
conversion of ice to liquid water is 6.0 KJ mol 9. If for the heterogeneous equilibrium
at 0° C ) CaCO3(s) ⇌ CaO(s) + CO2(s)
(A) 20.1 (B) 2.013 K = at 1 atm the temperature is given by
(C) 2.198 (D) 21.98 ∆S ∆H
(A) T = (B) T=
3. For which reaction, the change of entropy ∆H ∆S
will be positive ? ∆G ∆G
(C) T = (D) T =
(A) H2(g) + I2(g) ⇌ 2H1(g) R ∆ H°
(B) HCl(g) + NH3(g) ⇌ NH14Cl(s) 10. When temperature of a reaction is changed
(C) NH4NO3(s) ⇌ N2O(g) + 2H2O(g) from T1 to T2, half is found to decrease. Thus,
(D) MgO(s) ⇌ Mg(g)+ H2O(l) (A) T1> T2 and reaction is endothermic
4. For the reaction, N2(g) + 3H2, (g)⟶ 2NH, (B) T2> T1 and reaction is exothermic
(g) ∆ H 95.3 kJ and ∆ S = 198.3 Jk-1 Find out (C) T1> T2 and reaction is exothermic
the temperature at which the reaction will (D) T1> T2 and reaction can be exothermic
proceed in forward direction. or endothermic
(A) T<480.6 K (B) T>480.6 K 11. Increasing the temperature of the closed
(C) T<2078 K (D) T>207 K system to 35° C would be expected to
5. A hypothetical reaction, A → 2B, proceed produce all of the changes listed below,
through following sequence of steps: except
A → C ; ∆ H = q1 (A) an increase in pressure of the vapour
C→ D; ∆ H = q2 phase
1 (B) an increase in pressure of the vapour
D→ B; ∆ H = q3
2 phase
The heat of reaction for A → 2B is (C) an increase in average kinetic energy of
(A) q1 – q2 + 2q3 (B) q1 + q2 - 2q3 system
(C) q1 + q2 + 2q3 (D) q1 + q2 - 2q3 (D) None of the above
6. The entropy change involved in the 12. Out of following, the correct for adsorption
isothermal reversible expansion of 2 moles of gaseswill be ?
of an ideal gas volume of 10 l at 27° C is
(A) 38.3 J/mol keivin (a) ∆S < 0 (b) ∆G < 0
(B) 383 J/mol keivin (c) ∆ H < 0 (d) ∆ Stotal < 0
(C) 3.83 J/mol keivin (A) a, b (B) a, b, c
(D) 3830 J/mol keivin (C) a, b, c, d (D) b, d

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13. Heat of formation of water is 260 kJ. How (C) ≥0 (D) =0

water is decomposed by 130 kJ of heat ?
23. Under which of the following sets of
(A) 0.25 mol (B) 1 mol
condition, ∆ G is always negative ?
(C) 0.5 mol (D) 2 mol
(A) ∆ H = -ve and ∆ S = +ve
14. The amount of heat evolved when 500 cm3, (B) ∆ H = -ve and ∆ S = -ve
0.1 M HCl is mixed with 200 cm3 at 0.2 (C) ∆ H = +ve and ∆ S = +ve
MNaOH is (D) ∆ H = +ve and ∆ S = -ve
(A) 2.282 kJ
24. ∆ U° of combustion of methane is –x kJ mol -1
(B) 1.292 kJ
the value of ∆ H° is
(C) 0.292 kJ
(A) =∆ U° (B) =∆ U°
(D) 3.392 kJ
(C) < U° (D) =0
15. The heat of neutralization is highest for the
25. The Joule-Thomson experiment is an
reaction between
example of which of the following process?
(A) NH4OH-CH3COOH
(i) Isothermal process
(B) HNO3-NH4OH
(ii) Isoenthalpic process
(C) NaOH-CH3COOH
(iii) Adiabatic process
(D) HCl-NaOH
(iv) Isochoric process
16. Which of one of the following is always not Select the correct answer using the codes
negative ? given below
(A) Enthalpy of combustion (A) (i) and (ii) (B) (ii) and (iii)
(B) Enthalpy of formation (C) (i) and (iv) (D) (ii) and (iv)
(C) Enthalpy of neutralization
26. A reaction occurs spontaneously, if
(D) Lattice enthalpy
(A) T∆ S> ∆ H and ∆ H is +ve and ∆ S is -ve
17. The heat of formation of CO2 is -95 kcal. The (B) T∆ S=∆ H and both ∆ H and ∆ S are +ve
amount of carbon which on burn ing will (C) T∆ S < ∆ H and both ∆ H and ∆ S is +ve
evolve 1000 kcal is (D) T∆ S > ∆ H and both ∆ H and ∆ S are +ve
(A) 12.63 g (B) 17.95 g
27. For 2A(g)→A2(g)∆ G and ∆ S are
(C) 126.3 g (D) 179.5 g
(A) -ve, -ve (B) -ve, +ve
18. (∆ H - ∆ E) for the formation of NH3 from N2 (C) +ve, -ve (D) +ve, +ve
and H2 is
28. For the process to occur under adiabatic
(A) RT (B) 2RT
conditions, the correct condition is
(C) -RT (D) -2RT
(A) ∆ T = 0 (B) ∆ P = 0
19. ∆ G for a reaction at 300 k is -16 kcal and ∆ H (C) q = 0 (D) W = 0
is -10 kcal. The entropy of the reaction is
29. ∆ H = ∆ E is for the case
(A) 20 cal K-1 (B) 86 cal K-1
-1 (A) C2H4 + H2(g)→C2H6(g)
(C) 166 cal K (D) 100 cal K-1
(B) C(s) + CO2(g) → 2CO(g)
20. For the reaction H2O(l ) ⇌ H2O(g) at 373 k (C) NH4HS(s)→ NH3(g) + H2S(g)
and 1 atm pressure is (D) CH4(g)+ 2O2(g)→ CO2(g) + 2H2O(g)
(A) ∆ E = 0 (B) ∆ H = T∆ S
30. Three moles of an ideal gas expanded
(C) ∆ E + ∆ E (D) ∆ H =0
spontaneously into vacuum. The work done
21. 16g of oxygen gas expands isothermally and will be
reversibly at 300 k from 10 dm3 . The work (A) 3 Joules (B) 9 Joules
done is (C) Zero (D) Infinite
(A) zero (B) -2872 J
(C) +2875 J (D) ∞
31. The intensive property is
22. In a reversible process ∆ Ssys +∆ Ssurr is (A) Moles (B) Volume
(A) >0 (B) <0 (C) Enthalpy (D) Temperature

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32. Thermodynamics is concerned with (C) Negative (D) Infinite

(A) Total energy of a system
42. Which plot represents for an exothermic
(B) Energy changes in a system
reaction
(C) Rate of a chemical charge
(D) Mass changes in nuclear reactions
33. Which of the following is an extensive
property (A) (B)
(A) Mass (B) Enthalpy
(C) Energy (D) All of these

34. For an ideal gas, the value of ( dVdE ) is

T (C) (D)
(A) Positive (B) Zero
(C) Negative (D) Interchangeable
35. The work done by 100 calorie of heat in 43. For a sample can fitin the orbital of 3p
isothermal expansion of ideal gas is changed isothermally from pi to pf, the
(A) 418.4 J (B) 4.184 J entropy change is given by
(C) 41.84 J (D) None of these Pf
36. Enthalpy of 1 mole monoatomic ideal gas is
equal to
(A) ∆ S = nRT In
Pi( )
Pi
(A)
3
2
RT (B)
5
2
RT (B) ∆ S = nRT In
Pf( )
(C) RT (D) 2 RT Pf

37. For the reaction CO(g) +

1
O2(g)→CO2(g)
(C) ∆ S = nRT In
Pi( )
2 Pi
Which one of the statement is correct at
constant T and P ?
(D) ∆ S = nRT In
Pf( )
(A) ∆ H =∆ E (B) ∆ H <∆ E 44. The addition of a catalyst during a chemical
(C) ∆ H >∆ E reaction alters which of the following
(D) ∆ H is Independent of physical state of quantitites ?
reactants (A) Entropy
(B) Internal energy
38. When the egg is hard boiled, there is
(C) Enthalpy
(A) Increase in disorder
(D) Activation energy
(B) Decrease in disorder
(C) No change in disorder 45. Which of the following statements is correct
(D) ∆ G is negative for the spontaneous dsorption of a gas ?
(A) ∆ S is negative and therefore ∆ H
39. Entropy of an adiabatic reversible process is
should be highly positive
(A) Positive (B) Zero
(B) ∆ S is negative and therefore ∆ H should
(C) Negative (D) Constant
be highly negative
40. For the precipitatino of AgCl by Ag+ ions (C) ∆ S is positive and therefore ∆ H should
and HCl be highly negative
(A) ∆ H = 0 (B) ∆ G = 0 (D) ∆ S is positive and therefore ∆ H should
(C) ∆ G = -ve (D) ∆ H = ∆ G also be highly positive

41. In case of an ideal gas, Joule Thomson

coefficient is
(A) Zero (B) Positive

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