Safe Design and Operation of Cryogenic Enclosures

SAFE DESIGN AND OPERATION
OF CRYOGENIC ENCLOSURES
Doc 170/17
Revision of Doc 170/12
EUROPEAN INDUSTRIAL GASES ASSOCIATION AISBL
AVENUE DES ARTS 3-5 • B – 1210 BRUSSELS

Tel: +32 2 217 70 98 • Fax: +32 2 219 85 14
E-mail: info@eiga.eu • Internet: www.eiga.eu
Doc 170/17
SAFE DESIGN AND OPERATION

OF CRYOGENIC ENCLOSURES
As part of a programme of harmonization of industry standards, the European Industrial Gases Association
(EIGA) has issued the publication EIGA Doc 170, Safe design and operation of cryogenic enclosures. This
has been jointly produced by members of the International Harmonization Council.
This publication is intended as an international harmonized publication for the worldwide use and
application by all members of Asia Industrial Gases Association (AIGA), Compressed Gas Association
(CGA), EIGA, and Japan Industrial and Medical Gases Association (JIMGA). Regional editions have the
same technical content as the EIGA edition, however, there are editorial changes primarily in formatting,
units used and spelling. Also, any references to regional regulatory requirements are those that apply to
European requirements.
Disclaimer
All technical publications of EIGA or under EIGA's name, including Codes of practice, Safety procedures and any other technical
information contained in such publications were obtained from sources believed to be reliable and are based on technical information
and experience currently available from members of EIGA and others at the date of their issuance.
While EIGA recommends reference to or use of its publications by its members, such reference to or use of EIGA's publications by
its members or third parties are purely voluntary and not binding.
Therefore, EIGA or its members make no guarantee of the results and assume no liability or responsibility in connection with the
reference to or use of information or suggestions contained in EIGA's publications.
EIGA has no control whatsoever as regards, performance or non performance, misinterpretation, proper or improper use of any
information or suggestions contained in EIGA's publications by any person or entity (including EIGA members) and EIGA expressly
disclaims any liability in connection thereto.
EIGA's publications are subject to periodic review and users are cautioned to obtain the latest edition.
 EIGA 2017 - EIGA grants permission to reproduce this publication provided the Association is acknowledged as the source
EUROPEAN INDUSTRIAL GASES ASSOCIATION AISBL

Avenue des Arts 3-5 B 1210 Brussels Tel +32 2 217 70 98 Fax +32 2 219 85 14
E-mail: info@eiga.eu Internet: www.eiga.eu
EIGA DOC 170/17
Table of Contents
1 Introduction............................................................................................................................................... 1
2 Scope and purpose .................................................................................................................................. 1
3 Definitions................................................................................................................................................. 1
3.1 Publication terminology ................................................................................................................. 1
3.2 Technical definitions ...................................................................................................................... 2
4 Design considerations .............................................................................................................................. 3

4.1 Types of insulation......................................................................................................................... 3
4.2 Enclosure casing ........................................................................................................................... 4
4.3 Piping design ................................................................................................................................. 4
4.4 Enclosure materials of construction............................................................................................... 5
4.5 Load calculation............................................................................................................................. 6
4.6 Structure beams and process equipment support ......................................................................... 6
4.7 Foundations ................................................................................................................................... 7
4.8 Enclosure bottom........................................................................................................................... 7
4.9 Maintenance facilities .................................................................................................................... 8
4.10 Protection of small bore lines ........................................................................................................ 8
4.11 Protection from cryogenic embrittlement ....................................................................................... 8
4.12 Special considerations for flammable and toxic fluids ................................................................... 8
5 Construction ............................................................................................................................................. 9
6 Operation of cryogenic enclosures ......................................................................................................... 10

6.1 Purge gas—Air separation unit processes .................................................................................. 11
6.2 Purge gas—Processes with flammable or toxic gases................................................................ 13
6.3 Maintenance ................................................................................................................................ 14
7 Enclosure hazards .................................................................................................................................. 15

7.1 General hazards .......................................................................................................................... 15
7.2 Overpressure ............................................................................................................................... 15
7.3 Unsafe compositions ................................................................................................................... 17
7.4 Cold temperatures ....................................................................................................................... 18
7.5 Equipment erosion....................................................................................................................... 19
7.6 Feed stocks containing oxides of nitrogen .................................................................................. 19
8 Troubleshooting ...................................................................................................................................... 19
8.1 Process leaks and detection........................................................................................................ 21
8.2 Ice on enclosure external surfaces and piping ............................................................................ 22
8.3 Purge gas sampling ..................................................................................................................... 23
8.4 Purge gas flow and pressure changes ........................................................................................ 23
8.5 Emergency condition guidance ................................................................................................... 23
9 Changes, modifications, and repairs to cryogenic enclosures ............................................................... 24

9.1 Management of change ............................................................................................................... 24
9.2 Structural members and panels................................................................................................... 24
9.3 Insulation removal ....................................................................................................................... 24
9.4 Confined space entry................................................................................................................... 24
9.5 Equipment isolation ..................................................................................................................... 24
9.6 Perlite removal from piping and process equipment ................................................................... 25
9.7 Piping and equipment .................................................................................................................. 25
10 References ............................................................................................................................................. 25
Figures
Figure 1—Casing pressure versus time ........................................................................................................ 16
EIGA DOC 170/17
Tables
Table 1 Enclosure upset scenarios symptoms and consequences .............................................................. 19
Amendments from 170/12
Section Change
Editorial to align style with IHC associations
2 Scope amendment
4.11 Section on cryogenic embrittlement added
8.5 Emergency condition guidance expanded
Note: Technical changes from the previous edition are underlined

EIGA DOC 170/17
1 Introduction
Cryogenic processes often operate inside enclosures that insulate the process equipment and
interconnecting piping from ambient air and temperature. This prevents many problems, including
excessive heat leak into the process and water freezing around the equipment. In many cases, the
enclosure is purged with a dry gas to prevent ambient air from entering the enclosure and creating
hazardous mixtures.
2 Scope and purpose
Cryogenic enclosures can create potential process safety hazards. This publication identifies general
hazards and provides guidance to reduce their frequency and consequences. It provides safety
guidance and addresses design and operating practices only as they affect safety.
This publication addresses both cryogenic air separation unit (ASU) and hydrogen/carbon monoxide
(HYCO) processes. A number of existing publications cover special requirements of these processes
and their equipment [1, 2, 3, 4, 5].
This publication is primarily to document current practices and is intended to apply to new facilities. It is
recognized that some existing plants may not meet all recommendations or requirements from this
publication. This publication need not be applied retroactively, including where this publication uses
the word “shall”.
This publication does not cover the following:
• Generally accepted engineering practices for structures and process equipment; only those issues
that are specific to cryogenic enclosures are included;
• Enclosures for processes producing liquid hydrogen or helium. The extreme cold temperatures of
these processes require specialized knowledge and practices that are beyond the scope of this
publication; and
• External structures on/attached to the cryogenic enclosure for example, platforms, ladders, vents,
lightning arrestors, etc. For more information on the safe location of oxygen and nitrogen vents
relative to the location of platforms and ladders, see EIGA Doc 154, Safe Location of Oxygen and
Inert Gas Vents [6].
3 Definitions
For the purpose of this publication, the following definitions apply.
3.1 Publication terminology
3.1.1 Shall
Indicates that the procedure is mandatory. It is used wherever the criterion for conformance to specific
recommendations allows no deviation.
3.1.2 Should
Indicates that a procedure is recommended.
3.1.3 May
Indicates that the procedure is optional.
3.1.4 Will
Is used only to indicate the future, not a degree of requirement.
1
EIGA DOC 170/17
3.1.5 Can
Indicates a possibility or ability.
3.2 Technical definitions
3.2.1 Air separation unit
Separates air into its components. In this publication, an ASU is assumed to operate at cryogenic
temperatures.
3.2.2 Coldbox and cylindrical enclosure
Enclosure containing insulation that separates a cryogenic process from the surrounding environment.
The terms coldbox or box are often used to refer to an enclosure with a rectangular cross section, and
the term cylindrical enclosure to refer to an enclosure with a cylindrical cross section. However, the term
coldbox is sometimes used to refer to all enclosures, regardless of cross section shape.
3.2.3 Cryogenic
Temperatures less than approximately –90 °C (–130 °F) [10].
NOTE—Cryogenic processes require insulation to reduce heat transfer from the surrounding
environment.
3.2.4 Derime
Periodic preventive maintenance procedure where the process equipment is warmed up while
simultaneously being swept with clean dry gas to remove any accumulated moisture, carbon dioxide,
and atmospheric impurities.
NOTE—Also known as defrosting, de-icing, and thawing.
3.2.5 Enclosure
Structure that retains the insulation and surrounds the equipment.
NOTE—Cryogenic processes are often insulated by placing the cryogenic equipment and piping in one
or more enclosures that are filled with insulation.
3.2.6 HYCO
Processes that cryogenically process gaseous mixtures containing hydrogen (H2) and/or carbon
monoxide (CO).
3.2.7 Perlite eruption
Rapid, uncontrolled displacement of perlite within the insulation space that can result in a violent perlite
release. It is commonly caused by the rapid vaporization of pooled cryogenic liquid in the perlite that
has suddenly been warmed, moved, or physically disturbed.
3.2.8 Perlite release
Uncontrolled spillage of perlite to the environment.
2
EIGA DOC 170/17
4 Design considerations
4.1 Types of insulation
The enclosure has one or more types of insulation to reduce heat leak into the process piping and
equipment. The most common insulation methods used are perlite, mineral wool, and vacuum.
4.1.1 Perlite
Perlite is an inert volcanic glass that forms an odourless, non-flammable, non-toxic lightweight powder
aggregate when expanded by heat. It is a highly effective insulating material used to reduce refrigeration
losses or heat leak into the cryogenic enclosure.
CAUTION: Since it is a lightweight powder, it can become an asphyxiation hazard if inhaled or if a

person becomes submerged in perlite.
4.1.2 Mineral wool
Mineral wool is a wool-like inorganic material produced by blowing steam or air through molten slag or
rock. Mineral wool shall be non-combustible and contain less than 0.5% by weight of organic material
[7]. Industry experience has shown that this level of organic material is operationally acceptable. One
test for combustibility of materials is addressed in ISO 1182, Reaction to fire tests for products-Non-
combustibility test, which may be used to test for organic materials [8].
Mineral wool should have a pH between 6 and 9.5. If the pH is outside of this range and the mineral
wool becomes wet, it becomes corrosive to piping and equipment.
4.1.3 Vacuum
With vacuum insulation, the item to be insulated is placed within some type of enclosure. A vacuum is
pulled on the annular space between the item and the enclosure, which reduces heat transfer by
conduction. The heat leak can be further reduced by placing insulation (typically perlite, metal foils, or
other “super-insulation”) within the space to further reduce heat leak through conduction or radiation.
Vacuum insulation provides more resistance to heat leak than mineral wool or perlite. Vacuum insulation
may be considered, particularly for small coldboxes or piping. Such insulation leads to a better insulation
and more compact enclosures, which are convenient for transport and on-site erection.
With vacuum insulation, no nitrogen purge is needed. For enclosures with vacuum insulation, the vessel
walls shall be designed to withstand full vacuum conditions. Helium leak tests are generally required
during assembly to detect small leaks.
If the filling of insulating material (for example, perlite) is performed by vacuum suction, precautions
shall be taken to avoid damaging piping lines or connections in the annular space, for example,
controlling the rate of filling, reinforcing the supports of small lines or connections.
Vacuum gauge or fittings should be installed to verify the vacuum level within the annular space, which
will allow the insulating properties to be confirmed during operation.
Relief devices (rupture discs and/or lift plates that can be maintained by vacuum suction) shall be
installed to protect the annular space against overpressure. When an insulation barrier is placed
upstream of the relieving device, it shall be designed not to restrict the relieving capacity.
Getters or adsorbents may be used in the annular space to trap various gases, which can be released
in the annular space. Because oxygen can enter the annular space inadvertently (for example, leaks
from ambient air), the compatibility of these getters or adsorbents with oxygen shall be considered [9,
10].
3
EIGA DOC 170/17
Super-insulation typically consists of thin metal foils to reduce radiant heat transfer. The thin metals can
be combustible in oxygen. A risk assessment shall be performed when using super-insulation.
4.2 Enclosure casing
The enclosure casing is typically made from carbon steel plates. The plates can be bolted or welded
together to enclose the insulation. The plates can then be attached to a frame or support structure, or
the plates can be self-supporting. Damage to the enclosure beam structure could damage equipment
or reduce the support to process equipment and piping.
The enclosure cross section can be rectangular or cylindrical. The enclosure can be overpressurized in
case of leaks or higher purge gas pressure (see 7.2).
4.2.1 Cylindrical enclosures
Cylindrical enclosures surround the cryogenic equipment and piping. Equipment is typically not
supported from the enclosure structure; rather it is supported with a separate support system.
If a cylindrical enclosure is pressurized to the point of failure, the pressure-volume (PV) energy will most
probably be significantly larger than a similarly sized rectangular enclosure. This is particularly true if
the enclosure is designed for vacuum insulation. The possibility of higher stored PV energy shall be
considered in the design of cylindrical enclosures (see 7.2).
4.2.2 Rectangular enclosures
Rectangular enclosures have a structural skeleton of beams, and some or all equipment and piping are
supported from these beams. Metal plates are attached to structural frame. The plates can be attached
to the frame on either the inside (towards the insulation) or the outside (towards the ambient).
Rectangular enclosures can contain less pressure before failure. Damage to the enclosure beam
structure could damage equipment or reduce the support to process equipment and piping.
4.2.3 Perlite filling/removal nozzles
Perlite filling/removal nozzles should be located to allow safe access for adding and removing perlite.
Nozzles may be added to the coldbox at multiple levels including the roof. It is recommended to locate
removal nozzle(s) at the platform levels for access. The distance between nozzles is typically
10 m to 12 m (32 ft to 39 ft). Details of perlite filling and removal procedures are given in EIGA Doc 146
[11].
4.2.4 Enclosures with multiple sections
Enclosures may have multiple sections depending on process and equipment layout. Design
consideration should be given to installation of isolation barriers between enclosure sections that would
prevent perlite from flowing from one section to another. Isolation barriers reduce the possibility of perlite
bridging that can lead to collapse when removing perlite from adjacent sections. Isolation barriers
should allow for purge gas flow. See 6.1.3.
4.3 Piping design
Leaks from process equipment and piping, whether large or small, can overpressure the enclosure
and/or create hazardous atmospheres. Therefore, design and construction methods shall be used to
reduce the probability of leaks.
Piping within the perlite insulation space should have welded joints because these joints significantly
reduce the possibility of leaks. Mechanical joints (such as bolted flanges or threaded connections)
should be avoided. If mechanical joints are used, a blanket or stuffing box of mineral wool should be
used to isolate a potential mechanical joint leak. The mineral wool stuffing box prevents a leak from
causing perlite erosion of the equipment (see 7.5) and also allows for easier maintenance. These
4
EIGA DOC 170/17
isolated small enclosures should have their base or floor sloped above perlite’s angle of repose. This
ensures that perlite will naturally fill underneath and around these enclosures and insulate the
enclosures [11].
All pipes, including instrument and utility lines, shall be designed so that the thermal and mechanical
stresses are less than the maximum allowable, which minimizes the risk of line failure. Stresses shall
be considered for the following:
• nozzles;
• transition joints;
• process bellows, flexible joints, or braided hose;
• valve or other piping equipment weaker than connected pipes, and
• flanges.
All operating modes shall be considered in the design, including:
• cooldown and warm-up cycles, such as start up, shutdown and deriming; and
• piping that cycles as part of normal operation such as piping for cryogenic adsorbers.
Dead-ended, non-flowing piping requires seal loops to prevent cryogenic liquids from flowing by gravity
towards the enclosure surface. Seal loops should be routed to provide adequate vaporization of
cryogenic liquid to form a vapor lock. Omitting the seal loops will result in excessive process heat leak,
boiling of the cryogenic liquid, and potential accumulation of unsafe mixtures. This excessive heat leak
can result in ice forming on the enclosure surface (see 8.2). Some examples of this piping are drains
from cryogenic equipment and the high-pressure side of liquid level taps [2].
Other piping design items that should be considered are:
• protection of small bore lines (see 4.10);
• piping loads from perlite insulation;
• supporting process piping that operates with two phase flow during any mode of operation, to
prevent excessive vibration from causing cyclic fatigue cracking;
• design and selection of specialized joints used to join dissimilar metals such as those utilizing
explosion-bonded material; and
• if the piping can be exposed to oxygen-enriched fluids, it shall be designed for oxygen service [4,
5, 12].
4.4 Enclosure materials of construction
Plates shall be manufactured from materials compatible with the temperature that they are exposed to
during normal operations.
Bolted panels on the cryogenic enclosure shall be sealed using a gasket, mastic, or other sealant to
prevent water from entering the enclosure.
When constructing the enclosure, materials such as valve boots, wiring insulation, and sealants that
are not oxygen compatible may be used in small amounts.
Enclosures surfaces shall be protected from corrosion due to atmospheric conditions. Areas that are
particularly susceptible to atmospheric corrosion are:
5
EIGA DOC 170/17
• flat horizontal sections such as roofs or the top of horizontal ducts; and
• areas where the enclosure surface can have water trapped against it such as the contact zone
between plates and external beams.
Corrosion can eventually lead to a breach in the enclosure surface, potentially causing three problems:
• Moisture/rain water can enter the enclosure, which will reduce insulation effectiveness and create
ice. The ice can restrict the movement of piping or equipment as the process cools down or warms
up. Restricting the movement can damage the piping or equipment, in turn leading to process leaks;
• Release of purge gas; and
• Release of perlite.
Corrosion protection can be provided by painting, other surface treatment, or material selection.
Corrosion protection is usually only provided on the external enclosure surface. Internal corrosion
protection is typically not needed because the enclosure is purged with dry nitrogen. Internal corrosion
protection is only used if extensive corrosion is anticipated during construction.
Elastomer sealants and metal bolts shall be appropriate for the expected atmospheric corrosion
environment to which they will be exposed. This design precaution will avoid a possible breach in the
enclosure from a corrosion failure.
Top horizontal plates (such as the roof) shall be designed to provide natural drainage of rain water. A
welded roof provides the maximum protection from rain water ingress or ice damage. Any penetrations,
access panels, or elastomeric boots can be prone to water leakage. These shall be designed and
maintained to prevent water ingress.
The enclosure shall be periodically inspected and maintained. Particular care should be taken in case
the coldbox is located in areas with potentially corrosive atmospheres such as a heavy industrial area
or in the proximity to the sea.
4.5 Load calculation
The design of the enclosure shall consider the expected loads imposed during the life of the enclosure.
These include, but are not limited to, the following:
• Transportation (if any), which can include road, rail, and ship;
• Lifting (if any);
• Erection;
• Fluid pressure from the purge gas or fluidized perlite (see 7.2);
• Different operating modes, both warm and cold. Both shall include the cases with and without
process fluid, and also if the system is pressurized or not. Any transient modes shall also be
considered (see 4.3);
• Perlite load on piping, equipment, enclosure and foundations, and
• Environmental conditions on-site such as snow, wind, and earthquakes.
4.6 Structure beams and process equipment support
The main part of the support structure is usually constructed of carbon steel. However, portions of the
support structure can become colder than the embrittlement temperature of carbon steel. These
supports shall be made of materials compatible for the anticipated temperatures.
6
EIGA DOC 170/17
Consideration shall be given to reducing cold conduction between the cryogenic and non-cryogenic
portions of the enclosure, particularly through the equipment support structures. This may require
placing distance between the process pipes or equipment and coldbox structure members to prevent
cold migration.
Structural members in the cold zone of the enclosure will contract if they become cold. The loads that
this contraction imposes on the outer structure and plates shall be considered in the enclosure design.
Combustible material shall be avoided for any supports.
4.7 Foundations
Foundations for cryogenic equipment have the potential for the lower side of the concrete to reach a
temperature of 32 F (0 C) or less, resulting in the freezing of the sub-surface and subsequent frost
heaving effects. Frost heaving generally depends on soil conditions, ambient temperatures, and the
amount of water available in the soil. The build-up of large layers of ice under cold foundations can take
years. To prevent frost heaving at coldbox foundations, the soil under the foundations shall be kept from
freezing. A site-specific evaluation should be performed to rate the potential for this effect to occur.
Where such a possibility exists, consideration shall be given to one of the following mitigation
techniques:
• On small foundations, the heat leak into the area from the atmosphere can cancel the cooling effect
through the foundation;
• Provide an air circulation space that is open to atmosphere between the cold equipment or
enclosure bottom and the top of the concrete;
• Provide an elevated foundation that has an air circulation space between the top of the soil and the
bottom of the concrete foundation slab;
• Provide electric heating cables in the concrete foundation. The heaters and junction boxes should
be accessible for periodic checks and maintenance; and
• Install open air conduits in the foundation that rely on convection.
A temperature sensor may be installed on the foundation to measure the effectiveness of heating the
soil.
4.8 Enclosure bottom
Typically, industry practice for ASUs is to construct the lower enclosure sections from carbon steel. The
floor is either carbon steel or concrete. It is recognized that carbon steel will crack and release small
amounts of fluids and (in some cases) perlite, if it comes into contact with cryogenic liquid(s). Industry
experience shows that small leaks do not immediately affect the structural integrity of the overall
enclosure and do not pose a significant risk to personnel. See 8.1 for the procedures that should be
used to determine the risk of such a leak and the time period in which the leak shall be repaired.
For HYCO boxes, see 4.12.
Cryogenic pumps are more susceptible to liquid leaks because:
• they are often installed with bolted flanges for maintenance;
• they have rotating parts that require seals, which can develop leaks; and
• their motion creates vibrations, which can lead to leaks.
Therefore, for pumps installed in enclosures, one or more of the following leak detection methods may
be installed:
7
EIGA DOC 170/17
• temperature detector(s) below the pumps (typically near the enclosure floor);
• seal leak detectors; or
• temperature switch on the pump shaft.
These leak detection methods may trigger one or more of the following:
• shutdown of the pump;
• closing pump isolation valves; or
• alarm to alert the operator of an abnormal situation.
4.9 Maintenance facilities
During enclosure design, consideration should be given to what sections could need maintenance
access. If the enclosure is insulated with perlite, sections that need access should have means provided
to be isolated without removing perlite from the entire enclosure. Ducts or stuffing boxes may be
installed to allow removal of insulation at the local area rather than the entire box.
Some of the process equipment requires regular maintenance, such as expansion turbines and pumps.
Typically, this equipment is installed in a separate section, and has its own isolated and dedicated
enclosure which is insulated. An enclosure with separate sections has special considerations for its
purge gas system; these are described in 6.1.3. Where possible, these dedicated enclosures shall be
designed so that maintenance work can be performed by personnel working outside the enclosure. This
eliminates the need for personnel to physically enter the enclosure.
Ladders may be installed inside the enclosure for construction or to allow repair of equipment and
piping. These ladders shall either have safety cages or safety cable to prevent falls.
4.10 Protection of small bore lines
Small bore lines, particularly instrument tubes, are more susceptible to damage both in the construction
phase and when operating the coldbox. Consideration should be given to protecting these lines from
damage due to falling objects or inadvertent construction climbing. Any protection support shall account
for the expansion and contraction of these lines during operation.
4.11 Protection from cryogenic embrittlement
When valves and cryogenic piping are installed adjacent to or penetrating the coldbox enclosure,
consideration shall be given to preventing cold migration from the valves and piping to the coldbox
cladding that could result in cold embrittlement. Vents from the coldbox shall be directed away from the
cladding to a safe location.
4.12 Special considerations for flammable and toxic fluids
The consequences of releasing process fluids are more severe if the process contains toxic or
flammable fluids. Therefore, additional requirements are needed for HYCO enclosures.
Each specific plant shall have a risk assessment. If the risk assessment shows a significant hazard
exists, the consequence of the leak shall be mitigated by one or more of the following:
• Purge gas flow rates sufficient to dilute and remove small leaking flows from the enclosure;
• Alarms and/or shutdowns, based on the monitoring devices;
• Protect non-cryogenic compatible materials from being impacted by cryogenic liquids such as catch
basins or baffles/plates to divert the liquid flow to safe areas; or
8
EIGA DOC 170/17
• A cryogenic liquid retention basin constructed of materials suitable for cryogenic temperatures. The
basin shall be sized to give time to shut down the plant and purge the remaining liquid from the
process equipment. The basin does not need to be sized to contain the entire process inventory.
The basin support shall be designed to withstand the load corresponding to the basin full of
cryogenic liquid.
At least one method for detecting liquid leaks shall be used. The most common methods are low
temperature detection devices or sampling the enclosure purge gas composition and/or pressure.
These are discussed further in 4.8 and 6.2.
If an enclosure has a pump, the consequence of a leak shall be mitigated by either:
• the enclosure floor constructed of cryogenic compatible materials; or
• a liquid retention basin installed under the pump.
During construction, additional quality assurance requirements may be considered to ensure that the
piping and equipment are constructed in accordance with the design. This may include extra non-
destructive testing (NDT) and extra inspection.
Due to possible flammable and toxic fluid release, metal plates of HYCO enclosures shall be
continuously welded to ensure the tightness. Use of mastic instead of continuous welding is not allowed.
To ensure the seal weld integrity, inspection or other quality assurance methods may be required.
In certain parts of the process in HYCO boxes, the process temperature can be less than the liquefaction
temperature of nitrogen. If the process fluids become colder than the nitrogen liquefaction temperature,
either during a process upset or normal operating conditions, then special considerations could be
necessary to the prevent the nitrogen purge from condensing on equipment and piping. Some methods
to prevent or minimize this include:
• Wrapping the cold equipment (i.e., equipment operating at less than –196 °C [–320 °F]) in special
insulation, and preventing nitrogen from circulating through this area;
• Using a different composition of purge gas to prevent nitrogen condensation; and
• Using vacuum insulation to minimize heat leak and prevent nitrogen circulation to the cold
equipment.
5 Construction
Cryogenic enclosures have special construction requirements:
• The erection plan for a shipped/unpacked coldbox shall clearly identify piping and equipment
supports that were installed only for shipping. The plan shall specify that these are to be removed
prior to insulating the cryogenic enclosure;
WARNING: Failure to remove these supports can restrain piping movements during cooldown and
could potentially lead to piping failure.
• Enclosures that are shipped via maritime transport shall be sealed to prevent sea water ingress;
• When installing mineral wool, care shall be taken so as to not damage or crush small bore lines;
• All hot work and cutting operations performed inside any enclosure shall take care not to
inadvertently damage adjacent equipment;
• Procedures or controls shall be used for materials brought within the enclosure to ensure no foreign
substances or incompatible materials are left inside;
9
EIGA DOC 170/17
• Piping and equipment shall be pressure and leak tested before installing insulation. It is critical to
find all leaks before insulation is installed, because once insulation is installed, it will be difficult to
detect or fix the leak. Also, leaks in perlite can erode equipment (see 7.5). Small leaks might not be
immediately observed; it is good practice to soap test joints and wait several minutes to ensure that
any leaks are found;
• When installing specialized joints used to join dissimilar metals, proper procedures shall be used to
prevent damage from excessive heat exposure during welding and brazing work;
• Expansion joints are engineered piping elements. They shall be installed in accordance with the
manufacturer’s instructions;
• Rain and other liquid water shall be completely excluded from the cryogenic enclosure when
installing the insulation. The enclosure needs to be carefully monitored during construction to
ensure any openings are sealed or covered up to prevent rain water ingress. Rain water entering
the enclosure insulation will saturate the perlite or mineral wool and this liquid water will be very
difficult to remove from the granular insulation by purging alone during the start-up of the plant;
• Water shall be excluded from structured aluminium packing (aluminium structured packing is
sometimes inside vessels). Liquid water can enter a vessel either from rain or condensation of
humid air. If liquid water contacts aluminium structured packing, it can react to form hydrogen. There
are documented instances of liquid water contacting structured packing for long periods, and the
top of the column was sealed. A significant amount of hydrogen collected at the top of the column
and exploded when the top pipe was cut open;
• It is important to keep the insulation dry after it is installed. This requires installing the insulation as
late in the construction period as possible. After the insulation is installed, the following shall be
done:
• Seal all openings to prevent water ingress, and
• Start the purge as soon as it is available.
As the plant becomes cold, the atmosphere in the enclosure will contract, drawing in atmospheric
air unless a purge is established.
• The density of perlite when installed should be measured. If the density is greater than the design
value, the insulating properties are reduced and the loads on the piping, enclosure, and equipment
will be increased;
• It is not common industry practice to flow gas into the enclosure during construction to test for
tightness or sealing; and
• A cold test is where the piping and equipment is cooled down before insulation is installed. This
may help to find some leaks. However, industry experience is that when proper design and
construction procedures are followed, cold tests are not effective in finding additional leaks. In
addition, cold tests will also bring significant amounts of water inside the enclosure, which shall be
removed prior to installing the insulation.
6 Operation of cryogenic enclosures
Cryogenic enclosures are fairly simple to operate and normally do not need significant attention. The
most important operating requirement is to keep the atmosphere within the enclosure within operating
bounds by ensuring proper purge gas pressure, flow, and composition.
The manufacturer shall supply procedures and recommendations for operating scenarios. These
typically include:
10
EIGA DOC 170/17
• start-up from warm condition that includes cooling the enclosure at a rate that does not create
excessive thermal stresses;
• start-up from a cold condition;
• normal operation (see 6.1, 6.2, and 6.3);
• shutdown, where the enclosure will remain in a cold condition;
• warming the enclosure from cold to ambient temperature, either for maintenance or an extended
shutdown; and
• maintaining the enclosure at a warm temperature.
The enclosure operator shall follow the manufacturer’s recommendations and procedures, unless these
are modified with proper management of change (MOC) procedures [13].
General guidance on identifying and resolving abnormal conditions is given in Section 8. However, if
specific guidance from a manufacture differs from Section 8, the manufacturer’s guidance shall be
followed.
6.1 Purge gas—Air separation unit processes
This section gives guidance for enclosure purge gas systems for ASUs.
6.1.1 Composition
Moisture-free, oil-free nitrogen shall be used for the purge gas, except as noted in the following
paragraphs. During normal operation, the nitrogen purge comes from the cryogenic process or
vaporized liquid, and has less than 1 part per million by volume (ppmv) water (–75 °C [–167 °F]) and is
considered moisture-free. Nitrogen with higher dewpoints (up to –40 °C [104 °F] or 80 ppmv) may be
used for short periods. The nitrogen coming from the cryogenic process or vaporized liquid is deemed
to be oil-free, provided it is compressed without contacting a lubricant.
Nitrogen has a liquefaction point of 77 K (–196 °C [–320 °F]) at 1.0133 bara (14.696 psia) and the
coldest part of the process will be slightly warmer than this temperature. As a result, the purge nitrogen
will not liquefy.
In the ASU process, the pure nitrogen, whether liquid or vapour, will be under slight pressure (for
example, 0.1 bar [1.45 psi]) and therefore will be 1 or 2 degrees warmer than nitrogen at atmospheric
pressure.
The maximum oxygen concentration in the nitrogen purge shall be determined to avoid oxygen
condensation on cold equipment and piping. A typical specification is less than 5% oxygen; however,
the manufacturer’s specification shall be followed. The condensed liquids will create potential hazards
as if there was a liquid leak, including over pressurization, liquid pools within perlite, cold migration, and
unsafe atmospheres.
Moisture-free, oil-free air purge gas may be used for short periods to cooldown or startup from warm
conditions. As soon as nitrogen is available from the process, it shall be used for purging the enclosure.
This minimizes the potential to condense air on process piping and equipment. Nitrogen purge gas shall
be used when restarting up under cold conditions unless otherwise stated in the manufacturer’s
operating procedures.
If nitrogen purge gas is not available during extended periods for shutdown and cold standby, the
operating procedures shall have instructions on how the enclosure is kept moisture-free. In these cases,
dry oil-free air may be specified by the manufacturer.
11
EIGA DOC 170/17
Some processes (for example, high pressure nitrogen generators) can be operated safely using
moisture-free, oil-free air for enclosure purging, because all process conditions are greater than the
dew point of air. For clean atmospheric pressure air, this is –191.3 °C (–312.3 °F). When considering if
air can be used, the actual atmospheric pressure and composition of air shall be considered, including
trace contaminants. Trace contaminants can significantly raise the dew point of air.
Nitrogen-rich gas that is recovered from some parts of the cryogenic processes might not be suitable
as an enclosure purge gas. Hydrocarbon gas impurities in the recovered nitrogen can elevate the
nitrogen dew point, increasing the likelihood of forming a hydrocarbon-rich liquid phase inside the
cryogenic enclosure.
6.1.2 Pressure
The pressure of the purge gas shall be greater than atmospheric at all points in the enclosure to prevent
oxygen, trace contaminants, and moisture in the air from entering the cryogenic enclosure. When
designing the system, both the frictional and static pressure changes shall be considered. The purge
gas is colder than the surrounding atmospheric air, and therefore, it will tend to have a greater density.
This greater density means that at elevations above grade, the static pressure will decrease more
rapidly inside the enclosure than in the surrounding atmosphere. This difference in static pressure
between the purge gas and atmospheric air shall be considered when determining the desired purge
gas pressure within the enclosure.
Measurements shall be used to ensure that there is positive pressure at all points within the enclosure.
These may be a combination of pressure and/or flow measurements, with the number and type
determined by the manufacturer. The measurements may be local indicators or in the distributed control
system (DCS). The pressure measurement system may also have low and high pressure alarms.
The purge gas flowrate and inlet pressure may also be indicated locally or in the DCS.
Changes in purge gas pressures or flows should be monitored. Changes can indicate a blockage or
leak within the cryogenic enclosure and/or purge gas system and should be investigated (see Section
8).
6.1.3 Injection system
There is significant flow resistance to the purge gas within the perlite or mineral wool. Due to this
resistance, it may be necessary to inject the purge gas at multiple points within the enclosure to ensure
that the purge gas pressure is maintained at all points.
It may be desirable to have separate enclosures or sections of the enclosure. These sections typically
contain pumps or expanders, or large equipment items (this does not refer to small mineral wool packed
boxes for flanged valves). If purge gas does not flow between these sections, then each shall have its
own purge gas supply system that can be isolated for maintenance or process operation. Each separate
system should have its own flow and/or pressure monitoring.
The injection system shall be designed so that the purge gas velocity is less than the perlite fluidization
velocity, which prevents eroding equipment and/or piping (see 7.5).
6.1.4 Venting
ASU enclosures may have some type of vent. However, some ASU systems do not have a continuous
vent. As long as there is positive purge pressure in all sections of the enclosure, a continuous sweep
of the entire coldbox is not necessary.
Often the vent pressure control is a weighted disk to maintain a backpressure on the enclosure.
Nitrogen is injected into the enclosure to make up any losses from leaks plus any vented nitrogen.
The vent, if present, shall be located to prevent personnel from being exposed to an oxygen-deficient
atmosphere.
12
EIGA DOC 170/17
Vents may have a desiccant moisture trap to prevent water from entering the enclosure if air is pulled
in during an upset. A moisture trap adds flow resistance to the vent, and this shall be accounted for in
sizing the purge gas and vent system.
6.1.5 Sample points
In the event of a suspected leak within the enclosure, it is useful to be able to measure the purge gas
composition. These manual measurements are useful to determine the existence, location, and size of
any leaks within the enclosure. (Because nitrogen is used as the purge gas, measuring the composition
will not be able to determine nitrogen leaks). Means to measure the purge gas composition may be
provided at several sampling points on the enclosure. The number and location of sampling points
should take into account enclosure size, the presence of internal partitions, or potential leak points such
as flanged connections. See also 7.3 and 8.3.
6.2 Purge gas—Processes with flammable or toxic gases
The most common cryogenic processes with flammable or toxic gases have carbon monoxide or
hydrogen. Special considerations are needed for these enclosures.
6.2.1 Composition
The purge gas for HYCO cryogenic enclosures shall be non-flammable and contain less than 1%
oxygen (also moisture-free and oil-free). The lower oxygen concentration is to ensure that flammable
atmospheres are not formed. Nitrogen is typically used as purge gas. Air shall never be used as a
backup, temporary, or start-up enclosure purge since the possibility of a leak inside the enclosure during
the start-up would lead to the formation of a flammable mixture inside the enclosure. The liquefaction
point of carbon monoxide is 82 K (–191 °C [312 °F]), which is slightly warmer than nitrogen.
6.2.1.1 Hydrogen—Specific hazards
Hydrogen has a molecular weight of 2.016 g/mol and air has a molecular weight of 28.95 g/mol.
Therefore, any small leaks will dissipate very readily to the upper atmosphere.
A large leak will form a flammable mixture with the oxygen in the air. Hydrogen has very low ignition
energy. The flammable mixture can ignite from many external sources, or even the velocity of the
escaping gas can provide sufficient ignition energy. The flame produced is light blue and cannot be
seen in the daytime (it can be seen at night). Ultraviolet (UV) flame detectors may be installed to aid in
sensing hydrogen leaks and flames.
DANGER: Because hydrogen fires are difficult to see during daylight, personnel working in proximity to
hydrogen shall be trained in the hazards and safety procedures to avoid getting burned.
6.2.2 Pressure
The pressure of the purge gas shall be greater than atmospheric at all points in the enclosure to prevent
oxygen, trace contaminants and moisture from entering the cryogenic enclosure.
Due to the size of the enclosure it is very difficult, if not impossible, to perform a leak test, so it is
necessary to assume there will be small leaks in the enclosure. Failure to maintain the purge pressure
greater than the prevailing barometric pressure could allow atmospheric air into the cryogenic
enclosure, creating the hazards associated with oxygen and moisture. Some potential upset scenarios
that could lead to this condition are:
• Rapid rise in barometric pressure;
• High velocity wind impacting the enclosure surface; or
• Sudden process change, either due to rapid operator changes or upsets that lowers the process
temperature to less than –196 °C (–384 °F), the liquefaction temperature of the nitrogen purge gas.
13
EIGA DOC 170/17
The rapid liquefaction of the purge gas could potentially place a portion of the enclosure in a slight
vacuum.
The manufacturer shall consider these possible scenarios when designing the enclosure and
developing the operating procedures. The design and procedures shall ensure that the purge gas
pressure is sufficient to prevent air ingress.
6.2.3 Injection system
See 6.1.3 for general information on injection points.
6.2.3.1 Positive flow is required to sweep out small leaks
A positive flow of purge gas is required to sweep out any small leaks arising from process equipment.
This avoids accumulating the process gases (carbon monoxide and hydrogen). Therefore, the flowrate
of the purge gas shall be indicated either in the control room (with the DCS or other monitoring
equipment) or in the field. There shall be low flow alarms to warn the operator of potential unsafe
conditions.
6.2.3.2 Pressures and flows to the DCS
The following monitoring devices shall be installed:
• local purge pressure indication;
• local purge flowrate indication;
• low purge pressure alarm in the control room; and
• high pressure alarm in the control room.
Other instrumentation may be added, either as required by a risk assessment or to aid in

troubleshooting.
6.2.4 Venting
HYCO cryogenic enclosures shall be vented with a dedicated vent not shared with other systems in the
facility. This isolation eliminates backflow from other processes and limits the means by which air enters
the enclosure. If there is a leak in the process, then hydrogen and carbon monoxide will be present in
the purge gas vented from the enclosure. The vent shall be designed and located considering the
possibility that it can contain flammable or toxic gases. The composition of the purge gas vent shall be
monitored either continually or periodically. The manufacturer shall provide the maximum
concentrations that are allowed during operation of flammable and toxic components in the enclosure
purge gas.
6.2.5 Sample points
Measuring the purge gas composition within the enclosure is useful to determine the existence, location,
and size of any leaks within the enclosure. The number and location of sample points should consider
the enclosure size, the probability and consequence of process leaks, and the presence of internal
partitions or potential leak points.
Multiple sample points may be piped together so that the enclosure purge gas composition can be more
easily monitored. The separate sample points can then be used individually to better determine the
source of a leak. See also 8.3.
6.3 Maintenance
Enclosures require little maintenance. Typical maintenance tasks include:
14
EIGA DOC 170/17
• maintaining roof to prevent water ingress;
• preventing rust to maintain enclosure;
• maintaining valve boots;
• checking perlite level, particularly immediately after initial plant commissioning or reinstalling perlite;
• checking proper functioning of purge gas system per manufacturer’s recommendations for purge
pressure and/or flow;
• periodic checks for process leaks, typically only visual for ice spots;
• checking the moisture trap on the purge gas outlet, if present; and
• other requirements per manufacturer’s recommendations.
EIGA Doc 147 provides guidance on coldbox maintenance for ASUs [2].
7 Enclosure hazards
7.1 General hazards
There are several types of hazards that can potentially occur in a cryogenic enclosure:
• A gaseous or liquid leak from the process can overpressure the enclosure. A liquid leak can create
pressures greater than the leak source if the cryogenic liquid rapidly vaporizes;
• The enclosures are typically not designed as pressure containing vessels or structures. However,
other design considerations such as wind and seismic loading, can result in a structure which can
contain some significant amount of pressure. If the internal pressure exceeds this unintended
design pressure, then the enclosure will fail, releasing both pressure and insulation. Enclosures
that can withstand greater internal pressure before failing include those with cylindrical cross
sections and those designed to normally operate with full vacuum (to minimize heat leak);
• A gaseous or liquid leak from the process can create a toxic or flammable mixture (depending on
the composition of the process fluids);
• If the gas inside the enclosure has a composition different from design, then it can liquefy on the
process piping. This liquefaction will further change the fluid compositions. These differing
compositions can create hazards, possibly due to either oxygen enrichment or flammability;
• If liquids form or collect within the enclosure, they can embrittle or weaken the enclosure outer
panels and structural members of the enclosure. If the panels fracture from exposure to cold
temperature, this will lead to release of perlite, and the fragments themselves could pose a hazard
to personnel in the plant; and/or
• A high velocity vapour jet into perlite will fluidize the perlite, eroding equipment and piping in a short
time.
7.2 Overpressure
Coldbox casings are constructed to have minimal leaks and are internally purged to exclude ambient
air from the enclosure. Pressurization of the internal volume greater than the normal purge pressure
can occur from any of the following:
• excess purge gas;
• leaking process fluids; or
15
EIGA DOC 170/17
• rapid vaporization of cryogenic pools and leaks, which can occur if the liquid is disturbed or warmed.
Consideration shall be given to relief of this over pressurization and the structural design of the coldbox
during these events.
Over pressurization can occur rapidly and the flowrate is difficult to predict. The size of liquid pools and
the vaporizing heat leak, pressure and size of line breaks, and failed purge gas regulation can result in
gas flows that exceed normal casing relief capacity. Additionally, the insulation retards gas flow and
results in flow resistance between the line break and casing pressure relief device.
In the case of loose fill perlite, fluidization occurs even at a low gas flowrate. Pressures at the source of
the release can lift the entire column of perlite above the release. This results in a combined total
pressure of the casing static pressure and the pressure due to the weight of the column of perlite.
Depending on the size or configuration of the relief device, some initial choking of the relief device can
also occur as the perlite begins to flow through the device. Once flowing, the density of the flowing gas
is a combination of the gas and flowing media. This phenomenon shall be considered when sizing the
enclosure relief device.
Figure 1 indicates the general trends of the pressure load on the casing wall during over pressurization
of an enclosure.
Casing wall
4 - Enclosure pressure
pressure
gas only ΔPPRV
1 - Initial P
2 - Perlite static
P + ΔPPRV
3 - P decreases as
perlite blown out
Time
LEGEND
1 = Initial casing pressure consisting of the purge gas pressure plus static perlite load.
2 = Static head of fluidized perlite, plus pressure drop through relief device.
3 = Decrease in static pressure as perlite is blown from the enclosure.
4 = Enclosure pressure, where the perlite has been blown out of the enclosure. There is less static perlite head,
because the perlite has been blown out. The only back pressure is from the gas flow through the casing relief
device or any breach.
Figure 1—Casing pressure versus time
Leaks can also partially fluidize the perlite, which can create an empty space around the leak point.
This space can suddenly collapse, causing a sudden pressure rise and possibly deform the enclosure.
The enclosure design shall consider the possibility of overpressure events. Small to medium size
overpressurization events (such as excessive purge gas flow and small leaks) are typically relieved by
placing one or more relief devices on the top or side of the casing. The location and direction of relief
16
EIGA DOC 170/17
devices shall consider the surrounding area and potential perlite engulfment of personnel in the area.
For breakaway relief devices, designs should consider incorporating a restraining mechanism to
prevent endangering personnel.
The experience of the industry is large releases of gases or liquids into the enclosure are rare events
when using proper design and operating procedures. However, it is recognized that it is impossible to
design an enclosure that can withstand a large release of gas or liquid such as if a large diameter pipe
fails. Such a scenario will cause the enclosure to fail, releasing pressure and perlite to the environment.
Considerations for scenarios where the enclosure fails due to overpressure:
• The manufacturer may provide likely weak spots in the casing that will fail in a significant
overpressure event;
• When plates are used as structural support (as in a stress-skin design), consideration shall be given
to the losing one or more of these plates in an overpressurization event; and
• Site emergency plans shall be developed that define the measures to take in the event of a vapour,
liquid or insulation release from the cryogenic enclosure. An emergency plan for perlite releases is
discussed in EIGA Doc 146 [11]. With proper design/operating procedures and emergency plans;
it is extremely unlikely that personnel will be injured by such an event.
Cylindrical casings can retain significantly more pressure than an equivalent square or rectangular
casing. The resultant relief of this pressure in an uncontrolled manner can be much more damaging
than in a rectangular enclosure. The cylindrical enclosure can fail in one of three locations:
• cylinder-to-foundation attachment (typically bolts);
• cylinder itself; or
• cylinder-to-roof attachment.
7.3 Unsafe compositions
If a fluid is released from the process into the cryogenic enclosure, it can create an unsafe atmosphere.
It shall be recognized that the insulating material generally has a high resistance to flow, and the
composition can vary greatly within the enclosure. Caution shall be used to ensure that the measured
composition is representative of the enclosure area being considered.
The following potential hazardous compositions can occur.
7.3.1 Oxygen-deficient atmospheres
The atmosphere within the enclosure generally contains insufficient oxygen to sustain life. This is the
typical composition. It is necessary for all operating personnel to be trained in this hazard and to use
appropriate procedures, equipment, and personal protective equipment (PPE).
WARNING: Nitrogen atmospheres do not support life, and unconsciousness or death can occur within
a few breaths.
In some severe weather climates, the enclosure may be located within a larger building. This will allow
operating and maintenance tasks to be completed in a more controlled environment. In this case, there
is an additional enclosure hazard: leaks from the enclosure can create a hazardous atmosphere within
the building. A risk assessment shall be performed and mitigation and countermeasures shall be used.
The general hazards of oxygen-deficient atmospheres and countermeasures are discussed in several
publications [12, 14, 15, 16, 17, 18].
17
EIGA DOC 170/17
7.3.2 Oxygen-enriched atmospheres
In processes that contain oxygen-enriched fluids, a process leak has the potential to create an oxygen-
enriched atmosphere. This can be detected by analysing the cryogenic enclosure atmosphere. An
oxygen-enriched atmosphere within the enclosure creates the following hazards:
• It raises the dew point of the purge gas, and this can liquefy on cold process piping and equipment.
This liquid can migrate in the enclosure, and expose non-cryogenic materials to cryogenic
temperatures;
• The oxygen-enriched atmosphere can leak from the enclosure and expose personnel to the
hazardous atmosphere;
• When the enclosure is shut down and personnel enter to repair a leak, this can potentially expose
the repair personnel to the hazardous atmosphere; and
• The atmosphere within might not be uniform at all locations, so sample point readings might not be
representative of the composition in all locations.
The general hazards of high oxygen atmospheres are discussed in publications [12, 19, 20].
7.3.3 Flammable or toxic atmospheres
For HYCO processes, a process leak can form a flammable or toxic mixture inside the enclosure. This
can lead to a flammable/toxic mixture external to the enclosure due to enclosure leaks. A flammable or
toxic atmosphere within the enclosure creates the following hazards:
• It raises the dew point of the purge gas, and this can liquefy on cold process piping and equipment.
This liquid can migrate in the enclosure, and expose non-cryogenic materials to cryogenic
temperatures;
• The flammable or toxic atmosphere can leak from the enclosure and expose personnel to the
hazardous atmosphere;
• When the enclosure is shut down and personnel enter to repair a leak, this can potentially expose
the repair personnel to the hazardous atmosphere; and
• The atmosphere within might not be uniform at all locations, so sample point readings might not be
representative of the composition in all locations.
7.3.4 Moisture
While not a specific hazard in itself, if water enters the enclosure, it can create operating problems and
personnel hazards. If water enters the enclosure either as liquid (typically from rain) or as vapour (either
with the purge gas or by leaking in from outside), it will freeze and form ice. The ice can agglomerate
with perlite or mineral wool. These frozen masses will restrict piping movement during cool down and
increase the likelihood of a leak. In perlited enclosures the agglomerates can become very large and
heavy and fall through loose perlite, potentially damaging equipment.
7.4 Cold temperatures
Equipment within the enclosure typically encounters a wide range of temperatures, from the lowest
possible temperature in the process to the highest expected ambient temperature. This can range from
–196 °C to 65 °C (–320 °F to 149 °F).The enclosure is designed to withstand the temperatures that can
be expected at each location in all operating modes, including process upsets.
During normal operation, the insulation ensures that the enclosure panels are near ambient
temperatures. Therefore, the enclosure panels are typically not manufactured from cryogenic
compatible materials. In the event of a process leak, panels can crack as discussed in 4.6 and 4.8. Site
18
EIGA DOC 170/17
emergency plans shall be developed that define the measures to take in the event of a vapour, liquid,
or insulation release from the cryogenic enclosure. An emergency plan for perlite releases is discussed
in EIGA Doc 146 [11].
Abnormal conditions can create ice either in the interior or on the exterior of the enclosure. Some
possible causes of ice formation are described in 8.2. If a significant amount of ice accumulates, it can
break free and fall. It can also break free during derime and warming up of the enclosure. If large ice
spots are observed, consider restricting access to the enclosure and surrounding area to prevent
personnel from being injured by falling ice. Also, it may be necessary to construct temporary protection
for critical equipment.
7.5 Equipment erosion
Any leak within a perlite insulated cryogenic enclosure should be investigated. After determining the
risk of continued operation (see 8.1), the leak shall be repaired as soon as practical. A small leak can
fluidize and circulate the perlite, enlarging the hole and possibly eroding adjoining piping or equipment
quite rapidly. This erosion can occur very quickly, causing significant damage in a short time, even as
quickly as a few hours. The erosion will occur more rapidly with a vapour leak than a liquid leak. Higher
pressure vapours will erode at a much greater rate than lower pressure vapours; however, low pressure
vapours can erode equipment at a relatively high rate. Copper and aluminium will erode more quickly
than stainless steel.
7.6 Feed stocks containing oxides of nitrogen
Feed stocks that contain both trace amounts of oxides of nitrogen (mixtures of nitric oxide (NO) and
nitrogen dioxide (NO2), also known as NO x) and conjugated dienes present an explosion hazard. At
cryogenic temperatures, oxides of nitrogen and the conjugated dienes will form a gum which collects in
the cryogenic process equipment. The gum can decompose explosively when warmed, such as in a
defrost. The process equipment shall be defrosted or solvent washed periodically to remove the gum
before the gum accumulates to unsafe levels [21, 22].
8 Troubleshooting
This section describes the possible symptoms and causes of abnormal operational conditions and their
respective corrective actions. Table 1 gives troubleshooting guidelines. It lists various scenarios, how
they can be detected, and the potential consequences. The short-term consequences are the
immediate conditions from the scenario. The potential ultimate consequences are the potential results
if no mitigating actions are taken and the hazard is left unabated.
Table 1 Enclosure upset scenarios symptoms and consequences
Possible symptoms 1) Consequences

Scenario
Monitoring device Indication Short term Potential ultimate
Increase, if purge
Purge gas Atmospheric air enters
gas is on pressure
Increased flowmeter Increased nitrogen enclosure if purge gas
control.
leakage from leakage to flowrate is insufficient to
enclosure Decrease, if purge environment maintain positive
Purge gas pressure gas flow is in manual pressure in enclosure.
or flow control.
Coldbox pressure Increase a) Equipment erosion
ASU process
b) Enclosure
gas leak: Portable oxygen No change
No change overpressure
nitrogen-rich gas detector c) Perlite release
a) Equipment erosion
Coldbox pressure Increase b) Enclosure
ASU process overpressure
Gas leak: Oxygen-rich mixture c) Oxygen reaction
oxygen-rich gas Portable oxygen %oxygen > inlet d) Perlite release
detector purge e) Oxygen saturated
perlite
19
EIGA DOC 170/17

Scenario
a) Equipment erosion
Coldbox pressure Increase b) Enclosure
overpressure
HYCO process Flammable and/or
c) Explosion or fire
gas leak Concentration toxic mixture
Flammable or toxic d) Flammable/toxic gas
greater than alarm release
gas detector
point e) Perlite release
a) Potential flammable
gas mixture forms at
enclosure vent or
leak points, with
HYCO hydrogen Bottom pressure Significant hydrogen hydrogen fire
< 0 mbar
leak indicator leak b) Perlite or cryogenic
liquid release
c) Toxic or flammable
gas release
d) Large explosion
Coldbox pressure Increase
Foundation
a) Embrittlement of
temperature Low temperature
structural supports
ASU process indication
b) Enclosure
liquid leak: Ice on enclosure No change overpressure
nitrogen-rich exterior
Visual inspection c) Cryogenic liquid
liquid Visible vapour exiting release
enclosure
d) Perlite release
Portable oxygen
No change
detector
Coldbox pressure Increase a) Embrittlement of
Foundation structural supports
temperature Low temperature b) Enclosure
ASU process indication overpressure
liquid leak: Ice on enclosure c) Oxygen reaction
Oxygen rich mixture
oxygen-rich exterior d) Cryogenic liquid
liquid Visual inspection release
Visible vapour exiting
enclosure e) Perlite release
Portable oxygen %oxygen > inlet f) Perlite saturated with
detector purge liquid oxygen
Coldbox pressure Increase
a) Embrittlement of
Foundation structural supports
temperature Low temperature
b) Enclosure
indication
overpressure
HYCO process Ice on enclosure Flammable and/or c) Explosion or fire
liquid leak exterior toxic mixture
Visual inspection d) Flammable/toxic gas
Visible vapour exiting release
enclosure
e) Cryogenic liquid
Concentration release
Flammable or toxic
greater than alarm f) Perlite release
gas detector
point
a) Liquefied air inside
enclosure
Approximately b) Ice forms within
Pressure indicator
0 mbar enclosure
a) Atmospheric air
c) Equipment or piping
ASU loss of enters enclosure
damage
purge gas b) Oxygen-rich
d) Perlite or cryogenic
mixture
Purge gas flow Low flow or low liquid release
indication alarm e) Oxygen saturated
perlite
20
EIGA DOC 170/17

Scenario
Pressure indicator Approx 0 mbar a) Liquefied air inside
enclosure
Purge gas flow Low flow or low b) Ice forms within
indication alarm enclosure
c) Equipment or piping
a) Atmospheric air
Flammable or toxic damage
HYCO loss of Normal enters enclosure
purge gas gas detector d) Perlite or cryogenic
b) Oxygen-rich
liquid release
mixture
e) If simultaneous
Portable oxygen process leak, then
Oxygen detected formation of
detector
flammable mixture
inside enclosure
1)
Some scenarios may have more than one symptom.
8.1 Process leaks and detection
Process leaks give rise to different abnormal operation depending on quantity and temperature of the
liquid or gases released. In case of small leaks, they may not affect mechanically integrity of the
structure or perlite agglomeration and they can be deduced by routine means such as:
• ice spots or blocks on the external side of the enclosure;
• vapours from the bottom of the enclosure;
• purge gas pressure or flow changes;
• purge gas composition changes; or
• low temperatures as detected by temperature probes (if probes are installed).
Large leaks can be detected by the previous symptoms. They can also change the operating
parameters and be detected by these process changes;
• pressures;
• temperatures, or
• decreases in liquid levels or cryogenic liquid production.
In extreme cases, a leak can freeze the ground surrounding the foundation, causing it to heave. The
enclosure will then tilt and is no longer vertical. This indicates a significant safety hazard and should be
investigated immediately.
Rotating equipment such as pumps or turbines are more likely to leak, so temperature indication or seal
leak detectors may be helpful in detecting the leak sources. Temperature indicators at the base of the
enclosure may detect leaks for cryogenic liquids.
After identifying the leaking points, the risk of continued operation shall be assessed. Items to be
considered should include:
• size of leak;
• composition of the fluids leaking from the process (for example, flammable, toxic, oxidizers);
• potential for the leak becoming worse;
21
EIGA DOC 170/17
• potential for equipment damage, including equipment erosion (see 7.5);
• consequence of releasing process fluids to the enclosure or atmosphere;
• possibility and consequence of enclosure failure;
• risk of ice build-up on the enclosure panels and restriction of access to platforms and valves as a
result of ice accumulation;
• risk of perlite release and/or eruption;
• risk of damage to equipment or small bore piping located near ground level from ice accumulation
falling off the enclosure panels during significant change in weather causing melting of ice; and
• any other items identified by the risk assessment team.
The risk assessment may allow the plant to continue to run for an extended time or it may require
immediate shutdown and repair. If the repair requires perlite to be removed, EIGA Doc 146 gives
guidance for safely removing perlite [11].
Once a leak has been identified, it is imperative that the process pressure be greater than the purge
gas pressure at all times. Failure to do so will allow perlite to flow into the process equipment. Once
perlite is in the equipment, it is extremely difficult to remove. Perlite within process equipment can create
both operating and safety problems.
WARNING: If perlite becomes lodged within portions of an ASU, it can create areas where oxygen and
hydrocarbons can collect together. This can lead to a serious explosion that can damage equipment
and injure or kill personnel. Further guidance can be found in EIGA Doc 146 and EIGA Doc 65, Safe
Operation of Reboilers/Condensers in Air Separation Units [11, 3].
8.2 Ice on enclosure external surfaces and piping
Ice on the external face of an enclosure indicates excessive heat leak. This can be caused by one of
the following:
• process leaks with relative cold transfer from the process to the enclosure;
• locally missing insulation inside coldbox;
• degradation of insulation due to moisture entering the coldbox (typically caused by rain water
ingress or loss of purge gas);
• loss of vacuum in the case of vacuum jacketed enclosures; or
• improperly designed piping (see 4.3).
If the enclosure surface or external piping has ice, it may indicate that hazardous mixtures are
accumulating within process piping by concentrating some components (see 4.3). Therefore, any ice
should be investigated to ensure that a safety hazard is not present.
Ice spots on top can be also due to settling of perlite level some weeks after the initial start-up. More
frequent inspections should be performed during this period to identify if such settling has occurred.
Inspection and refilling should be carried out, where necessary.
The presence of ice can be a safety hazard (see 8.1). In addition to ice spots, thermography or thermal
imaging can detect cold or warm areas on the enclosure. Thermal images can be useful in identifying
operating problems.
22
EIGA DOC 170/17
8.3 Purge gas sampling
As described in 6.1.5 and 6.2.5, sampling points may be provided at different elevations of the coldbox.
Sampling purge gas at different elevations and analysing for oxygen can indicate leaks from oxygen
containing process streams. Leaks of nitrogen cannot be detected in this way because the purge gas
is nitrogen.
In the case of HYCO plants, continuous or periodic analysing on purge gas outlet for the main
representative components (for example, hydrogen, methane, and carbon monoxide) shall be carried
out. Greater than normal concentrations can indicate a process leak.
8.4 Purge gas flow and pressure changes
Enclosure casing pressure and purge gas flowrate indications can be useful for detecting process leaks
inside the enclosure. Any significant change in flowrate or pressure during operation shall be
investigated since these can signify leaks or blockages that could affect enclosure operation and safety.
8.5 Emergency condition guidance
The site emergency plan shall consider including the following items.
In the event of leaks being suspected or discovered, they should be dealt with only by personnel who
have been adequately trained and have proper equipment.
Many of the enclosure alarms that can indicate an internal leak could potentially lead to an unsafe
atmosphere or could over pressurize the box. Responding to the alarms may include having the
operator go to the enclosure to eliminate the alarm condition. Operators shall be trained on the response
to such alarms, so to be able to evaluate when it is safe to attempt to rectify the alarm by field action
and when it is necessary to not physically approach the hazardous area.
If a leak is suspected or discovered, the potential rapid and severe consequences shall be considered.
In particular, if the pressure inside the enclosure goes high, the possibility of sudden perlite release
shall be considered. If the probability of a perlite release is high, a restricted access area should be
established and permission to enter such a space shall be issued by a responsible person.
When working in cryogenic enclosures with interconnected sections, consideration shall be given to
monitoring internal conditions of all enclosure sections. A sudden rise in pressure can occur in a section
where perlite is being removed as well as in adjacent sections. This rise could cause an eruption or
release to the atmosphere from adjacent sections or could affect the section where work is being done.
The restricted area size and location should be determined taking into account:
• location and elevation of relieving devices;
• permanent working places on the premises that could be affected by perlite release;
• possibility of perlite ingestion by adjacent processes;
• venting during perlite release of oxygen-enriched or oxygen-deficient streams (and flammable

streams in case of HYCO); and
• fog cloud from cryogenic release.
It may be decided to open the enclosure to investigate or repair the leak. In these cases, the plant
operators shall exercise caution if any openings are made into the coldbox. Some of the hazards with
an opening in the enclosure are described in 9.2.
23
EIGA DOC 170/17
9 Changes, modifications, and repairs to cryogenic enclosures
All work shall be carried out using a safe work permit system [2, 23].
9.1 Management of change
Enclosures are engineered to perform a specific purpose; any modification to a cryogenic enclosure is
a management of change (MOC) and shall be addressed under a MOC system [13]. Experts in the
design and operations of enclosures shall be involved in changes to any enclosure structure.
Repairs to cryogenic enclosures that are not introducing changes are a replacement in kind. Repairs
shall be carried out in accordance with the original enclosure supplier’s structural design, insulation
specifications, purge system specification, etc. If the repair requires a modification to the structure,
however simple, it shall be considered as a change in accordance with MOC procedures.
9.2 Structural members and panels
Welding or cutting shall not be performed on the panels or structural members of the enclosure from
the outside without an engineering review of the structural design and its limitations.
Removing or modifying of panels could have one or more of the following hazards:
• Opening a panel can release all the perlite in the enclosure above the opening;
• There could be piping or wiring behind the panel that could be damaged;
• The panel could bear part of the structure load, and removal could affect the structural integrity of
the enclosure;
• The atmosphere behind the panel can be asphyxiating, oxygen-enriched, flammable and/or toxic;
or
• If perlite surrounded by liquid cryogen is disturbed, it can cause a perlite eruption.
9.3 Insulation removal
EIGA Doc 146 gives guidance on removing and installing perlite [11].
EIGA Doc 146 discusses the hazard of removing perlite when cryogenic liquids have collected within
the perlite [11]. In addition, the liquids could have a hazardous composition and the enriched liquid
could create problems as described in 7.3.
9.4 Confined space entry
If a repair to the process piping or equipment inside the enclosure has to be carried out, the work inside
the enclosure shall be conducted following confined spaces entry regulation(s) applicable to the location
and the owner/operator’s confined space entry work process procedures. All other applicable
regulations shall be followed [24]. For more information, see EIGA Doc 146 [11].
9.5 Equipment isolation
Some portions of the process equipment and piping inside the enclosure can be left cold or pressurized
or contain hazardous energy or fluids while work is performed on other portions of the equipment/piping.
The operator of the enclosure shall define appropriate circuit isolation procedures and lockout/tagout
(LOTO) protection to ensure entrants are not exposed to unsafe work conditions. Experts
knowledgeable in process isolation shall be engaged to review the isolation method and adequacy of
any lockout, purging, and depressurizing performed before the entry begins.
24
EIGA DOC 170/17
9.6 Perlite removal from piping and process equipment
If a leak or process line break occurs and the process pressure is less than the enclosure pressure
(even for a short time), then perlite can enter the process piping and equipment.
In these cases, a risk assessment shall be performed to determine the consequences and hazards of
perlite within the process. These include, but are not limited to the following:
• blocking small openings within equipment, particularly the small channels within brazed aluminium
heat exchangers. See EIGA Doc 145, Safe Use of Brazed Aluminum Heat Exchangers [1];
• increased pressure drop due to blocking of piping and other flow paths;
• operating problems with perlite continually accumulating on filters, strainers, and screens;
• reducing process performance by blocking distributors within columns and heat exchangers;
• potential for dry or pool boiling within reboilers, heat exchangers, leading to potential accumulation
of hazardous mixtures; and
• damaging rotating equipment and valves when they ingest perlite.
When perlite is suspected within the process, it is prudent to stop the process immediately to prevent
the perlite from moving further into the process.
DANGER: Failure to remove perlite and continuing to operate can lead to significant performance
degradation and/or accumulation of hazardous mixtures. These can lead to explosions and personnel
injury.
WARNING: This is an extremely serious situation. Experts shall be consulted before attempting to
remove perlite from the equipment or piping.
In almost all cases, the assessment determines that the perlite shall be removed from the process. This
is done by:
• Entering process equipment and physically removing the perlite;
• Stopping reboiler operation, to prevent perlite from migrating further into the process;
• Flushing the plant with liquids, and draining the perlite with the liquids. This could require repeated
filling and draining of low points and sumps;
• Repeatedly cleaning and reinstalling filters, strainers, and screens; and
• Pressurization and rapid depressurization of process equipment (see EIGA Doc 147, Safe Practices
Guide for Cryogenic Air Separation Plants [2]).
9.7 Piping and equipment
Much of the piping and equipment within the coldbox is cleaned for oxygen or cryogenic service. Before
returning such piping and equipment to process service, it shall be appropriately cleaned [4, 5].
10 References
[1] EIGA Doc 145, Safe Use of Brazed Aluminium Heat Exchangers for Producing Pressurized
Oxygen, European Industrial Gases Association. www.eiga.eu
25
EIGA DOC 170/17
NOTE—This publication is part of an international harmonization program for industry standards. The
technical content of each regional document is identical, except for regional regulatory requirements.
See the referenced document preface for a list of harmonized regional references.
[2] EIGA Doc 147, Safe Practices Guide for Cryogenic Air Separation Plants, European Industrial
Gases Association. www.eiga.eu
[3] EIGA Doc 65, Safe Operation of Reboilers/Condensers in Air Separation Units, European
Industrial Gases Association. www.eiga.eu
[4[ EIGA Doc 33, Cleaning of Equipment for Oxygen Service, European Industrial Gases Association.
www.eiga.eu
[5] CGA G-4.1, Cleaning Equipment for Oxygen Service, Compressed Gas Association, Inc.
www.cganet.com
[6] EIGA Doc 154, Safe Location of Oxygen and Inert Gas Vents, European Industrial Gases
Association. www.eiga.eu
[7] BSI BS 2972, Methods of Test for Inorganic Thermal Insulating Properties, British Standards
Institute. www.bsigroup.com
[8] ISO 1182, Reaction to Fire Tests for Products—Non-Combustibility Test, International
Organization for Standardization. www.iso.org
[9] Safety Info 23, Fire in LOX Vacuum Jacketed Piping, European Industrial Gases Association.
www.eiga.eu
[10] Steinberg, T. A., Newton, B. E. and Beeson, H. D. Flammability and Sensitivity of Materials in
Oxygen-Enriched Atmospheres, Volume 9, ASTM International. www.astm.org
[11] EIGA Doc 146, Perlite Management, European Industrial Gases Association. www.eiga.eu
[12] EIGA PP-14, Definitions of Oxygen Enrichment/Deficiency Safety Criteria Used in IHC Member
Associations, European Industrial Gases Association. www.eiga.eu
[13] EIGA Doc 51, Management of Change, European Industrial Gases Association. www.eiga.eu
[14] CGA SB-2, Oxygen-Deficient Atmospheres, Compressed Gas Association, Inc. www.cganet.com
[15]. EIGA Doc 44, Hazards of Inert Gases, European Industrial Gases Association. www.eiga.eu
26
EIGA DOC 170/17
[16] CSB Safety Bulletin, Nitrogen-Enriched Atmospheres Can Kill, U.S. Chemical Safety and Hazard
Investigation Board. www.csb.gov
[17] CSB Safety Bulletin, Hazards of Nitrogen Asphyxiation, U.S. Chemical Safety and Hazard
Investigation Board. www.csb.gov
[18] CSB Final Report: PowerPoint Presentation, The Hazards of Nitrogen Asphyxiation. U.S.
Chemical Safety and Hazard Investigation Board. www.csb.gov
[19] EIGA Doc 4, Fire Hazards of Oxygen and Oxygen Enriched Atmospheres, European Industrial
Gases Association. www.eiga.eu
[20] CGA P-39, Guidelines for Oxygen-Rich Atmospheres, Compressed Gas Association, Inc.
www.cganet.com
[21] Bohlken, S. F., Heat Exchanger Explosion in a Nitrogen-Wash Unit, Chemical Engineering
Progress, April 1961, Vol. 57, pp. 49-52. www.aiche.org
[22] Sakai, Y., This Ammonia Unit Exploded, Petroleum Refinery, January 1961, Vol. 40, pp. 178-181.
[23] EIGA Doc 40, Work Permit Systems, European Industrial Gases Association. www.eiga.eu
[24] Code of Federal Regulations, Title 29 (Labor), U.S. Government Printing Office. www.gpo.gov
27

Safe Design and Operation of Cryogenic Enclosures

Uploaded by

Copyright:

Available Formats

Safe Design and Operation of Cryogenic Enclosures

Uploaded by

Document Information

Original Title

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Safe Design and Operation of Cryogenic Enclosures

Uploaded by

Copyright:

Available Formats

SAFE DESIGN AND OPERATION

EUROPEAN INDUSTRIAL GASES ASSOCIATION AISBL

AVENUE DES ARTS 3-5 • B – 1210 BRUSSELS

SAFE DESIGN AND OPERATION

EUROPEAN INDUSTRIAL GASES ASSOCIATION AISBL

2 Scope and purpose .................................................................................................................................. 1

4 Design considerations .............................................................................................................................. 3

6 Operation of cryogenic enclosures ......................................................................................................... 10

7 Enclosure hazards .................................................................................................................................. 15

9 Changes, modifications, and repairs to cryogenic enclosures ............................................................... 24

Amendments from 170/12

Note: Technical changes from the previous edition are underlined

2 Scope and purpose

This publication does not cover the following:

For the purpose of this publication, the following definitions apply.

3.1 Publication terminology

Indicates that a procedure is recommended.

Indicates that the procedure is optional.

Is used only to indicate the future, not a degree of requirement.

Indicates a possibility or ability.

3.2 Technical definitions

3.2.1 Air separation unit

3.2.2 Coldbox and cylindrical enclosure

Temperatures less than approximately –90 °C (–130 °F) [10].

NOTE—Also known as defrosting, de-icing, and thawing.

Structure that retains the insulation and surrounds the equipment.

3.2.7 Perlite eruption

3.2.8 Perlite release

Uncontrolled spillage of perlite to the environment.

4.1 Types of insulation

CAUTION: Since it is a lightweight powder, it can become an asphyxiation hazard if inhaled or if a

4.1.2 Mineral wool

4.2 Enclosure casing

4.2.1 Cylindrical enclosures

4.2.2 Rectangular enclosures

4.2.3 Perlite filling/removal nozzles

4.2.4 Enclosures with multiple sections

4.3 Piping design

• process bellows, flexible joints, or braided hose;

• valve or other piping equipment weaker than connected pipes, and

All operating modes shall be considered in the design, including:

Other piping design items that should be considered are:

• protection of small bore lines (see 4.10);

• piping loads from perlite insulation;

4.4 Enclosure materials of construction

• Release of purge gas; and

4.5 Load calculation

• Lifting (if any);

• Perlite load on piping, equipment, enclosure and foundations, and

• Environmental conditions on-site such as snow, wind, and earthquakes.

4.6 Structure beams and process equipment support

Combustible material shall be avoided for any supports.

• Install open air conduits in the foundation that rely on convection.

4.8 Enclosure bottom

For HYCO boxes, see 4.12.

Cryogenic pumps are more susceptible to liquid leaks because:

• they are often installed with bolted flanges for maintenance;

• their motion creates vibrations, which can lead to leaks.

• seal leak detectors; or