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Student Exploration: Stoichiometry

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The key takeaways are that a mole is defined as 6.02 x 10^23 particles of a substance and is related to Avogadro's number. Stoichiometry uses moles and molar masses to determine amounts of substances in chemical reactions.

A mole is defined as 6.02 x 10^23 particles of a substance. A mole of a substance has a mass in grams equal to its molar mass. Avogadro's number is fundamental to relating particles to moles.

Scientists find the molecular mass by adding the atomic masses of each atom in the molecule. The molar mass of a substance is equal to its molecular mass in grams. Molar masses are used to convert between moles and mass.

Name: ________Sofie Goodman_______ Date: __3/5/2021______________________

Student Exploration: Stoichiometry

Vocabulary: Avogadro’s number, balanced equation, cancel, coefficient, conversion factor,


dimensional analysis, molar mass, mole, molecular mass, stoichiometry

Prior Knowledge Questions (Do these BEFORE using the Gizmo.)

1. A 250 mL glass of orange juice contains 22 grams of sugar. How much sugar is in a two-liter

(2,000 mL) bottle of orange juice? ___176 grams__________________________________

2. It requires two sticks of butter to make a batch of 20 cookies. How much butter will it take to

make 150 cookies? ______15 sticks__________________________________

Gizmo Warm-up
Just as a cook follows a recipe to decide how
much of each ingredient to add, a chemist uses
stoichiometry to determine the amounts of
substances involved in chemical reactions. The
Stoichiometry Gizmo allows you to try your hand
at figuring out the amounts of reactants and
products that take part in a chemical reaction.

To begin, check that this equation is shown:

Fe2O3 + 3CO  2Fe + 3CO2

1. Look at the coefficients (such as the “3” in 3CO) in front of each substance in the equation.
The coefficients tell you how many molecules or atoms take part in a chemical reaction. In
the spaces below, list the number of each molecule or atom in the equation:

Fe2O3 __1___ CO __3___ Fe __2___ CO2 __3___

2. In a balanced equation, the same number of each kind of atom is shown on each side
of the equation. Calculate the number of iron (Fe), oxygen (O), and carbon atoms (C).

Reactants Iron: _2____ Oxygen: __6___ Carbon: __3___

Products Iron: __2___ Oxygen: _6____ Carbon: __3___

Based on these values, is the equation balanced? ___Yes________

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Get the Gizmo ready:
Activity A:  Check that the equation is still:
Moles Fe2O3 + 3CO  2Fe + 3CO2
 If not, click New equation until it reappears.

Introduction: A mole is:


A) A mammal known for digging up gardens.
B) A small, dark spot on the skin.
C) A spy embedded within an enemy government.
D) 6.02 × 1023 particles of a substance.
E) All of the above.

The correct answer, of course, is E. In chemistry, the mole (mol) is defined as an amount of a
substance that contains 6.02 × 1023 particles of that substance. This number, called
Avogadro’s number, is special because this number of particles has a mass in grams that is
equal to the mass in universal mass units of a single particle of the substance.

Question: How do scientists find the molecular mass and molar mass of a substance?

1. Calculate: The molecular mass of a molecule is the sum of the masses of each atom in the
molecule. The unit of molecular mass is the universal mass unit (u).

Iron’s atomic mass is 55.85 u, carbon’s mass is 12.01 u, and oxygen’s mass is 16.00 u.

A. Calculate the molecular mass of carbon monoxide (CO) by adding the

atomic mass of carbon and the atomic mass of oxygen: ____28

grams/mole________________

B. Calculate the molecular mass of carbon dioxide (CO2): _____44

grams/mole_____

C. Calculate the molecular mass of iron (III) oxide (Fe2O3): ___160

grams/mole______

2. Infer: A mole of a substance has a mass in grams that is equal to the molecular mass. For
example, a carbon atom has a mass of 12.01 u. A mole of carbon has a mass of 12.01 g.
Based on their molecular masses, list the molar mass of each substance:

Fe2O3 ___160 grams_ CO __28 grams________ Fe ___56 grams_______


CO2 ___44 grams_________

Check your answers on the Gizmo by inspecting the middle row of tiles on the right side of
the Gizmo. These tiles show the units “1 mol” on top and “g” below.

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3. Practice: Hydrogen has an atomic mass of 1.01 u. What is the molar mass of these
substances?

H2O ____18 grams______ CH4 ___16 grams_______ H2CO3 ___62 grams_______


C6H12O6 ____180 grams______

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Get the Gizmo ready:
Activity B:
 Check that the equation is still:
Canceling units
Fe2O3 + 3CO  2Fe + 3CO2

Introduction: While solving problems in stoichiometry, it is useful to pay attention to the units of
the answer. The process of comparing units is called dimensional analysis. A common
technique involves using conversion factors to convert from one unit to another. Units that
appear in the numerator and denominator of a fraction can be canceled out. For example,
converting 2 moles of carbon monoxide to grams involves multiplying by a conversion factor:

2 mol CO • 28.01 g CO = 56.02 g CO


1 mol CO

All conversion factors are equivalent to one. For example, the conversion factor given above is
equivalent to one because the numerator (28.01 g CO) and denominator (1 mol CO) represent
the same amount of CO. The “mol CO” unit is canceled, leaving an answer unit of grams.

Question: How do we solve problems in stoichiometry?

1. Observe: The first question is: “How many moles of carbon monoxide (CO) are required to
react completely with 1.75 moles of iron (III) oxide (Fe2O3)?” (If this is not the question you
see, click New question until it appears.)

A. What unit is given in the question?

_________Moles______________________________

B. What quantity is asked for?

_________Moles____________________________________

2. Find: Look for the conversion factor that contains the units “mol Fe2O3” on top and “mol CO”
on the bottom. Drag the tile containing this factor down to the green strip at the bottom.

According to the tile, how many moles of CO react with one mole of Fe2O3? ____3 moles__

3. Analyze: To get an answer in moles of CO, you need to cancel the moles of Fe2O3. Turn on
Show units.

A. What units are given to the right of the equals sign? __Moles________________

B. If these aren’t the units you want, click Flip tile. What unit is given now? __Moles__

4. Calculate: If the units are correct, multiply or divide the numbers to solve the problem.

A. How many moles of CO will react with 1.75 moles of Fe2O3? ___5.25 mol CO___

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B. Turn on Show numerical result. Were you correct?
_____Yes____________________

(Activity B continued on next page)

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Activity B (continued from previous page)

5. Practice: Turn off Show units and Show numerical result. Click New question, and use
what you’ve learned to solve another stoichiometry problem. For each problem, list the units
given, the units asked for, and the solution.

The problems in the Gizmo are given in random order, so you may have to click Next
question several times to see a new problem. (Note: Each term in the equation is either a
solid (s), liquid (l), gas (g), or an aqueous solution (aq).)

If you are stuck, try one of the following hints:


 If the given unit is grams (or liters or particles), convert from that unit to moles first.
Then convert to moles of the answer substance.
 If the answer unit is grams, liters, or particles, find the number of moles of the answer
substance first. Then convert the moles of answer substance to the desired unit.
 If you have a calculator, try to calculate the solution to each problem yourself before
turning on the Show numerical solution checkbox.

Problems:

A. What volume of carbon dioxide (CO2) will be produced if 2.90 moles of iron (Fe) is
produced? [Note: In the Gizmo, it is assumed that all gases are at standard
temperature and pressure, or STP.]

Given unit: __Moles___ Answer unit: _Liters___ Solution: __97.4 L CO2_

B. What mass of iron (Fe) can be obtained from 3.80 g iron (III) oxide (Fe2O3) reacting
with excess carbon monoxide (CO)?

Given unit: _____grams____ Answer unit: ___grams____ Solution: __2.66 g Fe__

C. How many moles of iron (Fe) will be produced from 6.20 moles of carbon monoxide
(CO) reacting with excess iron (III) oxide (Fe2O3)?

Given unit: __moles_____ Answer unit: ___moles_____ Solution: ___0.20 mol


Fe_

D. How many molecules of carbon monoxide (CO) are needed to react with excess iron
(III) oxide (Fe2O3) to produce 11.6 g of iron (Fe)?

Given unit: _____moles___ Answer unit: ___grams _____ Solution: ___8.73 grams
CO_________

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6. On your own: Click New equation to try solving problems with a new chemical equation.
There are five equations in all, and five problems per equation. The Gizmo will keep track of
how many problems you solve. Good luck!

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