Location via proxy:   [ UP ]  
[Report a bug]   [Manage cookies]                
Scribd
Upload
88 views

Exercise 01: Component N-Butane

The document provides calculations using various equations of state (EOS) to model the behavior of hydrocarbon and ammonia gas mixtures at different temperatures and pressures. It includes calculations using the van der Waals, Redlich-Kwong (RK), Soave-Redlich-Kwong (SRK), and Peng-Robinson (PR) EOS for n-butane, ammonia, and mixtures of CO2, CO, H2, and H2O. Component properties like critical temperature, pressure, and parameters for each EOS are provided. Molar volumes, compressibility factors and other properties are calculated at various conditions.

Uploaded by

sadia
Copyright
© © All Rights Reserved
Available Formats
Download as XLSX, PDF, TXT or read online on Scribd
88 views

Exercise 01: Component N-Butane

The document provides calculations using various equations of state (EOS) to model the behavior of hydrocarbon and ammonia gas mixtures at different temperatures and pressures. It includes calculations using the van der Waals, Redlich-Kwong (RK), Soave-Redlich-Kwong (SRK), and Peng-Robinson (PR) EOS for n-butane, ammonia, and mixtures of CO2, CO, H2, and H2O. Component properties like critical temperature, pressure, and parameters for each EOS are provided. Molar volumes, compressibility factors and other properties are calculated at various conditions.

Uploaded by

sadia
Copyright
© © All Rights Reserved
Available Formats
Download as XLSX, PDF, TXT or read online on Scribd
You are on page 1/ 17

Exercise 01

Component n-Butane
Temp 393.3 K
Pressure 16.6 atm
Tr 0.925194071983063
R 8.20573 m3.atm/mol.k
w 0.2
Ideal gas law PV = nRT

V 194.41648246988 m3/mol
V 0.19441648246988 m3/kmol

Van dar waals EOS P = RT/V-b -a/V2

Tc 425.1 K
Pc 37.47 atm

a 137000.420452154
b= 11.6368288730985

V 0.27 m3/kmol

RK-EOS P = RT/V-b -a/V(V+b)


alpha 1.03964143322939
a 144321.934870036
b 8.06571882852202
V 0.1601 m3/kmol

SRK-EOS P = RT/V-b -a/V(V+b)


m 0.78776
alpha 1.06
a 147148.089786148
b 8.06571882852202
V 0.1632 m3/kmol

PENG-ROBINSON EOS P = RT/V-b -a/(V(V+b)+b(V-b)


m 0.6722832
alpha 1.051
a 156055.79295574
b 7.24276229061649

V 0.14657 m3/kmol
Exercise 02

Component Ammonia Gas


Temp 450 K
Pressure 56 atm
Tr 1.10919398570372
R 8.20573 m3.atm/mol.k
w 0.253
Ideal gas law PV = nRT

V 65.9389017857143 m3/mol
0.065938901785714 m3/kmol

Van dar waals EOS P = RT/V-b -a/V2

Tc 405.7 K
Pc 111.35 atm

a 41989.739197505
b= 3.73716284351145

V 0.056 m3/kmol

RK-EOS P = RT/V-b -a/V(V+b)


alpha 0.949502793864007
a 40398.5974421936
b 2.59030231009466
V 0.05696 m3/kmol

SRK-EOS P = RT/V-b -a/V(V+b)


m 0.866956416
alpha 0.9099
a 38713.6131143566
b 2.59030231009466
V 0.05755 m3/kmol

PENG-ROBINSON EOS P = RT/V-b -a/(V(V+b)+b(V-b)


m 0.74753929072
alpha 0.922
a 41959.4103994386
b 2.32601015380153

V 0.056489 m3/kmol
Exercise 03
Compressibility Factor at P= 50
Component Ammonia Gas
Temp 400 K
Pressure 50 atm
Tr 0.98595020951442
R 8.20573 m3.atm/mol.k
w 0.253

Van dar waals EOS P = RT/V-b -a/V2

Tc 405.7 K
Pc 111.35 atm

a 41989.739197505
b= 3.73716284351145

V 0.055 m3/kmol
Z 0.000837829175466
RK-EOS P = RT/V-b -a/V(V+b)
alpha 1.00709979644522
a 42849.1833027009
b 2.59030231009466
V 0.0555 m3/kmol
Z 0.000845445804334
SRK-EOS P = RT/V-b -a/V(V+b)
m 0.866956416
alpha 0.9099
a 38713.6131143566
b 2.59030231009466
V 0.05553 m3/kmol
Z 0.000845902802066
PENG-ROBINSON EOS P = RT/V-b -a/(V(V+b)+b(V-b)
m 0.74753929072
alpha 0.922
a 41959.4103994386
b 2.32601015380153

V 0.055 m3/kmol
Z 0.000837829175466
Compressibility Factor at P= 250s
Component Ammonia Gas
Temp 400 K
Pressure 250 atm
Tr 0.98595020951442
R 8.20573 m3.atm/mol.k
w 0.253

Van dar waals EOS P = RT/V-b -a/V2

Tc 405.7 K
Pc 111.35 atm

a 41989.739197505
b= 3.73716284351145

V 0.006162 m3/kmol
Z= 0.000469336670839
RK-EOS P = RT/V-b -a/V(V+b)
alpha 1.00709979644522
a 42849.1833027009
b 2.59030231009466
V 0.00056 m3/kmol
Z 4.26531216601082E-05
SRK-EOS P = RT/V-b -a/V(V+b)
m 0.866956416
alpha 0.9099
a 38713.6131143566
b 2.59030231009466
V 0.00556 m3/kmol
Z 0.000423484565054
PENG-ROBINSON EOS P = RT/V-b -a/(V(V+b)+b(V-b)
m 0.74753929072
alpha 0.922
a 41959.4103994386
b 2.32601015380153

V 0.0056489 m3/kmol
Z 0.000430255748117
Exercise 04
Components Molar Flowrate Units Mole fraction Pc (atm)
CO2 189 kmol/h 0.09393638171 72.88
CO 630 kmol/h 0.313121272366 34.5409
H2 63 kmol/h 0.031312127237 12.96
H2O 1130 kmol/h 0.561630218688 217.71
Total 2012 kmol/h 1
R 8.20573 m3.atm/mol.k
Temperature 500 K
Pressure 1 atm

SRK calculation at P= 1 atm SRK calculation at P= 200 atm

SRK-EOS P = RT/V-b -a/V(V+b) SRK-EOS P = RT/V-b -a/V(V+b)

a 45347.5150862422 a 45347.51508624
b 5.45647263711731 b 5.4564

V 4.096 m3/kmol V 0.02051

Ideal Gas Equation PV= RT

V 4.102865 m3/kmol V 0.020514325


Tc (K) Tr w m alpha ai
304.2 1.643655489809 0.224 0.823745024 0.5899 21559.5
132.9 3.762227238525 0.048 0.555146496 0.2414 50291.42
33.19 15.06477854776 -0.216 0.131804544 0.384 213214.4
647.1 0.772678102303 0.345 1.0020816 1.257 41547.72

P= 200 atm

/V-b -a/V(V+b)

m3/kmol

m3/kmol 0.020514
Exercise 05
bi Components Mole fraction Units Pc (atm)
4.877500324 Ammonia 0.25 111.35
10.29134225 Hydrogen 0.5625 12.96
27.42841231 Nitrogen 0.1875 33.56
1.632778575 Total 1
R 8.20573 m3.atm/mol.k
Temperature 550 K
Pressure 270 atm

SRK Calculation:
SRK-EOS P = RT/V-b -a/V(V+b)

a 4878.15466043747
b 2.17299124067629
V 0.0187 m3/kmol

Ideal Gas Equation PV= RT

V 0.016715375925926 m3/kmol

m3/kmol
Tc (K) Tr w m alpha ai
405.7 1.35568153808 0.253 0.866956416 0.7358 31306.1616986
33.19 16.5712564025 -0.216 0.131804544 0.354 866.089975365
126.2 4.35816164818 0.038 0.539557856 0.17077 2332.69835242
Exercise 06
bi Components Ammonia Units
2.5903023101 SRK Calculation
1.8206980095 R 8.20573 m3.atm/mol.k
2.6734561751 Temperature 499.8 K
Pressure 10 atm
Tc 405.7 K
Pc 111.352 atm
w 0.25
Tr 1.23194478678827

SRK-EOS P = RT/V-b -a/V(V+b)


m 0.8625
alpha 0.8193
a 34858.2190730216
b 2.59025578551836
V 0.404 m3/kmol

RK-EOS Calculation P = RT/V-b -a/V(V+b)


alpha 0.90095765154415
a 38332.4535494216
b 2.59025578551836
V 0.403 m3/kmol

Ideal Gas Equation PV= RT

V 0.4101223854 m3/kmol

Comparison
we compare the specific volume that are obtained from these three equations. For Ammo
but in bromine case, SRK and RK model are valid
Components Nitrogen Units Components

R 8.20573 m3.atm/mol.k R
Temperature 183.8 K Temperature
Pressure 19.743 atm Pressure
Tc 126.2 K Tc
Pc 33.56 atm Pc
w 0.039 w
Tr 1.4564183835 Tr

SRK-EOS P = RT/V-b -a/V(V+b) SRK-EOS


m 0.541118304 m
alpha 0.789 alpha
a 10777.648299 a
b 2.6734561751 b
V 0.07208 m3/kmol V

RK-EOS Calculation P = RT/V-b -a/V(V+b) RK-EOS Calculation


alpha 0.8286228858 alpha
a 11318.892314 a
b 2.6734561751 b
V 0.07098 m3/kmol V

Ideal Gas Equation PV= RT Ideal Gas Equation

V 0.0763922998 m3/kmol V

hree equations. For Ammonia and nitrogen gas SRK,RK and ideal gas equation are valid
Exercise 07
Bromine Units Components
Methanol
8.20573 m3.atm/mol.k CO
500 K H2
20 atm Total
588 K
102.073 atm R
0.108 Temperature
0.8503401361 Pressure

P = RT/V-b -a/V(V+b)
0.647939136
1.1034
107578.87519 SRK calculation at P= 1 atm
4.0954545762
0.007047 m3/kmol SRK-EOS

P = RT/V-b -a/V(V+b) a
1.0844353369 b
105729.86565
4.0954545762 V
0.00721 m3/kmol RK-EOS Calculation

PV= RT a
b
0.20514325 m3/kmol
V

Ideal Gas Equation

V
Molar Flowrate Units Mole fraction Pc (atm) Tc (K) Tr w m
100 kmol/h 0.25 79.93 512.6 1.117831 0.564 1.311751
100 kmol/h 0.25 34.54 132.9 4.311512 0.048 0.555146
200 kmol/h 0.5 12.96 33.19 17.26424 -0.216 0.131805
400 1

8.20573 m3.atm/mol.k
573 K
100 atm

P= 1 atm

P = RT/V-b -a/V(V+b)

9568.33061385478
2.73406801421642

0.04797 m3/kmol
P = RT/V-b -a/V(V+b)

11657.8656372869
2.73406801421642

0.04756 m3/kmol

PV= RT

0.0470188329 m3/kmol
alpha ai bi alpha for RK ai bi
0.85633 81028.69 4.559366 0.945827615285128 89497.24 4.559366
0.162 2384.476 2.73551 0.48159855977242 7088.642 2.73551
0.3412 834.7737 1.820698 0.240672414641322 588.8248 1.820698

You might also like