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Chapter Practice Problems: Acids & Bases

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CHAPTER PRACTICE PROBLEMS

ACIDS & BASES


Q.1. How can RCOOH be converted to RCH2COOH?

Q.2. Complete the following equation:


H3C CH2
CO 2 H2O / H
  HCl
 peroxide
  
? Mg
ether
? ? ?
CH3

Q.3. Complete the following equation:


O OH

SOCl2 AlCl3 Zn Hg


 
  (G) Anhydrous
(H) Conc.HCl
(I)

Q.4. Convert:
HO O O OH
O

(a)  (b) 

Cl Br
O CH3 HO CH3
O OH
O Cl
CH3
OH
Br
(c) (d) 


NH2

Q.5. Write the major products when the following compounds are treated with aqueous alkaline Br 2.
(a) (b) H2N NH2
NH2

H3C O
O O

Q.6. Bring out the following transformations:


(a) RCH2OH   RNH2 (b) RCH2OH 
 RCH2CH2NH2 (c) RCH2OH 
 RCH2NH2

Q.7. Complete the following equation and give the:


O
NaN3 N2 H2O

   ?
 ? ?  CO2
?
Cl

Q.8. Complete the following equations:


AlCl3 Zn Hg SOCl2 AlCl3
 
succinic anhydrie C  10H10O3  conc.HCl 
C  10H12O2 C10H11OCl C10H10O 4
( A) (B) (C) (D)

Q.9. Complete the following equations:

C H MgBr H2O H Pt

 
 65 
  ? ? H2O
? H2
?

Q.10. (a) How will you synthesize aspirin from phenol?


(b) How will you synthesize oil of winter green from phenol?
(c) How will you synthesize cinnamic acid from phenol?

***

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