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    Review Synthesis of Methanol Part 1. Catalysts and Kinetics

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    Ylm Ptana
    This document is a review of catalysts and kinetics for the synthesis of methanol. It discusses various catalyst types that have been used and developed for methanol synthesis, including precipitated copper/zinc oxide/alumina catalysts, Raney copper catalysts, and precious metal catalysts like palladium catalysts. It also examines the selectivity of copper-based catalysts and produces methanol as well as byproducts like higher alcohols, hydrocarbons, esters, and ketones. Finally, it analyzes the equilibrium and kinetics of methanol synthesis reactions over different supported copper catalysts using hydrogen-carbon monoxide and hydrogen-carbon monoxide-carbon dioxide mixtures.

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    Review Synthesis of Methanol Part 1. Catalysts and Kinetics

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    Ylm Ptana
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    This document is a review of catalysts and kinetics for the synthesis of methanol. It discusses various catalyst types that have been used and developed for methanol synthesis, including precipitated copper/zinc oxide/alumina catalysts, Raney copper catalysts, and precious metal catalysts like palladium catalysts. It also examines the selectivity of copper-based catalysts and produces methanol as well as byproducts like higher alcohols, hydrocarbons, esters, and ketones. Finally, it analyzes the equilibrium and kinetics of methanol synthesis reactions over different supported copper catalysts using hydrogen-carbon monoxide and hydrogen-carbon monoxide-carbon dioxide mixtures.

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    This document is a review of catalysts and kinetics for the synthesis of methanol. It discusses various catalyst types that have been used and developed for methanol synthesis, including precipitated copper/zinc oxide/alumina catalysts, Raney copper catalysts, and precious metal catalysts like palladium catalysts. It also examines the selectivity of copper-based catalysts and produces methanol as well as byproducts like higher alcohols, hydrocarbons, esters, and ketones. Finally, it analyzes the equilibrium and kinetics of methanol synthesis reactions over different supported copper catalysts using hydrogen-carbon monoxide and hydrogen-carbon monoxide-carbon dioxide mixtures.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    56 views1 page

    Review Synthesis of Methanol Part 1. Catalysts and Kinetics

    Uploaded by

    Ylm Ptana
    This document is a review of catalysts and kinetics for the synthesis of methanol. It discusses various catalyst types that have been used and developed for methanol synthesis, including precipitated copper/zinc oxide/alumina catalysts, Raney copper catalysts, and precious metal catalysts like palladium catalysts. It also examines the selectivity of copper-based catalysts and produces methanol as well as byproducts like higher alcohols, hydrocarbons, esters, and ketones. Finally, it analyzes the equilibrium and kinetics of methanol synthesis reactions over different supported copper catalysts using hydrogen-carbon monoxide and hydrogen-carbon monoxide-carbon dioxide mixtures.

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    of 1

    Applied Catalysis, 36 (1988) 1-65

    Elsevier Science Publishers B.V., Amsterdam - Printed in The Netherlands

    Review

    Synthesis of Methanol

    Part 1. Catalysts and Kinetics

    G.C. CHINCHEN, P.J. DENNY, J.R. JENNINGS**, MS. SPENCER and K.C. WAUGH
    ICI Chemicals & Polymers Group, Research & Technology Department, Billingham Catalysis
    Centre, P.O. Box 1, Billingham, Cleveland TS23 ILB (U.K.)
    (Received 20 March 1987, accepted 9 July 1987)

    CONTENTS

    1. Introduction.. ............................................................................................................................... 2
    2. Catalysts and catalyst development.. ......................................................................................... 4
    2.1. Introduction .................................................................................................................... 4
    2.2. Precipitated copper/zinc oxide/alumina catalysts.. .................................................... 5
    2.2.1. Effects of additives.. ....................................................................................................... 6
    2.3. Raney copper catalysts.. ................................................................................................ 9
    2.4. Intermetallic compounds ............................................................................................... 11
    2.5. Precious metal catalysts ............................................................................................... .15
    2.5.1. Palladium catalysts ....................................................................................................... .15
    2.5.2. Other precious metals ................................................................................................... .20
    3. Selectivity of copper-based catalysts ........................................................................................ .23
    3.1. General background.. .................................................................................................... .23
    3.2. Higher alcohols ............................................................................................................... 27
    3.3. Hydrocarbons ................................................................................................................. 29
    3.4. Esters.. ............................................................................................................................. 31
    3.5. Ethers.. ............................................................................................................................ 32
    3.6. Ketones ........................................................................................................................... 33
    4. Equilibrium and kinetics.. .......................................................................................................... .34
    4.1. Introduction.. ................................................................................................................. .34
    4.2. Equilibrium of methanol synthesis ............................................................................. .34
    4.3. Equilibria of reactions related to methanol synthesis ............................................... .37
    4.4. Kinetic expressions.. ..................................................................................................... .38
    4.5. Kinetics of synthesis from hydrogen-carbon monoxide mixtures over supported
    copper catalysts.. ........................................................................................................... .39
    4.6. Kinetics of synthesis from hydrogen-carbon monoxide-carbon dioxide mixtures
    over supported copper catalysts.. ................................................................................. .41
    4.6.1. Copper/zinc oxide catalysts ......................................................................................... .41
    4.6.2. Commercial copper/zinc oxide/alumina catalysts ..................................................... .43
    4.6.3. Other supported copper catalysts ................................................................................ .47

    *ICI Chemicals and Polymers Group, Research and Technology Department, P.O. Box 90,
    Wilton, Middlesbrough, Cleveland TS6 8JE, lJ.K.

    0166-9834/88/$03.50 0 1988 Elsevier Science Publishers B.V.

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