Location via proxy:   [ UP ]  
[Report a bug]   [Manage cookies]                
Scribd Logo
Upload

Welcome to Scribd!

  • 106 views

    Exercises 4

    Uploaded by

    Maulida Fajriyah
    The document contains 13 exercises related to gravimetric analysis. The exercises cover topics like equilibrium constants, solubility products, precipitation of ions from solution, and quantitative calculations involving precipitation reactions for analytical determination. The goal of the exercises is to practice quantitative chemical calculations and principles involved in gravimetric analysis.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd

    Exercises 4

    Uploaded by

    Maulida Fajriyah
    106 views2 pages
    The document contains 13 exercises related to gravimetric analysis. The exercises cover topics like equilibrium constants, solubility products, precipitation of ions from solution, and quantitative calculations involving precipitation reactions for analytical determination. The goal of the exercises is to practice quantitative chemical calculations and principles involved in gravimetric analysis.

    Copyright

    © © All Rights Reserved

    Available Formats

    PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    The document contains 13 exercises related to gravimetric analysis. The exercises cover topics like equilibrium constants, solubility products, precipitation of ions from solution, and quantitative calculations involving precipitation reactions for analytical determination. The goal of the exercises is to practice quantitative chemical calculations and principles involved in gravimetric analysis.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    106 views2 pages

    Exercises 4

    Uploaded by

    Maulida Fajriyah
    The document contains 13 exercises related to gravimetric analysis. The exercises cover topics like equilibrium constants, solubility products, precipitation of ions from solution, and quantitative calculations involving precipitation reactions for analytical determination. The goal of the exercises is to practice quantitative chemical calculations and principles involved in gravimetric analysis.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 2

    Exercises for Gravimetric Analysis

    1. When making equilibrium calculations in which the reaction quotient is set equal
    to the equilibrium constant, why must we express solute concentrations in mol/L,
    gas pressures in atmospheres (actually in bars), and omit solids, liquids and
    solvents?

    2. Why is the equilibrium constant for a reaction a dimensionless quantity?

    3. Consider the following equilibria.

    (1) AgCl(s) º Ag+(aq) + Cl-(aq) K = 1.8 x 10-10

    (2) Ag+(aq) + Cl-(aq) º AgCl(aq) K = 2.0 x 103

    a) Calculate the equilibrium constant for the reaction AgCl(s) º AgCl(aq).


    b) Calculate the concentration of AgCl(aq) in equilibrium with excess
    undissolved solid AgCl.

    4. Find the equilibrium concentration of La3+(aq) when excess solid La(IO3)3 is


    stirred with a solution of 0.050 M LiIO3. Ksp = 1.0 x 10-11 for La(IO3)3.

    5. Which salt, MgCO3 (Ksp = 3.5 x 10-8) or CaCO3 (Ksp = 4.5 x 10-9), will be more
    soluble in water? Explain.

    6. Is it possible to precipitate 99.0% of 0.010 M Ce3+ by adding oxalate (C2O42-)


    without precipitating 0.010 M Ca2+?

    CaC2O4 Ksp = 1.3 x 10-8

    Ce2(C2O4)3 Ksp = 3 x 10-29

    7. Why is a high relative supersaturation undesirable in a gravimetric precipitation?

    8. What measures can be taken to decrease the relative supersaturation?


    Exercises for Gravimetric Analysis

    9. Why are ionic precipitates usually washed with an electrolyte solution instead of
    pure water?

    10. Why is it less desirable to wash a AgCl precipitate with NaNO3(aq) than with
    HNO3(aq)?

    11. If Ag+ is added to a solution containing 0.10 M Cl-, Br-, I- and CrO32-, in what order
    will the anions precipitate? Explain.

    AgCl Ksp = 1.8 x 10-10

    AgBr Ksp = 5.0 x 10-13

    AgI Ksp = 8.3 x 10-17

    Ag2CrO4 Ksp = 1.2 x 10-12

    12. Twenty dietary iron tablets with a total mass of 22.131 g were ground and mixed
    thoroughly. Then 2.998 g of the powder were dissolved in HNO3 and heated to
    convert all iron into Fe3+. Addition of NH3 precipitated Fe2O3 A xH2O, which was
    ignited to give 0.264 g Fe2O3 (159.69 g/mol). What is the average mass of
    FeSO4 A 7H2O (278.01 g/mol) in each tablet?

    13. A 0.649-g sample containing only K2SO4 (174.27 g/mol) and (NH4)2SO4 (132.14
    g/mol) was dissolved in water and treated with Ba(NO3)2 to precipitate all sulfate
    as BaSO4 (233.39 g/mol). If 0.977 g of precipitate was formed, what is the mass
    percent K2SO4 in the sample?

    Solutions for Gravimetric Analysis Exercises

    You might also like