4.-Carboxylic-Acid-its-derivatives

AtoZ CHEMISTRY Carboxylic Acid & its derivatives
Carboxylic Acid & its derivatives

(C) Bothare equally acidic
1. Acid & its Preparation
(D) None of these
Q 1. Which of the following acids is present in vinegar
Q 9. The product in the reaction
?
(A) Formic acid (B) Acetic acid
(C) Tartaric acid (D) Butyric acid  1. O3
2. H 2O2 / H 2O

Product, is
Q 2.
CH O
The general formula n 2n 2 could be for open
COOH C=O
chain
(A) diols (B) diketones COOH O
(A) (B)
(C) carboxylic acids (D) dialdehydes O
Q 3. The higher boiling points of carboxylic acids are
due to
(C) O (D) None of these
(A) their acidic nature
(B) intermolecular hydrogen bonding Q 10. In the reaction

(C) their dimerization
R – mgx +
CO 
2
H3O
 product, is
(D) both (B) and (C)
(A) RCOOH (B) R–CHO
Q 4. Which of the following is not acid derivatives ? O
(A) R  CN (B) RCOCl (C) R–C–R (D)
R  CH2 OH
(C) R  NC (D) R  COOR ' Q 11. In the givenreaction:
Q 5. Which of the following acids is the strongest ? NBS H3O
C6 H 5  CH 3   A 
NaCN
 B 
C
CH3COOH CH2ClCOOH hv
(A) (B) C is
CHCl COOH
2 CCl3COOH C6 H5  CH2  Br
(C) (D)
(A)
Q 6. Among the acids,
C6 H5  CH2  CN
 I  HC  C  COOH (B)
O
 II  H2C  CHCOOH ||
C5H5  CH 2  C NH 2
(C)
CH CH COOH
3 2 C6 H5  CH2  COOH
(III)
(D)
The acid strength follows the sequence 
(A) I  II  III (B) I  II  III Q 12. Which halo derivative(s) on treatment with O H
(C) I  II  III (D) I  II  III will give carboxylic acid ?
Q 7. Acetic acid exists in a dimer state in benzene due
to
(A) condensation reaction
(B) presence of carbonyl group (A) (B)
(C) presence of carbonyl group
(D) presence of   hydrogen
O
(C) (D) All of these
 Q 13. Which one of the following compounds is least
Which e  pair is more acidic in
R–C–O–H
Q 8.  reactive with water ?
(A) l.p. At   c  atom
(B) l.p. at  c-atom
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(D) hexane-2,3,5- triol

A 
(1) conc. NaOH
 2 H

(A) (B) Q 18. benzoic acid, A would be
(C) (D)
(A) (B)
Q 14. Predict the final product (S) formed in the
following reaction sequence
(C) (D)
(A) 2. Preparation of Acid Derivatives

H2 N  CH2 3 CH2CH2COOH Q 1. In the reaction
(D)
R  N  C  H 2O / H  
Products are
(A)
R  COOH, NH3
(B)
R  NH2 , HCOOH
(C) (D)
(C)
R  CONH2
Q 15. Compound O
A would not be (D) R – NH – C – H
Q 2. Hydrolysis of Amide is taster in
(A) Basic medium
(A) (B) (B) Acidic medium
(C) Neutral medium
(D) None of these
(C) (D) Q 3. In the reaction
A 
K2Cr2O7
R  COOH  PCl5 
Q 16. H carboxylic acid A would be Products are
RCOCl  HOCl3
(A)
R COCl  P2O5
(B)
(A) (B) RCOCl  H3PO4
(C)
RCOCl  H PO
3 3
(D)
Q 4. Which one of the following acids of thermally
most unstable ?
(C) (D)
(A) CH3-CO-COOH
A (one mole)   2 mole of formic acid, A
HIO4
Q 17. (B) CH3-CO-CH2-COOH
would be (C) CH3-CO-CH2-CH2-COOH
(A) Butane -2, 3-diol (D) CH3-CO-CH2-CH2-CH2-COOH
(B) pentan-2, 3, 4- triol Q 5. For the following acids the rate of
(C) hexane-2,3,4,5-tetraol decarboxylation on heating would be
(A) (B)
(II)
(III)
NO2  CH 2  COOH
(IV)
HOOC  CH2  COOH
(C) (D)
(A) III  I  IV  II (B) I  III  IV  II Q 9.
(C) III  IV  I  II (D) I  IV  III  II
Q 6. Ease of esterification of following alcohol with
HCOOH is  excess   
HO
 X,X is
2
CH 3  CH 2OH (CH 3 )2 CH  OH (CH 3 )3 C  OH

I II III
(A) III  II  I (B) I  II  III (A)
(C) II  I  III (D) II  III  I
Q 7. Consider the following compounds
The decreasing order of reactivity towards
hydrolysis by aqueous NaOH is
(B)
(I)
(C)
(D)
(II)
Q 10. 
KOH
 
PhCH2Cl
 X, X is
(III)
(IV)
(A) I  II  III  IV (B) III  II  IV  I (A)
(C) IV  I  II  III (D) I  IV  II  III
Q 8. In the given reaction
(B)
  X  , [x] is :
H
(C)

(A) negative charge in can’t be

(D) delocalized into the carbonyl group
(B) CH3 group in CH3CO3H shows +I effect
(C) both are correct
Q 11. X, (D) none is correct
Q 14. In the given reaction:
X is
B will be
(A)
(A)
(B)
(B)
(C)
(C)
(D)
(D)
Q 12. An optically active compound ‘x’ has molecular
formula C4 H5O3 . It evolves CO 2 with aq. Q 15. Consider the reaction,
NaHCO3 . ‘X’ reacts with LiAIH 4 to give
(A) and (B)
achiral compound ‘x’ is
(A) and (B) respectively are
(A)
(A)
(B)
(B)
(C)
(D) (C)
Peroxyacetic acid  CH3CH3H  is a weaker acid

(D) Both (A) and (B)
Q 13.
than acetic acid  CH3CO2H  since

Q 16. In the given reaction, R  COOH 

1.SOCl2 2. NaN3
3.Ag 2O 4.R ' NH 2

Product, is
O O
(A) R – C – NH – R’ (B) R – C – NH2

PCl5  excess  O
 [P],
(C) R’ – C – NH2 (D)
RNH2
[P] will be Q 5. In the reaction
R  COOH 
1.SOCl2 2. NaN3
3. 4. H 2 O
Product, is
(A)
R  CH2 COOH (B) R  COOR
(A) (B)
(C)
RNH 2 (D) None of these
Q 6. Which of the following compound(s) will give
HVZ reaction ?
(C) (D)
3. Hundsdiecker Reaction, curtius Reaction,

HVZ Reaction, Hoffmann bromamide reaction
Q 1. The reaction,
(A) (II) Only (B) (III) Only
RCOOAg  Br2 
CCl4
 RBr  AgBr  CO 2
is (C) Both (II) and (III) (D) All four
called CH3CH2  COOH 
P/ Br2
 A 
(A) HVZ Q 7.
 B  

H /
(B) Hunsdiecker reaction 
aq.KOH

(D), compound (D) is
(C) Hofmann’s reaction
(D) Carbylamine reaction CH2  CH  COOH
(A)
H2SO4  conc.
Q 2.
RCOOH  N3H 

RNH2  CO2  N2 (B)
The above reaction is called
(A) HVZ reaction
(B) Hunsdiecker reaction (C)
(C) Schmidt reaction (D) CH  C  COOH
(D) decarboxylation reaction
CH3  CH2  COOH
Q 3. The product (C) in the following reactions is Q 8. In the reaction sequence
  A     B    C   X   Y  Z
PBr3
RCOOH 
NH3 Heat P2O5 Br2 H 2O

RNH 2
(A) (B) RCN
RCONH 2 (A)
(C) RNC (D)
Q 4. In the reaction
(B)
(B)
(C)
(C)
(D) All are Correct (D)
Q 9. Which of the following will not give HVZ Q 13. During Hoffmann bromamide reaction, the
reaction ? intermediate formed is
C2 H5 – CH – COOH  
(A) R  N  C (B) R  N  C  O
(A) OH
(C) R  C  N  O (D) R  N  O
(B)
CH3CBr2COOH
CH 3CHI 2 
KCN
 
H 2O


C2 H5 – CH – COOH Q 14. ?
Here the end product would be
(C) Br
(A) 2- cyanopropionic acid
(D)
CH 
3 2 CHCOOH (B) ethane -1, 1-dicarboxylic acid
Q 10. In the reaction (C) 2-methyl ethanoic acid
(D) propionic acid
R  CH 2COOH  Cl 2 
PBr3

Product, is Q 15. In a set of the given reaction, acetic acid yielded a
R – CH – COOH R – CH COBr product C.
(A) Br (B) Br CH3COOH  PCl5  C
R – CH – COOH R – CH – COCl
The product C would be
(C) Cl (D) Cl CH3CH  OH C6 H5
(A)
Q 11. In the given reaction
C2H 5
CH 3COOH  (i) Br2 / P
 ii  NaCN 
(iii) H 2O / H  / 
[X] , [X] will be (B) CH3 – C(OH) C6 H5
CH3  COOH CH3CH  OH C2 H5
(A) (C)
HOOC  CH2  CH2  COOH (D)
CH3COC6 H5
(B)
4. Tests of Acid & its derivatives

Q 1. Which of the following acid gives +ve silver
(C) (D)
mirror test
O
CH3COOH
(A) (B) CH3 – C – COOH
(D) Ph  COOH
Q 12. In the reaction T,
(C) HCOOH
the structure of the Product T is
Q 2. Which of the following acid decolourises
KMnO4
(A)
(A) HCOOH (B) PhCOOH


(C)
CH COOH
3 (D) None of these (C) NaOH / NaI / H
Q 3. Which of the following acid produces poisonous (D) 20% acetic acid
gas on heating ? Q 7. In the following reaction,
 COOH2 RCH 2COOH 
 X Br2 / P Excess NH3
(A) CHOOH (B) Y the

CH  COOH2
major amounts of X and Y are
(A) RCHBrCONH2 ; RCH  NH2  COOH
2
(C) (D) All of these
Q 4. In the reaction
O (B) RCHBrCOOH; RCH2CONH2
C
(C) RCH2 COBr; RCH2 COONH4
O
1. H 1H 2O
(D) RCHBrCOOH; RCH NH2  COOH
2NH3  
C
2. 
O Product, is H 2SO4
O Q 8. Oxalic acid on treatment with conc.
gives
C – NH2
(A) CO only (B)
CO2 only
CO2  H2O H2O  CO  CO2
C – NH2 (C) (D)
(A)
CH3CH2CH2CH2CH2COOH 
O Q 9.
O NH 2
C – OH
CH3 CH2 CH 2CH 2CH – COOH
the reagents used in the conversion are
C – NH2 Br2 /  ii  NH 3  excess 
(A) (i) Red P,
(B) O
PBr3 /  ii  NH 3
O (B) (i)
C
(C) (i) 3  
PBr , NaCN / ii LiAlH 4
NH (D) None of the above

C
Q 10. In the given reaction product ‘X’ is
ClCH2CH2CH2COOH  aq.KOH
(C) O  ‘x’
(D) None of these (A)   butyrolactone
CH3CH2COOH 
Cl2
Red P
  A 
alc. KOH
  B (B)   butyrolactum
Q 5.
(C) crotonic acid
The compound (B) is
CH3 CHCOOH (D)   hydroxybutyric acid
Q 11. Identify A and B in the following reaction
(A) OH
CH2 CH2 COOH
CH3CH3 
B
 CH 3COOH 
A
 CH 3CH 2OH
(B) OH
H2C  CHCOOH A B
(C)
(A) HI  Re d P
ClCH CH COOH
2 2
LiAlH 4
(D)
(B) Ni / 
Q 6. How will you convert butan -2-one to propanoic LiAlH 4
acid ?
(A) Tollen’s reagent Pd  BaSO4 Zn  HCl
(C)
(B) Fehling’s solution
(D)
LiAlH4 HI  Re d P
CH3COOH  CH 2  C  O   X 
Q 12. (X) is most
probably
(A)
CH3CO2 O (B)
CH3COOCH2 CH3
(C)
CH CH COOCH
3 2 3 (D) 2
 COOH (A) II only (B) III only
Q 13. A compound undergoes the following sequence
of reactions : (C) Both (II) and (III) (D) All four
C3H5 N 
 C3H 6O 2 

Hydrolysis Cl2 / P
Q 16. Identify X and Y in the following sequence of
 A reactions respectively :
C3H 5O 2Cl 
NH3
 C3H 7 NO 2 CH3CHO 
HNO3
 X 
P4O10

Y
 B  C
The compound (C) is (A)
C2H5OH and C 2 H 4
(A) 1- nitropropane
(B)
CH2 COOH and  CH3CO2 O
(B) 2-aminopropionic acid
(C) 2-nitropropane (C)
CH3COOH and CH3COOCH3
(D) 2-hydroxypropanamide
C H OH
(D) 2 5 and
CH3COOH
Q 14. On vigorous oxidation by permanganate solution,
CH3 2 C  CH  CH2CH3 gives: Q 17. In the reaction
  A    B

OH OH CH3CH2COONH4 
P2O5 H / H 2O

(A) and (B) are
CH3 – C – CH – CH2CH 3
CH3CH2 CONH2 , CH3 CH2 COO
CH 3 (A)
(A)
H3C CH3CH2 COONH2 ,CH3 CH2 COOH
(B)
CH – COOH + CH3CH 2COOH
(B) H3C CH3CH2 CN, CH3 CH2 CH2 COO
(C)
H3C CH CH CN,CH CH COOH
(D) 3 2 3 2
CH – OH + CH3CH2CH2OH
(C) H3C Q 18. Identify the product ‘Y’ in the following reaction
H3C sequence.
C = O + CH3CH 2COOH CH2 – CH2 – COOH
(D) H3C
CH2 – CH2 – COOH
Zn Hg
Q 15. Which of the following compound(s) will give Ca  
Heat
 'X'  
HCl,heat
 'Y'
HVZ reaction ?
(A) Pentane (B) Cyclobutane
(C) Cyclopentane (D) Cyclopentanone

Answer Key
1. Acid & its Preparation
(1). B (2). C (3). D
(4). C (5). D (6). A
(7). B (8). B (9). A
(10). A (11). D (12). D
(13). B (14). D (15). A
(16). A (17). C (18). B
2. Preparation of Acid Derivatives

(1). B (2). A (3). A
(4). A (5). A (6). B
(7). B (8). D (9). B
(10). D (11). A (12). C
(13). A (14). C (15). C
(16). D
3. Hundsdiecker Reaction, curtius Reaction,

HVZ Reaction, Hoffmann bromamide reaction
(1). B (2). C (3). B
(4). A (5). C (6). C
(7). A (8). D (9). B
(10). C (11). A (12). C
(13). C (14). D (15). B
4. Tests of Acid & its derivatives

(1). C (2). A (3). B
(4). C (5). C (6). D
(7). D (8). D (9). A
(10). A (11). D (12). A
(13). B (14). D (15). D
(16). B (17). D (18). C


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AtoZ CHEMISTRY Carboxylic Acid & its derivatives

Carboxylic Acid & its derivatives

(D) hexane-2,3,5- triol

(A) 2. Preparation of Acid Derivatives

CH 3  CH 2OH (CH 3 )2 CH  OH (CH 3 )3 C  OH

RISHI SIR [B.TECH. IIT KANPUR] www.atozchemistry.com 39

(A) negative charge in can’t be

Peroxyacetic acid  CH3CH3H  is a weaker acid

RISHI SIR [B.TECH. IIT KANPUR] www.atozchemistry.com 40

Q 16. In the given reaction, R  COOH 

(A) R – C – NH – R’ (B) R – C – NH2

3. Hundsdiecker Reaction, curtius Reaction,

4. Tests of Acid & its derivatives

RISHI SIR [B.TECH. IIT KANPUR] www.atozchemistry.com 42

(A) CHOOH (B) Y the

NH (D) None of the above

RISHI SIR [B.TECH. IIT KANPUR] www.atozchemistry.com 44

2. Preparation of Acid Derivatives

3. Hundsdiecker Reaction, curtius Reaction,

4. Tests of Acid & its derivatives

RISHI SIR [B.TECH. IIT KANPUR] www.atozchemistry.com 45

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